Citation: Nagesh K. Tripathi. Porous carbon spheres: Recent developments and applications[J]. AIMS Materials Science, 2018, 5(5): 1016-1052. doi: 10.3934/matersci.2018.5.1016
[1] | David Cruz-Uribe, Michael Penrod, Scott Rodney . Poincaré inequalities and Neumann problems for the variable exponent setting. Mathematics in Engineering, 2022, 4(5): 1-22. doi: 10.3934/mine.2022036 |
[2] | Giovanni Scilla, Bianca Stroffolini . Partial regularity for steady double phase fluids. Mathematics in Engineering, 2023, 5(5): 1-47. doi: 10.3934/mine.2023088 |
[3] | Chiara Gavioli, Pavel Krejčí . Deformable porous media with degenerate hysteresis in gravity field. Mathematics in Engineering, 2025, 7(1): 35-60. doi: 10.3934/mine.2025003 |
[4] | Catharine W. K. Lo, José Francisco Rodrigues . On the obstacle problem in fractional generalised Orlicz spaces. Mathematics in Engineering, 2024, 6(5): 676-704. doi: 10.3934/mine.2024026 |
[5] | Ugo Gianazza, Sandro Salsa . On the Harnack inequality for non-divergence parabolic equations. Mathematics in Engineering, 2021, 3(3): 1-11. doi: 10.3934/mine.2021020 |
[6] | Lucio Boccardo, Giuseppa Rita Cirmi . Regularizing effect in some Mingione’s double phase problems with very singular data. Mathematics in Engineering, 2023, 5(3): 1-15. doi: 10.3934/mine.2023069 |
[7] | Fernando Farroni, Giovanni Scilla, Francesco Solombrino . On some non-local approximation of nonisotropic Griffith-type functionals. Mathematics in Engineering, 2022, 4(4): 1-22. doi: 10.3934/mine.2022031 |
[8] | Dario Bambusi, Beatrice Langella . A C∞ Nekhoroshev theorem. Mathematics in Engineering, 2021, 3(2): 1-17. doi: 10.3934/mine.2021019 |
[9] | Claudia Lederman, Noemi Wolanski . Lipschitz continuity of minimizers in a problem with nonstandard growth. Mathematics in Engineering, 2021, 3(1): 1-39. doi: 10.3934/mine.2021009 |
[10] | Daniela De Silva, Ovidiu Savin . On the boundary Harnack principle in Hölder domains. Mathematics in Engineering, 2022, 4(1): 1-12. doi: 10.3934/mine.2022004 |
Dedicated to Giuseppe Mingione on his 50th anniversary.
Minimizers of the variable exponent energy ∫|∇u|p(x)dx have been studied in hundreds of papers. In almost all cases, it is assumed that there exist constants c,C∈(1,∞) such that c⩽p(x)⩽C for all x. However, it is possible to use limiting procedures to study the borderline cases when p(x)=1 or p(x)=∞ for some points [34,35]. In recent years, minimizers of non-autonomous functionals
infu∫Ωφ(x,|∇u|)dx |
have been studied when φ has generalized Orlicz growth with tentative applications to anisotropic materials [57] and image processing [31]. Again, the upper and lower growth rates are usually assumed to lie in (1,∞). In this article we consider the case when the upper growth rate is allowed to equal ∞ in some points and the lower growth rate is greater than n, the dimension. We prove the Harnack inequality for minimizers of such energies.
Let us recall some information of the context by way of motivation. PDE with generalized Orlicz growth have been studied in many papers lately, both in the general setting and in particular special cases, such as the double phase case (e.g., [3,5,16,17,53]), perturbed variable exponent [52], Orlicz variable exponent [27], degenerate double phase [4], Orlicz double phase [6,10], variable exponent double phase [18,49,50], multiple-phase [7,22], and double variable exponent [56]. Our framework includes all these cases.
In the generalized Orlicz case it is known that solutions with given boundary values exist [15,28,33], minimizers or solutions with given boundary values are locally bounded, satisfy Harnack's inequality and belong to C0,αloc [9,36,37,55] or C1,αloc [38,39], quasiminimizers satisfy a reverse Hölder inequality [32], minimizers for the obstacle problem are continuous [41] and the boundary Harnack inequality holds for harmonic functions [12]. Some articles deal with the non-doubling [13] or parabolic [54] case as well as with the Gauss image problem [44]. We refer to the surveys [11,48] and monographs [14,30,42] for an overview. Advances have also been made in the field of (p,q)-growth problems [19,20,21,45,46,47].
In [8,9], the Harnack inequality was established in the doubling generalized Orlicz case for bounded or general solutions. In the current paper, we consider the effect of removing the assumption that the growth function is doubling thus allowing the upper growth rate to equal ∞. The approach is based on ideas from [35,43] involving approximating the energy functional. This is more difficult compared to the variable exponent case, since the form of the approximating problem is unclear as is the connection between solutions and minimizers. Additionally, the challenge in taking limits without the doubling assumption is to track the dependence of various constants on the parameters and to ensure that no extraneous dependence is introduced in any step. Nevertheless, we improve even the result for the variable exponent case.
Let us consider an example of our main result, Theorem 5.5. In the variable exponent case φ(x,t):=tp(x) we compare with our previous result [35,Theorem 6.4]. In the previous result, we assumed that 1p is Lipschitz continuous, but now we only need the more natural log-Hölder continuity.
Furthermore, the previous result applied only to small balls in which the exponent was (locally) bounded. The next example shows that the new result applies even to some sets where the the exponent is unbounded.
Example 1.1 (Variable exponent). Define p:B1→(n,∞] on the unit ball B1 as p(x):=2nloge|x|. Hence p(0)=∞ but p<∞ a.e. Assume that f∈W1,p(⋅)(B1) with ϱp(⋅)(|∇f|)<∞. If u∈f+W1,p(⋅)0(B1) is a minimizer of the p(⋅)-energy, then the Harnack inequality
supBr(u+r)⩽CinfBr(u+r) |
holds for r⩽14. The constant C depends only on n and ϱp(⋅)(|∇f|). Note that Br we have, in the notation of Theorem 5.5, p−=2nloger and q∘=2nlog2er so that q∘p−=1+log2+log1rlog2+log1r is bounded independent of r.
In the double phase case we also obtain a corollary of Theorem 4.6 which improves earlier results in that the dependence of the constant is only on qp, not p and q. Note that the usual assumption of Hölder continuity of a is a special case of the inequality in the lemma, see [30,Proposition 7.2.2]. Also note that the "+r" in the Harnack inequality is not needed in this case, since the double phase functional satisfies (A1) in the range [0,K|B|] rather than [1,K|B|].
Corollary 1.2 (Double phase). Let Ω⊂Rn be a bounded domain, n<p<q and H(x,t):=tp+a(x)tq. Assume that f∈W1,H(Ω) and
a(x)≲a(y)+|x−y|αwithqp⩽1+αn |
for every x,y∈Ω. Then any minimizer u of the φ-energy with boundary value function f satisfies the Harnack inequality
supBru⩽CinfBru. |
The constant C depends only on n, qp and ϱH(|∇f|).
We briefly introduce our definitions. More information on Lφ-spaces can be found in [30]. We assume that Ω⊂Rn is a bounded domain, n⩾2. Almost increasing means that there exists a constant L⩾1 such that f(s)⩽Lf(t) for all s<t. If there exists a constant C such that f(x)⩽Cg(x) for almost every x, then we write f≲g. If f≲g≲f, then we write f≈g.
Definition 2.1. We say that φ:Ω×[0,∞)→[0,∞] is a weak Φ-function, and write φ∈Φw(Ω), if the following conditions hold for a.e. x∈Ω:
● y↦φ(y,f(y)) is measurable for every measurable function f:Ω→R.
● t↦φ(x,t) is non-decreasing.
● φ(x,0)=limt→0+φ(x,t)=0 and limt→∞φ(x,t)=∞.
● t↦φ(x,t)t is L-almost increasing on (0,∞) with constant L independent of x.
If φ∈Φw(Ω) is additionally convex and left-continuous with respect to t for almost every x, then φ is a convex Φ-function, and we write φ∈Φc(Ω). If φ does not depend on x, then we omit the set and write φ∈Φw or φ∈Φc.
For φ∈Φw(Ω) and A⊂Rn we denote φ+A(t):=esssupx∈A∩Ωφ(x,t) and φ−A(t):=esssupx∈A∩Ωφ(x,t).
We next define the un-weightedness condition (A0), the almost continuity conditions (A1) and the growth conditions (aInc) and (aDec). Note that the constants Lp and Lq are independent of x even though p and q can be functions.
Definition 2.2. Let s>0, p,q:Ω→[0,∞) and let ω:Ω×[0,∞)→[0,∞) be almost increasing with respect to the second variable. We say that φ:Ω×[0,∞)→[0,∞) satisfies
(A0) if there exists β∈(0,1] such that φ(x,β)⩽1⩽φ(x,1β) for a.e. x∈Ω;
(A1- ω) if for every K⩾1 there exists β∈(0,1] such that, for every ball B,
φ+B(βt)⩽φ−B(t)whenω−B(t)∈[1,K|B|]; |
(A1- s) if it satisfies (A1-ω) for ω(x,t):=ts;
(A1) if it satisfies (A1-φ);
(aInc)p(⋅) if t↦φ(x,t)tp(x) is Lp-almost increasing in (0,∞) for some Lp⩾1 and a.e. x∈Ω;
(aDec)q(⋅) if t↦φ(x,t)tq(x) is Lq-almost decreasing in (0,∞) for some Lq⩾1 and a.e. x∈Ω.
We say that (aInc) holds if (aInc)p holds for some constant p>1, and similarly for (aDec). If in the definition of (aInc)p(⋅) we have Lp=1, then we say that φ satisfies (Inc)p(⋅), similarly for (Dec)q(⋅).
Note that if φ satisfies (aInc)p with a constant Lp, then it satisfies (aInc)r for every r∈(0,p) with the same constant Lp. This is seen as follows, with s<t:
φ(x,s)sr=sp−rφ(x,s)sp⩽sp−rLpφ(x,t)tp=Lp(st)p−rφ(x,t)tr⩽Lpφ(x,t)tr. |
Condition (A1) with K=1 was studied in [30] under the name (A1′). The condition (A1-ω) was introduced in [8] to combine (A1) and (A1-n) as well as other cases. It is the appropriate assumption if we have a priori information that the solution is in W1,ω or the corresponding Lebesgue or Hölder space. The most important cases are ω=φ and ω(x,t)=ts, that is (A1) and (A1-s).
Definition 2.3. Let φ∈Φw(Ω) and define the modular ϱφ for u∈L0(Ω), the set of measurable functions in Ω, by
ϱφ(u):=∫Ωφ(x,|u(x)|)dx. |
The generalized Orlicz space, also called Musielak–Orlicz space, is defined as the set
Lφ(Ω):={u∈L0(Ω):limλ→0+ϱφ(λu)=0} |
equipped with the (Luxemburg) quasinorm
‖u‖Lφ(Ω):=inf{λ>0:ϱφ(uλ)⩽1}. |
We abbreviate ‖u‖Lφ(Ω) by ‖u‖φ if the set is clear from context.
Definition 2.4. A function u∈Lφ(Ω) belongs to the Orlicz–Sobolev space W1,φ(Ω) if its weak partial derivatives ∂1u,…,∂nu exist and belong to Lφ(Ω). For u∈W1,φ(Ω), we define the quasinorm
‖u‖W1,φ(Ω):=‖u‖Lφ(Ω)+‖∇u‖Lφ(Ω). |
We define Orlicz–Sobolev space with zero boundary values W1,φ0(Ω) as the closure of {u∈W1,φ(Ω):suppu⊂Ω} in W1,φ(Ω).
In the definition ‖∇u‖Lφ(Ω) is an abbreviation of ‖|∇u|‖Lφ(Ω). Again, we abbreviate ‖u‖W1,φ(Ω) by ‖u‖1,φ if Ω is clear from context. W1,φ0(Ω) is a closed subspace of W1,φ(Ω), and hence reflexive when W1,φ(Ω) is reflexive. We write f+W1,φ0(Ω) to denote the set {f+v:v∈W1,φ0(Ω)}.
Definition 2.5. We say that u∈W1,φloc(Ω) is a local minimizer if
∫supphφ(x,|∇u|)dx⩽∫supphφ(x,|∇(u+h)|)dx |
for every h∈W1,φ(Ω) with supph⋐Ω. We say that u∈W1,φ(Ω) is a minimizer of the φ-energy with boundary values f∈W1,φ(Ω), if u−f∈W1,φ0(Ω), and
∫Ωφ(x,|∇u|)dx⩽∫Ωφ(x,|∇v|)dx |
for every v∈f+W1,φ0(Ω).
Let h∈W1,φ(Ω) have compact support in Ω, f∈W1,φ(Ω) and u∈f+W1,φ0(Ω) is a minimizer of the φ-energy. Then u+h∈f+W1,φ0(Ω) by the definition. By the φ-energy minimizing property,
∫Ωφ(x,|∇u|)dx⩽∫Ωφ(x,|∇(u+h)|)dx; |
the integrals over the set Ω∖supph cancel, and so u is a local minimizer. Hence every minimizer u∈W1,φ(Ω) of the φ-energy with boundary values f is a local minimizer.
We denote by φ∗ the conjugate Φ-function of φ∈Φw(Ω), defined by
φ∗(x,t):=sups⩾0(st−φ(x,s)). |
From this definition, we have Young's inequality st⩽φ(x,s)+φ∗(x,t). Hölder's inequality holds in generalized Orlicz spaces for φ∈Φw(Ω) with constant 2 [30,Lemma 3.2.13]:
∫Ω|u||v|dx⩽2‖u‖φ‖v‖φ∗. |
We next generalize the relation φ∗(φ(t)t)⩽φ(t) which is well-known in the convex case, to weak Φ-functions. The next results are written for φ∈Φw but can be applied to φ∈Φw(Ω) point-wise.
Lemma 3.1. Let φ∈Φw satisfy (aInc)1 with constant L. Then
φ∗(φ(t)Lt)⩽φ(t)L. |
Proof. When s⩽t we use sφ(t)Lt−φ(s)⩽sφ(t)Lt⩽φ(t)L to obtain
φ∗(φ(t)Lt)=sups⩾0(sφ(t)Lt−φ(s))⩽max{φ(t)L,sups>t(sφ(t)Lt−φ(s))}. |
On the other hand, by (aInc)1 we conclude that sφ(t)Lt⩽φ(s) when s>t, so the second term is non-positive and the inequality is established.
If φ∈Φw is differentiable, then
ddtφ(t)tp=φ′(t)tp−ptp−1φ(t)t2p=φ(t)tp+1[tφ′(t)φ(t)−p]. |
Thus φ satisfies (Inc)p if and only if tφ′(t)φ(t)⩾p. Similarly, φ satisfies (Dec)q if and only if tφ′(t)φ(t)⩽q. It also follows that if φ satisfies (Inc)p and (Dec)q, then
1qtφ′(t)⩽φ(t)⩽1ptφ′(t) | (3.2) |
and so φ′ satisfies (aInc)p−1 and (aDec)q−1. We next show that the last claim holds even if only (aInc) or (aDec) is assumed of φ which is convex but not necessarily differentiable.
For φ∈Φc we denote the left and right derivative by φ′− and φ′+, respectively. We define the left derivative to be zero at the origin, i.e., φ′−(0):=0. Assume that φ satisfies (aInc)p with p>1, and let t0>0 be such that φ(t0)<∞. Then
φ′+(0)=limt→0+φ(t)t⩽limt→0+Lptp−1φ(t0)tp0=0. |
Since φ′+ is right-continuous we also obtain that
limt→0+φ′+(t)=φ′+(0)=0. |
Lemma 3.3. Let φ∈Φc satisfy (aInc)p and (aDec)q with constants Lp and Lq, respectively. Then
1(Lqe−1)qtφ′+(t)⩽φ(t)⩽2ln(2Lp)ptφ′−(t) |
for every t⩾0, and φ′− and φ′+ satisfy (aInc)p−1 and (aDec)q−1, with constants depending only on qp, Lp and Lq.
Proof. Since φ is convex we have
φ(t)=∫t0φ′+(τ)dτ=∫t0φ′−(τ)dτ, |
for a proof see e.g., [51,Proposition 1.6.1,p. 37]. Let r∈[0,1). Since the left derivative is increasing, we obtain
φ(t)−φ(rt)=∫trtφ′−(τ)dτ⩽(t−rt)φ′−(t). |
Thus
tφ′−(t)⩾φ(t)−φ(rt)1−r⩾φ(t)1−Lprp1−r |
where in the second inequality we used (aInc)p of φ. Choosing r:=(2Lp)−1/p we get
1−Lprp1−r=1/21−(2Lp)−1/p=p2p(1−(2Lp)−1/p). |
Writing h:=1p and x:=2Lp, we find that
p(1−(2Lp)−1/p)=1−x−hh⩽dxsds|s=0=lnx, |
where the inequality follows from convexity of s↦xs. Thus tφ′−(t)⩾p2ln(2Lp)φ(t).
Let R>1. Since φ′+ is increasing, we obtain
φ(Rt)−φ(t)=∫Rttφ′+(τ)dτ⩾(Rt−t)φ′+(t). |
Thus
tφ′+(t)⩽φ(Rt)−φ(t)R−1⩽φ(t)LqRq−1R−1 |
where (aDec)q of φ was used in the second inequality. With R:=1+1q we get
tφ′+(t)⩽Lq(1+1q)q−11/qφ(t)⩽q(Lqe−1)φ(t). |
We have established the inequality of the claim.
We abbreviate cq:=1Lqe−1 and cp:=2ln(2Lp). Since φ is convex, we have φ′−⩽φ′+ and so
cqqtφ′−(t)⩽cqqtφ′+(t)⩽φ(t)⩽cpptφ′−(t)⩽cpptφ′+(t) |
Thus we obtain by (aDec)q of φ for 0<s<t that
φ′+(t)tq−1⩽qcqφ(t)tq⩽qLqcqφ(s)sq⩽qpLqcpcqφ′+(s)sq−1 |
and (aDec)q−1 of φ′+ follows. The proof for (aInc)p−1 is similar as are the proofs for φ′−.
Before Lemma 3.3 we noted that limt→0+φ′+(x,t)=0, and hence
lim|y|→0φ′+(x,|y|)|y|y⋅z=(lim|y|→0+φ′+(x,|y|))(lim|y|→0+y|y|⋅z)=0 |
for z∈Rn. In light of this, we define
φ′+(x,|∇u|)|∇u|∇u⋅∇h:=0when∇u=0. |
Theorem 3.4. Let φ∈Φc(Ω) satisfy (aInc)p and (aDec)q with 1<p⩽q. Denote φ′h:=φ′+χ{∇u⋅∇h⩾0}+φ′−χ{∇u⋅∇h<0}. If u∈W1,φloc(Ω), then the following are equivalent:
(i) u is a local minimizer;
(ii) ∫supphφ′h(x,|∇u|)|∇u|∇u⋅∇hdx⩾0 for every h∈W1,φ(Ω) with supph⋐Ω.
Proof. Let h∈W1,φ(Ω) with E:=supph⋐Ω be arbitrary. Define g:Ω×[0,1]→[0,∞] by g(x,ε):=|∇(u(x)+εh(x))|; in the rest of the proof we omit the first variable and abbreviate g(x,ε) by g(ε).
Note that g(ε)2=|∇u(x)|2+ε2|h(x)|2+2ε∇u(x)⋅∇h(x) and g⩾0. Thus in [0,1] the function g has a local minimum at zero for x∈Ω with ∇u(x)⋅∇h(x)⩾0 and a maximum otherwise. This determines whether we obtain the right- or left-derivative and so
limε→0+φ(x,g(ε))−φ(x,g(0))ε=φ′h(x,g(0))g′(0)=φ′h(x,|∇u|)|∇u|∇u⋅∇h | (3.5) |
for almost every x∈E.
Let us then find a majorant for the expression on the left-hand side of (3.5). By convexity,
|φ(x,g(ε))−φ(x,g(0))ε|⩽φ′+(x,max{g(ε),g(0)})|g(ε)−g(0)|ε |
for a.e. x∈E. Since ε∈[0,1] we have
max{g(ε),g(0)}⩽max{|∇u|+ε|∇h|,|∇u|}⩽|∇u|+|∇h|. |
By the triangle inequality,
|g(ε)−g(0)ε|=||∇u+ε∇h|−|∇u|ε|⩽|∇h|⩽|∇u|+|∇h|. |
Combining the estimates above, we find that
|φ(x,g(ε))−φ(x,g(0))ε|⩽φ′+(x,|∇u|+|∇h|)(|∇u|+|∇h|). |
By Lemma 3.3, φ′+(x,t)t≲φ(x,t) for every t⩾0, so that
φ′+(x,|∇u|+|∇h|)(∇u|+|∇h|)≲φ(x,|∇u|+|∇h|). |
By (aDec),
φ(x,|∇u|+|∇h|)⩽φ(x,2|∇u|)+φ(x,2|∇h|)⩽Lq2q(φ(x,|∇u|)+φ(x,|∇h|))a.e. |
Combining the estimates, we find that
|φ(x,g(ε))−φ(x,g(0))ε|≲φ(x,|∇u|)+φ(x,|∇h|)a.e. |
The right hand side is integrable by [30,Lemma 3.1.3(b)], since |∇u|,|∇h|∈Lφ(Ω) and φ satisfies (aDec). Thus we have found a majorant. By dominated convergence and (3.5), we find that
∫Eφ′h(x,|∇u|)|∇u|∇u⋅∇hdx=limε→0+∫Eφ(x,g(ε))−φ(x,g(0))εdx. | (3.6) |
Let us first show that (ⅰ) implies (ⅱ). By (ⅰ),
∫Eφ(x,g(ε))−φ(x,g(0))εdx⩾0 |
for ε∈(0,1], and hence (ⅱ) follows by (3.6).
Let us then show that (ⅱ) implies (ⅰ). For θ∈[0,1] and s,t⩾0 we have
g(θt+(1−θ)s)=|θ∇u+θt∇h+(1−θ)∇u+(1−θ)s∇h|⩽|θ∇u+θt∇h|+|(1−θ)∇u+(1−θ)s∇h|=θg(t)+(1−θ)g(s), |
so g(ε) is convex. Since t↦φ(x,t) and g(ε) are convex for almost every x∈E, and t↦φ(x,t) is also increasing, the composed function t↦φ(x,g(t)) is convex for a.e. x∈E. Thus
∫Eφ(x,g(1))−φ(x,g(0))dx⩾∫Eφ(x,g(ε))−φ(x,g(0))εdx. |
Since the above inequality holds for every ε∈(0,1), (3.6) implies that
∫Eφ(x,g(1))−φ(x,g(0))dx⩾∫Eφ′h(x,|∇u|)|∇u|∇u⋅∇hdx⩾0, |
which is (i).
We conclude the section by improving the Caccioppoli inequality from [8]; in this paper we only need the special case ℓ=1 and s=q, but we include the general formulation for possible future use. We denote by η a cut-off function in BR, more precisely, η∈C∞0(BR), χBσR⩽η⩽χBR and |∇η|⩽2(1−σ)R, where σ∈(0,1). Note that the auxiliary function ψ is independent of x in the next lemma. Later on we will choose ψ to be a regularized version of φ+B. Note also that the constant in the lemma is independent of q1.
Lemma 3.7 (Caccioppoli inequality). Suppose φ∈Φc(Ω) satisfies (aInc)p and (aDec)q with constants Lp and Lq, and let ψ∈Φw be differentiable and satisfy (A0), (Inc)p1 and (Dec)q1, p1,q1⩾1. Let β∈(0,1] be the constant from (A0) of ψ. If u is a non-negative local minimizer and η is a cut-off function in BR⊂Ω, then
∫BRφ(x,|∇u|)ψ(u+RβR)−ℓηsdx⩽K∫BRψ(u+RβR)−ℓφ(x,Ku+RβR)ηs−qdx |
for any ℓ>1p1 and s⩾q, where K:=8sq(Lqe−1)Lqln(2Lp)p(p1ℓ−1)(1−σ)+Lp.
Proof. Let us simplify the notation by writing ˜u:=u+R and v:=˜uβR. Since ∇u=∇˜u, we see that ˜u is still a local minimizer. By (A0) of ψ and v⩾1β, we have 0⩽ψ(v)−ℓ⩽1.
We would like to use Theorem 3.4 with h:=ψ(v)−ℓηs˜u. Let us first check that h is a valid test function for a local minimizer, that is h∈W1,φ(BR) and has compact support in BR⊂Ω. As ˜u∈Lφ(BR) and |h|⩽˜u, it is immediate that h∈Lφ(BR). By a direct calculation,
∇h=−ℓψ(v)−ℓ−1ηs˜uψ′(v)∇v+sψ(v)−ℓηs−1˜u∇η+ψ(v)−ℓηs∇˜u. |
Note that ˜u∇v=v∇˜u. Since ψ is differentiable we may use (3.2) to get
|ℓψ(v)−ℓ−1ηsψ′(v)v∇˜u|⩽ℓψ(v)−ℓ−1q1ψ(v)|∇˜u|⩽q1ℓ|∇˜u|∈Lφ(BR). |
For the third term in ∇h, we obtain |ψ(v)−ℓηs∇˜u|⩽|∇˜u|∈Lφ(BR). The term with ∇η is treated as h itself. Thus h∈W1,φ(BR). Since s>0 and η∈C∞0(BR), h has compact support in BR⊂Ω and so it is a valid test-function for a local minimizer.
We next calculate
∇˜u⋅∇h=−ψ(v)−ℓ−1ηs[ℓψ′(v)v−ψ(v)]|∇˜u|2+sψ(v)−ℓηs−1˜u∇˜u⋅∇η. |
The inequality p1ψ(t)⩽ψ′(t)t from (3.2) implies that ℓψ′(v)v−ψ(v)⩾(p1ℓ−1)ψ(v)>0. Since ˜u is a local minimizer, we can use the implication (i)⇒(ii) of Theorem 3.4 to conclude that
[p1ℓ−1]∫BRφ′h(x,|∇˜u|)|∇˜u|ψ(v)−ℓηsdx⩽s∫BRφ′h(x,|∇˜u|)ψ(v)−ℓ˜u|∇η|ηs−1dx. |
Since φ′−⩽φ′h⩽φ′+, we obtain 1q(Lqe−1))tφ′h(x,t)⩽φ(x,t)⩽2ln(2Lp)ptφ′h(x,t) from Lemma 2. Using also |∇η|˜u⩽21−σv, we have
∫BRφ(x,|∇˜u|)ψ(v)−ℓηsdx⩽4sq(Lqe−1)ln(2Lp)p(p1ℓ−1)(1−σ)∫BRφ(x,|∇˜u|)|∇˜u|ηs−1ψ(v)−ℓvdx, |
Note that the constant in front of the integral can be estimated from above by K2Lq.
Next we estimate the integrand on the right hand side. By Young's inequality
φ(x,|∇˜u|)|∇˜u|v⩽φ(x,ε−1q′Lpv)+φ∗(x,ε1q′L−1pφ(x,|∇˜u|)|∇˜u|), |
where 1q+1q′=1. We choose ε:=LpKη(x)∈(0,1] and use (aInc)q' of φ∗ [30,Proposition 2.4.9] (which holds with constant Lq) and Lemma 3.1 to obtain
φ∗(x,ε1q′L−1pφ(x,|∇˜u|)|∇˜u|)⩽Lqεφ∗(x,φ(x,|∇˜u|)Lp|∇˜u|)⩽LqεLpφ(x,|∇u|)=LqKη(x)φ(x,|∇u|). |
In the other term we estimate ε−1q′Lp⩽K1−1q′L1q′pε−1q′=η−1q′K and use (aDec)q of φ:
φ(x,ε−1q′Lpv)⩽Lqη1−qφ(x,Kv). |
With these estimates we obtain that
∫BRφ(x,|∇˜u|)ψ(v)−ℓηsdx⩽12∫BRφ(x,|∇˜u|)ψ(v)−ℓηsdx+K2∫BRψ(v)−ℓφ(x,Kv)ηs−qdx. |
The first term on the right-hand side can be absorbed in the left-hand side. This gives the claim.
The next observation is key to applications with truly non-doubling growth.
Remark 3.8. In the previous proof the assumption (aDec)q is only needed in the set ∇η≠0 since we can improve the estimate on the right-hand side integral to |∇η|˜u⩽21−σvχ{∇η≠0} and only drop the characteristic function in the final step.
The following definition is like [8,Definition 3.1], except φ+Br has replaced φ−Br. Furthermore, we are more precise with our estimates so as to avoid dependence on p and q.
Definition 4.1. Let φ∈Φw(Br) satisfy (aInc)p with p⩾1 and constant Lp. We define ψBr:Br→[0,∞] by setting
ψBr(t):=∫t0τp−1sups∈(0,τ]φ+Br(s)spdτfort⩾0. |
It is easy to see that ψBr∈Φw. Using that φ is increasing for the lower bound and (aInc)p for the upper bound, we find that
ln(2)φ+Br(t2)=∫tt/2τp−1φ+Br(t/2)τpdτ⩽ψBr(t)⩽∫t0tp−1Lpφ+Br(t)tpdτ=Lpφ+Br(t). | (4.2) |
As in [8,Definition 3.1], we see that ψBr is convex and satisfies (Inc)p. If φ satisfies (A0), so does ψBr, since φ+Br≃ψBr. If φ satisfies (aDec)q, then ψBr is strictly increasing and satisfies (aDec)q, and, as a convex function, also (Dec) [30,Lemma 2.2.6].
We note in both the above reasoning and in the next theorem that constants have no direct dependence on p or q, only on Lp, Lq and qp.
Theorem 4.3 (Bloch-type estimate). Let φ∈Φc(Ω) satisfy (A0) and (A1). Let B2r⊂Ω with r⩽1 and φ|B2r satisfy (aInc)p and (aDec)q with p,q∈[n,∞). If u is a non-negative local minimizer, then
∫Br|∇log(u+r)|ndx⩽C, |
where C depends only on n, Lp, Lq, qp, the constants from (A0) and (A1), and ϱφ(|∇u|).
Proof. Let us first note that φ satisfies (aInc)n with the constant Lp. Let β be the smaller of the constants from (A0) and (A1). Denote v:=u+2r2βr and γ:=2Kβ, where K is from Caccioppoli inequality (Lemma 3.7) with ℓ=1, s=q and σ=12. Since p⩾n, we see that
K⩽16q2(Lqe−1)Lqln(2Lp)p(p−1)+Lp⩽16(Lqe−1)Lqln(2Lp)(qp)2nn−1+Lp. |
When |∇u|>γv, we use (aInc)n to deduce that
φ−B2r(γv)vn⩽γnφ(x,γv)(γv)n⩽γnLpφ(x,|∇u|)|∇u|n |
for a.e. x∈Br. Rearranging gives |∇u|nvn≲φ(x,|∇u|)φ−B2r(γv). Since v⩾1β and γ⩾1, we obtain by (A0) that φ−B2r(γv)⩾1. If also φ−B2r(γv)⩽1|B2r|, then φ+B2r(βγv)⩽φ−B2r(γv) by (A1). Otherwise, (φ−B2r(γv))−1⩽|B2r|. In either case,
|∇u|nvn≲φ(x,|∇u|)φ−B2r(γv)≲φ(x,|∇u|)(1φ+B2r(βγv)+|B2r|) |
for a.e. x∈Br. When |∇u|⩽γv, we use the estimate |∇u|nvn⩽γn instead. Since u+r⩾12(u+2r)=βrv, we obtain that
∫Br|∇log(u+r)|ndx=∫Br|∇u|n(u+r)ndx⩽1(βr)n∫Br|∇u|nvndx≲−∫Brφ(x,|∇u|)φ+B2r(βγv)+|B2r|φ(x,|∇u|)+1dx=−∫Brφ(x,|∇u|)φ+B2r(βγv)dx+2nϱφ(|∇u|)+1. |
It remains to bound the integral on the right-hand side.
Let ψB2r be as in Definition 4.1, let η∈C∞0(B2r) be a cut-off function such that η=1 in Br and choose ψ(t):=ψB2r(βγt). Then
−∫Brφ(x,|∇u|)φ+B2r(βγv)dx≲−∫B2rφ(x,|∇u|)φ+B2r(βγv)ηqdx⩽Lp−∫B2rφ(x,|∇u|)ψ(v)ηqdx, |
where the second inequality follows from (4.2). We note that ψ satisfies (A0), (Inc)p and (Dec). Now we use the Caccioppoli inequality (Lemma 3.7) for φ and ψ with ℓ=1, s=q and σ=12 to get
−∫B2rφ(x,|∇u|)ψ(v)ηqdx⩽K−∫B2rφ(x,Kv)ψ(v)dx⩽ln(2)K; |
the last inequality holds by (4.2) and γ=2Kβ since
φ(x,Kv)ψ(v)=φ(x,Kv)ψB2r(βγv)⩽ln(2)φ(x,Kv)φ+B2r(12βγv)⩽ln(2). |
We next show that the Bloch estimate implies a Harnack inequality for suitable monotone functions. We say that a continuous function u is monotone in the sense of Lebesgue, if it attains its extrema on the boundary of any compact set in its domain of definition. We say that φ∈Φw(Ω) is positive if φ(x,t)>0 for every t>0 and a.e. x∈Ω. If φ satisfies (aDec)q(⋅) for q<∞ a.e., then it is positive.
Lemma 4.4. If φ∈Φw(Ω) is positive, then every continuous local minimizer is monotone in the sense of Lebesgue.
Proof. Let u∈W1,φloc(Ω)∩C(Ω) be a local minimizer and D⋐Ω. Fix M>max∂Du and note that (u−M)+ is zero in some neighborhood of ∂D since u is continuous. Thus h:=(u−M)+χD belongs to W1,φ(Ω)∩C(Ω) and has compact support in Ω. Using that u is a local minimizer, we obtain that
∫supphφ(x,|∇u|)dx⩽∫supphφ(x,|∇(u−h)|)dx=0. |
Since φ(x,t)>0 for every t>0 and a.e. x∈Ω, it follows that ∇u=0 a.e. in supph. Thus ∇h=0 a.e. in Ω. Since h is continuous and equals 0 in Ω∖D, we conclude that h≡0.
Hence u⩽M in D. Letting M→max∂Du, we find that u⩽max∂Du. The proof that min∂Du⩽u in D is similar.
For x∈Ω we write rx:=12dist(x,∂Ω). Let 1⩽p<∞. In [43,Definition 3.6] a function u:Ω→R is called a Bloch function if
supx∈Ωrpx−∫Brx|∇u|pdx<∞. |
Note that if u is an analytic function in the plane and p=2, then by the mean value property
supx∈Ωrx(−∫Brx|u′|2dx)12≈supx∈Ωd(x,∂Ω)|u′(x)|≈supx∈Ω(1−|x|2)|u′(x)|, |
which connects this with Bloch functions in complex analysis. In the next theorem we assume for logu a Bloch-type condition. In the case p=n the next result was stated in [35,Lemma 6.3].
Lemma 4.5. Let u:Ω→(0,∞) be continuous and monotone in the sense of Lebesgue. If B4r⋐Ω, and
rp−∫B2r|∇logu|pdx⩽A |
for p>n−1, then
supBru⩽CinfBru |
for some C depending only on A, p and n.
Proof. Denote v:=logu. Since the logarithm is increasing, v is monotone in the sense of Lebesgue because u is.
As u is continuous and positive in ¯B3r⊂Ω, it is bounded away from 0. Thus v∈W1,p(B2r) is uniformly continuous in B3r. Mollification gives a sequence (vi)∞i=0 of functions in C∞(B2r)∩W1,p(B2r), such that v is the limit of vi in W1,p(B2r) and vi→v pointwise uniformly in B2r, as i→∞ [25,Theorem 4.1 (ii),p. 146]. By the Sobolev–Poincaré embedding W1,p(∂BR)→C0,1−n−1p(∂BR),
(osc∂BRvi)p≲Rp−n+1∫∂BR|∇vi|pdS |
for every R∈(0,2r), where dS denotes the (n−1)-dimensional Hausdorff measure and the constant depends only on p and n (see, e.g., [26,Lemma 1], stated for the case n=p=3). Integrating with respect to R gives
∫2rr(osc∂BRvi)pdR≲∫2rrRp−n+1∫∂BR|∇vi|pdSdR≲rp−n+1∫B2r|∇vi|pdx. |
Since vi→v uniformly, we obtain that (osc∂BRv)p=limi→∞(osc∂BRvi)p for every R. Using this and vi→v in W1,p(B2r), it follows by Fatou's Lemma that
∫2rr(osc∂BRv)pdR⩽lim infi→∞∫2rr(osc∂BRvi)pdR⩽lim infi→∞Crp−n+1∫B2r|∇vi|pdx=Crp−n+1∫B2r|∇v|pdx. |
As v is continuous and monotone in the sense of Lebesgue, we have that oscBrv⩽oscBRv=osc∂BRv for R∈(r,2r), and therefore
r(oscBrv)p⩽∫2rr(osc∂BRv)pdR⩽Crp−n+1∫B2r|∇v|pdx⩽CrA. |
Since
oscBrv=supx,y∈Br|v(x)−v(y)|=supx,y∈Br|logu(x)u(y)|=logsupBruinfBru, |
it now follows that
supBru⩽exp((CA)1/p)infBru. |
We conclude this section with the Harnack inequality for local minimizers. The novelty of the next theorem, apart from the technique, is that the constant depends only on qp, not on p and q separately.
Theorem 4.6 (Harnack inequality). Let φ∈Φc(Ω) satisfy (A0) and (A1). We assume that B2r⊂Ω with r⩽1 and φ|B2r satisfies (aInc)p and (aDec)q with p,q∈(n,∞).
Then any non-negative local minimizer u∈W1,φloc(Ω) satisfies the Harnack inequality
supBr(u+r)⩽CinfBr(u+r) |
when B4r⊂Ω. The constant C depends only on n, β, Lp, Lq, qp and ϱφ(|∇u|).
Proof. Let u∈W1,φloc(Ω) be a non-negative local minimizer. By Theorem 4.3,
∫Br|∇log(u+r)|ndx⩽C, |
where C depends only on n, Lp, Lq, qp, the constants from (A0) and (A1), and ϱφ(|∇u|). Since p>n, φ satisfies (aInc)p and u∈W1,φloc(Ω), u is continuous and Lemma 4.4 yields that u+r is monotone in the sense of Lebesgue. Thus we can apply Lemma 4.5 to u+r, which gives the Harnack inequality.
Let us study minimizers with given boundary values.
Definition 5.1. Let p∈[1,∞), φ∈Φc(Ω) and define, for λ⩾1,
φλ(x,t):=∫t0pλτp−1+min{φ′−(x,τ),pλτp−1}dτ=1λtp+∫t0min{φ′−(x,τ),pλτp−1}dτ. |
Note that since t↦φλ(x,t) is convex for a.e. x∈Ω, the left derivative φ′− exists for a.e. x∈Ω, and therefore the above definition makes sense.
Lemma 5.2. If φ∈Φc(Ω), then φλ∈Φc(Ω) satisfies φλ(⋅,t)≈tp with constants depending on λ. Furthermore,
min{φ(x,t2),λ(t2)p}+1λtp⩽φλ(x,t)⩽φ(x,t)+1λtp |
for λ⩾1, φλ(x,t)⩽φΛ(x,t)+1λtp for any Λ⩾λ⩾1, and φλ→φ as λ→∞.
Proof. It follows from the definition that pλτp−1⩽φ′λ(x,τ)⩽p(1λ+λ)τp−1. Integrating over τ∈[0,t] gives φλ(⋅,t)≈tp. Let Λ⩾λ⩾1. Since the minimum in the integrand is increasing in λ, we see that
φλ(x,t)⩽φΛ(x,t)+(1λ−1Λ)tp⩽φ(x,t)+1λtp, |
and thus lim supλ→∞φλ⩽φ. On the other hand, Fatou's Lemma gives
φ(x,t)=∫t0limλ→∞(pλτp−1+min{φ′−(x,τ),pλτp−1})dτ⩽lim infλ→∞∫t0pλτp−1+min{φ′−(x,τ),pλτp−1}dτ=lim infλ→∞φλ(x,t). |
One of the terms in the minimum min{φ′−(x,τ),pλτp−1} is achieved in at least a set of measure t2. Since both terms are increasing in τ, this implies that
φλ(x,t)⩾min{∫t/20φ′−(x,τ)dτ,∫t/20pλτp−1dτ}+1λtp=min{φ(x,t2),λ(t2)p}+1λtp. |
Since φλ(x,t)≈tp, it follows by [30,Proposition 3.2.4] that W1,φλ(Ω)=W1,p(Ω) and the norms ‖⋅‖φλ and ‖⋅‖p are comparable. However, the embedding constant blows up as λ→∞ unless φ also satisfies (aDec)p. This approximation approach is similar to that in [24]. Note in the next results that f is bounded by the Sobolev embedding in W1,p(Ω).
Lemma 5.3. Let q:Ω→(n,∞), and let φ∈Φc(Ω) satisfy (A0), (aInc)p and (aDec)q(⋅), p>n. Assume that f∈W1,φ(Ω) with ϱφ(∇f)<∞. Then there exists a sequence (uλk) of Dirichlet φλk-energy minimizers with the boundary value function f and a minimizer of the φ-energy u∞∈f+W1,φ0(Ω) such that uλk→u∞ uniformly in Ω as λk→∞.
Proof. Note that we use W1,φλ(Ω)=W1,p(Ω) and W1,φλ0(Ω)=W1,p0(Ω) several times in this proof. Let λ⩾p. Note that f∈W1,p(Ω) since tp≲φ(x,t)+1 by (A0) and (aInc)p. By [29,Theorem 6.2] there exists a minimizer uλ∈f+W1,p0(Ω) of
∫Ωφλ(x,|∇u|)dx. |
Fix λ⩾1. By Lemma 5.2 and tp≲φ(x,t)+1, we have tp≲min{φ(x,t2),λtp}+1≲φλ(x,t)+1. Also by the same lemma, φλ≲φ+1λtp≲φ+1. Since f is a valid test-function and uλ is a φλ-minimizer, we have
∫Ω|∇uλ|pdx≲∫Ωφλ(x,|∇uλ|)+1dx⩽∫Ωφλ(x,|∇f|)+1dx≲∫Ωφ(x,|∇f|)+1dx<∞, |
and hence {\varrho}_p(\nabla u_\lambda) is uniformly bounded. Note that the implicit constants do not depend on \lambda .
Since u_\lambda-f\in W^{1, p}_0(\Omega) , the Poincaré inequality implies that
\|u_\lambda-f\|_p \lesssim \|\nabla (u_\lambda-f)\|_{p} \lesssim \|\nabla u_\lambda\|_p +\|\nabla f\|_p {\leqslant} c. |
Therefore, \|u_\lambda\|_p {\leqslant} \|u_\lambda-f\|_p + \|f\|_p {\leqslant} c and so \|u_\lambda\|_{1, p} is uniformly bounded. Since f + W_0^{1, p}(\Omega) is a closed subspace of W^{1, p}(\Omega) , it is a reflexive Banach space. Thus there exists a sequence (\lambda_k)_{k = 1}^\infty tending to infinity and a function u_\infty \in f + W_0^{1, p}(\Omega) such that u_{\lambda_k}\rightharpoonup u_\infty in W^{1, p}(\Omega) . Since p > n , the weak convergence u_{\lambda_k}-f\rightharpoonup u_\infty-f in W^{1, p}_0(\Omega) and compactness of the Sobolev embedding [1,Theorem 6.3 (Part IV),p. 168] imply that u_{\lambda_k}-f \to u_\infty-f in the supremum norm. Hence u_{\lambda_k} \to u uniformly in \Omega .
We note that the modular {\varrho}_{{\varphi}_\lambda} satisfies the conditions of [23,Definition 2.1.1]. Hence, it is weakly lower semicontinuous by [23,Theorem 2.2.8], and we obtain that
\begin{equation} \begin{split} \int_\Omega{\varphi}_\lambda(x,|\nabla u_\infty|)\,dx &{\leqslant} \liminf\limits_{k\to\infty} \int_\Omega{\varphi}_\lambda(x,|\nabla u_{\lambda_k}|)\,dx {\leqslant} \liminf\limits_{k\to\infty} \int_\Omega (1+\tfrac C{\lambda_k}){\varphi}_{\lambda_k}(x,|\nabla u_{\lambda_k}|) + \tfrac C{\lambda_k}\,dx\\ &{\leqslant} \liminf\limits_{k\to\infty} \int_\Omega{\varphi}_{\lambda_k}(x,|\nabla u_{\lambda_k}|) \,dx \lesssim \int_\Omega {\varphi}(x,|\nabla f|)+1\,dx \end{split} \end{equation} | (5.4) |
for fixed \lambda{\geqslant} 1 , where in the second inequality we used Lemma 5.2 and the fact that t^p \lesssim {\varphi}_\lambda(x, t) +1 . It follows by monotone convergence that
\int_\Omega{\varphi}(x,|\nabla u_\infty|)\,dx = \lim\limits_{\lambda\to\infty} \int_\Omega \min\{{\varphi}(x,|\nabla u_\infty|), \lambda |\nabla u_\infty|^p\}\,dx {\leqslant} \limsup\limits_{\lambda\to\infty}\int_\Omega {\varphi}_\lambda(x,|\nabla u_\infty|)\,dx, |
and hence |\nabla u_\infty| \in L^{\varphi}(\Omega) . Since p > n , \Omega is bounded and u_\infty -f \in W^{1, p}_0(\Omega) , we obtain by [58,Theorem 2.4.1,p. 56] that u_\infty - f\in L^\infty(\Omega) . Moreover, L^\infty(\Omega)\subset L^{\varphi}(\Omega) since \Omega is bounded and {\varphi} satisfies {\rm{(A0)}}. These and f\in L^{\varphi}(\Omega) yield that u_\infty \in L^{{\varphi}}(\Omega) . Hence we have u_\infty \in W^{1, {\varphi}}(\Omega) . Since u_\infty -f \in W^{1, p}_0(\Omega) and p > n , it follows that u_\infty-f can be continuously extended by 0 in \Omega^c [2,Theorem 9.1.3]. Then we conclude as in [40,Lemma 1.26] that u_\infty-f\in W^{1, {\varphi}}_0(\Omega) .
We conclude by showing that u_\infty is a minimizer. Suppose to the contrary that there exists u\in f+W^{1, {\varphi}}_0(\Omega) with
\int_\Omega{\varphi}(x,|\nabla u_\infty|)\,dx - \int_\Omega{\varphi}(x,|\nabla u|)\,dx = : \varepsilon > 0. |
By {\varphi}_\lambda\lesssim {\varphi}+1 , {\varphi}_\lambda\to{\varphi} and dominated convergence, there exists \lambda_0 such that
\int_\Omega{\varphi}_\lambda(x,|\nabla u_\infty|)\,dx - \int_\Omega{\varphi}_\lambda(x,|\nabla u|)\,dx {\geqslant}\tfrac \varepsilon2 |
for all \lambda{\geqslant} \lambda_0 . From the lower-semicontinuity estimate (5.4) we obtain k_0 such that
\int_\Omega{\varphi}_\lambda(x,|\nabla u_\infty|)\,dx {\leqslant} \int_\Omega{\varphi}_{\lambda_k}(x,|\nabla u_{\lambda_k}|)\,dx + \tfrac \varepsilon4 |
for all k{\geqslant} k_0 . By increasing k_0 if necessary, we may assume that \lambda_k{\geqslant} \lambda_0 when k{\geqslant} k_0 . For such k we choose \lambda = \lambda_k above and obtain that
\int_\Omega{\varphi}_{\lambda_k}(x,|\nabla u|) + \tfrac \varepsilon2 {\leqslant} \int_\Omega{\varphi}_{\lambda_k}(x,|\nabla u_{\lambda_k}|)\,dx + \tfrac \varepsilon4. |
This contradicts u_{\lambda_k} being a {\varphi}_{\lambda_k} -minimizer, since u \in f + W^{1, {\varphi}}_0(\Omega) \subset f + W^{1, {\varphi}_{\lambda_k}}_0(\Omega) . Hence the counter-assumption was incorrect, and the minimization property of u_\infty is proved.
We conclude this paper with the Harnack inequality for {\varphi} -harmonic functions. Here we use Remark 3.8 to handle the possibility that q could be unbounded and thus {\varphi} non-doubling, like in Example 1.1. This is possible since q^\circ is the supremum of q only in the annulus, not the whole ball.
Theorem 5.5 (Harnack inequality). Let p, q : \Omega \to (n, \infty) , and {\varphi} \in \Phi_{\mathit{\rm{c}}}(\Omega) be strictly convex and satisfy {\rm{(A0)}}, (A1), {({\rm{aInc}})_{p(\cdot)}} and {\left( {{\rm{aDec}}} \right)_{q(\cdot)}} with \inf p > n . Assume that f\in W^{1, {\varphi}}(\Omega) with {\varrho}_{\varphi}(|\nabla f|) < \infty . Then there exists a unique minimizer u of the {\varphi} -energy with boundary values f . Let B_{4r}\subset \Omega , p^-: = \inf\limits_{B_{2r}} p and q^\circ: = \sup\limits_{B_{2r}\setminus B_r} q . If \frac{q^\circ}{p^-} < \infty , then the Harnack inequality
\sup\limits_{B_r}(u+r) {\leqslant} C\inf\limits_{B_r} (u+r) |
holds for all non-negative minimizers with C depending only on n , \beta , L_p , L_q , \frac{q^\circ}{p^-} and {\varrho}_{\varphi}(|\nabla f|) .
Proof. By Lemma 5.3, there exists a sequence (u_k)\subset f+W^{1, p}_0(\Omega) of minimizers of the {\varphi}_{\lambda_k} energy which converge uniformly to a minimizer u_\infty\in f+W^{1, {\varphi}}_0(\Omega) of the {\varphi} -energy. Since {\varphi} is strictly convex, the minimizer is unique and so u = u_\infty .
From {\rm{(A0)}} and {\left( {{\rm{aInc}}} \right)_{{p^ - }}} we conclude that t^{p^-}\lesssim{\varphi}(x, t)+1 . It follows from Lemma 5.2 that {\varphi}_\lambda(\cdot, t)\simeq {\varphi}(\cdot, t)+\frac1\lambda t^{p^-} . Thus {\varphi}_\lambda satisfies {\rm{(A0)}} and {\rm{(A1)}} with the same constants as {\varphi} . Since u_k\to u in L^\infty(\Omega) and u is non-negative we can choose a sequence \varepsilon_k\to 0^+ such that u_k+ \varepsilon_k is non-negative. By Theorem 4.1 with Remark 3.8,
\int_{B_r} |\nabla\log(u_k+ \varepsilon_k+r)|^n \,dx {\leqslant} C, |
where C depends only on n , L_p , L_q , \frac{q^\circ}{p^-} , \beta from {\rm{(A0)}} and (A1), and {\varrho}_{{\varphi}_{\lambda_k}}(|\nabla u_k|) . Since u_k is a minimizer, {\varrho}_{{\varphi}_{\lambda_k}}(|\nabla u_k|){\leqslant} {\varrho}_{{\varphi}_{\lambda_k}}(|\nabla f|)\lesssim {\varrho}_{\varphi}(|\nabla f|)+1 . Thus by Lemma 4.5, we have
\sup\limits_{B_r}(u_k+ \varepsilon_k+r) {\leqslant} C\inf\limits_{B_r} (u_k+ \varepsilon_k+r), |
with C independent of k . Since u_k+ \varepsilon_k\to u_\infty uniformly, the claim follows.
Peter Hästö was supported in part by the Jenny and Antti Wihuri Foundation.
The authors declare no conflict of interest.
[1] |
Manocha SM (2003) Porous carbons. Sadhana 28: 335–348. doi: 10.1007/BF02717142
![]() |
[2] |
Singh A, Lal D (2010) Preparation and characterization of activated carbon spheres from polystyrene sulphonate beads by steam and carbon dioxide activation. J Appl Polym Sci 115: 2409–2415. doi: 10.1002/app.31340
![]() |
[3] | Cukierman AL (2013) Development and environmental applications of activated carbon cloths. ISRN Chem Eng 2013: 1–31. |
[4] | Tripathi NK, Singh VV, Sathe M, et al. (2018) Activated carbon fabric: An adsorbent material for chemical protective clothing. Defence Sci J 68: 83–90. |
[5] |
Khan MK, Maclachlan MJ (2015) Polymer and carbon spheres with an embedded shell of plasmonic gold nanoparticles. ACS Macro Lett 4: 1351–1355. doi: 10.1021/acsmacrolett.5b00742
![]() |
[6] |
Baghel A, Singh B, Prasad GK, et al. (2011) Preparation and characterization of active carbon spheres prepared by chemical activation. Carbon 49: 4739–4744. doi: 10.1016/j.carbon.2011.06.080
![]() |
[7] |
Romero-Anaya AJ, Ouzzine M, Lillo-Ródenas MA, et al. (2014) Spherical carbons: Synthesis, characterization and activation processes. Carbon 68: 296–307. doi: 10.1016/j.carbon.2013.11.006
![]() |
[8] | Tripathi NK, Sathe M (2017) Pilot scale production of activated carbon spheres using fluidized bed reactor and its evaluation for the removal of hexavalent chromium from aqueous solutions. J Inst Eng India Ser E 98: 141–147. |
[9] |
Amorós-Pérez A, Cano-Casanova L, Ouzzine M, et al. (2018) Spherical activated carbons with high mechanical strength directly prepared from selected spherical seeds. Materials 11: 770. doi: 10.3390/ma11050770
![]() |
[10] |
Singh A, Lal D (2008) Microporous activated carbon spheres prepared from resole-type crosslinked phenolic beads by physical activation. J Appl Polym Sci 110: 3283–3291. doi: 10.1002/app.28846
![]() |
[11] |
Wickramaratne NP, Jaroniec M (2013) Activated carbon spheres for CO2 adsorption. ACS Appl Mater Inter 5: 1849–1855. doi: 10.1021/am400112m
![]() |
[12] |
Klefer H, Munoz M, Modrow A, et al. (2016) Polymer-based spherical activated carbon as easy-to-handle catalyst support for hydrogenation reactions. Chem Eng Technol 39: 276–284. doi: 10.1002/ceat.201500445
![]() |
[13] |
Boopathi M, Singh B, Vijayaraghavan R (2008) A review on NBC body protective clothing. Open Text J 1: 1–8. doi: 10.2174/1876520300801010001
![]() |
[14] |
Yenisoy-Karakaş S, Aygün A, Güneş M, et al. (2004) Physical and chemical characteristics of polymer-based spherical activated carbon and its ability to adsorb organics. Carbon 42: 477–484. doi: 10.1016/j.carbon.2003.11.019
![]() |
[15] | Lee T, Ooi CH, Othman R, et al. (2014) Activated carbon fiber-the hybrid of carbon fiber and activated carbon. Rev Adv Mater Sci 36: 118–136. |
[16] |
Liu Z, Ling L, Qiao W, et al. (1999) Preparation of pitch-based spherical activated carbon with developed mesopore by the aid of ferrocene. Carbon 37: 663–667. doi: 10.1016/S0008-6223(98)00242-5
![]() |
[17] |
Mao H, Chen X, Huang R, et al. (2018) Fast preparation of carbon spheres from enzymatic hydrolysis lignin: Effects of hydrothermal carbonization conditions. Sci Rep 8: 9501. doi: 10.1038/s41598-018-27777-4
![]() |
[18] |
Nakagawa K, Mukai SR, Tamura K, et al. (2007) Mesoporous activated carbons from phenolic resins. Chem Eng Res Des 85: 1331–1337. doi: 10.1205/cherd06119
![]() |
[19] |
Singh A, Lal D (2006) Effect of reaction parameters on the particle sizes of crosslinked spherical phenolic beads by suspension polymerization of phenol and formaldehyde. J Appl Polym Sci 100: 2323–2330. doi: 10.1002/app.22995
![]() |
[20] |
Singh A, Yadav RK, Srivastava A (2009) Synthesis of resole-type phenolic beads from phenol and formaldehyde by suspension polymerization technique. J Appl Polym Sci 112: 1005–1011. doi: 10.1002/app.29480
![]() |
[21] |
Li R, Wang L, Shahbazi A (2015) A review of hydrothermal carbonization of carbohydrates for carbon spheres preparation. Trends Renew Energ 1: 43–56. doi: 10.17737/tre.2015.1.1.009
![]() |
[22] |
Liu J, Wickramaratne NP, Qiao SZ, et al. (2015) Molecular-based design and emerging applications of nanoporous carbon spheres. Nat Mater 14: 763–774. doi: 10.1038/nmat4317
![]() |
[23] |
Li S, Pasc A, Fierro V, et al. (2016) Hollow carbon spheres, synthesis and applications-a review. J Mater Chem A 4: 12686–12713. doi: 10.1039/C6TA03802F
![]() |
[24] |
Roberts AD, Li X, Zhang H (2014) Porous carbon spheres and monoliths: Morphology control, pore size tuning and their applications as Li-ion battery anode materials. Chem Soc Rev 43: 4341–4356. doi: 10.1039/C4CS00071D
![]() |
[25] |
Zhang P, Qiao ZA, Dai S (2015) Recent advances in carbon nanospheres: Synthetic routes and applications. Chem Commun 51: 9246–9256. doi: 10.1039/C5CC01759A
![]() |
[26] |
González-García P (2018) Activated carbon from lignocellulosics precursors: A review of the synthesis methods, characterization techniques and applications. Renew Sust Energ Rev 82: 1393–1414. doi: 10.1016/j.rser.2017.04.117
![]() |
[27] |
Moreno-Castilla C (2016) Colloidal and micro-carbon spheres derived from low-temperature polymerization reactions. Adv Colloid Interfac 236: 113–141. doi: 10.1016/j.cis.2016.08.003
![]() |
[28] |
Hong M, Chen J, Zhang M, et al. (2016) High-frequency fabrication of discrete and dispersible hollow carbon spheres with hierarchical porous shells by using secondary-crosslinking pyrolysis. RSC Adv 6: 16141–16149. doi: 10.1039/C5RA25932K
![]() |
[29] |
Wu Q, Li W, Tan J, et al. (2015) Hydrothermal synthesis of magnetic mesoporous carbon microspheres from carboxymethylcellulose and nickel acetate. Appl Surf Sci 332: 354–361. doi: 10.1016/j.apsusc.2015.01.195
![]() |
[30] |
Ma X, Gan L, Liu M, et al. (2014) Mesoporous size controllable carbon microspheres and their electrochemical performances for supercapacitor electrodes. J Mater Chem A 2: 8407–8415. doi: 10.1039/C4TA00333K
![]() |
[31] |
Ge H, Xu H, Lu T, et al. (2016) Microfluidic production of porous carbon spheres with tunable size and pores. J Colloid Interf Sci 461: 168–172. doi: 10.1016/j.jcis.2015.09.018
![]() |
[32] |
Huang X, Zhou LJ, Voiry D, et al. (2016) Monodisperse mesoporous carbon nanoparticles from polymer/silica self-aggregates and their electrocatalytic activities. ACS Appl Mater Inter 8: 18891–18903. doi: 10.1021/acsami.6b05739
![]() |
[33] |
Mhamane D, Kim MS, Park BH, et al. (2018) Orderly meso-perforated spherical and apple-shaped 3D carbon microstructures for high-energy supercapacitors and high-capacity Li-ion battery anodes. J Mater Chem A 6: 6422–6434. doi: 10.1039/C7TA11360A
![]() |
[34] |
Pol VG, Shrestha LK, Ariga K (2014) Tunable, functional carbon spheres derived from rapid synthesis of resorcinol-formaldehyde resins. ACS Appl Mater Inter 6: 10649–10655. doi: 10.1021/am502324m
![]() |
[35] |
Zhu D, Wang Y, Gan L, et al. (2015) Nitrogen-containing carbon microspheres for supercapacitor electrodes. Electrochim Acta 158: 166–174. doi: 10.1016/j.electacta.2015.01.155
![]() |
[36] |
Lu W, Liu M, Miao L, et al. (2016) Nitrogen-containing ultramicroporous carbon nanospheres for high performance supercapacitor electrodes. Electrochim Acta 205: 132–141. doi: 10.1016/j.electacta.2016.04.114
![]() |
[37] |
Anceschi A, Magnacca G, Trotta F, et al. (2017) Preparation and characterization of microporous carbon spheres from high amylose pea maltodextrin. RSC Adv 7: 36117–36123. doi: 10.1039/C7RA05343F
![]() |
[38] |
Tian H, Liu J, O'Donnell K, et al. (2016) Revisiting the Stӧber method: Design of nitrogen-doped porous carbon spheres from molecular precursors of different chemical structures. J Colloid Interf Sci 476: 55–61. doi: 10.1016/j.jcis.2016.05.008
![]() |
[39] |
Böhringer B, Guerra Gonzalez O, Eckle I, et al. (2011) Polymer-based spherical activated carbons-From adsorptive properties to filter performance. Chem Ing Tech 83: 53–60. doi: 10.1002/cite.201000166
![]() |
[40] |
Sun N, Sun C, Liu H, et al. (2013) Synthesis, characterization and evaluation of activated spherical carbon materials for CO2 capture. Fuel 113: 854–862. doi: 10.1016/j.fuel.2013.03.047
![]() |
[41] |
Zhang C, Hatzell KB, Boota M, et al. (2014) Highly porous carbon spheres for electrochemical capacitors and capacitive flowable suspension electrodes. Carbon 77: 155–164. doi: 10.1016/j.carbon.2014.05.017
![]() |
[42] |
Yu Q, Guan D, Zhuang Z, et al. (2017) Mass production of monodisperse carbon microspheres with size-dependent supercapacitor performance via aqueous self-catalyzed polymerization. ChemPlusChem 82: 872–878. doi: 10.1002/cplu.201700182
![]() |
[43] |
Huang YP, Hsi HC, Liu SC (2013) Preparation of spherical activated phenol-formaldehyde beads from bamboo tar for adsorption of toluene. J Air Waste Manage 63: 977–983. doi: 10.1080/10962247.2013.804011
![]() |
[44] |
Zhang C, Song W, Sun G, et al. (2014) Synthesis, characterization, and evaluation of activated carbon spheres for removal of dibenzothiophene from model diesel fuel. Ind Eng Chem Res 53: 4271–4276. doi: 10.1021/ie403773f
![]() |
[45] |
Zhang C, Song W, Zhang X, et al. (2018) Synthesis, characterization and evaluation of resin-based carbon spheres modified by oxygen functional groups for gaseous elemental mercury capture. J Mater Sci 53: 9429–9448. doi: 10.1007/s10853-018-2231-6
![]() |
[46] | Zhang C, Song W, Zhang X, et al. (2018) Synthesis and evaluation of activated carbon spheres with copper modification for gaseous elemental mercury removal. J Porous Mat 2018: 1–11. |
[47] |
Mestre AS, Tyszko E, Andrade MA, et al. (2015) Sustainable activated carbons prepared from a sucrose-derived hydrochar: Remarkable adsorbents for pharmaceutical compounds. RSC Adv 5: 19696–19707. doi: 10.1039/C4RA14495C
![]() |
[48] |
Romero-Anaya AJ, Lillo-Ródenas MA, Linares-Solano A (2014) Activation of a spherical carbon for toluene adsorption at low concentration. Carbon 77: 616–626. doi: 10.1016/j.carbon.2014.05.066
![]() |
[49] |
Liu J, Sun N, Sun C, et al. (2015) Spherical potassium intercalated activated carbon beads for pulverised fuel CO2 post-combustion capture. Carbon 94: 243–255. doi: 10.1016/j.carbon.2015.06.036
![]() |
[50] |
Wang Q, Liang X, Qiao W, et al. (2009) Preparation of polystyrene-based activated carbon spheres with high surface area and their adsorption to dibenzothiophene. Fuel Process Technol 90: 381–387. doi: 10.1016/j.fuproc.2008.10.008
![]() |
[51] |
Wang Q, Liang X, Zhang R, et al. (2009) Preparation of polystyrene-based activated carbon spheres and their adsorption of dibenzothiophene. New Carbon Mater 24: 55–60. doi: 10.1016/S1872-5805(08)60036-0
![]() |
[52] |
Yang JB, Ling LC, Liu L, et al. (2002) Preparation and properties of phenolic resin-based activated carbon spheres with controlled pore size distribution. Carbon 40: 911–916. doi: 10.1016/S0008-6223(01)00222-6
![]() |
[53] |
Menya E, Olupot PW, Storz H, et al. (2018) Production and performance of activated carbon from rice husks for removal of natural organic matter from water: A review. Chem Eng Res Des 129: 271–296. doi: 10.1016/j.cherd.2017.11.008
![]() |
[54] |
Shi Y, Zhang X, Liu G (2015) Activated carbons derived from hydrothermally carbonized sucrose: Remarkable adsorbents for adsorptive desulfurization. ACS Sustain Chem Eng 3: 2237–2246. doi: 10.1021/acssuschemeng.5b00670
![]() |
[55] |
Zhang C, Lin S, Peng J, et al. (2017) Preparation of highly porous carbon through activation of NH4Cl induced hydrothermal microsphere derivation of glucose. RSC Adv 7: 6486–6491. doi: 10.1039/C6RA26141H
![]() |
[56] |
Fan Y, Liu PF, Yang ZJ, et al. (2015) Bi-functional porous carbon spheres derived from pectin as electrode material for supercapacitors and support material for Pt nanowires towards electrocatalytic methanol and ethanol oxidation. Electrochim Acta 163: 140–148. doi: 10.1016/j.electacta.2015.02.157
![]() |
[57] |
Chowdhury ZZ, Hamid SBA, Rahman MM, et al. (2016) Catalytic activation and application of micro-spherical carbon derived from hydrothermal carbonization of lignocellulosic biomass: Statistical analysis using Box-Behnken design. RSC Adv 6: 102680–102694. doi: 10.1039/C5RA26189A
![]() |
[58] |
Yang W, Feng Y, Xiao D, et al. (2015) Fabrication of microporous and mesoporous carbon spheres for high-performance supercapacitor electrode materials. Int J Energ Res 39: 805–811. doi: 10.1002/er.3301
![]() |
[59] | Wang L, Li Y, Yang K, et al. (2017) Hierarchical porous carbon microspheres derived from biomass-corncob as ultra-high performance supercapacitor electrode. Int J Electrochem Sc 12: 5604–5617 |
[60] |
Yang X, Xia H, Liang Z, et al. (2017) Monodisperse carbon nanospheres with hierarchical porous structure as electrode material for supercapacitor. Nanoscale Res Lett 12: 550. doi: 10.1186/s11671-017-2318-z
![]() |
[61] |
Liu M, Gan L, Xiong W, et al. (2013) Nickel-doped activated mesoporous carbon microspheres with partially graphitic structure for supercapacitors. Energ Fuel 27: 1168–1173. doi: 10.1021/ef302028j
![]() |
[62] |
Lin F, Wang Y, Lin Z (2016) One-pot synthesis of nitrogen-enriched carbon spheres for hexavalent chromium removal from aqueous solution. RSC Adv 6: 33055–33062. doi: 10.1039/C5RA27738H
![]() |
[63] |
Ng SWL, Yilmaz G, Ong WL, et al. (2018) One-step activation towards spontaneous etching of hollow and hierarchical porous carbon nanospheres for enhanced pollutant adsorption and energy storage. Appl Catal B-Environ 220: 533–541. doi: 10.1016/j.apcatb.2017.08.069
![]() |
[64] |
Hao ZQ, Cao JP, Zhao XY, et al. (2018) Preparation of porous carbon spheres from 2-keto-l-gulonic acid mother liquor by oxidation and activation for electric double-layer capacitor application. J Colloid Interf Sci 513: 20–27. doi: 10.1016/j.jcis.2017.11.006
![]() |
[65] | Ma M, Zhang C, Huang G, et al. (2015) Synthesis and electrochemical performance of polyacrylonitrile carbon nanostructure microspheres for supercapacitor application. J Nanomater 2015: 1–10. |
[66] |
Chang B, Guan D, Tian Y, et al. (2013) Convenient synthesis of porous carbon nanospheres with tunable pore structure and excellent adsorption capacity. J Hazard Mater 262: 256–264. doi: 10.1016/j.jhazmat.2013.08.054
![]() |
[67] |
Wang Y, Chang B, Guan D, et al. (2015) Mesoporous activated carbon spheres derived from resorcinol-formaldehyde resin with high performance for supercapacitors. J Solid State Electr 19: 1783–1791. doi: 10.1007/s10008-015-2789-8
![]() |
[68] |
Kim C, Kim K, Moon JH (2017) Highly N-doped microporous carbon nanospheres with high energy storage and conversion efficiency. Sci Rep 7: 14400. doi: 10.1038/s41598-017-14686-1
![]() |
[69] |
Sun Y, Zhao J, Wang J, et al. (2017) Sulfur-doped millimeter-sized microporous activated carbon spheres derived from sulfonated poly(styrene-divinylbenzene) for CO2 capture. J Phys Chem C 121: 10000–10009. doi: 10.1021/acs.jpcc.7b02195
![]() |
[70] |
Sun Y, Li K, Zhao J, et al. (2018) Nitrogen and sulfur co-doped microporous activated carbon macro-spheres for CO2 capture. J Colloid Interf Sci 526: 174–183. doi: 10.1016/j.jcis.2018.04.101
![]() |
[71] | Thommes M, Kaneko K, Neimark AV, et al. (2015) Physisorption of gases, with special reference to the evaluation of surface area and pore size distribution (IUPAC Technical Report). Pure Appl Chem 87: 1051–1069. |
[72] |
Oh WC, Kim JG, Kim H, et al. (2009) Preparation of spherical activated carbon and their physicochemical properties. J Korean Ceram Soc 46: 568–573. doi: 10.4191/KCERS.2009.46.6.568
![]() |
[73] | Dixit S, Shrivastava R, Goswami CS, et al. (2013) Effect of activation parameters on the surface and mechanical properties of activated carbon spheres. Int J Met Mat Sc Eng 3: 75–84. |
[74] |
Wu Q, Li W, Liu S (2014) Carboxyl-rich carbon microspheres prepared from pentosan with high adsorption capacity for heavy metal ions. Mater Res Bull 60: 516–523. doi: 10.1016/j.materresbull.2014.09.015
![]() |
[75] |
Zhou J, Wang Y, Wang J, et al. (2016) Effective removal of hexavalent chromium from aqueous solutions by adsorption on mesoporous carbon microspheres. J Colloid Interf Sci 462: 200–207. doi: 10.1016/j.jcis.2015.10.001
![]() |
[76] |
Liu MX, Deng XX, Zhu DZ, et al. (2016) Magnetically separated and N,S co-doped mesoporous carbon microspheres for the removal of mercury ions. Chinese Chem Lett 27: 795–800. doi: 10.1016/j.cclet.2016.01.038
![]() |
[77] |
Song X, Gunawan P, Jiang R, et al. (2011) Surface activated carbon nanospheres for fast adsorption of silver ions from aqueous solutions. J Hazard Mater 194: 162–168. doi: 10.1016/j.jhazmat.2011.07.076
![]() |
[78] |
Pan ZZ, Dong L, Lv W, et al. (2017) A hollow spherical carbon derived from the spray drying of corncob lignin for high-rate-performance supercapacitors. Chem-Asian J 12: 503–506. doi: 10.1002/asia.201601724
![]() |
[79] |
Tang J, Wang J, Shrestha LK, et al. (2017) Activated porous carbon spheres with customized mesopores through assembly of diblock copolymers for electrochemical capacitor. ACS Appl Mater Inter 9: 18986–18993. doi: 10.1021/acsami.7b04967
![]() |
[80] |
Ho HC, Goswami M, Chen J, et al. (2018) Amending the structure of renewable carbon from biorefinery waste-streams for energy storage applications. Sci Rep 8: 8355. doi: 10.1038/s41598-018-25880-0
![]() |
[81] |
Zhou L, Xie G, Chen X (2018) Carbonization-dependent nitrogen-doped hollow porous carbon nanospheres synthesis and electrochemical study for supercapacitors. J Solid State Chem 261: 1–8. doi: 10.1016/j.jssc.2018.02.001
![]() |
[82] |
Ruan CQ, Wang Z, Lindh J, et al. (2018) Carbonized cellulose beads for efficient capacitive energy storage. Cellulose 25: 3545–3556. doi: 10.1007/s10570-018-1811-6
![]() |
[83] |
Chen Z, Ye S, Evans SD, et al. (2018) Confined assembly of hollow carbon spheres in carbonaceous nanotube: A spheres-in-tube carbon nanostructure with hierarchical porosity for high-performance supercapacitor. Small 14: 1704015. doi: 10.1002/smll.201704015
![]() |
[84] |
Sun Z, Shen S, Ma L, et al. (2016) Controlled synthesis of N-doped carbon spheres with different morphologies for supercapacitors. RSC Adv 6: 104642–104647. doi: 10.1039/C6RA22424E
![]() |
[85] |
Liu M, Wang X, Zhu D, et al. (2017) Encapsulation of NiO nanoparticles in mesoporous carbon nanospheres for advanced energy storage. Chem Eng J 308: 240–247. doi: 10.1016/j.cej.2016.09.061
![]() |
[86] |
Chen A, Xia K, Zhang L, et al. (2016) Fabrication of nitrogen-doped hollow mesoporous spherical carbon capsules for supercapacitors. Langmuir 32: 8934–8941. doi: 10.1021/acs.langmuir.6b02250
![]() |
[87] |
Hong YJ, Kang YC (2015) General formation of Tin nanoparticles encapsulated in hollow carbon spheres for enhanced lithium storage capability. Small 11: 2157–2163. doi: 10.1002/smll.201402994
![]() |
[88] |
Mutuma BK, Matsoso B, Ranganathan K, et al. (2016) Generation of open-ended, worm-like and graphene-like structures from layered spherical carbon materials. RSC Adv 6: 20399–20408. doi: 10.1039/C5RA25880D
![]() |
[89] |
Pappas GS, Ferrari S, Huang X, et al. (2016) Heteroatom doped-carbon nanospheres as anodes in lithium ion batteries. Materials 9: 35. doi: 10.3390/ma9010035
![]() |
[90] |
Kim MH, Kim KB, Park SM, et al. (2016) Hierarchically structured activated carbon for ultracapacitors. Sci Rep 6: 21182. doi: 10.1038/srep21182
![]() |
[91] |
Chen XY, Chen C, Zhang ZJ, et al. (2013) Nitrogen-doped porous carbon spheres derived from polyacrylamide. Ind Eng Chem Res 52: 12025–12031. doi: 10.1021/ie4017013
![]() |
[92] |
Chang B, Yang B, Guo Y, et al. (2015) Preparation and enhanced supercapacitance performance of porous carbon spheres with a high degree of graphitization. RSC Adv 5: 2088–2095. doi: 10.1039/C4RA09204J
![]() |
[93] |
Ren W, Zhang Z, Wang Y, et al. (2015) Preparation of porous silicon/carbon microspheres as high performance anode materials for lithium ion batteries. J Mater Chem A 3: 5859–5865. doi: 10.1039/C4TA07093C
![]() |
[94] |
Wang M, Zhang H, Wang Q, et al. (2015) Steam-etched spherical carbon/sulfur composite with high sulfur capacity and long cycle life for Li/S battery application. ACS Appl Mater Inter 7: 3590–3599. doi: 10.1021/am5075562
![]() |
[95] |
Jia Z, Li Z, Li S, et al. (2016) Adsorption performance and mechanism of methylene blue on chemically activated carbon spheres derived from hydrothermally-prepared poly(vinyl alcohol) microspheres. J Mol Liq 220: 56–62. doi: 10.1016/j.molliq.2016.04.063
![]() |
[96] |
Fu J, Chen Z, Wang M, et al. (2015) Adsorption of methylene blue by a high-efficiency adsorbent (polydopamine microspheres): Kinetics, isotherm, thermodynamics and mechanism analysis. Chem Eng J 259: 53–61. doi: 10.1016/j.cej.2014.07.101
![]() |
[97] |
Wei D, Zhang Y, Fu J (2017) Fabrication of carbon nanospheres by the pyrolysis of polyacrylonitrile-poly(methyl methacrylate) core–shell composite nanoparticles. Beilstein J Nanotech 8: 1897–1908. doi: 10.3762/bjnano.8.190
![]() |
[98] |
Zhang W, Zhou Z (2017) Citrus pectin-derived carbon microspheres with superior adsorption ability for methylene blue. Nanomaterials 7: 161. doi: 10.3390/nano7070161
![]() |
[99] |
Bedin KC, Martins AC, Cazetta AL, et al. (2016) KOH-activated carbon prepared from sucrose spherical carbon: Adsorption equilibrium, kinetic and thermodynamic studies for methylene blue removal. Chem Eng J 286: 476–484. doi: 10.1016/j.cej.2015.10.099
![]() |
[100] |
Shao X, Wang W, Xue R, et al. (2004) Adsorption of methane and hydrogen on mesocarbon microbeads by experiment and molecular simulation. J Phys Chem B 108: 2970–2978. doi: 10.1021/jp035715d
![]() |
[101] |
Choma J, Osuchowski Ł, Dziura A, et al. (2015) Benzene and methane adsorption on ultrahigh surface area carbons prepared from sulphonated styrene divinylbenzene resin by KOH Activation. Adsorpt Sci Technol 33: 587–594. doi: 10.1260/0263-6174.33.6-8.587
![]() |
[102] |
Choma J, Osuchowski Ł, Marszewski M, et al. (2014) Highly microporous polymer-based carbons for CO2 and H2 adsorption. RSC Adv 4: 14795. doi: 10.1039/c3ra47278g
![]() |
[103] |
Wang ZQ, Sun LX, Xu F, et al. (2016) The synthesis of nitrogen-doped mesoporous carbon spheres for hydrogen storage. Mater Sci Forum 852: 864–869. doi: 10.4028/www.scientific.net/MSF.852.864
![]() |
[104] |
Sun N, Sun C, Liu J, et al. (2015) Surface-modified spherical activated carbon materials for pre-combustion carbon dioxide capture. RSC Adv 5: 33681–33690. doi: 10.1039/C5RA02665B
![]() |
[105] |
Jahandar LM, Atkinson JD, Hashisho Z, et al. (2016) The role of beaded activated carbon's surface oxygen groups on irreversible adsorption of organic vapors. J Hazard Mater 317: 284–294. doi: 10.1016/j.jhazmat.2016.05.087
![]() |
[106] |
Romero-Anaya AJ, Lillo-Ródenas MA, Linares-Solano A (2015) Factors governing the adsorption of ethanol on spherical activated carbons. Carbon 83: 240–249. doi: 10.1016/j.carbon.2014.10.092
![]() |
[107] |
Jahandar LM, Atkinson JD, Hashisho Z, et al. (2016) The role of beaded activated carbon's pore size distribution on heel formation during cyclic adsorption/desorption of organic vapors. J Hazard Mater 315: 42–51. doi: 10.1016/j.jhazmat.2016.04.071
![]() |
[108] |
Qi J, Li J, Li Y, et al. (2017) Synthesis of porous carbon beads with controllable pore structure for volatile organic compounds removal. Chem Eng J 307: 989–998. doi: 10.1016/j.cej.2016.09.022
![]() |
[109] |
Zhang P, Zhu H, Dai S (2015) Porous carbon supports: Recent advances with various morphologies and compositions. ChemCatChem 7: 2788–2805. doi: 10.1002/cctc.201500368
![]() |
[110] |
Munoz M, Kolb V, Lamolda A, et al. (2017) Polymer-based spherical activated carbon as catalytic support for hydrodechlorination reactions. Appl Catal B-Environ 218: 498–505. doi: 10.1016/j.apcatb.2017.07.001
![]() |
[111] |
Hadidi L, Mahmoud AYF, Purkait TK, et al. (2017) Cellulose nanocrystal-derived hollow mesoporous carbon spheres and their application as a metal-free catalyst. Nanotechnology 28: 505606. doi: 10.1088/1361-6528/aa95a2
![]() |
[112] |
Yang S, Zhu Y, Cao C, et al. (2018) Controllable synthesis of multiheteroatoms co-doped hierarchical porous carbon spheres as an ideal catalysis platform. ACS Appl Mater Inter 10: 19664–19672. doi: 10.1021/acsami.8b03283
![]() |
[113] |
Veerakumar P, Muthuselvam P, Pounraj T, et al. (2018) Low-cost palladium decorated on m-aminophenol-formaldehyde-derived porous carbon spheres for the enhanced catalytic reduction of organic dyes. Inorg Chem Front 5: 354–363. doi: 10.1039/C7QI00553A
![]() |
[114] |
Galeano C, Meier JC, Soorholtz M, et al. (2014) Nitrogen-doped hollow carbon spheres as a support for platinum-based electrocatalysts. ACS Catal 4: 3856–3868. doi: 10.1021/cs5003492
![]() |
[115] |
With PC, Wilde N, Modrow A, et al. (2015) Polymer-based spherical activated carbons in combination with TS-1 as efficient epoxidation catalysts. Chem Eng Technol 38: 1671–1676. doi: 10.1002/ceat.201500366
![]() |
[116] |
Wang X, Xin C, Shi C, et al. (2018) Simple preparation of spherical activated carbon with mesoporous structure from phenolic resol and associated catalytic performance in isobutane dehydrogenation. Trans Tianjin Univ 24: 351–360. doi: 10.1007/s12209-018-0144-8
![]() |
[117] |
Zhao Q, Lin Y, Han N, et al. (2017) Mesoporous carbon nanomaterials in drug delivery and biomedical application. Drug Deliv 24: 94–107. doi: 10.1080/10717544.2017.1399300
![]() |
[118] |
Yamamoto O, Sawai J, Sasamoto T (2002) Activated carbon sphere with antibacterial characteristics. Mater Trans 43: 1069–1063. doi: 10.2320/matertrans.43.1069
![]() |
[119] |
Yamaguchi J, Tanaka T, Inagi R (2017) Effect of AST-120 in chronic kidney disease treatment: Still a controversy? Nephron 135: 201–206. doi: 10.1159/000453673
![]() |
[120] |
Schute K, Louven Y, Detoni C, et al. (2016) Selective liquid phase adsorption of biogenic HMF on hydrophobic spherical activated carbons. Chem Ing Tech 88: 355–362. doi: 10.1002/cite.201500133
![]() |
[121] |
Meng Y, Wang S, Li C, et al. (2016) Photothermal combined gene therapy achieved by polyethyleneimine-grafted oxidized mesoporous carbon nanospheres. Biomaterials 100: 134–142. doi: 10.1016/j.biomaterials.2016.05.033
![]() |
[122] |
Wang T, Zhao P, Zhao Q, et al. (2016) The mechanism for increasing the oral bioavailability of poorly water-soluble drugs using uniform mesoporous carbon spheres as a carrier. Drug Deliv 23: 420–428. doi: 10.3109/10717544.2014.916767
![]() |
[123] | Karkalić R, Maslak V, Nikolić A, et al. (2015) Application of permeable materials for CBRN protective equipment. Zast Mater 56: 239–242. |
[124] |
Fernández JF, Nierobisch P, Niemeyer B (2014) Performance evaluation of protective clothing against toxic industrial chemicals. Chem Ing Tech 86: 35–40. doi: 10.1002/cite.201300055
![]() |
[125] |
Fichtner S, Hofmann J, Möller A, et al. (2013) Decomposition of 2-chloroethylethylsulfide on copper oxides to detoxify polymer-based spherical activated carbons from chemical warfare agents. J Hazard Mater 262: 789–795. doi: 10.1016/j.jhazmat.2013.09.052
![]() |
[126] |
Tagliavini M, Engel F, Weidler PG, et al. (2017) Adsorption of steroid micropollutants on polymer-based spherical activated carbon (PBSAC). J Hazard Mater 337: 126–137. doi: 10.1016/j.jhazmat.2017.03.036
![]() |
1. | Peter Hästö, Jihoon Ok, Regularity theory for non-autonomous problems with a priori assumptions, 2023, 62, 0944-2669, 10.1007/s00526-023-02587-3 | |
2. | Michela Eleuteri, Petteri Harjulehto, Peter Hästö, Bounded variation spaces with generalized Orlicz growth related to image denoising, 2025, 310, 0025-5874, 10.1007/s00209-025-03731-9 |