The future of green hydrogen is with the selection of electrolysis technologies that harmonize performance, cost, and sustainability. In this study, we evaluated proton exchange membrane (PEM) and Alkaline electrolyzers using an integrated multi-criteria decision-making framework. Weighting the criteria using the fuzzy best-worst method (FBWM) revealed efficiency (0.0899) and capital expenditure (0.0800) as the most prominent, highlighting the significance of cost-performance trade-offs in stakeholder decisions. Greenhouse gas emissions and water consumption scored high on environmental metrics. Moreover, a technique for order preference by similarity to ideal solution (TOPSIS) results showed a narrow lead of PEM (CCi = 0.507) over Alkaline (CCi = 0.493), owing mostly to superior technical parameters like hydrogen purity and current density. Weighted aggregated sum product assessment (WASPAS) analysis confirmed this finding, with PEM returning a sum score of 0.432 compared to Alkaline's 0.414. Sensitivity analysis across four weighting scenarios determined the test of rankings robustness: PEM did better in all but the cost-dominant scenario, in which Alkaline did better due to lower capital spending (CAPEX) and longer stack lifespan. These findings support informed technology selection under different stakeholder priorities and can assist in future hydrogen infrastructure planning.
Citation: Leila Bekrit, Chakib Seladji. A multi-criteria techno-economic evaluation of PEM and Alkaline electrolyzers for green hydrogen production using fuzzy BWM, TOPSIS, and WASPAS[J]. Clean Technologies and Recycling, 2026, 6(1): 56-74. doi: 10.3934/ctr.2026003
The future of green hydrogen is with the selection of electrolysis technologies that harmonize performance, cost, and sustainability. In this study, we evaluated proton exchange membrane (PEM) and Alkaline electrolyzers using an integrated multi-criteria decision-making framework. Weighting the criteria using the fuzzy best-worst method (FBWM) revealed efficiency (0.0899) and capital expenditure (0.0800) as the most prominent, highlighting the significance of cost-performance trade-offs in stakeholder decisions. Greenhouse gas emissions and water consumption scored high on environmental metrics. Moreover, a technique for order preference by similarity to ideal solution (TOPSIS) results showed a narrow lead of PEM (CCi = 0.507) over Alkaline (CCi = 0.493), owing mostly to superior technical parameters like hydrogen purity and current density. Weighted aggregated sum product assessment (WASPAS) analysis confirmed this finding, with PEM returning a sum score of 0.432 compared to Alkaline's 0.414. Sensitivity analysis across four weighting scenarios determined the test of rankings robustness: PEM did better in all but the cost-dominant scenario, in which Alkaline did better due to lower capital spending (CAPEX) and longer stack lifespan. These findings support informed technology selection under different stakeholder priorities and can assist in future hydrogen infrastructure planning.
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