Research article

Correlation between fracture surface topography, skewness, and kurtosis with mechanical properties in epoxy-MgO nanocomposites

  • Published: 26 September 2025
  • Epoxy resins are widely used in structural and protective coatings, but their brittleness and crack growth limit use in demanding applications. Improving toughness in epoxy and related polymers is still a challenge. In this work, epoxy-MgO nanocomposites were studied to evaluate their mechanical performance and fracture behavior. Tests included ultimate tensile strength, Young's modulus, and fracture surface analysis. In addition, skewness (Rsk) and kurtosis (Rku) were used as quantitative measures of the fracture surfaces. Results showed that adding MgO nanoparticles improved both strength and stiffness compared with pure epoxy, while the mid-range MgO contents gave the best results. Fracture surface observations confirmed that the nanoparticles created more uniform and less crack-sensitive morphologies than in pure epoxy. These findings indicate that MgO nanoparticles enhance the stability and fracture toughness of epoxy. Skewness and kurtosis provided useful parameters for characterizing fractures among the composites. This study also shows how statistical descriptions of surface morphology can be linked with mechanical behavior. The results offer guidance for optimizing nanoparticle design in structural and functional nanocomposite applications.

    Citation: Muhannad Mahdi Abd, Ali Jalil Mjali, Salahaldin Mansur Baseem Alduwaib. Correlation between fracture surface topography, skewness, and kurtosis with mechanical properties in epoxy-MgO nanocomposites[J]. AIMS Materials Science, 2025, 12(5): 993-1003. doi: 10.3934/matersci.2025045

    Related Papers:

  • Epoxy resins are widely used in structural and protective coatings, but their brittleness and crack growth limit use in demanding applications. Improving toughness in epoxy and related polymers is still a challenge. In this work, epoxy-MgO nanocomposites were studied to evaluate their mechanical performance and fracture behavior. Tests included ultimate tensile strength, Young's modulus, and fracture surface analysis. In addition, skewness (Rsk) and kurtosis (Rku) were used as quantitative measures of the fracture surfaces. Results showed that adding MgO nanoparticles improved both strength and stiffness compared with pure epoxy, while the mid-range MgO contents gave the best results. Fracture surface observations confirmed that the nanoparticles created more uniform and less crack-sensitive morphologies than in pure epoxy. These findings indicate that MgO nanoparticles enhance the stability and fracture toughness of epoxy. Skewness and kurtosis provided useful parameters for characterizing fractures among the composites. This study also shows how statistical descriptions of surface morphology can be linked with mechanical behavior. The results offer guidance for optimizing nanoparticle design in structural and functional nanocomposite applications.



    加载中


    [1] Taieh NK, Khudhur SK, Fahad EAA, et al. (2023) High mechanical performance of 3-aminopropyl triethoxy silane/epoxy cured in a sandwich construction of 3D carbon felts foam and woven basalt fibers. Nanotechnol Rev 12: 20220519. https://doi.org/10.1515/ntrev-2022-0519 doi: 10.1515/ntrev-2022-0519
    [2] Ali MM, Taieh NK, Hussein HA, et al. (2024) Nanostructured Co3O4-graced 3D carbon felts for improved mechanical interlocking in epoxy composites: Morphological and mechanical/tribological optimization. J Mater Sci 59: 7716–7732. https://doi.org/10.1007/s10853-024-09646-w doi: 10.1007/s10853-024-09646-w
    [3] Kadhim N, Mei Y, Wang Y, et al. (2018) Remarkable improvement in the mechanical properties of epoxy composites achieved by a small amount of modified helical carbon nanotubes. Polymers 10: 1103. https://doi.org/10.3390/polym10101103 doi: 10.3390/polym10101103
    [4] Kadhim N, Zaman A, Jiang M, et al. (2021) A cast-in-place fabrication of high performance epoxy composites cured in an in-situ synthesized 3D foam of nanofibers. Compos Part B-Eng 205: 108495. https://doi.org/10.1016/j.compositesb.2020.108495 doi: 10.1016/j.compositesb.2020.108495
    [5] Zaghloul MYM, Zaghloul MMY, Zaghloul MMY (2021) Developments in polyester composite materials—An in-depth review on natural fibres and nano fillers. Compos Struct 278: 114698. https://doi.org/10.1016/j.compstruct.2021.114698 doi: 10.1016/j.compstruct.2021.114698
    [6] Fuseini M, Zaghloul MMY, Abakar D, et al. (2025) Review of epoxy nano-filled hybrid nanocomposite coatings for tribological applications. FlatChem 49: 100768. https://doi.org/10.1016/j.flatc.2024.100768 doi: 10.1016/j.flatc.2024.100768
    [7] Ekrem M, Koyunbakan M, Ünal B (2024) Investigation of the mechanical and thermal properties of epoxy adhesives reinforced by carbon nanotubes and silicon dioxide nanoparticles in single-lap joints. J Adhes Sci Technol 38: 3860–3875. https://doi.org/10.1080/01694243.2024.2358037 doi: 10.1080/01694243.2024.2358037
    [8] Zhang T, Chao X, Liang J, et al. (2025) Enhanced mechanical properties of epoxy composites reinforced with silane-modified Al2O3 nanoparticles: An experimental study. J Compos Sci 9: 252. https://doi.org/10.3390/jcs9050252 doi: 10.3390/jcs9050252
    [9] Singh SK, Singh TJ, Halder S, et al. (2025) Investigation of mechanical and thermo-mechanical properties of dopamine-functionalized TiO2/epoxy nanocomposites. Polym Compos 46: 12457–12479. https://doi.org/10.1002/pc.29755 doi: 10.1002/pc.29755
    [10] Ali A, Koloor SSR, Alshehri AH, et al. (2023) Carbon nanotube characteristics and enhancement effects on the mechanical features of polymer-based materials and structures–A review. J Mater Res Technol 24: 6495–6521. https://doi.org/10.1016/j.jmrt.2023.04.072 doi: 10.1016/j.jmrt.2023.04.072
    [11] Hornak J (2021) Synthesis, properties, and selected technical applications of magnesium oxide nanoparticles: A review. Int J Mol Sci 22: 12752. https://doi.org/10.3390/ijms222312752 doi: 10.3390/ijms222312752
    [12] Peddamallu N, Nagaraju G, Sridharan K, et al. (2019) Understanding the electrical, thermal, and mechanical properties of epoxy magnesium oxide nanocomposites. IET Sci Meas Technol 13: 632–639. https://doi.org/10.1049/iet-smt.2018.5514 doi: 10.1049/iet-smt.2018.5514
    [13] Saeed AQ, Al-Obad ZKM (2023) Effect of magnesium oxide, boron nitride, and hybrid nanoparticles on the mechanical properties of epoxy nanocomposites. AIP Conf Proc 2830: 030036. https://doi.org/10.1063/5.0157176 doi: 10.1063/5.0157176
    [14] Mohapatra P, Behera S, Sahoo S, et al. (2024) Explore the effect of magnesium oxide nanoparticles decorated graphene oxide hybrid nanofillers reinforced polyaniline ternary nanocomposites on optical, thermal, and dielectric properties. Adv Nat Sci Nanosci Nanotechnol 15: 045013. https://dx.doi.org/10.1088/2043-6262/ad7c1e doi: 10.1088/2043-6262/ad7c1e
    [15] Yang J, Wang X, Khan MR, et al. (2024) New opportunities and advances in magnesium oxide (MgO) nanoparticles in biopolymeric food packaging films. Sustain Mater Techno 40: e00976. https://doi.org/10.1016/j.susmat.2024.e00976 doi: 10.1016/j.susmat.2024.e00976
    [16] Hegde VN, Manju V, Lumbini J, et al. (2024) Effect of calcination temperature on structural, morphological elastic and electrical properties of MgO nanoparticles synthesized by combustion method. J Phys Chem Solids 192: 112071. https://doi.org/10.1016/j.jpcs.2024.112071 doi: 10.1016/j.jpcs.2024.112071
    [17] Raja T, Devarajan Y, Nath JK, et al. (2025) Investigation on the thermal performance of MgO-filled basalt fiber/PLA composites for high-temperature industrial applications. Results Eng 27: 105923. https://doi.org/10.1016/j.rineng.2025.105923 doi: 10.1016/j.rineng.2025.105923
  • Reader Comments
  • © 2025 the Author(s), licensee AIMS Press. This is an open access article distributed under the terms of the Creative Commons Attribution License (http://creativecommons.org/licenses/by/4.0)
通讯作者: 陈斌, bchen63@163.com
  • 1. 

    沈阳化工大学材料科学与工程学院 沈阳 110142

  1. 本站搜索
  2. 百度学术搜索
  3. 万方数据库搜索
  4. CNKI搜索

Metrics

Article views(623) PDF downloads(43) Cited by(0)

Article outline

Figures and Tables

Figures(5)  /  Tables(1)

/

DownLoad:  Full-Size Img  PowerPoint
Return
Return

Catalog