Review Topical Sections

Titania based nanocomposites as a photocatalyst: A review

  • Titanium dioxide or Titania is a semiconductor compound having remarkable dielectric, electronic and physico-chemical surface properties. It has excellent photocatalytic efficiency in presence of UV light. The curious grey matter of scientists has forced them to focus their attention to make Titania capable of utilizing the whole visible spectrum of light also. The hurdle that they faced was larger band gap of 3 eV and more, for this, efforts were directed towards adding other materials to Titania. The present article reviews the recent advances in the synthesis of different Titanium-based nanocomposite materials and their photocatalytic efficiency so as to apply them for several applications such as removal of dyes, other water pollutants, microbes and metals. A brief explanation of the photocatalytic process and the structural properties of TiO2 are also touched upon. Various past and recent approaches made in these directions of utilizing Titania based nanocomposites for photocatalytic activities are reviewed. It is suggested that there is a need to establish the kinetics of photo-corrosion and thermodynamic part of the photo-corrosion of various composites developed by different group across the globe, so that Titania based nanocomposites could be commercially utilized.

    Citation: Madhuri Sharon, Farha Modi, Maheshwar Sharon. Titania based nanocomposites as a photocatalyst: A review[J]. AIMS Materials Science, 2016, 3(3): 1236-1254. doi: 10.3934/matersci.2016.3.1236

    Related Papers:

    [1] Qian Zhang, Haigang Li, Ming Li, Lei Ding . Feature extraction of face image based on LBP and 2-D Gabor wavelet transform. Mathematical Biosciences and Engineering, 2020, 17(2): 1578-1592. doi: 10.3934/mbe.2020082
    [2] Fang Zhu, Wei Liu . A novel medical image fusion method based on multi-scale shearing rolling weighted guided image filter. Mathematical Biosciences and Engineering, 2023, 20(8): 15374-15406. doi: 10.3934/mbe.2023687
    [3] Haohao Xu, Yuchen Gong, Xinyi Xia, Dong Li, Zhuangzhi Yan, Jun Shi, Qi Zhang . Gabor-based anisotropic diffusion with lattice Boltzmann method for medical ultrasound despeckling. Mathematical Biosciences and Engineering, 2019, 16(6): 7546-7561. doi: 10.3934/mbe.2019379
    [4] Michael James Horry, Subrata Chakraborty, Biswajeet Pradhan, Maryam Fallahpoor, Hossein Chegeni, Manoranjan Paul . Factors determining generalization in deep learning models for scoring COVID-CT images. Mathematical Biosciences and Engineering, 2021, 18(6): 9264-9293. doi: 10.3934/mbe.2021456
    [5] Auwalu Saleh Mubarak, Zubaida Said Ameen, Fadi Al-Turjman . Effect of Gaussian filtered images on Mask RCNN in detection and segmentation of potholes in smart cities. Mathematical Biosciences and Engineering, 2023, 20(1): 283-295. doi: 10.3934/mbe.2023013
    [6] Jimin Yu, Jiajun Yin, Shangbo Zhou, Saiao Huang, Xianzhong Xie . An image super-resolution reconstruction model based on fractional-order anisotropic diffusion equation. Mathematical Biosciences and Engineering, 2021, 18(5): 6581-6607. doi: 10.3934/mbe.2021326
    [7] Chen Yue, Mingquan Ye, Peipei Wang, Daobin Huang, Xiaojie Lu . SRV-GAN: A generative adversarial network for segmenting retinal vessels. Mathematical Biosciences and Engineering, 2022, 19(10): 9948-9965. doi: 10.3934/mbe.2022464
    [8] Hao Wang, Guangmin Sun, Kun Zheng, Hui Li, Jie Liu, Yu Bai . Privacy protection generalization with adversarial fusion. Mathematical Biosciences and Engineering, 2022, 19(7): 7314-7336. doi: 10.3934/mbe.2022345
    [9] Hui Yao, Yuhan Wu, Shuo Liu, Yanhao Liu, Hua Xie . A pavement crack synthesis method based on conditional generative adversarial networks. Mathematical Biosciences and Engineering, 2024, 21(1): 903-923. doi: 10.3934/mbe.2024038
    [10] Wei-wei Jiang, Guang-quan Zhou, Ka-Lee Lai, Song-yu Hu, Qing-yu Gao, Xiao-yan Wang, Yong-ping Zheng . A fast 3-D ultrasound projection imaging method for scoliosis assessment. Mathematical Biosciences and Engineering, 2019, 16(3): 1067-1081. doi: 10.3934/mbe.2019051
  • Titanium dioxide or Titania is a semiconductor compound having remarkable dielectric, electronic and physico-chemical surface properties. It has excellent photocatalytic efficiency in presence of UV light. The curious grey matter of scientists has forced them to focus their attention to make Titania capable of utilizing the whole visible spectrum of light also. The hurdle that they faced was larger band gap of 3 eV and more, for this, efforts were directed towards adding other materials to Titania. The present article reviews the recent advances in the synthesis of different Titanium-based nanocomposite materials and their photocatalytic efficiency so as to apply them for several applications such as removal of dyes, other water pollutants, microbes and metals. A brief explanation of the photocatalytic process and the structural properties of TiO2 are also touched upon. Various past and recent approaches made in these directions of utilizing Titania based nanocomposites for photocatalytic activities are reviewed. It is suggested that there is a need to establish the kinetics of photo-corrosion and thermodynamic part of the photo-corrosion of various composites developed by different group across the globe, so that Titania based nanocomposites could be commercially utilized.


    At present, image color rendering as a major branch of image processing has attracted much attention. With the development of deep learning, image color rendering based on neural network has gradually become a research hotspot [1,2,3,4,5]. Because traditional color rendering methods require manual intervention and have high requirements of reference images. Moreover, when the structure and color of the image are complex, color rendering effect is not ideal [6,7,8,9,10]. Color rendering methods based on deep learning can be easily deployed in the actual production environment, and the limitation of the traditional methods can be solved [11,12,13]. By using the neural network model and the corresponding dataset training model [14,15], the image can be automatically rendered according to the model, without being affected by human or other factors [16,17,18,19].

    Larsson [20] used the convolutional neural network to consider the brightness of the image as input, decomposed the color and saturation of the image by the super-column model, to realize color rendering. Iizuka [21] combined the low-dimensional feature and global feature of the image by using the fusion layer in the convolutional neural network, for generating the color of the image and processing images of any resolution. Zhang [22] designed an appropriate loss function to handle the multi-mode uncertainty in color rendering and maintain the color diversity. However, when the grayscale image features are extracted using the above mentioned method, up-sampling is adopted to make the image size consistent, resulting in the loss of image information. Moreover, the network structure cannot well extract and understand the complex features of the image, and the rendering effect is limited [23,24,25].

    Isola [26] improved conditional generative adversarial networks (CGAN) to achieve the transformation between images. The proposed pix2pix model can realize conversion between different images, for example, color rendering can be realized by learning the mapping relationship between grayscale image and color image [27,28]. But the pix2pix model based generative adversarial networks (GAN) has the disadvantage of training instability. Moreover, the current image rendering methods based on deep learning are not good at rendering robust images. Gabor filter can easily extract texture information in all scales and directions of the image, and reduce the influence of light change and noise in the image to a certain extent.

    Therefore, we propose a color rendering method using Gabor filter based improved pix2pix for robust image. The contributions of this paper are mainly there-folds:

    (1) The improved pix2pix model can not only automatically complete image rendering and achieve good visual effect, but also achieve more stable training and better image quality.

    (2) Gabor filter was added to enhance the robustness of model rendered images.

    (3) The metric data of a series of experiments show that the proposed method has better performance for robust image.

    The rest of the paper is organized as follows. Section 2 introduces the previous work, including Gabor filter and pix2pix model. Section 3 describes the method and its design details. Section 4 introduces the experiment and comparison experiment, and evaluates the image quality. Section 5 conclusions the paper and outlooks the future work.

    Fourier transform is a powerful tool in signal processing, which can help us transform images from spatial domain to frequency domain, and extract features that are not easy to extract in spatial domain. However, after Fourier transform, frequency features of images at different locations are often mixed together, but Gabor filter can extract spatial local frequency features, which is an effective texture detection tool [29,30]. The Gabor filter is derived by multiplying a Gaussian by a cosine function [31,32,33], it is defined as

    g(x,y,λ,θ,φ,σ,γ)=exp(x2+γ2y22σ2)exp(i(2πxλ+φ)) (2.1)
    greal(x,y,λ,θ,φ,σ,γ)=exp(x2+γ2y22σ2)cos(i(2πxλ+φ)) (2.2)
    gimag(x,y,λ,θ,φ,σ,γ)=exp(x2+γ2y22σ2)sin(i(2πxλ+φ)) (2.3)

    where, x=xcosθ+ysinθ,y=xsinθ+ycosθ. Where, x, y represent the coordinate position of the pixel, λ represents the wavelength of the filter, θ represents the tilt degree of the Gabor kernel image, φ represents the phase offset, σ represents the standard deviation of the Gaussian function, and γ represents the aspect ratio.

    In order to make full use of the characteristics of Gabor filters, r filter extracts the texture features of the image in 6 scales and 4 directions. Namely, the Gabor it is necessary to design Gabor filters with different directions and scales to extract features. In this study, the Gaboscales are 7, 9, 11, 13, 15 and 17. The Gabor directions are 0°, 45°, 90° and 135°, as shown in Figure 1(a). Extract effective texture feature sets from the output results of the filter. The extracted texture feature sets are shown in Figure 1(b), with 24 texture feature maps in total.

    Figure 1.  Gabor filter.

    At present, image rendering based on generative adversarial networks [34] attracts much attention because it can directly generate color images by using mapping relations. Therefore, it is widely used in image processing, text processing, natural language processing and other fields. pix2pix model [26] is a model for image-to-image conversion based generative adversarial networks. It can better synthesize image or generate color image. The following are the main features of the pix2pix model.

    (1) Both the generator and discriminator structure use the convolution unit of Conv-Batchnorm-ReLU, namely, convolutional layer, batch normalization and ReLU Loss are used.

    (2) The input of the pix2pix model is the specified image, such as the label image to the real image, the input is the label image, the input is the grayscale image to the color image, and the input is the grayscale image. The grayscale image as the input of the generator, and the input and output of the generator as the input of the discriminator, so as to establish the corresponding relationship between the input image and the output image, realize user control, and complete image color rendering.

    (3) PatchGAN was used as discriminator for pix2pix model. Specifically, the image is divided into several fixed-size blocks, and the authenticity of each block is determined. Finally, the average value is taken as the final output. A network structure similar to U-net is adopted as a generator, and skip connections are added between i and ni at each layer to simulate U-net, where n is the total number of layers of the network. Not only can the path be shrunk for context information, but the symmetric extension path can be positioned precisely.

    (4) The loss function of the pix2pix model is as follows, which is composed of L1 loss and Vanilla GAN loss. Where, let x be the input image, y be the expected output, G be the generator, and D be the discriminator:

    G=argminGmaxDLcGAN(G,D)+λLL1(G) (2.4)
    LcGAN(G,D)=Ex,y(logD(x,y))+Ex(log(1D(x,G(x)))) (2.5)
    LL1(G)=Ex,y(yG(x)1) (2.6)

    In view of the detail problems existing in the generative adversarial networks based image color rendering method in complex scenes, this paper proposes an image color rendering method using Gabor filter based improved pix2pix for robust image. The network framework is shown in Figure 2. The rendering process is shown in Figure 3. After selecting the data set for training, the trained generator is used for color rendering.

    Figure 2.  Method framework.
    Figure 3.  Rendering procedure.

    Firstly, we preprocessed the image with Gabor filter, and extracted the texture feature set of the image as input for training and verification. By comparing 24 Gabor texture feature maps with 6 scales and 4 directions, the texture map with 7 scales and 0° direction has the best color rendering effect. Secondly, this paper utilizes the existing pix2pix model architecture for image transformation to perform color rendering by learning the mapping relationship between grayscale image and color image. Finally, although the pix2pix model solves some problems existing in the generative adversarial networks, it still has the instability problem of training on large-scale image dataset. Therefore, the least square loss in LSGAN [35] is used in the objective function of pix2pix model, and the penalty term similar to WGAN_GP [36] is added. We improve the overall model framework, it is shown that the proposed method has a better performance on the rendering of robust images by a series of comparison experiments.

    The generator in generative adversarial networks hopes that the output data distribution can be more close to the distribution of the real data. Meanwhile, the discriminator of generative adversarial networks needs to make a judgment between the real data and the output data by the generator to find the real data and the fake data. The loss function can generate more real data through the Lipschitz constraint generative adversarial networks. The traditional generative adversarial networks uses the cross entropy loss or Vanilla GAN loss as the loss function. The classification is correct, but gradient dispersion occurs when the generator is updated [36,37]. LSGAN uses the square loss as the objective function, and the least square loss function penalizes the samples (fake samples) that are in the discriminant true but far away from the decision boundary, and drags the false samples far away from the decision boundary into the decision boundary, to improve the quality of the generated image.

    Therefore, compared with the traditional generative adversarial networks, the image generated by LSGAN has higher quality and a more stable training process. So the least square loss function is adopted in the framework of this paper.

    {minDVLSGAN(D)=12ExPdata(x)[(D(x)b)2]+12EzPz(z)[(D(G(z))a)2]minDVLSGAN(D)=12EzPz(z)[(D(G(z))c)2] (3.1)

    where, the input image is x, expected output is y, generator is G, discriminator is D, noise is z, labels of generated sample and real sample are a and b, respectively. c is the value set by the generator to let the discriminator think the generated image is real data.

    Generative adversarial networks can generate better data distribution, but it has the problem of training instability. Improving the training stability of generative adversarial networks is a hot topic in deep learning. Wasserstein generative adversarial networks (WGAN) [38] uses Wasserstein distance to generate a value function with better theoretical properties than JS divergence in order to constrain the Lipschitz constant of the discriminator function, which basically solves the problems of generative adversarial networks training instability and model collapse and ensures the diversity of generated samples [39]. WGAN_GP continues to improve on WGAN, and its penalty term is derived from the Wasserstein distance, where the penalty coefficient is 10.

    The objective function of WGAN_GP is as follows, adding the original critic loss and the gradient penalty term of WGAN_GP.

    L=E˜xPg[D(˜x)]E˜xPr[D(x)]+λE˜xPˆx[(ˆxD(ˆx21)2] (3.2)

    where, E˜xPg[D(˜x)]E˜xPr[D(x)] is the original critic loss, λE˜xPˆx[(ˆxD(ˆx21)2] denotes the gradient penalty term of WGAN_GP, ˆx=tˆx+(1t)x, 0t1, and λ is the penalty coefficient.

    To verify the effectiveness and accuracy of the proposed method, we conducted extensive experiments on summer dataset [40], with 1231 pieces of train set, and 309 pieces of test set. Experiment 1 is conducted to test the effect of application of the Gabor filter and different objective functions in the pix2pix model environment. Experiment 2 is performed to test the rendering effect when different Gabor texture feature maps are given as input. Experiment 3 is conducted to test whether the penalty term should be added in the discriminator. Experiment 4 is the rendering effect of low-quality or robust images was tested by adding noise and dimming the brightness of the image for assessing the robustness of this model.

    Training parameters: The experiment was performed on a PC with Intel(R) Core(TM) i7-9750H CPU @ 2.6 GHz 2.59 GHz, a graphics card NVIDIA GeForce GTX 1650, and CUDA+Cudnn for acceleration training. The proposed method is implemented based on Python 3.7 and Pytorch framework. The number of experimental training iterations is 200, optimizer is Adam, batch_size is 1, learning rate is 0.0002, and number of processes is 4.

    Network structures and implementation details: All the models we train are designed to 256 × 256 images. The input image of the model is 512 × 256; the left one is the original color image, and the right one is the texture feature map processed by the Gabor filter, as shown in Figure 4. By default, the pix2pix model uses a generator similar to U-net, PatchGAN, and Vanilla GAN loss.

    Figure 4.  Spliced input graph with 512 × 256.

    Evaluation Metrics: To reflect image color rendering quality of different models more objectively, peak signal to noise ratio (PSNR) and structural similarity (SSIM) indexes are adopted to evaluate the rendered images [41,42]. These two indexes are often used in the evaluation metrics of image processing. PSNR is an objective standard to evaluate the quality of the color image produced. The calculation formula is as follows:

    PSNR=10log10(2n1)2MSE (4.1)
    MSE=1H×WHi=1Wj=1[X(i,j)Y(i,j)]2 (4.2)

    where, H and W represent the width and height of the image respectively, (i,j) represents each pixel point, and n represents the number of bits of the pixel, X and Y represent two images respectively.

    Because PSNR index also has its limitations, it cannot completely reflect the consistency of image quality and human visual effect, so SSIM index is used for further comparison. SSIM is a metric to measure the similarity of two images. By comparing the image rendered by the model with the original color image, the effectiveness and accuracy of this algorithm are demonstrated. The calculation formula is as follows:

    SSIM=(2μxμy+c1)(2σxy+c2)(μ2xμ2y+c1)(σ2xσ2y+c2) (4.3)

    where, μx and μy respectively represent the average value of the real image and the generated image, σ2x and σ2y respectively represent the variance of the real image and the generated image, σxy represents the covariance of the real image and the generated image, c1=(k1,L)2 and c2=(k2,L)2 are constants that maintain stability, and L is the dynamic range of pixel value, k1=0.01, k2=0.03.

    In this study, the Gabor filter extracts the texture features of the image in 6 scales and 4 directions. For convenience, according to the texture feature set shown in Figure 1(b), the images are numbered from left to right and from top to bottom. The direction is assumed to be d and the size is s, as shown in Figure 5. For example, G1 means "s = 7, d = 0°". So the direction is 0° and the scale is 7. G6 means "s = 17, d = 0°". So the direction is 0° and the scale is 17. By default, the pix2pix model uses Vanilla GAN loss. Based on pix2pix model, the model using least squares loss function is called LSpix (least squares pix2pix). Based on Gabor filter, the model using Gabor texture maps is called pixGn (pix2pix Gabor n), n = 1, 6, 7, 13.

    Figure 5.  Texture feature map with Gabor.

    To test the effect of application of the Gabor filter and different objective functions in the pix2pix model environment, we divided the experiment into adding Gabor filters (Figures 6(c), (e)), not adding Gabor filters (Figures 6(b), (d)), using least squares loss (Figures 6(d), (e)) or Vanilla GAN loss (Figures 6(b), (c)). By comparing the images in Figure 6, it can be confirmed that the rendering effect preprocessed by least square loss or Gabor filter is better, which is the LSpixG1 model. This is because Gabor can preprocess images and obtain multi-scale and multi-direction features of images, so as to achieve good and fast feature extraction and learning during network model learning. Moreover, compared with other loss functions, the least square loss function only reaches saturation at one point, which is not easy to cause the problem of gradient disappearance.

    Figure 6.  Effect of Gabor filter and use of different objective functions.

    Tables 1 and 2 compare the distortion and structural similarity between the rendered image and the ground truth, show the maximum, minimum, and average indexes. This is an additional interpretation of Figure 6. The LSpix model has the highest score in the maximum and average PSNR, which is 3.591dB and 1.083dB higher than that of the pix2pix model. Meanwhile, the LSpix model has the highest score in SSIM, which is 1.618%, 15.649% and 3.848% higher than that of the pix2pix model, respectively. This proves that our model is closer to ground truth in structure, and the colors are more reductive.

    Table 1.  PSNR index of different models (dB).
    Network MAX PSNR MIN PSNR AVE PSNR
    pix2pix 29.204 11.126 23.024
    pixG1 28.225 10.477 19.981
    LSpix 32.795 11.003 24.107
    pixG6 27.874 9.883 20.012
    LSpixG6 32.616 10.632 21.409
    LSpixG1 32.524 11.238 21.354
    Note: Bold font is the best value for each column.

     | Show Table
    DownLoad: CSV
    Table 2.  SSIM index of different models (%).
    Network MAX SSIM MIN SSIM AVE SSIM
    pix2pix 92.888 52.474 82.163
    pixG1 86.101 36.592 69.145
    LSpix 94.506 68.123 86.011
    pixG6 85.625 33.117 68.845
    LSpixG6 91.312 56.897 78.387
    LSpixG1 91.757 54.785 78.485
    Note: Bold font is the best value for each column.

     | Show Table
    DownLoad: CSV

    In order to test the rendering effect when different Gabor texture feature maps are input, we use different feature images as input. Figure 7 shows how different Gabor texture images are rendered when Vanilla GAN loss is the target function of the pix2pix model. Figures 5(c), (d), that is, the direction is the scale is 7 and 45° or 90°, contain incomplete details of the original image, resulting in incomplete input texture features. Therefore, the generated image is blurred, as shown in Figures 7(a), (b). Although the 7th and 13th texture images were considered as training sets (pixG7+G13 model) with a total of 1231 × 2 images taken together, the rendering effect was not significantly improved, as shown in Figure 7(b). Evidently, by comparing the images in Figure 7, it can be found out that the visual effect of Figures 7(c)–(e) is good and not blurred. And Table 3 and 4 show the evaluation indexes after the input of different feature maps. The data show that incomplete input of texture feature map is not desirable.

    Figure 7.  Effect of inputting different Gabor texture images.
    Table 3.  PSNR index of different models (dB).
    Network MAX PSNR MIN PSNR AVE PSNR
    pixG1 28.225 10.477 19.981
    pixG6 27.874 9.883 20.012
    pixG7 27.565 9.232 17.600
    pixG1+G13 28.960 9.947 20.682
    Note: Bold font is the best value for each column.

     | Show Table
    DownLoad: CSV
    Table 4.  SSIM index of different models (%).
    Network MAX SSIM MIN SSIM AVE SSIM
    pixG1 86.101 36.592 69.145
    pixG6 85.625 33.117 68.845
    pixG7 91.188 4.964 39.057
    pixG1+G13 87.615 42.562 71.630
    Note: Bold font is the best value for each column.

     | Show Table
    DownLoad: CSV

    And to compare the operation efficiency of input different texture maps, the training time is shown in Table 5, in hours. Regardless of whether the Gabor filter was used, which texture map was entered, the operation time was around 9 hours. However, if two texture maps are used for training, such as G1 and G13 are used in pixG1+G13 model, the training set doubles and the pre-training time doubles. Even though the results shown in Figure 7(d) are good, the method is not desirable. This is because when we use filtering, we need to extract multi-scale and multi-direction features and remove redundant information. Once the important information is removed, it will certainly have a certain impact on the results, resulting in blurred images.

    Table 5.  Pre-training time of inputing different texture maps (h).
    Model pix2pix pixG1 pixG6 pixG7 pixG7+G13 pixG1+G13
    Time 8.72 9.00 8.76 8.43 15.27 16.52

     | Show Table
    DownLoad: CSV

    Figure 8 shows the performance on whether or not to add a penalty item in the discriminator based on the pixG1 model. Figure 8(a) is the effect of not adding penalty items, and Figure 8(b) is the effect of adding penalty items. Obviously, Figure 8(b) has less error in detail and better visual effect. Penalty term, that is, gradient punishment is carried out by interpolation method to make the model satisfy Lipschitz constraint. The addition of punishment terms similar to WGAN_GP basically solves the problems of training instability and model collapse in the GAN model and ensures the diversity of generated samples.

    Figure 8.  Adding the effect of the penalty item.

    Tables 6 and 7 show the evaluation indexes whether or not to add a penalty item. With the addition of penalty term, the LSpix_GP model achieved the highest score in the minimum PSNR, which was 0.904dB higher than that of the original pix2pix model. Evidently, in the texture map extracted based on Gabor filter, the image with scale of 7 and direction of 0° has the best training effect. Furthermore, when the objective function is least squares loss, the average SSIM and performance are improved. When penalty term is added, the score of maximum and average SSIM is the highest, which is 1.753% and 1.083% higher than that of the pix2pix model. Therefore, the image rendered by the LSpixG1_GP model is better than that of the original model.

    Table 6.  PSNR index of different models (dB).
    Network MAX PSNR MIN PSNR AVE PSNR
    pix2pix 29.204 11.126 23.024
    pixG1 28.225 10.477 19.981
    pixG6 27.874 9.883 20.012
    LSpix 32.795 11.003 24.107
    LSpixG1 32.524 11.238 21.354
    LSpix_GP 31.859 12.030 24.019
    LSpixG1_GP 32.342 11.514 21.290
    LSpixG6 32.616 10.632 21.409
    LSpixG1_GP 32.113 11.067 21.384
    Note: Bold font is the best value for each column.

     | Show Table
    DownLoad: CSV
    Table 7.  SSIM index of different models (%).
    Network MAX SSIM MIN SSIM AVE SSIM
    pix2pix 92.888 52.474 82.163
    pixG1 86.101 36.592 69.145
    pixG6 85.625 33.117 68.845
    LSpix 94.506 68.123 86.011
    LSpixG1 91.757 54.785 78.485
    LSpix_GP 94.641 67.250 85.967
    LSpixG1_GP 90.772 54.308 78.067
    LSpixG6 91.312 56.897 78.387
    LSpixG6_GP 90.941 52.740 78.236
    Note: Bold font is the best value for each column.

     | Show Table
    DownLoad: CSV

    To compare the operating efficiency of different objective functions given as input and increase the punishment items, the running time is listed in Table 8 in hours. For example, LSpixG6_GP represents using the least squares loss, adding the penalty item, the direction is 0° and the scale is 17. Regardless of whether Gabor filter was used, which texture map was input, whether Vanilla GAN loss or least square loss was the target function, the training time was approximately 9 h. Although the algorithm efficiency of adding the filter alone is basically the same, the time of using the filter after adding the penalty term will be increased by 2–3 h. Therefore, the algorithm in this study adopts LSpixG1_GP model, namely Gabor texture map with model input scale of 7 and direction of 0°, least squares loss and penalty term.

    Table 8.  Pre-training time of using different models (h).
    Model pix2pix LSpix LSpixG1 LSpix_GP LSpixG1_GP LSpixG6 LSpixG6_GP
    Time 8.72 8.66 8.66 8.72 11.17 8.72 11.72
    Note: Bold font is the best value for each row.

     | Show Table
    DownLoad: CSV

    In order to evaluate the robustness of the model for rendering robust image, the rendering effect of low-quality images was tested by adding noise and dimming the image brightness, as shown in Figure 9. When testing the noise image, the Gaussian noise image with mean value of 0 and variance of 10 is added. When testing low-illumination images, power operation is performed on the pixels of the image, and the power is set to 2.5 to generate low-illumination images.

    Figure 9.  Test images.

    We use PSNR evaluation metric to evaluate the rendering results of each model for low-quality images. As shown in Table 9, the image rendered by the LSpix model is of higher quality when rendering noisy images. As shown in Table 10, images rendered by Gabor filter models are generally of good quality for low-illumination images. After the Gabor filter, the objective function is least square loss and the penalty term is added, the image quality of the LSpixG1_GP model is higher than that of the original model. This is because the method in this paper uses Gabor filter to avoid the interference of noise to the image to a certain extent. And when extracting features, the depth information of the image can be extracted to avoid the influence of light on the image. Clearly, the proposed method in this paper is robust to color rendering of low-quality images.

    Table 9.  PSNR index of noise image (dB).
    Network MAX PSNR MIN PSNR AVE PSNR
    pix2pix 29.489 10.770 22.528
    pixG1 25.657 10.562 18.665
    LSpix 29.655 11.805 22.528
    LSpixG1 27.650 12.409 19.942
    LSpix_GP 29.516 11.950 22.504
    LSpixG1_GP 27.306 11.548 19.966
    Note: Bold font is the best value for each column.

     | Show Table
    DownLoad: CSV
    Table 10.  PSNR index of low-illumination image (dB).
    Network MAX PSNR MIN PSNR AVE PSNR
    pix2pix 21.977 8.723 12.535
    pixG1 26.158 7.864 14.441
    LSpix 21.457 9.119 12.579
    LSpixG1 24.565 7.946 14.171
    LSpix_GP 21.948 9.334 12.563
    LSpixG1_GP 24.337 7.886 14.127
    Note: Bold font is the best value for each column.

     | Show Table
    DownLoad: CSV

    We proposed a novel image color rendering method based on using Gabor filter based improved pix2pix for robust image and demonstrate its feasibility and superiority for a variety of tasks. It enables automatically render robust images and has good robustness with low-quality image rendering. The experimental results on summer dataset demonstrate that the proposed method can achieve high-quality performance with image color rendering. At present, the image resolution of image processing based on deep learning is limited, which leads to the limitation in the practical application of rendering method. In the future, we will focus on improving the resolution of network model input images.

    This work were partially supported by the National Natural Science Foundation of China (No. 62002285 and No. 61902311).

    The authors declare there is no conflict of interest.

    [1] Hashimoto K, Irie H, Fujishima A (2005) TiO2 photocatalysis: An historical overview and future prospects. Jpn J Appl Phys 44: 8269–8285. doi: 10.1143/JJAP.44.8269
    [2] Chen X, Mao SS (2007) Titanium dioxide nanomaterials: synthesis, properties, modifications, and applications. Chem Rev 107: 2891–959. doi: 10.1021/cr0500535
    [3] Fox MA, Dulay MT (1993) Heterogeneous photocatalysis. Chem Rev 93: 341–357. doi: 10.1021/cr00017a016
    [4] Hoffmann MR, Martin ST, Choi W, et al. (1995) Environmental applications of semiconductor photocatalysis. Chem Rev 95: 69–96. doi: 10.1021/cr00033a004
    [5] Lee Y, Misook K (2010) The optical properties of nanoporous structured Titanium dioxide and the photovoltaic efficiency on DSSC. Mater Chem Phys 122: 284–289. doi: 10.1016/j.matchemphys.2010.02.050
    [6] Fujishima A, Honda K (1972) Electrochemical photolysis of water at a semiconductor electrode. Nature 238: 37–38. doi: 10.1038/238037a0
    [7] Gabor A, Somorjai A, Contreras M, et al. (2006) Clusters, surfaces, and catalysis. P Natl Acad Sci USA 103: 10577–10583. doi: 10.1073/pnas.0507691103
    [8] Mills A, Hunte SL (1997) An overview of semiconductor photocatalysis. J Photoch Photobiol A 108: 1–35. doi: 10.1016/S1010-6030(97)00118-4
    [9] Burda C, Chen X, Narayanan R, et al. (2005) Chemistry and properties of nanocrystals of different shapes. Chem Rev 105: 1025–1102. doi: 10.1021/cr030063a
    [10] Pelizzetti E, Minero C (1994) Metal oxides as photocatalysts for environmental detoxification. Comment Inorg Chem 15: 297–337. doi: 10.1080/02603599408035846
    [11] Hisatomi T, Kubota J, Domen K (2014) Recent advances in semiconductors for photocatalytic and photoelectrochemical water splitting. Chem Soc Rev 43: 7520–7535. doi: 10.1039/C3CS60378D
    [12] Ramírez H, Ramírez M (2015) Photocatalytic Semiconductors: Synthesis, Characterization, and Environmental Applications. Springer International Publishing, ISBN 978-3-319-10999-2.
    [13] Chen H, Nanayakkara CE, Grassian VH (2012) Titanium dioxide photocatalysis in atmospheric chemistry. Chem Rev 112: 5919–5948. doi: 10.1021/cr3002092
    [14] Pelaez M, Nolan NT, Pillai SC, et al. (2012) A review on the visible light active Titanium dioxide photocatalysts for environmental applications. Appl Catal B 125: 331–349. doi: 10.1016/j.apcatb.2012.05.036
    [15] Kalathil S, Khan MM, Ansari SA, et al. (2013) Band gap narrowing of Titanium dioxide (TiO2) nanocrystals by electrochemically active biofilm and their visible light activity. Nanoscale 5: 6323–6326. doi: 10.1039/c3nr01280h
    [16] Khan MM, Ansari SA, Pradhan D, et al. (2014) Band gap engineered TiO2 nanoparticles for visible light induced photoelectrochemical and photocatalytic studies. J Mater Chem A 2: 637–644. doi: 10.1039/C3TA14052K
    [17] Carp O, Huisman CL, Reller A (2004) Photoinduced reactivity of Titanium dioxide. Prog Solid State Ch 32: 33–177. doi: 10.1016/j.progsolidstchem.2004.08.001
    [18] Chen Q, Peng LM (2007) Structure and applications of titanate and related nanostructures. Int J Nanotechnol 4: 261–270.
    [19] Amaratunga P (2010) Synthesis and characterization of monolayer protected gold nanoparticles and a Gold-Titanium dioxide nanocomposite intended for photovoltaic degradation of environmental pollutants. Arch Microbiol 151: 77–83.
    [20] Jang JS, Sun S, Choi H, et al. (2006) A composite deposit photocatalyst of CdS nanoparticles deposited on TiO2 Nanosheets. J Nanosci Nanotechno 6: 3642–3646. doi: 10.1166/jnn.2006.073
    [21] Inumaru K, Kasahara T, Yasui M, et al. (2005) Direct nanocomposite of crystallite TiO2 particles and mesoporous silica as a molecular selective and highly reactive photocatalyst. Chem Commun 2005: 2132–1233.
    [22] Pradhan S, Ghosh D, Chen S (2009) Janus nanostructures based on Au-TiO2 heterodimers and their photocatalytic activity in the oxidation of methanol. ACS Appl Mater Inter 1: 2060–2065.
    [23] Fujishima A, Rao TN, Tryk DA (2000) Titanium dioxide photocatalysis. J Photoch Photobio C 1: 1–21.
    [24] Wang S, Zhou S (2011) Photodegradation of Methyl orange by photocatalyst of CNTs/P-TiO2 under UV and visible-light irradiation. J Hazard Mater 185: 77–85. doi: 10.1016/j.jhazmat.2010.08.125
    [25] Ibrahim SA, Sreekantan S (2010) Effect of pH on TiO2 nanoparticles via sol-gel method. Adv Mater Res 173: 184–189.
    [26] Niederberger M, Bartl MH, Stucky GD (2002) Benzyl alcohol and transition metal chlorides as a versatile reaction system for the nonaqueous and low-temperature synthesis of crystalline nano-objects with controlled dimensionality. J Am Chem Soc 124: 13642–13643. doi: 10.1021/ja027115i
    [27] Parala H, Devi A, Bhakta R, et al. (2002) Synthesis of nano-scale TiO2 particles by a non-hydrolytic approach. J Mater Chem 12: 1625–1627. doi: 10.1039/b202767d
    [28] Lei H, Hou Y, Zhu M, et al. (2005) Formation and transformation of ZnTiO3 prepared by sol-gel process. Mater Lett 59: 197–200. doi: 10.1016/j.matlet.2004.07.046
    [29] Arnal P, Corriu RJP, Leclercq D, et al. (1996) Preparation of anatase, brookite and rutile at low temperature by non-hydrolytic sol-gel methods. J Mater Chem 6: 1925–1932. doi: 10.1039/JM9960601925
    [30] Arnal P, Corriu RJP, Leclercq D, et al. (1997) A solution chemistry study of nonhydrolytic Sol-Gel routes to Titania.Chem Mater9: 694–698.
    [31] Hay JN, Raval HM (1998) Preparation of inorganic oxides via a non-hydrolytic sol-gel route. J Sol-Gel Sci Techn 13: 109–112. doi: 10.1023/A:1008615708489
    [32] Hay JN, Raval HM (2001) Synthesis of organic-inorganic hybrids via the non-hydrolytic sol-gel process. Chem Mater 13: 3396–3403. doi: 10.1021/cm011024n
    [33] Lafond V, Mutin PH, Vioux A (2002) Non-hydrolytic sol-gel routes based on alkyl halide elimination: Toward better mixed oxide catalysts and new supports—Application to the preparation of a SiO2-TiO2 epoxidation catalyst. J Mol Cata A-Chem 182: 81–88.
    [34] Trentler TJ, Denler TE, Bertone JF, et al. (1999) Synthesis of TiO2 nanocrystals by nonhydrolytic solution-based reactions. J Am Chem Soc 121: 1613–1614. doi: 10.1021/ja983361b
    [35] Byrappa K, Adschiri T (2007) Hydrothermal technology for nanotechnology. Prog Cryst Growth Ch 53: 117–166. doi: 10.1016/j.pcrysgrow.2007.04.001
    [36] Andersson M, Österlund L, Ljungström S, et al. (2002) Preparation of nanosize anatase and rutile TiO2 by hydrothermal treatment of microemulsions and their activity for photocatalytic wet oxidation of phenol. J Phys Chem B 106: 10674–10679. doi: 10.1021/jp025715y
    [37] Yong CS, Park MK, Lee SK, et al. (2003) Preparation of size-controlled TiO2 nanoparticles and derivation of optically transparent photocatalytic films. Chem Mater 15: 3326–3331. doi: 10.1021/cm030171d
    [38] Cot F, Larbot A, Nabias G (1998) Preparation and characterization of colloidal solution derived crytalline titania powder. J Euro Ceram Soc 18: 2175–2181. doi: 10.1016/S0955-2219(98)00143-5
    [39] Yang J, Mei S, Ferreira JMF (2000) Hydrothermal synthesis of nanosized titania powders: influence of peptization and peptizing agents on the crystalline phases and phase transitions. J Am Ceram Soc 83: 1361–1268. doi: 10.1111/j.1151-2916.2000.tb01394.x
    [40] Yang J, Mei S, Ferreira JMF (2001) Hydrothermal synthesis of nanosized titania powders: Influence of tetraalkyl ammonium hydroxide on particle characteristics. J Am Ceram Soc 84: 1696–1702.
    [41] Yang J, Di L (2002) Rapid synthesis of nanocrystalline TiO2/SnO2 binary oxide and their photoinduced decompositopn of methyl orange. J Solid State Chem 165: 193–198. doi: 10.1006/jssc.2001.9526
    [42] Yang TY, Lin HM, Wei BY, et al. (2003) UV enhancement of the gas sensing properties of nano-TiO2. Rev Adv Mater Sci 4: 48–54.
    [43] Liveri VT (2002) Reversed micelles as nanometer-size solvent media. In Nano-Surface Chemistry. Rosoff M, Ed. Marcel Dekker: New York, 473–385.
    [44] Zhang D, Limin Q, Jiming M, et al. (2002) Formation of crystalline nanosized titania in reverse micelles at room temperature. J Mater Chem 12: 3677–3680. doi: 10.1039/b206996b
    [45] Hong SS, LeeSL, Lee GD (2003) Photocatalytic degradation of p-Nitrophenol over Titanium dioxide prepared by reverse microemulsion method using non-ionic suefactant with different hydrophpsilic groups. React Kinet Cat Lett 80: 145–151.
    [46] Kim KD, Kim TH (2005) Comparison of the growth mechanism of TiO2-coated SiO2 particles prepared by Sol-gel process and water-in-oil type microemulsion method. Colloid Surface A 255: 131–137. doi: 10.1016/j.colsurfa.2004.12.036
    [47] Li GL, Wang GH (1999) Synthesis of nanometer-sized TiO2 particles by a microemulsion method. Nanostruct Mater 11: 663–668.
    [48] Li Y, Cureton LT, Sun YP (2004) Improving photoreduction of CO2 with homogeneously dispersed nanoscale TiO2 catalysts. Chem Commun 2004: 1234–1235.
    [49] Chen X, Mao SS (2007) Titanium dioxide nanomaterials:? Synthesis, properties modifications, and applications. Chem Rev 107: 2891–2959.
    [50] Lim KT, Ha SH (2004) Synthesis of TiO2 nanoparticles utilizing hydrated reverse micelles in CO2. Langmuir 20: 2466–2471. doi: 10.1021/la035646u
    [51] Yu JC, Zhang L, Yu J (2002) Direct sonochemical preparation and characterization of highly active mesoporous TiO2 with a bicrystalline framework. Chem Mater 14: 4647–4653. doi: 10.1021/cm0203924
    [52] Li XL, Peng Q, Yi JX, et al. (2006) Near monodisperse TiO2 nanoparticles and nanorods. Chem A Euro J 12: 2111–2395. doi: 10.1002/chem.200690023
    [53] Xu J, Ao Y, Fu D, et al. (2008) Synthesis of fluorinedoped titania-coated activated carbon under low temperature with high photocatalytic activity under visible light. J Phys Chem Sol 69: 2366–2370. doi: 10.1016/j.jpcs.2008.03.017
    [54] Wang X, Zhuang J, Peng Q, et al. (2005) A general strategy for nanocrystal synthesis. Nature 437: 121–124. doi: 10.1038/nature03968
    [55] Krishna KM, Paii VA, Marathe VR, et al. (1990) Atheoretical approach to design of reduced band gap non corrosive electrode for photoelectrochemical solar cell. Int J Quantum Chem 24: 419–427.
    [56] Sharon M, Krishna KM, Mishra MK, et al. (1992) Theoretical investigation of optimal mixing ratio for PbO2 and TiO2 to produce a low band gap noncorrosive photoelectrode. J Chem Phys 163: 401–412.
    [57] Krishna KM, Sharon M, Mishra MK (1995) Preparation and characterization of a PbTiO3 + PbO mixed oxide photoelectrode. J Electroanalytic Chem 391: 93–99. doi: 10.1016/0022-0728(95)03905-V
    [58] Sharon M, Krishna KM, Mishra MK (1996) Preparation and characterization of mixed oxides obtained from various molar mixtures of beta-PbO2 and TiO2. J Phys Chem Solids 57: 615–626. doi: 10.1016/0022-3697(95)00272-3
    [59] Sharon M, Krishna KM, Mishra MK (1996) Pb1?xTixO: a new photoactive phase. J Mater Sci Lett 15: 1084–1087.
    [60] Wei XX, Cui H, Guo S, et al. (2013) Hybrid BiOBr-TiO2 nanocomposites with high visible lightphotocatalytic activity for water treatment. J Hazard Mater 263: 650–658. doi: 10.1016/j.jhazmat.2013.10.027
    [61] Chakraborty AK, Hossain ME, Rhaman MM, et al. (2014) Fabrication of Bi2O3/TiO2 nanocomposites and their applications to the degradation of pollutants in air and water under visible-light. J Environ Sci 26: 458–465. doi: 10.1016/S1001-0742(13)60428-3
    [62] Khan B, Ashraf U (2015) Sol-gel synthesis and characterization of nanocomposites of Cu/TiO2 and Bi/TiO2 metal oxides as photocatalysts. Int J Sci Technol 4: 40–48.
    [63] Dresselhaus MS, Dresselhaus G (2001) Carbon nanotubes: Synthesis, Structure, Properties and Applications: Topics in Applied Physics, Springer-Verlag. ISBN 3-54041-086-4, Berlin.
    [64] Saleh TA, Gupta VK (2011) Functionalization of tungsten oxide into MWCNT and its application for sunlight-induced degradation of rhodamine B. J Colloid Interface Sci 362: 337–344. doi: 10.1016/j.jcis.2011.06.081
    [65] Yu JC, Zhang L, Zheng Z, et al. (2003) Synthesis and characterization of phosphate mesoporous Titanium dioxide with high photocatalytic activity. Chem Mater 15: 2280–2286. doi: 10.1021/cm0340781
    [66] Lin L, Lin W, Zhu YX, et al. (2005)Phosphor-doped titania—a novel photocatalyst active in visible light. Chem Lett 34: 284–285.
    [67] Korosi L, Oszko A, Galbacs G, et al. (2007) Structural properties and photocatalytic behavior of phosphate-modified nanocrystalline titania films. Appl Catal B 77: 175–183. doi: 10.1016/j.apcatb.2007.07.019
    [68] Lin L, Lin W, Xie JL, et al. (2007) Photocatalytic properties of phosphor-doped titania nanoparticles. Appl Catal B 75: 52–58. doi: 10.1016/j.apcatb.2007.03.016
    [69] Jin C, Zheng RY, Guo Y, et al. (2009) Hydrothermal synthesis and characterization of phosphorous-doped TiO2 with high photocatalytic activity for methylene blue degradation. J Mol Catal A 313: 44–48. doi: 10.1016/j.molcata.2009.07.021
    [70] Wang S, Zhou S (2011) Photodegradation of methyl orange by photocatalyst of CNTs/P-TiO2 under UV and visible-light irradiation. J Hazard Mater 185: 77–85. doi: 10.1016/j.jhazmat.2010.08.125
    [71] Sharon M, Datta S, Shah S, et al. (2007) Photocatalytic degradation of E. coli and S. aureus by multi walled carbon nanotubes. Carbon Letts 8: 184–190.
    [72] Oza G, Pandey S, Gupta A, et al. (2013) Photocatalysis-assisted water filtration: Using TiO2-coated vertically aligned multi-walled carbon nanotube array for removal of Escherichia coli O157:H7. Mater Sci Eng C-Mater 33: 4392–4400.
    [73] Cong Y, Li X, Qin Y, et al. (2011) Carbon-doped TiO2 coating on multiwalled carbon nanotubes with higher visible light photocatalytic activity. Appl Catal B-Environ 107: 128–134.
    [74] Mamba G, Mbianda XY, Mishra AK (2014) Gadolinium nanoparticles decorated multiwalled carbon nanotube/titania nanocomposite for degradation of methylene blue in water under simulated solar light. Environ Sci Pollut Res 21: 5597–5609.
    [75] Mamba G, Mbianda XY, Mishra AK (2015) Photocatalytic degradation of diazo dye naphthol blue black in water using MWCNT/Gd, N, S-TiO2 nanocomposite under simulated solar light. J Environ Sci 33: 219–228. doi: 10.1016/j.jes.2014.06.052
    [76] Czech B, Buda W (2015) Photocatalytic treatment of pharmaceutical wastewater using new multiwall-carbon nanotubes/TiO2/SiO2 nanocomposite. Environ Res 137: 176–184. doi: 10.1016/j.envres.2014.12.006
    [77] Ptrovic M, Radjenovic J, Postigo C, et al. (2008) Emerging contaminants in waste waters: sources and occurrence. In: Barcello D, Ptrovic M, Eds. Emerging contaminants from Industrial and Municipal Waste. Springer, Berlin, Heidelberg, 1–35.
    [78] Gadipelly C, Perez-Gonzalez A, Yadav GD, et al. (2014) Pharmaceutical industry waste water—reviews of the technology for water treatment and re-use. Ind Eng Chem Res 53: 11571–11592. doi: 10.1021/ie501210j
    [79] Krishamoorthy K, Mohan R, Kim SJ (2001) Graphene oxide as photocatalytic material. Appl Phys Lett 98: 244101–114312.
    [80] Stengl V, Bakardjieva S, Gryger TM, et al. (2013) TiO2-graphene oxide nanocompositeas advanced photocatalytic materials. Chem Central J 7: 41–53.
    [81] Zhang Y, Zhou Z, Chen T, et al. (2014) Graphene TiO2 nanocomposite with high photocatalytic activity for degradation of sodium pentachlorophenol. J Environ Sci 26: 2114–2122. doi: 10.1016/j.jes.2014.08.011
    [82] Stein A (2003) Advances in microporous and mesoporous solids—Highlights of recent progress. Adv Mater 15: 763–775. doi: 10.1002/adma.200300007
    [83] Stein A, Melde BJ, Schroden RC (2003) Hybrid inorganic-organic mesoporous silicates—nanoscopic reactors coming of age. Adv Mater 12: 1403–1419.
    [84] Inumaru K, Kasahara T, Yasui M, et al. (2005) Direct nanocomposite of crystallite TiO2 particles and mesoporous silica as a molecular selective and highly active photocatalyst. Chem Commun 2005: 2131–2133.
    [85] Mohseni A, Malekina L, Fazaeli R, et al. (2013) Synthesis TiO2/SiO2/Ag nanocomposite by sonochemical method and investigation of photo-catalyst effect in waste water treatment. Nanocon 10: 16–18.
    [86] Li K, Huang C (2000) Selective oxidation of Hydrogen Sulfide to sulphur over LaVO4 catalyst: Promotional effect of Antimony oxide addition. Ind Eng Chem Res 45: 7096–7100.
    [87] Ye JH, Zhou ZG, Oshikiri M, et al. (2003) New visible light driven semiconductor photocatalyst and their application as functional eco-material. Mater Sci Forum 423: 825–830.
    [88] Huang H, Li D, Lin Q, et al. (2009) Efficient degradation of Benzene over LaVO4/TiO2 nano-crystalline heterojunction photocatalyst under visible light irradiation. Envron Sci Technol 43: 4164–4168. doi: 10.1021/es900393h
    [89] Visa M, Duta A (2013) Methyl orange and Cadmium simultaneous removal using fly ash and Photo-Fenton system. J Hazard Mater 244–245: 773–779.
    [90] Visa M (2012) Tailoring fly ash activated with bentonite as adsorbent for complex waste water treatment. Appl Surf Sci 263: 753–762. doi: 10.1016/j.apsusc.2012.09.156
    [91] Visa M, Andronic L, Duta A (2015) Fly ash-TiO2 nanocomposite material for multi-pollutants water treatment. J Environ Manage 150: 336–343.
    [92] Kaplan R, Erjavec B, Drazic G, et al. (2016) Simple synthesis of Anatase/rutile/brookite TiO2 nanocomposite with superior mineralization potential for photocatalytic degradation of water pollutants. Appl Catal B-Environ 181: 465–474. doi: 10.1016/j.apcatb.2015.08.027
    [93] Yu J, Qi L (2009) Template free fabrication of hierarchically flower like tungsten tri oxide assemblies with enhanced visible-light-driven photocatalytic activity. J Hazard Mater 169: 221–227.
    [94] Vicaksana Y, Liu S, Scott J, et al. (2014) Tungsten trioxide as a visible light photocatalyst for volatile organic carbon removal. Molecules 19: 17747–17762. doi: 10.3390/molecules191117747
    [95] Sajjad AKL, Sajjad S, Tian B, et al. (2010) Comparative studies of operational parameters of degradation of azo-dyes in visible light by highly efficient WOx/TiO2 photocatalyst. J Hazard Mater 177: 781–791.
    [96] Zhao G, Jr SES (1998) Multiple parameters for the comprehensive evaluation of the susceptibility of Escherichia coli to the silver ion. Biometals 11: 27–32. doi: 10.1023/A:1009253223055
    [97] Yamanaka M, Hara K, Kudo J (2005) Bactericidal actions of a Silver ion solution on Escherichia coli, studied by Energy-Filtering Transmission Electron Microscopy and Proteomic Analysis. Appl Environ Microb 71: 7589–7593. doi: 10.1128/AEM.71.11.7589-7593.2005
    [98] Jung WK, Koo HC, Kim KW, et al. (2008) Antibacterial activity and mechanism of action of the silver ion in Staphylococcus aureus and Escherichia coli. Appl Environ Microb 74: 2171–2178. doi: 10.1128/AEM.02001-07
    [99] Liu SX, Qu ZP, Han WX, et al. (2004) A mechanism for enhanced photocatalytic activity of silver loaded titania dioxide. Catal Today 93–95: 877–884.
    [100] Akhavan O (2009) Lasting antibacterial activities of Ag-TiO2/Ag/a-TiO2 nanocomposite thin film photocatalysts under solar light irradiation. J Colloid Interf Sci 336: 117–124. doi: 10.1016/j.jcis.2009.03.018
    [101] Xiang Q, Yu J, Cheng B, et al. (2010) Microwave hydrothermal preparation of Visible-light photocatalytic activity of Ag-TiO2 nanocomposite hollow sphere. Chem Asian J 5: 1466–1474.
  • This article has been cited by:

    1. Hongan Li, Guanyi Wang, Qiaozhi Hua, Zheng Wen, Zhanli Li, Ting Lei, An image watermark removal method for secure internet of things applications based on federated learning, 2022, 0266-4720, 10.1111/exsy.13036
    2. Hong-an Li, Guanyi Wang, Kun Gao, Haipeng Li, A Gated Convolution and Self-Attention-Based Pyramid Image Inpainting Network, 2022, 31, 0218-1266, 10.1142/S0218126622502085
    3. Peng Zhao, Yongxin Zhang, Qiaozhi Hua, Haipeng Li, Zheng Wen, Bio-Inspired Optimal Dispatching of Wind Power Consumption Considering Multi-Time Scale Demand Response and High-Energy Load Participation, 2023, 134, 1526-1506, 957, 10.32604/cmes.2022.021783
    4. Hong’an Li, Min Zhang, Dufeng Chen, Jing Zhang, Meng Yang, Zhanli Li, Image Color Rendering Based on Hinge-Cross-Entropy GAN in Internet of Medical Things, 2023, 135, 1526-1506, 779, 10.32604/cmes.2022.022369
    5. Xiaonan Shi, Jian Huang, Bo Huang, An Underground Abnormal Behavior Recognition Method Based on an Optimized Alphapose-ST-GCN, 2022, 31, 0218-1266, 10.1142/S0218126622502140
    6. Zhi-Hua zhao, Li Chen, Bifurcation Fusion Network for RGB-D Salient Object Detection, 2022, 31, 0218-1266, 10.1142/S0218126622502152
    7. Hong-an Li, Liuqing Hu, Qiaozhi Hua, Meng Yang, Xinpeng Li, Image Inpainting Based on Contextual Coherent Attention GAN, 2022, 31, 0218-1266, 10.1142/S0218126622502097
    8. Mei Gao, Baosheng Kang, Blind Image Inpainting Using Low-Dimensional Manifold Regularization, 2022, 31, 0218-1266, 10.1142/S0218126622502115
    9. Qianqian Liu, Xiaoyan Zhang, Qiaozhi Hua, Zheng Wen, Haipeng Li, Yan Huo, Adaptive Differential Evolution Algorithm with Simulated Annealing for Security of IoT Ecosystems, 2022, 2022, 1530-8677, 1, 10.1155/2022/6951849
    10. Hong’an Li, Jiangwen Fan, Qiaozhi Hua, Xinpeng Li, Zheng Wen, Meng Yang, Biomedical sensor image segmentation algorithm based on improved fully convolutional network, 2022, 197, 02632241, 111307, 10.1016/j.measurement.2022.111307
    11. Youzhong Ma, Qiaozhi Hua, Zheng Wen, Ruiling Zhang, Yongxin Zhang, Haipeng Li, Thippa Reddy G, k Nearest Neighbor Similarity Join Algorithm on High-Dimensional Data Using Novel Partitioning Strategy, 2022, 2022, 1939-0122, 1, 10.1155/2022/1249393
    12. Wenchao Ren, Liangfu Li, Shiyi Wen, Lingmei Ai, APE-GAN: A colorization method for focal areas of infrared images guided by an improved attention mask mechanism, 2024, 124, 00978493, 104086, 10.1016/j.cag.2024.104086
    13. Thavavel Vaiyapuri, Jaiganesh Mahalingam, Sultan Ahmad, Hikmat A. M. Abdeljaber, Eunmok Yang, Soo-Yong Jeong, Ensemble Learning Driven Computer-Aided Diagnosis Model for Brain Tumor Classification on Magnetic Resonance Imaging, 2023, 11, 2169-3536, 91398, 10.1109/ACCESS.2023.3306961
    14. Samarth Deshpande, Siddhi Deshmukh, Atharva Deshpande, Devyani Manmode, Sakshi Dhamne, Abha Marathe, 2023, Pseudo Coloring Using Deep Learning Approach, 979-8-3503-4805-7, 218, 10.1109/ICAECIS58353.2023.10170408
    15. Ali Salim Rasheed, Marwa Jabberi, Tarek M. Hamdani, Adel M. Alimi, PIXGAN-Drone: 3D Avatar of Human Body Reconstruction From Multi-View 2D Images, 2024, 12, 2169-3536, 74762, 10.1109/ACCESS.2024.3404554
    16. Mamoona Jamil, Mubashar Sarfraz, Sajjad A. Ghauri, Muhammad Asghar Khan, Mohamed Marey, Khaled Mohamad Almustafa, Hala Mostafa, Optimized Classification of Intelligent Reflecting Surface (IRS)-Enabled GEO Satellite Signals, 2023, 23, 1424-8220, 4173, 10.3390/s23084173
    17. Muhammad Asif Khan, Hamid Menouar, Ridha Hamila, 2023, Crowd Counting in Harsh Weather using Image Denoising with Pix2Pix GANs, 979-8-3503-7051-5, 1, 10.1109/IVCNZ61134.2023.10343548
    18. Huda F. AL-Shahad, Razali Yaakob, Nurfadhlina Mohd Sharef, Hazlina Hamdan, Hasyma Abu Hassan, An Improved Pix2pix Generative Adversarial Network Model to Enhance Thyroid Nodule Segmentation, 2025, 16, 17982340, 37, 10.12720/jait.16.1.37-48
    19. Qizhi Zou, Binghua Wang, Zhaofei Jiang, Qian Wu, Jian Liu, Xinting Ji, Dynamic style transfer for interior design: An IoT-driven approach with DMV-CycleNet, 2025, 117, 11100168, 662, 10.1016/j.aej.2024.12.030
    20. Alvan Reyhanza Vittorino, Giovanus Immanuel, Simeon Yuda Prasetyo, Eko Setyo Purwanto, 2024, Machine Learning Approaches for Diabetic Retinopathy Classification Utilizing Gabor, LBP, and HOG Feature Extraction, 979-8-3315-0857-9, 697, 10.1109/BTS-I2C63534.2024.10942171
  • Reader Comments
  • © 2016 the Author(s), licensee AIMS Press. This is an open access article distributed under the terms of the Creative Commons Attribution License (http://creativecommons.org/licenses/by/4.0)
通讯作者: 陈斌, bchen63@163.com
  • 1. 

    沈阳化工大学材料科学与工程学院 沈阳 110142

  1. 本站搜索
  2. 百度学术搜索
  3. 万方数据库搜索
  4. CNKI搜索

Metrics

Article views(9856) PDF downloads(1827) Cited by(29)

Other Articles By Authors

/

DownLoad:  Full-Size Img  PowerPoint
Return
Return

Catalog