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Electrochemical impedance spectroscopy analysis with a symmetric cell for LiCoO2 cathode degradation correlated with Co dissolution

1 Research Institute for Science and Engineering, Waseda University, 3-4-1, Okubo, Shinjuku-ku, Tokyo 169-8555, Japan
2 Graduate School of Science and Engineering, Waseda University, 3-4-1, Okubo, Shinjuku-ku, Tokyo 169-8555, Japan

Topical Section: Elecrtrochemical Analysis of Materials

Static degradation of LiCoO2 cathodes is a problem that hinders accurate analysis using our developed separable symmetric cell. Therefore, in this study we investigate the static degradation of LiCoO2 cathodes in separable symmetric cells by electrochemical impedance spectroscopy (EIS) and inductively coupled plasma analyses. EIS measurements of LiCoO2 cathodes are conducted in various electrolytes, with different anions and with or without HF and/or H2O. This allows us to determine the static degradation of LiCoO2 cathodes relative to their increase of charge transfer resistance. The increase of the charge transfer resistance of the LiCoO2 cathodes is attributed to cobalt dissolution from the active material of LiCoO2. Cobalt dissolution from LiCoO2 is revealed to occur even at low potential in the presence of HF, which is generated from LiPF6 and H2O. The results indicate that avoidance of HF generation is important for the analysis of lithium-ion battery electrodes by using the separable cell. These findings reveal the condition to achieve accurate analysis by EIS using the separable cell.
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Keywords electrochemical impedance spectroscopy (EIS); Lithium-ion Battery (LIB); LiCoO2 cathode; degradation; Co dissolution; LiPF6; LiClO4; HF

Citation: Hiroki Nara, Keisuke Morita, Tokihiko Yokoshima, Daikichi Mukoyama, Toshiyuki Momma, Tetsuya Osaka. Electrochemical impedance spectroscopy analysis with a symmetric cell for LiCoO2 cathode degradation correlated with Co dissolution. AIMS Materials Science, 2016, 3(2): 448-459. doi: 10.3934/matersci.2016.2.448

References

  • 1. Nishi Y (2001) Lithium ion secondary batteries; past 10 years and the future. J Power Sources 100: 101–106.
  • 2. Etacheri V, Marom R, Elazari R, et al. (2011) Challenges in the development of advanced Li-ion batteries: a review. Energy Environ Sci 4: 3243–3262.    
  • 3. Dunn B, Kamath H, Tarascon J-M (2011) Electrical energy storage for the grid: a battery of choices. Science 334: 928–935.    
  • 4. Yang Z, Zhang J, Kintner-Meyer MCW, et al. (2011) Electrochemical Energy Storage for Green Grid. Chem Rev 111: 3577–3613.    
  • 5. Broussely M, Biensan P, Bonhomme F, et al. (2005) Main aging mechanisms in Li ion batteries. J Power Sources 146: 90–96.    
  • 6. Vetter J, Novák P, Wagner MR, et al. (2005) Ageing mechanisms in lithium-ion batteries. J Power Sources 147: 269–281.
  • 7. Smart MC, Ratnakumar BV (2011) Effects of Electrolyte Composition on Lithium Plating in Lithium-Ion Cells. J Electrochem Soc 158: A379–A389.    
  • 8. Aurbach D, Markovsky B, Salitra G, et al. (2007) Talyossef, M. Koltypin, et al., Review on electrode–electrolyte solution interactions, related to cathode materials for Li-ion batteries. J Power Sources 165: 491–499.
  • 9. Aurbach D, Markovsky B, Rodkin A, et al. (2002) On the capacity fading of LiCoO2 intercalation electrodes. Electrochimica Acta 47: 4291–4306.    
  • 10. Takami N, Satoh A, Hara M, et al. (1995) Structural and Kinetic Characterization of Lithium Intercalation into Carbon Anodes for Secondary Lithium Batteries. J Electrochem Soc 142: 371–379.    
  • 11. Aurbach D, Levi MD, Levi E, et al. (1998) Common Electroanalytical Behavior of Li Intercalation Processes into Graphite and Transition Metal Oxides. J Electrochem Soc 145: 3024–3034.    
  • 12. Markovsky B, Levi MD, Aurbach D (1998) The basic electroanalytical behavior of practical graphite–lithium intercalation electrodes. Electrochimica Acta 43: 2287–2304.    
  • 13. Barsoukov E, Kim JH, Yoon CO, et al. (1999) Kinetics of lithium intercalation into carbon anodes: in situ impedance investigation of thickness and potential dependence. Solid State Ionics.
  • 14. Zhang D, Haran BS, Durairajan A, et al. (2000) Studies on capacity fade of lithium-ion batteries. J Power Sources 91: 122–129.    
  • 15. Nagasubramanian G (2000) Two- and three-electrode impedance studies on 18650 Li-ion cells. J Power Sources 87: 226–229.    
  • 16. Li J, Murphy E, Winnick J, et al. (2001) Studies on the cycle life of commercial lithium ion batteries during rapid charge–discharge cycling. J Power Sources 102: 294–301.    
  • 17. Seki S, Kihira N, Mita Y, et al. (2011) AC Impedance Study of High-Power Lithium-Ion Secondary Batteries—Effect of Battery Size. J Electrochem Soc 158: A163–A166.    
  • 18. Mukoyama D, Momma T, Nara H, et al. (2012) Electrochemical Impedance Analysis on Degradation of Commercially Available Lithium Ion Battery during Charge–Discharge Cycling. Chem Lett 41: 444–446.    
  • 19. Osaka T, Momma T, Mukoyama D, et al. (2012) Proposal of novel equivalent circuit for electrochemical impedance analysis of commercially available lithium ion battery. J Power Sources 205: 483–486.
  • 20. Hang T, Mukoyama D, Nara H, et al. (2013) Electrochemical impedance spectroscopy analysis for lithium-ion battery using Li4Ti5O12 anode. J Power Sources 222: 442–447.    
  • 21. Illig J, Ender M, Weber A, et al. (2015) Modeling graphite anodes with serial and transmission line models. J Power Sources 282: 335–347.    
  • 22. Hoshi Y, Narita Y, Honda K, et al. (2015) Optimization of reference electrode position in a three-electrode cell for impedance measurements in lithium-ion rechargeable battery by finite element method. J Power Sources 288: 168–175.    
  • 23. Osaka T, Mukoyama D, Nara H (2015) Review—Development of Diagnostic Process for Commercially Available Batteries, Especially Lithium Ion Battery, by Electrochemical Impedance Spectroscopy. J Electrochem Soc 162: A2529–A2537.
  • 24. Osaka T, Nara H, Mukoyama D, et al. (2013) New Analysis of Electrochemical Impedance Spectroscopy for Lithium-ion Batteries. J Electrochem Sci Tech 4: 157–162.    
  • 25. Mendoza-Hernandez OS, Ishikawa H, Nishikawa Y, et al. (2014) State of Charge Dependency of Graphitized-Carbon-Based Reactions in a Lithium-ion Secondary Cell Studied by Electrochemical Impedance Spectroscopy. Electrochimica Acta 131: 168–173.    
  • 26. Bünzli C, Kaiser H, Novák P (2015) Important Aspects for Reliable Electrochemical Impedance Spectroscopy Measurements of Li-Ion Battery Electrodes. J Electrochem Soc 162: A218–A222.
  • 27. Yokoshima T, Nara H, Mukoyama D, et al. (2011) Performance of Fine Reference Electrode in Thin Laminated Li-Ion Cell, in: Meet. Abstr, The Electrochemical Society, pp. 1451–1451.
  • 28. Jansen AN, Dees DW, Abraham DP, et al. ((2007)) Low-temperature study of lithium-ion cells using a LiySn micro-reference electrode. J Power Sources 174: 373–379.
  • 29. La Mantia F, Wessells CD, Deshazer HD, et al. (2013) Reliable reference electrodes for lithium-ion batteries. Electrochem Commun 31: 141–144.
  • 30. Gómez-Cámer JL, Novák P (2013) Electrochemical impedance spectroscopy: Understanding the role of the reference electrode. Electrochem Commun 34: 208–210.    
  • 31. Adler SB (2002) Reference Electrode Placement in Thin Solid Electrolytes. J Electrochem Soc 149: E166–E172.    
  • 32. Klink S, Höche D, La Mantia F, et al. (2013) FEM modelling of a coaxial three-electrode test cell for electrochemical impedance spectroscopy in lithium ion batteries. J Power Sources 240: 273–280.    
  • 33. Momma T, Yokoshima T, Nara H, et al. (2014) Distinction of impedance responses of Li-ion batteries for individual electrodes using symmetric cells. Electrochimica Acta 131: 195–201.    
  • 34. Chen CH, Liu J, Amine K (2001) Symmetric cell approach and impedance spectroscopy of high power lithium-ion batteries. J Power Sources 96: 321–328.
  • 35. Levi MD, Dargel V, Shilina Y, et al. (2014) Impedance Spectra of Energy-Storage Electrodes Obtained with Commercial Three-Electrode Cells: Some Sources of Measurement Artefacts. Electrochimica Acta 149: 126–135.    
  • 36. Amatucci G (1996) Cobalt dissolution in LiCoO2-based non-aqueous rechargeable batteries. Solid State Ionics 83: 167–173.
  • 37. Levi MD, Salitra G, Markovsky B, et al. (1999) Solid‐State Electrochemical Kinetics of Li‐Ion Intercalation into Li1 − x CoO2: Simultaneous Application of Electroanalytical Techniques SSCV, PITT, and EIS. J Electrochem Soc 146: 1279–1289.
  • 38. Momma T, Matsunaga M, Mukoyama D, et al. (2012) Ac impedance analysis of lithium ion battery under temperature control. J Power Sources 216: 304–307.    
  • 39. Nara H, Mukoyama D, Yokoshima T, et al. (2016) Impedance Analysis with Transmission Line Model for Reaction Distribution in a Pouch Type Lithium-Ion Battery by Using Micro Reference Electrode. J Electrochem Soc 163: A434–A441.

 

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