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Rapid synthesis of thin amorphous carbon films by sugar dehydration and dispersion

Chemistry Division, U. S. Naval Research Laboratory, Washington D. C., 20375, United States

Topical Section: 2D Materials

We have prepared amorphous carbon films with variable thicknesses down to <5 nm using a simple procedure which takes minutes and employs no special equipment. We prepare a carbonaceous suspension by the dehydration reaction of sulfuric acid with glucose and show that adding this mixture dropwise into water creates a thin carbon film on the water’s surface which can be transferred to an arbitrary substrate. This transparent brown film is non-conductive and has a chemical makeup, excluding hydrogen, of CS0.0213O0.4563. After brief annealing under 10% H2 in argon at 800 °C, the film has a high optical contrast and increased conductivity, with a chemical makeup of CO0.0828, suggesting that the material has at least short-range graphitic order. We repeat the experiment with chitosan replacing glucose and show using Raman spectroscopy and X-ray photoelectron spectroscopy (XPS) that it is likely that nitrogen incorporates into the graphitic lattice.
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References

1. Tro NJ (2011) Chemistry: A Molecular Approach, 2nd ed., Pearson Prentice Hall: Upper Saddle River, NJ, 1013.

2. Zhang J, Shen W, Pan D, et al. (2010) Controlled synthesis of green and blue luminescent carbon nanoparticles with high yields by the carbonization of sucrose. New J Chem 34: 591–593.

3. Peng H, Travas-Sejdic J (2009) Simple aqueous solution route to luminescent carbogenic dots from carbohydrates. Chem Mater 21: 5563–5565.

4. Li H, Kang Z, Liu Y, et al. (2012) Carbon nanodots: synthesis, properties and applications. J Mater Chem 22: 24230–24253.

5. Pan F, Jin J, Fu X, et al. (2013) Advanced oxygen reduction electrocatalyst based on nitrogen-doped graphene derived from edible sugar and urea. ACS Appl Mater Inter 5: 11108–11114.

6. Gupta SS, Sreeprasad TS, Maliyekkal SM, et al. (2012) Graphene from sugar and its application in water purification. ACS Appl Mater Inter 4: 4156–4163.

7. Ruiz-Hitzky E, Darder M, Fernandes FM, et al. (2011) Supported graphene from natural resources: Easy preparation and applications. Adv Mater 23: 5250–5255.

8. Ruan G, Sun Z, Peng Z, et al. (2011) Growth of graphene from food, insects, and waste. ACS Nano 5: 7601–7607.

9. Kubo S, White RJ, Yoshizawa N, et al. (2011) Ordered carbohydrate-derived porous carbons. Chem Mater 23: 4882–4885.

10. Yu C, Fan J, Tian B, et al. (2002) High-yield synthesis of periodic mesoporous silica rods and their replication to mesoporous carbon rods. Adv Mater 14: 1742–1745.

11. Titirici MM, Antonietti M (2010) Chemistry and materials options of sustainable carbon materials made by hydrothermal carbonization. Chem Soc Rev 39: 103–116.

12. Javid A, Kumar M, Yoon S, et al. (2016) Role of surface-electrical properties on the cell-viability of carbon thin films grown in nanodomain morphology. J Phys D Appl Phys 49: 264001.    

13. Javid A, Kumar M, Han JG (2015) Nanoscale surface conductivity analysis of plasma sputtered carbon thin films. RSC Adv 5: 96360–96365.

14. Kumar M, Piao JX, Jin SB, et al. (2016) Low temperature plasma processing for cell growth inspired carbon thin films fabrication. Arch Biochem Biophys 605: 41–48.

15. Piao JX, Kumar M, Javid A, et al. (2016) Pulsed DC-plasma sputtering induced synthesis of hydrogenated carbon thin films for L-929 cell cultivation. Surf Coat Tech.

16. Ryoo R, Joo SH, Jun S (1999) Synthesis of highly ordered carbon molecular sieves via template-mediated structural transformation. J Phys Chem B 103: 7743–7746.

17. Su C, Loh KP (2012) Carbocatalysts: Graphene oxide and its derivatives. Acc Chem Res 46: 2275–2285.

18. Qu L, Liu Y, Baek JB, et al. (2010) Nitrogen-doped graphene as efficient metal-free electrocatalyst for oxygen reduction in fuel cells. ACS Nano 4: 1321–1326.

19. Vijapur SH, Wang D, Botte GG (2013) The growth of transparent amorphous carbon thin films from coal. Carbon 54: 22–28.

20. Ferrari AC, Robertson J (2001) Origin of the 1150 cm-1 Raman mode in nanocrystalline diamond. Phys Rev B 63: 121405.

21. Jorio A, Dresselhaus M, Saito R, et al. (2011) Raman Spectroscopy in Graphene Related Systems, Wiley-VCH: Weinheim, Germany.

22. Kaplas T, Kuzhir P (2016) Ultra-thin graphitic film: Synthesis and physical properties. Nanoscale Res Lett 11: 1–6.

23. Kaplas T, Svirko Y (2012) Direct deposition of semitransparent conducting pyrolytic carbon films. J Nanophotonics 6: 061703–061703.

24. Ferrari AC, Basko DM (2013) Raman spectroscopy as a versatile tool for studying the properties of graphene. Nat Nanotechnol 8: 235–246.

25. Zhou JH, Sui ZJ, Zhu J, et al. (2007) Characterization of surface oxygen complexes on carbon nanofibers by TPD, XPS and FT-IR. Carbon 45: 785–796.

26. Desimoni E, Casella GI, Morone A, et al. (1990) XPS determination of oxygen-containing functional groups on carbon-fibre surfaces and the cleaning of these surfaces. Surf Interface Anal 15: 627–634.

27. López GP, Castner DG, Ratner BD (1991) XPS O1s binding energies for polymers containing hydroxyl, ether, ketone and ester groups. Surf Interface Anal 17: 267–272.

28. Plomp AJ, Su DS, Jong KPD, et al. (2009) On the nature of oxygen-containing surface groups on carbon nanofibers and their role for Platinum deposition—An XPS and titration study. J Phys Chem C 113: 9865–9869.

29. Wang H, Maiyalagan T, Wang X (2012) Review on recent progress in nitrogen-doped graphene: Synthesis, characterization, and its potential applications. ACS Catal 2: 781–794.

30. Shao Y, Zhang S, Engelhard MH, et al. (2010) Nitrogen-doped graphene and its electrochemical applications. J Mater Chem 20: 7491–7496.

31. Kondo T, Casolo S, Suzuki T, et al. (2012) Atomic-scale characterization of nitrogen-doped graphite: Effects of dopant nitrogen on the local electronic structure of the surrounding carbon atoms. Phys Rev B 86: 035436.    

32. Lahaye J, Nanse G, Bagreev A, et al. (1999) Porous structure and surface chemistry of nitrogen containing carbons from polymers. Carbon 37: 585–590.

33. Choudhary V, Burnett RI, Vlachos DG, et al. (2012) Dehydration of Glucose to 5-(Hydroxymethyl)furfural and Anhydroglucose: Thermodynamic Insights. J Phys Chem C 116: 5116–5120.

34. Franklin RE (1951) Crystallite Growth in Graphitizing and Non-Graphitizing Carbons. Proc R Soc Lond A Math Phys Sci 209: 196–218.

Copyright Info: © 2016, Keith E. Whitener Jr, licensee AIMS Press. This is an open access article distributed under the terms of the Creative Commons Attribution Licese (http://creativecommons.org/licenses/by/4.0)

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