Research article

One-off geophysical detection of chlorinated DNAPL during remediation of an industrial site: a case study

  • Received: 19 October 2020 Accepted: 05 January 2021 Published: 13 January 2021
  • The remediation of a polluted site relies, as a first stage, on the proper delineation of the contamination sources. In classical investigations, soil and water samples are collected throughout the field. These measurements allow a quantitative characterization of the gathered materials but only provide information about the medium in the vicinity of the points where they were collected. On the other hand, geophysical techniques can provide a quasi-continuous coverage of the investigated field. This paper describes a geophysical survey that was performed on an industrial site impacted by a chlorinated DNAPL. The precise location of the contamination was needed for the treatment of the saturated zone, while the unsaturated zone was remediated by general excavation of the sediments, followed by separate treatment. As this excavation allowed to get closer to the saturated zone, geophysical measurements were conducted at the bottom of the pit. Whereas Electrical Resistivity Tomography measurements only brought little information, Ground Penetrating Radar drew the remediation operations towards an area that preliminary point measurements had not identified as a possible source location.

    Citation: Eve-Agnès Fiorentino, Sheldon Warden, Maksim Bano, Pascal Sailhac, Thomas Perrier. One-off geophysical detection of chlorinated DNAPL during remediation of an industrial site: a case study[J]. AIMS Geosciences, 2021, 7(1): 1-21. doi: 10.3934/geosci.2021001

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  • The remediation of a polluted site relies, as a first stage, on the proper delineation of the contamination sources. In classical investigations, soil and water samples are collected throughout the field. These measurements allow a quantitative characterization of the gathered materials but only provide information about the medium in the vicinity of the points where they were collected. On the other hand, geophysical techniques can provide a quasi-continuous coverage of the investigated field. This paper describes a geophysical survey that was performed on an industrial site impacted by a chlorinated DNAPL. The precise location of the contamination was needed for the treatment of the saturated zone, while the unsaturated zone was remediated by general excavation of the sediments, followed by separate treatment. As this excavation allowed to get closer to the saturated zone, geophysical measurements were conducted at the bottom of the pit. Whereas Electrical Resistivity Tomography measurements only brought little information, Ground Penetrating Radar drew the remediation operations towards an area that preliminary point measurements had not identified as a possible source location.


    In [4] the authors obtained the following generalization of Montgomery identity for quantum calculus.

    Lemma 1. [4] (Quantum Montgomery identity) Let f:[a,b]R, be an arbitrary function with daqf quantum integrable on [a,b], then the following quantum identity holds:

    f(x)1babaf(t)daqt=(ba)10Kq,x(t)Daqf(tb+(1t)a)d0qt (1.1)

    where Kq,x(t) is defined by

    Kq,x(t)={qt,0txaba,qt1,xaba<t1. (1.2)

    Using this identity, the authors have obtained two Ostrowski type inequalities for quantum integrals and applied it in several special cases.

    Unfortunately, in the proof of this lemma an error is made when calculating the integrals involving the kernel Kq,x(t) on the interval [xaba,1]. Also, in the proofs of Theorem 3 and Theorem 4 a small mistake related to the convexity of |Daqf|r is made.

    In the present paper we prove that the identity (1.1) and, thus, all of the consequent results are incorrect and provide corrections for these results.

    The q-derivative of a function f:[a,b]R for q0,1 (see [5] or [2] for a=0) is given by

    Daqf(x)=f(x)f(a+q(xa))(1q)(xa),forxa,b]Daqf(a)=limxaDaqf(x)

    We say that f:[a,b]R is q-differentiable if limxaDaqf(x) exists. The q-derivative is a discretization of the ordinary derivative and if f is a differentiable function then ([1,3])

    limq1 Daqf(x)=f(x).

    Further, the q-integral of f is defined by

    xaf(t)daqt=(1q)(xa)k=0qkf(a+qk(xa)), x[a,b].

    If the series on the right hand-side is convergent, then the q-integral xaf(t)daqt exists and f:[a,b]R is said to be q-integrable on [a,x]. If f is continuous on [a,b] the series (1q)(xa)k=0qkf(a+qk(xa)) tends to the Riemann integral of f as q1 ([1], [3])

    limq1xaf(t)daqt=xaf(t)dt.

    If ca,x the q-integral is defined by

    xcf(t)daqt=xaf(t)daqtcaf(t)daqt.

    Obviously, the q-integral depends on the values of f at the points outside the interval of integration and an important difference between the definite q-integral and Riemann integral is that even if we are integrating a function over the interval [c,x], a<c<x<b, for q-integral we have to take into account its behavior at t=a as well as its values on [a,x]. This is the main reason for mistakes made in [4] since in the proof of Lemma 1 the following error was made:

    1xabaKq,x(t)Daqf(tb+(1t)a)d0qt=10(qt1)Daqf(tb+(1t)a)d0qtxaba0(qt1)Daqf(tb+(1t)a)d0qt.

    But Kq,x(t)(qt1) for t[0,1] or for t[0,xaba], so the equality does not hold.

    Now, we give a proof that the quantum Montgomery identity (1.1) is not correct, since it does not hold for all x[a,b]. As we shall see, the identity (1.1) is valid only if x=a+qm+1(ba) for some mN{0}. We have

    (ba)10Kq,x(t)Daqf(tb+(1t)a)d0qt=(ba)(1q)k=0qkKq,x(qk)Daqf(a+qk(ba)).

    For q0,1 let mN{0} be such that

    qm+1xaba<qm,

    in other words

    m=logqxaba1.

    Then

    Kq,x(qk)={qk+11,km,qk+1,km+1,

    and

    (ba)(1q)k=0qkKq,x(qk)Daqf(a+qk(ba))=(ba)(1q)(mk=0qk(qk+11)f(a+qk(ba))f(a+qk+1(ba))(1q)qk(ba)+k=m+1qk(qk+1)f(a+qk(ba))f(a+qk+1(ba))(1q)qk(ba))=mk=0(f(a+qk(ba))f(a+qk+1(ba)))+k=0qk+1(f(a+qk(ba))f(a+qk+1(ba)))=f(a+qm+1(ba))f(b)+k=0qk+1(f(a+qk(ba))f(a+qk+1(ba))).

    If we put S=k=0qkf(a+qk(ba))=1(1q)(ba)baf(t)daqt, we have

    k=0(qk+1)(f(a+qk(ba))f(a+qk+1(ba)))=qS(Sf(b))

    and

    1babaf(t)daqt+(ba)10Kq,x(t)Daqf(tb+(1t)a)d0qt=1babaf(t)daqt+(f(a+qm+1(ba))f(b))+qS(Sf(b))=(1q)S+f(a+qm+1(ba))f(b)+qSS+f(b)=f(a+qm+1(ba))

    which is obviously not equal to f(x), unless x=a+qm+1(ba).

    This is no surprise since Jackson integral takes into account only f(a+qk(xa)) for kN{0}. Thus, we have proved the next lemma which is a corrected version of Lemma 1 from [4].

    Lemma 2. (Quantum Montgomery identity) Let f:[a,b]R, be an arbitrary function with Daqf quantum integrable on [a,b], then for all xa,b the following quantum identity holds:

    f(a+qlogqxaba(ba))1babaf(t)daqt=(ba)10Kq,x(t)Daqf(tb+(1t)a)d0qt

    where Kq,x(t) is defined by

    Kq,x(t)={qt,0txaba,qt1,xaba<t1.

    In Theorem 3 and Theorem 4 from [4] the authors have used the identity (1.1) to derive Ostrowski type inequalities for functions f for which Daqf is quantum integrable on [a,b] and |Daqf|r, r1 is a convex function. Since these inequalities depends on the validity of Lemma 1, our discussion invalidates all the results from [4].

    More precisely, in all the inequalities an additional assumption x=a+qm(ba) for some mN{0} should be added. In Theorems 3 and 4 |Daqf(a)|r and |Daqf(b)|r should be swapped, since in the proofs of Theorem 3 and Theorem 4, when applying the convexity of |Daqf|r the following mistake was made

    |Daqf(tb+(1t)a)|rt|Daqf(a)|r+(1t)|Daqf(b)|r.

    Lastly, the integral K4(a,b,x,q) is incorrectly computed and should read:

    K4(a,b,x,q)=1q1+q(bxba)+q1+q(bxba)2.

    The main goal of this paper was to point out that some results in [4] are not correct. We have concentrated on Lemma 3 (Quantum Montgomery identity). The statement of that Lemma is not correct as we have shown. We also found and analyzed the mistake in the proof of Lemma 3.

    However, we went one step further and stated and proved the correct version of Lemma 3 (it is Lemma 2 in our paper). We have also explained how can all inequalities derived from Quantum Montgomery identity be corrected.

    Domagoj Kovačević was supported by the QuantiXLie Centre of Excellence, a project co financed by the Croatian Government and European Union through the European Regional Development Fund-the Competitiveness and Cohesion Operational Programme (Grant KK.01.1.1.01.0004).

    The authors declare that they have no competing interests.

    After our Correction was accepted we were contacted by the first author of [4], Professor Kunt, who suggested an alternate way to correct the results of [4].

    The incorrect version of Montgomery identity from [4]

    f(x)1babaf(t)daqt=(ba)10Kq,x(t)Daqf(tb+(1t)a)d0qt

    can be fixed in two ways: either by changing the left hand side or by changing the right hand side of this equation. In Lemma 2 we showed how to fix the identity by correcting the left hand side. This makes it easier to salvage the rest of results in [4], as all the results remain valid with the added assumption that x=a+qm(ba) for some mN{0}.

    Professor Kunt suggested correcting the right hand side of this equation to obtain the identity:

    f(x)1babaf(t)daqt=(ba)[xaba0qtDaqf(tb+(1t)a)d0qt+1xaba(qt1)Daqf(tb+(1t)a)d0qt].  ()

    By doing so, the proofs of all the remaining results have to be corrected as the bound used

    |1xaba(qt1)Daqf(tb+(1t)a)d0qt|1xaba|(qt1)Daqf(tb+(1t)a)|d0qt

    does not hold for q-integrals in general. This is discussed, for example, on page 12 in [1,Section 1.3.1,Remark (ii)].

    When xaba=qm or equivalently x=a+qm(ba) for some mN{0} the bound above does hold, which is why there is no need to change the rest of the results in [4] if one takes our approach. Nevertheless, we list below the results that can be obtained using identity (3.1). The results below are due to Professor Kunt.

    Theorem 3 in [4] should be as follows:

    Theorem 3. Let f:[a,b]R be an arbitrary function with Daqf is quantum integrable on [a,b]. If |Daqf|r, r1 is a convex function, then the following quantum integral inequality holds:

    |f(x)1babaf(t)daqt|(ba)[(11+q)11r[|Daqf(b)|r1(1+q)(1+q+q2)+|Daqf(a)|rq1+q+q2]1r+(xaba)[|Daqf(b)|r(xaba)11+q+|Daqf(a)|r(1(xaba)11+q)]1r] (3.1)

    for all x[a,b].

    Proof. Using convexity of |Daqf|r, we have that

    |Daqf(tb+(1t)a)|rt|Daqf(b)|r+(1t)|Daqf(a)|r. (3.2)

    By using (), quantum power mean inequality and (3.2), we have that

    |f(x)1babaf(t)daqt| (3.3)
    =(ba)|xaba0qtDaqf(tb+(1t)a)d0qt+1xaba(qt1)Daqf(tb+(1t)a)d0qt|=(ba)|10(qt1)Daqf(tb+(1t)a)d0qt+xaba0Daqf(tb+(1t)a)d0qt|(ba)|10(qt1)Daqf(tb+(1t)a)d0qt|+|xaba0Daqf(tb+(1t)a)d0qt|
    (ba)[10(1qt)|Daqf(tb+(1t)a)|d0qt+xaba0|Daqf(tb+(1t)a)|d0qt]
    (ba)[(101qtd0qt)11r(10(1qt)|Daqf(tb+(1t)a)|rd0qt)1r+(xaba0d0qt)11r(xaba0|Daqf(tb+(1t)a)|rd0qt)1r](ba)[(10(1qt)d0qt)11r×(|Daqf(b)|r10(1qt)td0q+|Daqf(a)|r10(1qt)(1t)d0qt)1r+(xaba0d0qt)11r×(|Daqf(b)|rxaba0td0qt+|Daqf(a)|rxaba0(1t)d0qt)1r]

    On the other hand, calculating the following quantum integrals we have

    10(1qt)d0qt=(1q)n=0qn(1qn+1)=(1q)[11qq1q2]=11+q, (3.4)
    10(1qt)td0qt=(1q)n=0qn[(1qn+1)qn]=(1q)[11q2q1q3]=11+qq1+q+q2=1(1+q)(1+q+q2), (3.5)
    10(1qt)(1t)d0qt=101qtd0qt10(1qt)td0qt=11+q1(1+q)(1+q+q2)=q1+q+q2, (3.6)
    xaba0d0qt=(1q)(xaba)n=0qn=xaba, (3.7)
    xaba0td0qt=(1q)(xaba)n=0qn(qn(xaba))=(xaba)211+q, (3.8)
    xaba0(1t)d0qt=xaba0d0qtxaba0td0qt=xaba(xaba)211+q=(xaba)[1(xaba)11+q]. (3.9)

    Using (3.4)–(3.9) in (3.3), we have (3.1).

    Theorem 4 in [4] should be as follows:

    Theorem 4. Let f:[a,b]R be an arbitrary function with Daqf is quantum integrable on [a,b]. If |Daqf|r, r>1 and 1r+1p=1 is convex function, then the following quantum integral inequality holds:

    |f(x)1babaf(t)daqt| (3.10)
    (ba)[(10(1qt)pd0qt)1p(|Daqf(b)|r11+q+|Daqf(a)|rq1+q)1r+(xaba)[|Daqf(b)|r(xaba)11+q+|Daqf(a)|r(1(xaba)11+q)]1r]

    for all x[a,b].

    Proof. By using () and quantum Hölder inequality, we have

    |f(x)1babaf(t)daqt|(ba)|10(qt1)Daqf(tb+(1t)a)d0qt|+|xaba0Daqf(tb+(1t)a)d0qt|(ba)[10(1qt)|Daqf(tb+(1t)a)|d0qt+xaba0|Daqf(tb+(1t)a)|d0qt](ba)[(10(1qt)pd0qt)1p(10|Daqf(tb+(1t)a)|rd0qt)1r+(xaba0d0qt)1p(xaba0|Daqf(tb+(1t)a)|rd0qt)1r](ba)[(10(1qt)pd0qt)1p(10[t|Daqf(b)|r+(1t)|Daqf(a)|r]d0qt)1r+(xaba0d0qt)1p(xaba0[t|Daqf(b)|r+(1t)|Daqf(a)|r]d0qt)1r](ba)[(10(1qt)pd0qt)1p(|Daqf(b)|r10td0qt+|Daqf(a)|r10(1t)d0qt)1r+(xaba0d0qt)1p(|Daqf(b)|rxaba0td0qt+|Daqf(a)|rxaba0(1t)d0qt)1r]=(ba)[(10(1qt)pd0qt)1p(|Daqf(b)|r11+q+|Daqf(a)|rq1+q)1r+(xaba)[|Daqf(b)|r(xaba)11+q+|Daqf(a)|r(1(xaba)11+q)]1r].

    We conclude this section by noting that the bounds obtained in the original paper [4] which, as we have previously shown, do hold with the added assumption x=a+qm(ba) for some mN{0}, are tighter than the bounds obtained above by Professor Kunt. Professor Kunt's bounds, however, hold for all x[a,b].



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