Research article Special Issues

Particulate matter levels and comfort conditions in the trains and platforms of the Athens underground metro

  • A study of indoor environmental quality inside the old (naturally ventilated) and new (air-conditioned) train cabins and platforms of four main stations of the Athens subway system (Attiko Metro), took place in different two-day measurements from June to August 2012. Portable instrumentation provided continuous measurements of particulate matter (PM10, PM2.5 and PM1), carbon dioxide (CO2) along with temperature (T) and absolute humidity (AH). PM concentrations were significantly higher on the underground platforms of the network from 3 to 10 times, as compared to outdoor measurements. In particular, mean PM1, PM2.5 and PM10 concentrations at the deeper and most crowded station of Syntagma reached 18.7, 88.1 and 320.8 μg m−3 respectively. On the contrary, the ground level, open station of the Airport, showed values comparable to the outdoor (2, 6.4 and 34.4 μg m−3, respectively). All PM fractions were lower than the platforms inside the old and new train cabins while the air conditioned trains experienced lower particulate pollution levels. More specifically, mean PM1, PM2.5 and PM10 concentrations were 5.5, 16.8 and 58.3 μg m−3, respectively in new cabins while in the old they reached 10.3, 47.5 and 238.8 μg m−3. The PM2.5/PM10 and PM1/PM2.5 ratios did not exceed 0.33 on both platforms and trains verifying the dominance of crustal coarse particles originating from the train and ground materials. As expected CO2 levels were higher inside the trains as compared to the platforms and in some cases surpassed the 1000 ppm limit during the hottest days of the experimental campaign. Temperature and humidity remained relatively stable on the platforms, whereas measurements inside the cabins fluctuated, depending on the type of train and track locations. Correlations between measured PM along the routes to and from the Airport indicated covariance of concentrations along train cabins of the same direction.

    Citation: Nikolaos Barmparesos, Vasiliki D. Assimakopoulos, Margarita Niki Assimakopoulos, Evangelia Tsairidi. Particulate matter levels and comfort conditions in the trains and platforms of the Athens underground metro[J]. AIMS Environmental Science, 2016, 3(2): 199-219. doi: 10.3934/environsci.2016.2.199

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  • A study of indoor environmental quality inside the old (naturally ventilated) and new (air-conditioned) train cabins and platforms of four main stations of the Athens subway system (Attiko Metro), took place in different two-day measurements from June to August 2012. Portable instrumentation provided continuous measurements of particulate matter (PM10, PM2.5 and PM1), carbon dioxide (CO2) along with temperature (T) and absolute humidity (AH). PM concentrations were significantly higher on the underground platforms of the network from 3 to 10 times, as compared to outdoor measurements. In particular, mean PM1, PM2.5 and PM10 concentrations at the deeper and most crowded station of Syntagma reached 18.7, 88.1 and 320.8 μg m−3 respectively. On the contrary, the ground level, open station of the Airport, showed values comparable to the outdoor (2, 6.4 and 34.4 μg m−3, respectively). All PM fractions were lower than the platforms inside the old and new train cabins while the air conditioned trains experienced lower particulate pollution levels. More specifically, mean PM1, PM2.5 and PM10 concentrations were 5.5, 16.8 and 58.3 μg m−3, respectively in new cabins while in the old they reached 10.3, 47.5 and 238.8 μg m−3. The PM2.5/PM10 and PM1/PM2.5 ratios did not exceed 0.33 on both platforms and trains verifying the dominance of crustal coarse particles originating from the train and ground materials. As expected CO2 levels were higher inside the trains as compared to the platforms and in some cases surpassed the 1000 ppm limit during the hottest days of the experimental campaign. Temperature and humidity remained relatively stable on the platforms, whereas measurements inside the cabins fluctuated, depending on the type of train and track locations. Correlations between measured PM along the routes to and from the Airport indicated covariance of concentrations along train cabins of the same direction.


    In mathematics chemistry and biology, a chemical compound can be represented by a molecular graph by converting atoms to vertices and bonds to edges. One of the primary mission of QSAR/QSPR research is to accurately convert molecular graphs into numerical values. Graph theoretic invariants of molecular graphs are called molecular descriptors which can be utilized to simulate the structural information of molecules, in order to make worthwhile physical and chemical properties of these molecules can be acquired by single numerical values. Such kinds of molecular descriptors are also referred to as topological indices.

    In the chemical literature, various topological indices relying only on vertex degrees of the molecular graphs can be utilized in QSPR/QSAR investigation on account of them can be obtained directly from the molecular architecture, and can be rapidly calculated for generous molecules (see [1,2]), and we call them VDB (vertex–degree–based) topological indices. To be more precise, for designated nonnegative real numbers $ \{\psi_{ij}\} $ $ (1\leq i\leq j\leq n-1) $, a VDB topological index of a an $ n $-order (molecular) graph $ G $ is expressed as

    $ TI(G)=1ijn1mijψij,
    $
    (1.1)

    where $ m_{ij} $ is the amount of edges connecting an $ i $-vertex and a $ j $-vertex of $ G $. A great deal of well–known VDB topological indices can be obtained by different $ \psi_{ij} $ in expression (1.1). We list some VDB topological indices in Table 1.

    Table 1.  Some well-known VDB topological indices.
    $ \psi_{ij} $ name
    $ i+j $ First Zagreb index
    $ \frac{1}{\sqrt{ij}} $ Randić index
    $ \frac{2\sqrt{ij}}{i+j} $ GA index
    $ \sqrt{\frac{i+j-2}{ij}} $ ABC index
    $ \frac{1}{\sqrt{i+j}} $ Sum–connectivity index
    $ \frac{(ij)^{3}}{(i+j-2)^{3}} $ AZI index
    $ \frac{2}{i+j} $ Harmonic index
    $ |i-j| $ Albertson index
    $ \sqrt{i^{2}+j^{2}} $ Sombor index
    $ \frac{ij}{i+j} $ ISI index

     | Show Table
    DownLoad: CSV

    The first Zagreb index [3] is the very first VDB topological index, as powerful molecular structure-descriptors [2], Zagreb indices can describe the peculiarities of the degree of branching in molecular carbon-atom skeleton. Thereafter, many VDB topological indices have been put forward to simulate physical, chemical, biological, and other attributes of molecules [4,5,6,7]. In 2021, Gutman [8] introduced a new VDB topological index named as the Sombor index which has a linear correlation with the entropy and the enthalpy of vaporization of octanes [9]. Das et al., give sharp bounds for Sombor index of graphs by means of some useful graph parameters and they reveal the relationships between the Sombor index and Zagreb indices of graphs [10]. Recently, Steiner Gutman index was introduced by Mao and Das [11] which incorporate Steiner distance of a connected graph $ G $. Nordhaus-Gaddum-type results for the Steiner Gutman index of graphs were given in [12]. In 2022, Shang study the Sombor index and degree-related properties of simplicial networks [13]. For more details of VDB topological indices, one can see [3,14,15,16,17,18,19,20,21,22,23,24,25,26] and the books [27,28,29].

    Fluoranthene is a eminent conjugated hydrocarbon which abound in coal tar [30]. A fluoranthene–type benzenoid system (f-benzenoid for short) is formed from two benzenoid units joined by a pentagon [31,32]. The ordinary structure modality of a f-benzenoid $ F $ is shown in Figure 1, where segments $ X $ and $ Y $ are two benzenoid systems. Each f-benzenoid possesses exactly one pentagon [32]. More and more attention is paid to f-benzenoids after the flash vacuum pyrolysis experiments of these nonalternant polycyclic aromatic hydrocarbons [33].

    Figure 1.  The ordinary structure modality of a f-benzenoid (F) and its construction from two benzenoid systems $ X $ and $ Y $.

    In the whole article, the terminology and notation are chiefly derived from [34,35,36,37,38,39,40,41]. A vertex of degree $ k $ is called a $ k $-vertex, and an edge linking a $ k $-vertex and a $ j $-vertex is designated as a $ (k, j) $-edge. Let $ n_{k} $ be the number of $ k $-vertices and let $ m_{kj} $ be the number of $ (k, j) $-edges in the molecular graph $ G $. A benzenoid system without internal vertices is said to be catacondensed. Analogously, a f-benzenoid $ F $ containing a unique internal vertex is referred to as catacatacondensed. We use $ h $-hexagon benzenoid system (or $ h $-hexagon f-benzenoid) to represent a benzenoid system (or f-benzenoid) containing $ h $ hexagons.

    Let $ L_{h} $ represent the $ h $-hexagon linear chain (as shown in Figure 2(a)). An f-benzenoid $ FL_{h} $ $ (h\geq3) $ obtaining from pieces $ X = L_{2} $ and $ Y = L_{h-2} $ is named as f-linear chain (as shown in Figure 2(b)).

    Figure 2.  Linear chain and f-linear chain.

    A fissure (resp. bay, cove, fjord and lagoon) of a f-benzenoid $ F $ is a path of degree sequences $ (2, 3, 2) $ (resp. $ (2, 3, 3, 2) $, $ (2, 3, 3, 3, 2) $, $ (2, 3, 3, 3, 3, 2) $ and $ (2, 3, 3, 3, 3, 3, 2) $) on the perimeter of $ F $ (see Figure 3). Fissures, bays, coves, fjords and lagoons are said to be different kinds of inlets and their number are signified by $ f $, $ B $, $ C $, $ F_{j} $ and $ L $, respectively [32,37]. Inlets determine many electronic and topological properties of f-benzenoids. Then, it can be found that $ f+2B+3C+4F_{J}+5L $ is the number of $ 3 $-vertices on the perimeter of $ F $. It is noted that lagoons cannot occur in the theory of benzenoid systems. For convenience, let $ r = f+B+C+F_{j}+L $ to represent the total number of inlets and $ b = B+2C+3F_{j}+4L $ is referred to as the quantity of bay regions, In addition, $ b $ is exactly the quantity of $ (3, 3) $-edges on the perimeter of $ F $. It is obvious that $ b\geq2 $ for any f-benzenoid $ F $.

    Figure 3.  Structural features occurring on the perimeter of f-benzenoids.

    It is noted that any f-benzenoid $ F $ contains merely either $ 2 $-vertex or $ 3 $-vertex. The vertices not on the perimeter are said to be internal, and we use $ n_{i} $ to represent their number.

    Lemma 1.1. [32] Let $ F $ be an $ n $-order, $ h $-hexagon f-benzenoid with $ m $ edges and $ n_{i} $ internal vertices. Then

    $ {\rm (i)} $ $ n = 4h+5-n_{i} $;

    $ {\rm (ii)} $ $ m = 5h+5-n_{i} $.

    Lemma 1.2. [32] Let $ F $ be an $ n $-order and $ h $-hexagon f-benzenoid with $ r $ inlets, Then

    $ {\rm (i)} $ $ m_{22} = n-2h-r $;

    $ {\rm (ii)} $ $ m_{23} = 2r $;

    $ {\rm (iii)} $ $ m_{33} = 3h-r $.

    From the perspective of mathematics and chemistry, finding the extremal values of some useful $ TI $ for significant classes of graphs is very interesting [14,19,23,40,41,42,43,44,45,46,47,48,49,50,51,52,53,54,55,56].

    As a matter of convenience, we use $ \Gamma_{m} $ to represent the collection of f-benzenoids containing exactly $ m $ edges. In [45], we derived extremal values for $ TI $ among all f-benzenoids with given order. It is noted that structure of f-benzenoids with given order is different from that of f-benzenoids with given number of edges. And we found that the technique for studying $ TI $ among all f-benzenoids with given order can not be used directly to investigate $ TI $ for all f-benzenoids with fixed number of edges. For this reason, we concentrate on the research of extremal values for $ TI $ among all f-benzenoids with given size.

    The main idea of this work is to construct f-benzenoids owning maximal $ r $ and minimal $ h $ at the same time in $ \Gamma_{m} $ depending on the number $ m $ is congruent to $ 0, 1, 2, 3 $ or $ 4 $ modulo $ 5 $. By making use of this technique, we obtain the extremum of $ TI $ over $ \Gamma_{m} $ and characterize their corresponding graphs on the basis of $ m $ is congruent to $ 0, 1, 2, 3 $ or $ 4 $ modulo $ 5 $. Afterwards the extremums of some well-known $ TI $ over $ \Gamma_{m} $ can be got by use of the previous results.

    The structure of this paper is as below. We first determine the maximal $ r $ in the set $ \Gamma_{m} $ in Section 2. By utilizing these results, we find the extremum of several famed $ TI $ over $ \Gamma_{m} $ in Section 3.

    We will find the f-benzenoids with maximal $ r $ in $ \Gamma_{m} $ in this section. Figure 4 illustrates three f-benzenoids pertaining to $ \Gamma_{42} $.

    Figure 4.  Some f-benzenoids in $ \Gamma_{42} $.

    At first, we try to obtain the maximum and minimum number of hexagons in any $ F\in\Gamma_{m} $.

    The spiral benzenoid system [57] $ T_{h} $ is a benzenoid system whose structure is in a "spiral" manner as illustrated in Figure 5. $ T_{h} $ has maximal $ n_{i} $ in all $ h $-hexagon benzenoid systems.

    Figure 5.  The spiral benzenoid system $ T_{h} $ with maximal number of internal vertices.

    As a matter of convenience, let $ SH_{h} $ $ (h\geq3) $ represent the collection of f-benzenoids formed by two spiral benzenoids $ X $ and $ Y $. Particularly, a f-spiral benzenoid is a f-benzenoid $ F^{\ast}\in SH_{h} $ in which $ X = T_{h-1} $ and $ Y = T_{1} $ (as shown in Figure 6). It is easy to see that that

    $ n_{i}(F^{\ast}) = 2h-\lceil\sqrt{12(h-1)-3}\rceil. $
    Figure 6.  f-benzenoid $ F'\in SH_{h} $ whose two pieces $ X $ and $ Y $ are both spiral benzenoid systems, and f-spiral benzenoid $ F^{\ast}\in SH_{h} $ with two pieces $ X = T_{h-1} $ and $ Y = T_{1} $.

    In [40], we proved that for every $ F'\in SH_{h} $ $ (h\geq3) $, the inequality

    $ ni(F)ni(F)
    $
    (2.1)

    holds, and the following graph operations were introduced.

    Operation 1. For any $ h $-hexagon f-benzenoid $ F $ having two segments $ X $ and $ Y $, let $ h_{1} = h(X) $ and $ h_{2} = h(Y) $. By substituting spiral benzenoid systems $ T_{h_{1}} $ and $ T_{h_{2}} $ for $ X $ and $ Y $, severally, another f-benzenoid $ F'\in SH_{h} $ can be obtained (as shown in Figure 7).

    Figure 7.  f-benzenoid $ F'\in SH_{h} $ is obtained from $ F $ by applying Operation 1 to it.

    For any $ h $-hexagon f-benzenoid $ F $, when $ h = 3 $, it is easily checked that

    $ ni(F)=1=2×312(31)3.
    $
    (2.2)

    When $ h\geq4 $, let $ h_{1} = h(X) $ and $ h_{2} = h(Y) $. Another $ F'\in SH_{h} $ (as shown in Figure 7) in which $ X = T_{h_{1}} $ and $ Y = T_{h_{2}} $ can be acquired by applying Operation 1 to $ F $. It is apparently that $ n_{i}(X)\leq n_{i}(T_{h_{1}}) $, $ n_{i}(Y)\leq n_{i}(T_{h_{2}}) $, therefore

    $ ni(F)=ni(X)+ni(Y)+1ni(Th1)+ni(Th2)+1=ni(F).
    $
    (2.3)

    So, the following Lemma can be deduced by Eqs (2.1) and (2.3).

    Lemma 2.1. [41] Let $ F $ be an $ h(h\geq3) $-hexagon f-benzenoid. Then

    $ ni(F)2h12(h1)3,
    $
    (2.4)

    and the equality is established when $ F $ is $ F^{\ast} $.

    For any $ F\in \Gamma_{m} $, $ h(F) $ over $ \Gamma_{m} $ is variable. Sharp bounds for $ h(F) $ in $ \Gamma_{m} $ is given below.

    Theorem 2.1. For any f-benzenoid $ F\in \Gamma_{m} $,

    $ 15(m4)h(F)m113(2m+4m31),
    $
    (2.5)

    where $ \lceil x\rceil $ is the smallest integer larger or equal to $ x $.

    Proof. On one hand, from Lemma 1.1 $ {\rm(ii)} $ we know that $ m = 5h(F)+5-n_{i}(F) $. Combining the fact that $ n_{i}(F)\geq1 $ for any $ F\in \Gamma_{m} $, we get

    $ h(F)\geq \left\lceil\frac{1}{5}(m-4)\right\rceil. $

    On the other hand, by Lemma 2.1 we know that $ n_{i}(F)\leq n_{i}(F^{\ast}) $. Consequently, from $ m = 5h(F)+5-n_{i}(F) $ we have

    $ m-3h(F)-5\geq\left\lceil\sqrt{12(h(F)-1)-3}\right\rceil\geq\sqrt{12(h(F)-1)-3}. $

    Hence,

    $ (3h(F)+(3-m))^{2}\geq4m-31. $

    Due to the fact that $ 3h(F)+(3-m) < 0 $, we deduce

    $ 3h(F)+(3-m)\leq-\sqrt{4m-31}, $

    i.e., $ h(F)\leq m-1-\left\lceil\frac{1}{3} \left(2m+\sqrt{4m-31}\right)\right\rceil. $

    Remark 1. Theorem 2.1 implies that f-spiral benzenoid $ F^{\ast} $ has the maximal number of hexagons over $ \Gamma_{m} $.

    For the sake of obtaining the extremum $ TI $ among all f-benzenoids in $ \Gamma_{m} $, we need to find the f-benzenoids $ F\in\Gamma_{m} $ possessing maximal $ r $.

    Recall that convex benzenoid systems (CBS for brevity) are a particular sort of benzenoid systems lack of bay regions [14]. Let $ \mathcal{HS}_{h} $ be the collection of benzenoid systems containing $ h $ hexagons.

    Lemma 2.2. [42] Let $ H\in \mathcal{HS}_{h} $. Under the below cases, $ H $ is definitely not a CBS:

    $ \rm (i) $ If $ h\geq4 $ and $ n_{i} = 1 $;

    $ \rm (ii) $ If $ h\geq5 $ and $ n_{i} = 2 $;

    $ \rm (iii) $ If $ h\geq6 $ and $ n_{i} = 3 $.

    Lemma 2.3. [52] Let $ H\in \mathcal{HS}_{h} $ such that $ n_{i}(H) = 4 $. Then $ H $ is bound to embody a subbenzenoid system given in Figure 8, there does not exist hexagons which are adjacent to fissures.

    Figure 8.  Benzenoid systems with 1, 2, 3 and 4 internal vertices, respectively.

    Lemma 2.4. Let $ S\in \mathcal{HS}_{h} $. If $ h\geq7 $ and $ n_{i}(S) = 4 $, then $ S $ is not a CBS.

    Proof. Let $ S $ be an $ h $ $ (h\geq7) $-hexagon benzenoid system, $ n_{i}(S) = 4 $, then by Lemma 2.3 $ S $ must contain one of the benzenoid systems of the form given in Figure 7. The proof is carried out in two cases.

    Case 1. If these four internal vertices form a path $ P_{4} $ or a $ K_{1,3} $, then $ S $ contains one of benzenoid systems $ (d) $–$ (f) $ in Figure 7 as its subbenzenoid systems. It is noted that $ h\geq7 $, by Lemma 2.2, it must not exist hexagons contiguous to the fissures, so, $ S $ has at least one hexagon contiguous to a $ (2, 2) $-edge, by means of such hexagons, it is succeeded in converting one of the fissures into a cove, bay or fjord. Hence, $ b(S)\geq1 $.

    Case 2. If these four internal vertices are not adjacent then $ S $ has possibility subbenzenoid systems as follows.

    1) There exist one type $ (a) $ and one type $ (c) $ benzenoid systems in $ S $;

    2) There exist two type $ (b) $ benzenoid systems in $ S $;

    3) There exist two type $ (a) $ and one type $ (b) $ benzenoid systems in $ S $.

    4) There exist four type $ (a) $ benzenoid systems in $ S $

    By Lemma 2.2, neither hexagons may be adjacent to the fissures in any of the cases indicated above. Since $ h\geq7 $, $ S $ has at least one hexagon contiguous to a $ (2, 2) $-edge, by means of such hexagons, it is succeeded in making one of the fissures become a cove, bay or fjord. Therefore, $ b(S)\geq1 $.

    The proof is completed.

    Lemma 2.5. [45] Let $ F $ be an $ h $-hexagon f-benzenoid. Then

    $ \rm 1) $ If $ n_{i} = 1 $, then $ r(F)\leq r(FL_{h}) = 2h-3\ (h\geq3) $;

    $ \rm 2) $ If $ n_{i} = 2 $, then $ r(F)\leq r(G_{h}) = 2h-4\ (h\geq4) $;

    $ \rm 3) $ If $ n_{i} = 3 $, then $ r(F)\leq r(R_{h}) = 2h-5\ (h\geq5) $;

    $ \rm 4) $ If $ n_{i} = 4 $, then $ r(F)\leq r(Z_{h}) = 2h-6\ (h\geq6) $.

    Next we find the f-benzenoids with maximal $ r $ in $ \Gamma_{m} $ with a fixed $ n_{i} $. Recall that $ M_{h} $, $ N_{h} $ and $ Q_{h} $ (see Figure 9) are benzenoid systems, and $ G_{h} $ (see Figure 10), $ R_{h} $ (see Figure 11), $ Z_{h} $ (see Figure 12) are f-benzenoids.

    Figure 9.  Three types of benzenoid systems.
    Figure 10.  f-benzenoids $ G_{4} $, and $ G_{h} $ $ (h\geq5) $.
    Figure 11.  f-benzenoids $ R_{5} $, and $ R_{h} $ $ (h\geq6) $.
    Figure 12.  f-benzenoids $ Z_{6} $, and $ Z_{h} $ $ (h\geq7) $.
    Figure 13.  f-benzenoids $ U_{7} $, and $ U_{h} $ $ (h\geq8) $.

    Lemma 2.6. [41] Let $ F $ be an $ h $-hexagon f-benzenoid. Then

    $ r(F)\leq r(FL_{h}) = 2h-3. $

    Lemma 2.7. [32] For any $ h $-hexagon f-benzenoid including $ n_{i} $ internal vertices and $ b $ bay regions, the number of $ (2, 2) $-edge and $ (2, 3) $-edge are $ m_{22} = b+5, m_{23} = 4h-2n_{i}-2b $, respectively.

    From Lemmas 1.2 $ {\rm(ii)} $ and 8, we get

    $ r=2hnib
    $
    (2.6)

    Furthermore, by Lemma 1.1 $ {\rm(ii)} $ and Eq (2.6), we deduce

    $ r=m3h5b
    $
    (2.7)

    Theorem 2.2. Let $ F $ be an $ h $-hexagon f-benzenoid. If $ n_{i} = 5 $, then $ r(F)\leq r(U_{h}) = 2h-7 $ $ (h\geq7) $.

    Proof. Let $ h _{1} = h(X) $ and $ h_{2} = h(Y) $, $ X $ and $ Y $ are two segments of $ F $. If $ n_{i} = 5 $, by the structure of f-benzenoid, equality $ n_{i}(X)+n_{i}(Y) = 4 $ holds, so, we have the following five cases.

    Case 1. $ n_{i}(X) = 1 $, $ n_{i}(Y) = 3 $, i.e., there exist one internal vertex and three internal vertices in $ X $ and $ Y $, respectively.

    Subcase 1.1. If $ h_{1} = 3 $, then $ X = M_{3} $.

    Subcase 1.1.1. If $ h_{2} = 5 $, i.e., $ Y = Q_{5} $, then $ F $ is the f-benzenoid $ D_{1} $, $ D_{2} $ or $ D_{3} $ (see Figure 14). It is clear that $ r(F) = r(D_{1}) = 8\leq 2h-7 $, $ r(F) = r(D_{2}) = 7\leq 2h-7 $ or $ r(F) = r(D_{3}) = 8\leq 2h-7 $.

    Figure 14.  f-benzenoids $ D_{1} $, $ D_{2} $, $ D_{3} $, $ D_{4} $ and $ D_{5} $.

    Subcase 1.1.2. If $ h_{2}\geq6 $, by Lemma 2.2 and the hypothesis that $ n_{i}(Y) = 3 $, $ Y $ is not a CBS, so $ b(Y)\geq1 $. Furthermore, $ b(F)\geq3 $, combining Eq (2.6) we obtain $ r = 2h-n_{i}-b\leq2h-8 < 2h-7 $.

    Subcase 1.2. If $ h_{1}\geq4 $, according to Lemma 2.2, $ X $ is definitely not a CBS, i.e., $ b(X)\geq1 $.

    Subcase 1.2.1. If $ h_{2} = 5 $, i.e., $ Y = Q_{5} $. It is clear that $ b(F)\geq4 $, then Eq (2.6) deduces $ r\leq2h-9 < 2h-7 $.

    Subcase 1.2.2. If $ h_{2}\geq6 $, $ Y $ is definitely not not a CBS according to Lemma 2.2, so, $ b(Y)\geq1 $. It is clear that $ b(F)\geq5 $, consequently from Eq (2.6) we obtain $ r\leq2h-10 < 2h-7 $.

    Case 2. $ n_{i}(X) = 3 $ and $ n_{i}(Y) = 1 $.

    Subcase 2.1. If $ h_{1} = 5 $, then $ X = Q_{5} $.

    Subcase 2.1.1. If $ h_{2} = 3 $, i.e., $ Y = M_{3} $, then $ F $ is the f-benzenoid $ D_{4} $, $ D_{5} $, $ D_{6} $ (see Figure 14), or $ D_{7} $ (as shown in Figure 15). $ r(F) = r(D_{4}) = 8\leq 2h-7 $, $ r(F) = r(D_{5}) = 7\leq 2h-7 $, $ r(F) = r(D_{6}) = 8\leq 2h-7 $, $ r(F) = r(D_{7}) = 7\leq 2h-7 $.

    Figure 15.  f-benzenoids $ D_{7} $, $ D_{8} $ and $ D_{9} $.

    Subcase 2.1.2. If $ h_{2}\geq4 $, $ Y $ is surely not a CBS in light of Lemma 2.2, i.e., $ b(X)\geq1 $. Hence, we have $ b(F)\geq4 $, it follows from Eq (2.6) that $ r\leq2h-9 < 2h-7 $.

    Subcase 2.2. If $ h_{1}\geq6 $, by Lemma 2.2, $ X $ is definitely not a CBS, hence $ b(X)\geq1 $.

    Subcase 2.2.1. If $ h_{2} = 3 $, i.e., $ Y = M_{3} $. We have $ b(F)\geq4 $, and Eq (2.6) infers that $ r\leq2h-9 < 2h-7 $.

    Subcase 2.2.2. f $ h_{2}\geq4 $, by Lemma 2.2, $ Y $ is certainly not a CBS, i.e., $ b(X)\geq1 $. Hence we have $ b(F)\geq5 $, by Eq (2.6), $ r\leq2h-10 < 2h-7 $.

    Case 3. $ n_{i}(X) = 2 $, $ n_{i}(Y) = 2 $, i.e., $ X $ and $ Y $ both have two internal vertices.

    Subcase 3.1. If $ h_{1} = 4 $, we note that $ n_{i}(X) = 2 $, so $ X $ must be the benzenoid system $ (b) $ in Figure 9.

    Subcase 3.1.1. If $ h_{2} = 4 $, $ Y $ is surely the benzenoid system $ (b) $ in Figure 9 according to the hypothesis $ n_{i}(Y) = 2 $, therefore, $ F $ is $ D_{8} $ or $ D_{9} $ (as shown in Figure 15). We get $ r(F) = r(D_{8}) = 8 < 2h-7 $ or $ r(F) = r(D_{9}) = 7 < 2h-7 $.

    Subcase 3.1.2. If $ h_{2}\geq5 $, by Lemma 2.2 and that $ n_{i}(Y) = 2 $, $ Y $ is not a CBS, so we know that $ b(X)\geq1 $. Then $ b(F)\geq4 $, by Eq (2.6) and the fact that $ n_{i} = 5 $, $ r\leq2h-9 < 2h-7 $.

    Subcase 3.2. If $ h_{2} = 4 $, we note that $ n_{i}(Y) = 2 $, so $ Y $ must be the benzenoid system $ (b) $ in Figure 8.

    Subcase 3.2.1. If $ h_{1} = 4 $, $ X $ must also be the benzenoid system $ (b) $ in Figure 9. Hence, $ F $ is $ D_{8} $ or $ D_{9} $ (as shown in Figure 15). $ r(F) = r(D_{8}) = 8\leq 2h-7 $ or $ r(F) = r(D_{9}) = 7\leq 2h-7 $.

    Subcase 3.2.2. If $ h_{1}\geq5 $, by Lemma 2.2 and $ n_{i}(X) = 2 $, $ X $ is definitely not a CBS, i.e., $ b(X)\geq1 $. Hence, $ b(F)\geq4 $, by Eq (2.6) and the fact that $ n_{i} = 5 $, we have $ r\leq2h-9 < 2h-7 $.

    Subcase 3.3. If $ h_{1}\geq5 $, $ h_{2}\geq5 $, it is noted that $ n_{i}(X) = n_{i}(Y) = 2 $, neither $ X $ nor $ Y $ are definitely CBS according to Lemma 2.2. So, both $ b(X) $ and $ b(Y) $ are greater than $ 1 $. Hence, $ b(F)\geq5 $, on the basis of Eq (2.6) we get $ r\leq2h-10 < 2h-7 $.

    Case 4. $ n_{i}(X) = 4 $ and $ n_{i}(Y) = 0 $, i.e., $ X $ contains four internal vertices, $ Y $ is a catacondensed benzenoid system.

    Subcase 4.1. If $ h_{1} = 6 $, then $ X $ is the benzenoid system $ (d) $, $ (e) $ or $ (f) $ in Figure 9.

    Subcase 4.1.1. If $ h_{2} = 1 $, $ F $ is the f-benzenoid $ D_{10} $, $ D_{11} $, $ D_{12} $ (see Figure 16), $ D_{13} $ (see Figure 17) or $ U_{7} $ (see Figure 12). $ r(F) = r(D_{10}) = 6\leq 2h-7 $, $ r(F) = r(D_{11}) = 6\leq 2h-7 $, $ r(F) = r(D_{12}) = 6\leq 2h-7 $, $ r(F) = r(D_{13}) = 6\leq 2h-7 $ or $ r(F) = r(U_{7}) = 7 = 2h-7 $.

    Figure 16.  f-benzenoids $ D_{10} $, $ D_{11} $ and $ D_{12} $.
    Figure 17.  f-benzenoids $ D_{13} $, $ D_{14} $, $ D_{15} $, $ D_{16} $, $ D_{17} $, $ D_{18} $, $ D_{19} $, $ D_{20} $ and $ D_{21} $.

    Subcase 4.1.2. If $ h_{2}\geq2 $, we have $ b(F)\geq2 $, by Eq (2.6), $ r\leq2h-7 $.

    Subcase 4.2. If $ h_{1}\geq7 $, in the light of Lemma 2.4, $ X $ is definitely not a CBS, hence $ b(Y)\geq1 $. In this situation $ b(F)\geq3 $, we get the inequality $ r\leq2h-8 < 2h-7 $ according to Eq (2.6).

    Case 5. $ n_{i}(X) = 0 $ and $ n_{i}(Y) = 4 $, i.e., $ X $ is a catacondensed benzenoid system, $ Y $ has four internal vertices.

    Subcase 5.1. If $ h_{2} = 6 $, then $ Y $ is the benzenoid system $ (d) $, $ (e) $ or $ (f) $ in Figure 8.

    Subcase 5.1.1. If $ h_{1} = 2 $, $ X $ must be the linear chain $ L_{2} $. In this event, $ F $ is $ D_{14} $, $ D_{15} $, $ D_{16} $, $ D_{17} $, $ D_{18} $, $ D_{19} $, $ D_{20} $ or $ D_{21} $ (see Figure 17). By further checking, we gain that $ r(F) = r(D_{14}) = 7\leq 2h-7 $, $ r(F) = r(D_{15}) = 8\leq 2h-7 $, $ r(F) = r(D_{16}) = 8\leq 2h-7 $, $ r(F) = r(D_{17}) = 7\leq 2h-7 $, $ r(F) = r(D_{18}) = 7\leq 2h-7 $, $ r(F) = r(D_{19}) = 8\leq 2h-7 $, $ r(F) = r(D_{20}) = 6\leq 2h-7 $ or $ r(F) = r(D_{21}) = 6\leq 2h-7 $.

    Subcase 5.1.2. If $ h_{1}\geq3 $, bearing in mind that $ X $ is a catacondensed benzenoid system and $ Y $ is the benzenoid system $ (d) $, $ (e) $ or $ (f) $ in Figure 8, then $ F $ must have f-benzenoid $ D_{14} $, $ D_{15} $, $ D_{16} $, $ D_{17} $, $ D_{18} $, $ D_{19} $, $ D_{20} $ or $ D_{21} $ (see Figure 17) as its subgraph.

    Subcase 5.1.2.1. If $ D_{14} $ is a subgraph in $ F $, it is obvious that $ D_{14} $ has two coves. Since $ X $ is a catacondensed benzenoid system and $ h_{1}\geq3 $, $ F $ has at least one hexagon contiguous to a $ (2, 2) $-edge of $ X $, and such hexagons can convert one fissure into a bay, or convert one cove into a fjord, or convert one fjord into a lagoon. In this instance $ b(F)\geq4 $. Consequently, $ r\leq2h-9 < 2h-7 $ can be got according to Eq (2.6).

    Subcase 5.1.2.2. If $ D_{15} $, $ D_{16} $ or $ D_{19} $ is a subpart f-benzenoid in $ F $, it is obvious each one of $ D_{15} $, $ D_{16} $ and $ D_{19} $ has a bay and a cove. Since $ X $ is a catacondensed benzenoid system and $ h_{1}\geq3 $, $ F $ contains at least one hexagon adjoining a $ (2, 2) $-edge of $ X $, and such hexagons will make one fissure become a bay, or make one cove become a fjord, or make one fjord become a lagoon. Consequently, $ b(F)\geq4 $, by Eq (2.6) it follows that $ r\leq2h-9 < 2h-7 $.

    Subcase 5.1.2.3. If $ D_{17} $ is a subpart f-benzenoid in $ F $, it is obvious that $ D_{17} $ has a fjord and a bay. Since $ X $ is a catacondensed benzenoid system and $ h_{1}\geq3 $, $ F $ has at least one hexagon adjoining a $ (2, 2) $-edge of $ X $, and such hexagons will convert one fissure into a bay, or convert one cove into a fjord, or convert one fjord into a lagoon. Consequently, $ b(F)\geq4 $, by Eq (2.6) it follows that $ r\leq2h-9 < 2h-7 $.

    Subcase 5.1.2.4. If $ D_{18} $ is a subpart f-benzenoid in $ F $, it is obvious that $ D_{18} $ has a fjord and two bays. Since $ X $ is a catacondensed benzenoid system and $ h_{1}\geq3 $, there exists has at least one hexagon adjoining a $ (2, 2) $-edge of $ X $ in $ F $, and these hexagons will convert one of the fissures into a bay, or convert one cove into a fjord, or convert one fjord into a lagoon. Consequently, $ b(F)\geq4 $, in light of Eq (2.6), $ r\leq2h-9 < 2h-7 $.

    Subcase 5.1.2.5. If $ D_{20} $ or $ D_{21} $ is a subpart f-benzenoid in $ F $, it is obvious that both $ D_{20} $ and $ D_{21} $ have a bay and two fjords. Since $ X $ is a catacondensed benzenoid system and $ h_{1}\geq3 $, $ F $ contains at least one hexagon adjoining a $ (2, 2) $-edge of $ X $, and such hexagons will make one fissure become a bay, or make one cove become a fjord, or make one fjord become a lagoon. Consequently, $ b(F)\geq4 $, according to Eq (2.6), $ r\leq2h-9 < 2h-7 $.

    Subcase 5.2. If $ h_{2}\geq7 $, by Lemma 2.4 and the fact that $ n_{i}(Y) = 4 $, $ Y $ is certainly not a CBS, i.e., $ b(Y)\geq1 $.

    Subcase 5.2.1. If $ h_{1} = 2 $, i.e., $ X = L_{2} $. From the structure of f-benzenoid, $ F $ is formed from $ X $ and $ Y $ joined by a pentagon, it is easily seen that there are at least one bay or one cove arisen in the process of construction of $ F $. It is clear that $ b(F)\geq2 $, by Eq (2.6) we have $ r\leq2h-7 $.

    Subcase 5.2.2. If $ h_{1}\geq3 $, we know that $ F $ is formed by joining from $ X $ and $ Y $ through a pentagon, in this construction process of $ F $, it is easily seen that there are at least one bay or one cove arisen. Then $ b(F)\geq2 $, by Eq (2.6), $ r\leq2h-7 $.

    The proof is completed.

    We recall that $ FL_{h} $ is the f-linear chain with $ h $ hexagons [40]. Extremal f-benzenoids with maximal $ r $ in $ \Gamma_{m} $ were determined in the following theorem.

    Theorem 2.3. Let $ F\in\Gamma_{m} $. Then

    $ \rm 1) $ If $ m\equiv0(mod5) $, then $ r(F)\leq \frac{2m-35}{5} = r(U_{\frac{m}{5}}) $;

    $ \rm 2) $ If $ m\equiv1(mod5) $, then $ r(F)\leq \frac{2m-32}{5} = r(Z_{\frac{m-1}{5}}) $;

    $ \rm 3) $ If $ m\equiv2(mod5) $, then $ r(F)\leq \frac{2m-29}{5} = r(R_{\frac{m-2}{5}}) $;

    $ \rm 4) $ If $ m\equiv3(mod5) $, then $ r(F)\leq \frac{2m-26}{5} = r(G_{\frac{m-3}{5}}) $;

    $ \rm 5) $ If $ m\equiv4(mod5) $, then $ r(F)\leq \frac{2m-23}{5} = r(FL_{\frac{m-4}{5}}) $.

    Proof. We know by Eq (2.5) that

    $ \left\lceil\frac{1}{5}(m-4)\right\rceil \leq h(F)\leq m-1-\left\lceil\frac{1}{3}\left(2m+\sqrt{4m-31}\right)\right\rceil. $

    1) If $ m\equiv0(mod5) $, then $ \left\lceil\frac{1}{5}(m-4)\right\rceil = \frac{m}{5} $. If $ h = \frac{m}{5} $, then by Lemma 1.1 $ {\rm(ii)} $

    $ m = 5h(F)+5-n_{i}(F) = m+5-n_{i}(F), $

    it means that $ n_{i}(F) = 5 $. Furthermore, Theorem 2.2 infers that $ r(F)\leq r(U_{\frac{m}{5}}) $ and we are done. So assume now that $ h(F)\geq\frac{m}{5}+1 $, then by equality (2.7) and the fact that $ b(F)\geq2 $

    $ r(F) = m-5-3h(F)-b(F)\leq m-5-3(\frac{m}{5}+1)-b(F) $
    $ \leq \frac{2m}{5}-10 = \frac{2m-50}{5}\leq \frac{2m-35}{5} = r(U_{\frac{m}{5}}). $

    2) If $ m\equiv1(mod5) $, then $ \left\lceil\frac{1}{5}(m-4)\right\rceil = \frac{m-1}{5} $. If $ h(F) = \frac{m-1}{5} $, then by Lemma 1.1 $ {\rm(ii)} $

    $ m = 5h(F)+5-n_{i}(F) = m+4-n_{i}(F), $

    thus $ n_{i}(F) = 4 $. Then $ r(F)\leq r(Z_{\frac{m-1}{5}}) $ by part 4 of Lemma 2.5. Otherwise $ h(F)\geq\frac{m-1}{5}+1 $, then by equality (2.7) and the obvious fact that $ b(F)\geq2 $

    $ r(F) = m-5-3h(F)-b(F)\leq m-5-3(\frac{m-1}{5}+1)-b(F) $
    $ \leq \frac{2m+3}{5}-10 = \frac{2m-47}{5}\leq \frac{2m-32}{5} = r(Z_{\frac{m-1}{5}}). $

    3) If $ m\equiv2(mod5) $, then $ \left\lceil\frac{1}{5}(m-4)\right\rceil = \frac{m-2}{5} $. If $ h(F) = \frac{m-2}{5} $, then by Lemma 1.1 $ {\rm(ii)} $

    $ m = 5h(F)+5-n_{i}(F) = m+3-n_{i}(F), $

    and so $ n_{i}(F) = 3 $. Then $ r(F)\leq r(R_{\frac{m-2}{5}}) $ by part 3 of Lemma 2.5. So assume now that $ h(F)\geq\frac{m-2}{5}+1 $, then by Eq (2.7) and the fact that $ b(F)\geq2 $

    $ r(F) = m-5-3h(F)-b(F)\leq m-5-3(\frac{m-2}{5}+1)-b(F) $
    $ \leq \frac{2m+6}{5}-10 = \frac{2m-44}{5}\leq \frac{2m-29}{5} = r(R_{\frac{m-2}{5}}). $

    4) If $ m\equiv3(mod5) $, then $ \left\lceil\frac{1}{5}(m-4)\right\rceil = \frac{m-3}{5} $. If $ h(F) = \frac{m-3}{5} $, then by Lemma 1.1 $ {\rm(ii)} $

    $ m = 5h(F)+5-n_{i}(F) = m+2-n_{i}(F), $

    thus $ n_{i}(F) = 2 $. By Lemma 2.5, $ r(F)\leq r(G_{\frac{m-3}{5}}) $ and we are done. If $ h(F)\geq\frac{m-3}{5}+1 $, then by equality (2.7) and the fact that $ b(F)\geq2 $

    $ r(F) = m-5-3h(F)-b(F)\leq m-5-3(\frac{m-3}{5}+1)-b(F) $
    $ \leq \frac{2m+9}{5}-10 = \frac{2m-41}{5}\leq \frac{2m-26}{5} = r(G_{\frac{m-3}{5}}). $

    5) If $ m\equiv4(mod5) $, then $ \left\lceil\frac{1}{5}(m-4)\right\rceil = \frac{m-4}{5} $. Since $ h\geq\frac{m-4}{5} $ and $ b(F)\geq2 $, then by Eq (2.7), we have

    $ r(F) = m-5-3h(F)-b(F)\leq m-5-\frac{3m-12}{5}-b(F) $
    $ \leq \frac{2m+12}{5}-7 = \frac{2m-23}{5} = r(FL_{\frac{m-4}{5}}). $

    In this part, we attempt to find the extremal values of $ TI $ over $ \Gamma_{m} $.

    It is noted that a f-benzenoid $ F $ contains only $ 2 $-vertex and $ 3 $-vertex. Hence, equation (1.1) reduces to

    $ TI(F)=m22ψ22+m23ψ23+m33ψ33,
    $
    (3.1)

    In the light of Lemmas 1.1 and 1.2,

    $ TI(F)=ψ22m+3(ψ33ψ22)h+(2ψ23ψ22ψ33)r,
    $
    (3.2)

    If $ U, V\in\Gamma_{m} $ then clearly

    $ TI(U)TI(V)=3(ψ33ψ22)(h(U)h(V))          +(2ψ23ψ22ψ33)(r(U)r(V)).
    $
    (3.3)

    For convenience, we set $ s = \psi_{33}-\psi_{22} $, $ q = 2\psi_{23}-\psi_{22}-\psi_{33} $.

    Theorem 3.1. For any $ F\in\Gamma_{m} $, we have the following results.

    $ {\rm a.} $ If $ s\leq0 $ and $ q\geq0 $,

    $ TI(F)\leq\left\{TI(Um5),if m0(mod 5)TI(Zm15),if m1(mod 5)TI(Rm25),if m2(mod 5)TI(Gm35),if m3(mod 5)TI(FLm45),if m4(mod 5)
    \right. $

    $ {\rm b.} $ If $ s\geq0 $ and $ q\leq0 $,

    $ TI(F)\geq\left\{TI(Um5),if m0(mod 5)TI(Zm15),if m1(mod 5)TI(Rm25),if m2(mod 5)TI(Gm35),if m3(mod 5)TI(FLm45),if m4(mod 5)
    \right. $

    Proof. Let $ F\in\Gamma_{m} $. By Eq (2.5)

    $ h(F)\geq \left\lceil\frac{1}{5}(m-4)\right\rceil = \left\{h(Um5),if m0(mod 5)h(Zm15),if m1(mod 5)h(Rm25),if m2(mod 5)h(Gm35),if m3(mod 5)h(FLm45),if m4(mod 5)
    \right. $

    i.e., f-benzenoids $ U_{\frac{m}{5}} $, $ Z_{\frac{m-1}{5}} $, $ R_{\frac{m-2}{5}} $, $ G_{\frac{m-3}{5}} $ and $ FL_{\frac{m-4}{5}} $ have minimal $ h $ over the set $ \Gamma_{m} $. Meanwhile, by Theorem 2.3, we have

    $ r(F)\leq \left\{r(Um5),if m0(mod 5)r(Zm15),if m1(mod 5)r(Rm25),if m2(mod 5)r(Gm35),if m3(mod 5)r(FLm45),if m4(mod 5)
    \right. $

    i.e., these five f-benzenoids have maximal number of inlets over $ \Gamma_{m} $. Hence, for any f-benzenoids $ F\in\Gamma_{m} $ and $ V\in\{U_{\frac{m}{5}}, Z_{\frac{m-1}{5}}, R_{\frac{m-2}{5}}, G_{\frac{m-3}{5}}, FL_{\frac{m-4}{5}}\} $, $ h(F)-h(V)\geq0 $ and $ r(F)-r(V)\leq0 $ hold simultaneously, from Eq (2.7), we have

    $ TI(F)-TI(V) = 3s(h(F)-h(V))+q(r(F)-r(V)). $

    If $ s\leq0 $ and $ q\geq0 $, then $ TI(F)-TI(V)\leq0 $, i.e., $ V $ reaches the maximum value of $ TI $ over $ \Gamma_{m} $. If $ s\geq0 $ and $ q\leq0 $, then $ TI(F)-TI(V)\geq0 $, i.e., $ V $ reaches the minimum value of $ TI $ over $ \Gamma_{m} $. Furthermore, which $ V\in\{U_{\frac{m}{5}}, Z_{\frac{m-1}{5}}, R_{\frac{m-2}{5}}, G_{\frac{m-3}{5}}, FL_{\frac{m-4}{5}}\} $ is the extremal graph depending on $ m $ is congruent to $ 0, 1, 2, 3 $ or $ 4 $ modulo $ 5 $.

    Example 1. Values of $ s $ and $ q $ for several famous $ TI $ are listed in Table 2:

    Table 2.  Values of $ s $ and $ q $ for six famous $ TI $.
    $ ij $ $ \frac{1}{\sqrt{ij}} $ $ \frac{2\sqrt{ij}}{i+j} $ $ \frac{1}{\sqrt{i+j}} $ $ \frac{(ij)^{3}}{(i+j-2)^{3}} $ $ \sqrt{\frac{i+j-2}{ij}} $
    $ q $ -1 -0.0168 -0.0404 -0.0138 -3.390 0.040
    $ s $ 5 -0.1667 0 -0.091 3.390 -0.040

     | Show Table
    DownLoad: CSV

    Therefore, the minimum extreme value of $ TI $ for the second Zagreb index, GA index and the AZI index can be determined in the light of Theorems 2.3 and 3.1, and we can obtain the maximum extreme value of $ TI $ for the ABC index.

    If f-benzenoid $ F\in\Gamma_{m} $, then from the Eqs (2.3) and (2.6) and Lemma 1.1$ ({\rm ii}) $ we have

    $ TI(F)=(2ψ23ψ33)m+6(ψ33ψ23)h(2ψ23ψ22ψ33)b               5(2ψ23ψ22ψ33).
    $
    (3.4)

    Consequently, for f-benzenoids $ U, V\in\Gamma_{m} $

    $ TI(U)TI(V)=6(ψ33ψ23)(h(U)h(V))          +(2ψ23+ψ22+ψ33)(b(U)b(V)).
    $
    (3.5)

    Set $ u = 6(\psi_{33}-\psi_{23}) $ and keep in mind that $ q = 2\psi_{23}-\psi_{22}-\psi_{33} $. Then

    $ TI(U)TI(V)=u(h(U)h(V))q(b(U)b(V)).
    $
    (3.6)

    It is noted that Eq (3.6) can be decided only by $ h $, $ b $ and the signs of $ u $ and $ q $. For any $ F\in\Gamma_{m} $, We know that

    $ h(F)\leq m-1-\left\lceil\frac{1}{3}\left(2m+\sqrt{4m-31}\right)\right\rceil, $

    and the equality can be achieved precisely when $ F $ is the f-spiral benzenoid $ F^{\ast} $ [41].

    In [41], we proved that $ n_{i}(F^{\ast}) = 2h-\left\lceil\sqrt{12(h-1)-3}\right\rceil $. But, $ b(F^{\ast})\neq2 $ may occur. It is noticeable if $ X $ in $ F^{\ast} $ is a CBS, $ F^{\ast} $ is a f-benzenoid satisfying that $ b(F^{\ast}) = 2 $ or $ 3 $. For the sake of simplicity, Let $ \mathbb{N} $ be the set of positive integers.

    The CBS, $ W = H(l_{1}, l_{2}, l_{3}, l_{4}, l_{5}, l_{6}) $ (as shown in Figure 18), can be completely determined by the positive integers $ l_{1}, l_{2}, l_{3}, l_{4} $ [14].

    Figure 18.  The general form of a CBS. The parameters $ l_{i}\geq 1, i = 1, 2, \cdots, 6, $ count the number of hexagons on the respective side of CBS.

    The following lemma gave requirements that there exists CBS with maximal $ n_{i} $ [53].

    Lemma 3.1. [53] Let $ h\in\mathbb{N} $. The conditions below are isovalent:

    (a) There is a CBS $ W $ containing $ h $ hexagons and $ 2h+1-\lceil\sqrt{12h-3} \ \rceil $ number of internal vertices.

    (b) There exist $ l_{1}, l_{2}, l_{3}, l_{4}\in\mathbb{N} $ satisfying the following equation

    $ h=l1l3+l1l4+l2l3+l2l4l2l312l1(l1+1)12l4(l4+1)+112h3 =l1+2l2+2l3+l43}
    $
    (3.7)

    If for $ h\in\mathbb{N} $, Eq (3.7) has a solution $ l_{1}, l_{2}, l_{3}, l_{4}\in\mathbb{N} $, then there is a CBS $ W $ meeting the conditions that $ n_{i}(W) = n_{i}(T_{h}) $.

    Now, we concentrate on the research for $ TI $ of f-benzenoids. For a $ h-1\in\mathbb{N} $, supposing that the system below

    $ h1=l1l3+l1l4+l2l3+l2l4l2l312l1(l1+1)12l4(l4+1)+112(h1)3 =l1+2l2+2l3+l43 li{l1,l2,l3,l4,l5,l6}, li=2}
    $
    (3.8)

    has a solution $ \{l_{1}, l_{2}, l_{3}, l_{4}\} $, then a CBS $ W_{h-1} $ containing $ n_{i}(W_{h-1}) = 2(h-1)+1-\left\lceil\sqrt{12(h-1)-3}\right\rceil $ number of internal vertices exists. Note that $ l_{i} = 2 $ in system (3.8), i.e., there exists one fissure on the side of $ l_{i} $ of $ W_{h-1} $, let $ u, w, v $ in Figure 1 represent the three vertices of this fissure. Now, we obtain an f-spiral benzenoid $ F^{\ast}_{1} $ in which $ X = W_{h-1} $ and $ Y = L_{1} $. It is obvious that

    $ ni(F1)=2h12(h1)3
    $
    (3.9)

    and $ b(F^{\ast}_{1}) = 2 $. (as shown in Figure 19)

    Figure 19.  A f-spiral benzenoid $ F^{\ast}_{1} $ whose fragment $ X $ is a convex spiral benzenoid system $ W_{h-1} $.

    Theorem 3.2. Let $ h-1\in\mathbb{N} $ such that the Eq (3.8) has a solution, and $ m = 3h+5+\left\lceil\sqrt{12(h-1)-3}\right\rceil $. Then for any $ F\in\Gamma_{m} $

    1) $ TI(F^{\ast}_{1})\geq TI(F) $, when $ u\geq0 $ and $ q\geq0 $;

    2) $ TI(F^{\ast}_{1})\leq TI(F) $, when $ u\leq0 $ and $ q\leq0 $.

    Proof. From Lemma 1.1 $ ({\rm ii}) $ and Eq (3.9), we have

    $ m(F^{\ast}_{1}) = 5h+5-(2h-\left\lceil\sqrt{12(h-1)-3}\right\rceil) = 3h+5+\left\lceil\sqrt{12(h-1)-3}\right\rceil $

    and so

    $ h = m-1-\left\lceil\frac{1}{3} \left(2m+\sqrt{4m-31}\right)\right\rceil. $

    It is obvious that $ b(F^{\ast}_{1}) = 2 $ and $ b(F)\geq2 $ for any $ F\in\Gamma_{m} $. Hence by Eq (3.6), we have

    $ TI(F)-TI(F^{\ast}_{1}) = u(h(F)-h(F^{\ast}_{1}))-q(b(F)-b(F^{\ast}_{1})) $
    $ = u\left[h(F)-\left(m-1-\left\lceil\frac{1}{3} \left(2m+\sqrt{4m-31}\right)\right\rceil\right)\right]-q[b(F)-2]. $

    And by Eq (2.5)

    $ h(F)\leq m-1-\left\lceil\frac{1}{3}\left(2m+\sqrt{4m-31}\right)\right\rceil. $

    If $ u\geq0 $ and $ q\geq0 $ then $ TI(F)-TI(F^{\ast}_{1})\leq0 $, i.e., $ F^{\ast}_{1} $ achieves maximal $ TI $ in $ \Gamma_{m} $. Similarly, if $ u\leq0 $ and $ q\leq0 $ then $ TI(F)-TI(F^{\ast}_{1})\geq0 $, i.e., $ F^{\ast}_{1} $ obtains minimal $ TI $ in $ \Gamma_{m} $.

    Example 2. The values of $ u $ and $ q $ for some famous $ TI $ are listed in the following Table 3:

    Table 3.  Values of $ u $ and $ q $ for six famous $ TI $.
    $ ij $ $ \frac{1}{\sqrt{ij}} $ $ \frac{2\sqrt{ij}}{i+j} $ $ \frac{1}{\sqrt{i+j}} $ $ \frac{(ij)^{3}}{(i+j-2)^{3}} $ $ \sqrt{\frac{i+j-2}{ij}} $
    $ q $ -1 -0.0168 -0.0404 -0.0138 -3.390 0.040
    $ u $ 18 -0.449 0.121 -0.233 20.344 -0.242

     | Show Table
    DownLoad: CSV

    Hence, by Theorem 3.1 we can deduce the minimal values of the Randć index and the the sum–connectivity index in f-spiral benzenoid $ F^{\ast}_{1} $ for those $ h $ such that Eq (3.8) holds.

    Example 3. Take consideration of the generalized Randć index

    $ R_{\alpha}(G) = \sum\limits_{1\leq i\leq j\leq n-1}m_{ij}(ij)^{\alpha}, $

    where $ \alpha\in\mathbb{R} $. Note that

    $ q = 2(6^{\alpha})-4^{\alpha}-9^{\alpha} = -4^{\alpha}((\frac{3}{2})^{\alpha}-1)^{2}\leq0 $

    for all $ \alpha\in\mathbb{R} $. Moreover, $ s = 9^{\alpha}-4^{\alpha}\geq0 $ if and only if $ \alpha\geq0 $ if and only if $ u = 6(9^{\alpha}-6^{\alpha})\geq0 $. Hence, by Theorem 3.1, the minimal value of $ R_{\alpha}(G) $ is obtained for all $ \alpha\geq0 $, and for any $ \alpha\leq0 $, the minimal value of $ R_{\alpha}(G) $ can be attained by the f-spiral benzenoid $ F^{\ast}_{1} $ for those $ h $ such that Eq (3.8) holds.

    This work investigates extremum $ TI $ over the collection of f-benzenoids having same number of edges. In practical terms, there are many other types of very useful topological indices for instance graph energy [58,59,60,61,62], Wiener index [63], Randić energy [64], Wiener polarity index [65], incidence energy [66], Harary index [67], entropy measures [68,69] and HOMO-LUMO index [70]. So, determining these topological indices for f-benzenoids is going to be extraordinary fascinating.

    It is noted that the current framework is for studying topological indices of deterministic networks. But random networks would be a very promising direction. In [71,72], the distance Estrada index of random graphs was discussed, and the author went deeply into (Laplacian) Estrada index for random interdependent graphs. So, studying VDB topological indices of random and random interdependent graphs is another interesting problem.

    This work was supported by Ningbo Natural Science Foundation (No. 2021J234). The authors are very grateful to anonymous referees and editor for their constructive suggestions and insightful comments, which have considerably improved the presentation of this paper.

    The authors declare there is no conflict of interest.

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