Novel catalysts for recycling PET bottles into monomers have been developed by depositing zinc onto the surface of SBA-15, mitigating ZnO catalyst agglomeration in glycolysis separation processes to enhance reaction yields. Various zinc compounds (Zn(OAc)2, ZnCl2, and ZnSO4) were employed as substrates for catalyst design on the porous, high-surface-area material SBA-15 via impregnation. The presence of distinct Zn species on SBA-15 was confirmed through XRD and EDS analyses. The acidity of the catalyst, a crucial factor in the PET glycolysis process, was assessed using different Zn-containing precursors. NH3-TPD measurement has revealed the highest acidity in ZnCl2, followed by Zn(OAc)2 and ZnSO4, respectively. Glycolysis reactions with a PET:EG ratio of 1:5 and a 1% catalyst at 200℃ for 2 hours revealed the catalytic efficacy of zinc-deposited compounds in the sequence ZnCl2 > Zn(OAc)2 > ZnSO4. Surprisingly, the ZnCl2 catalyst produced the highest yield of bis-2-hydroxyethyl terephthalate (BHET) at 75% and displayed exceptional recycling capability over three cycles, contributing significantly to resource recovery objectives aligned with the Sustainable Development Goals (SDGs).
Citation: Pailin Srisuratsiri, Ketsarin Chantarasunthon, Wanutsanun Sudsai, Pichet Sukprasert, Laksamee Chaicharoenwimolkul Chuaitammakit, Wissawat Sakulsaknimitr. Sustainable plastic bottle recycling: employing zinc-deposited SBA-15 as a catalyst for glycolysis of polyethylene terephthalate[J]. AIMS Environmental Science, 2024, 11(1): 90-106. doi: 10.3934/environsci.2024006
[1] | Abel Cabrera-Martínez, Andrea Conchado Peiró . On the {2}-domination number of graphs. AIMS Mathematics, 2022, 7(6): 10731-10743. doi: 10.3934/math.2022599 |
[2] | Abel Cabrera Martínez, Iztok Peterin, Ismael G. Yero . Roman domination in direct product graphs and rooted product graphs. AIMS Mathematics, 2021, 6(10): 11084-11096. doi: 10.3934/math.2021643 |
[3] | Yubin Zhong, Sakander Hayat, Suliman Khan, Vito Napolitano, Mohammed J. F. Alenazi . Combinatorial analysis of line graphs: domination, chromaticity, and Hamiltoniancity. AIMS Mathematics, 2025, 10(6): 13343-13364. doi: 10.3934/math.2025599 |
[4] | Shumin Zhang, Tianxia Jia, Minhui Li . Partial domination of network modelling. AIMS Mathematics, 2023, 8(10): 24225-24232. doi: 10.3934/math.20231235 |
[5] | Ana Klobučar Barišić, Antoaneta Klobučar . Double total domination number in certain chemical graphs. AIMS Mathematics, 2022, 7(11): 19629-19640. doi: 10.3934/math.20221076 |
[6] | Fu-Tao Hu, Xing Wei Wang, Ning Li . Characterization of trees with Roman bondage number 1. AIMS Mathematics, 2020, 5(6): 6183-6188. doi: 10.3934/math.2020397 |
[7] | Rangel Hernández-Ortiz, Luis Pedro Montejano, Juan Alberto Rodríguez-Velázquez . Weak Roman domination in rooted product graphs. AIMS Mathematics, 2021, 6(4): 3641-3653. doi: 10.3934/math.2021217 |
[8] | Mingyu Zhang, Junxia Zhang . On Roman balanced domination of graphs. AIMS Mathematics, 2024, 9(12): 36001-36011. doi: 10.3934/math.20241707 |
[9] | Huiqin Jiang, Pu Wu, Jingzhong Zhang, Yongsheng Rao . Upper paired domination in graphs. AIMS Mathematics, 2022, 7(1): 1185-1197. doi: 10.3934/math.2022069 |
[10] | Ahlam Almulhim . Signed double Italian domination. AIMS Mathematics, 2023, 8(12): 30895-30909. doi: 10.3934/math.20231580 |
Novel catalysts for recycling PET bottles into monomers have been developed by depositing zinc onto the surface of SBA-15, mitigating ZnO catalyst agglomeration in glycolysis separation processes to enhance reaction yields. Various zinc compounds (Zn(OAc)2, ZnCl2, and ZnSO4) were employed as substrates for catalyst design on the porous, high-surface-area material SBA-15 via impregnation. The presence of distinct Zn species on SBA-15 was confirmed through XRD and EDS analyses. The acidity of the catalyst, a crucial factor in the PET glycolysis process, was assessed using different Zn-containing precursors. NH3-TPD measurement has revealed the highest acidity in ZnCl2, followed by Zn(OAc)2 and ZnSO4, respectively. Glycolysis reactions with a PET:EG ratio of 1:5 and a 1% catalyst at 200℃ for 2 hours revealed the catalytic efficacy of zinc-deposited compounds in the sequence ZnCl2 > Zn(OAc)2 > ZnSO4. Surprisingly, the ZnCl2 catalyst produced the highest yield of bis-2-hydroxyethyl terephthalate (BHET) at 75% and displayed exceptional recycling capability over three cycles, contributing significantly to resource recovery objectives aligned with the Sustainable Development Goals (SDGs).
Multilevel programming deals with decision-making situations in which decision makers are arranged within a hierarchical structure. Trilevel programming, the case of multilevel programming containing three planner, occurs in a variety of applications such as planning [6,7], security and accident management [1,18], supply chain management [14,17], economics, [10] and decentralized inventory [9]. In a trilevel decision-making process, the first-level planner (leader), in attempting to optimize his objective function, chooses values for the variables that he controls. Next, the second-level planner in attempting to optimize his objective function while considering the reactions of the third-level planner chooses values for the variables that he controls. Lastly, the third-level planner, with regard to the decisions made by the previous levels, optimizes his own objective function. A number of researchers have studied the linear trilevel programming (LTLP) problem, and have proposed some procedures to solve it. Some algorithms are proposed based on penalty method [16], Kuhn-Tucker transformation [2], multi-parametric approach [5], and enumerating extreme points of constraint region [19] to find the exact optimal solution to special classes of trilevel programming problem. In addition, because of the complexity of solving trilevel problems especially for large-scale problems, some other researches attempted to use fuzzy [13] and meta-heuristic approaches [8,15] to find good approximate solutions for these problems. For a good bibliography of the solution approaches to solve trilevel programming problems, the interested reader can refer to [11].
The present study investigates the trilevel Kth-best algorithm offered by Zhang et. al. [19] at a higher level of accuracy. First, some of the geometric properties of the feasible region of the LTLP problem have been stated and proven. It ought to be mentioned that despite the similarity of some presented theoretical results in this paper with Ref. [19], the techniques of the proof are different. Then, a modified version of the trilevel Kth-Best algorithm has been proposed regarding unboundedness of objective functions in both the second level and third level which is not considered in the proposed Kth-Best algorithm in reference [19]. Moreover, it is shown that the amount of computations in the solving process by the modified trilevel Kth-Best algorithm is less than of that of the solving process by the traditional trilevel Kth-Best algorithm. In addition, in case of finding the optimal solution of linear trilevel programming problems with conflicting objective functions, the modified Kth-Best algorithm is capable of giving more accurate solutions.
The organization of the paper is as follows. Basic definitions concerning LTLP problem that we shall investigate, are presented in Section 2. Some theoretical and geometric properties of the LTLP problem are studied in Section 3. Based on the facts stated in Section 3, a modified trilevel Kth-Best algorithm is proposed to solve the LTLP problem in Section 4. To show the superiority of the proposed algorithm over the traditional Kth-Best algorithm, some numerical examples are presented in Section 5. Ultimately, the paper is concluded with Section 6.
As it is mentioned before, we consider the linear trilevel programming problem which can be formulated as follows:
minx1∈X1f1(x1,x2,x3)=3∑j=1αT1jxjs.t3∑j=1A1jxj≤b1where x2,x3 solve:minx2∈X2f2(x1,x2,x3)=3∑j=1αT2jxjs.t3∑j=1A2jxj≤b2where x3 solves:minx3∈X3f3(x1,x2,x3)=3∑j=1αT3jxjs.t3∑j=1A3jxj≤b3 | (2.1) |
where
In this section, we state some definitions and notations about the LTLP problem.
● Constraint region:
● Constraint region for middle and bottom level, for fixed
● Feasible set for the level 3, for fixed
● Rational reaction set for level 3, for fixed
● Feasible set for level 2, for fixed
● Rational reaction set for level 2, for fixed
● Inducible region :
In the above definitions, the term
Definition 2.1. A point
Definition 2.2. A feasible point
In view of the above Definitions, determining the solution for the LTLP problem (2.1) is equal to solve the following problem:
min{f1(x1,x2,x3):(x1,x2,x3)∈IR}. | (2.2) |
In this section, we will demonstrate some geometric properties of the problem (2.1). Let
Assumption 3.1.
Assumption 3.2.
Assumption 3.3.
Note that by Assumption 3.1, we can conclude that
Example 3.1.
maxx1x1+10x2−2x3+x4s.t0≤x1≤1maxx2,x3x2+2x3s.tx2+x3≤x10≤x2,x3≤1x4=0maxx4x4s.tx4≤x3x4≤1−x3 |
In this example, we have
Ψ3(x1,x2,x3)={x3 if 0≤x3≤12,1−x3 if 12≤x3≤1. |
Then,
and
Ψ2(x1)=argmax{x2+2x3:(x2,x3,x4)∈Ω2(x1)} | (3.1) |
It is clear that if
Ψ2(x1)={(x1,0,0) if0≤x1<1(0,1,0) ifx1=1 |
It is evident that
Lemma 3.1. Let
Proof. It follows from
minx2≥03∑j=2αT2jxjs.t3∑j=2A2jxj≤b2−A21ˉx1where x3 solves:minx3≥03∑j=2αT3jxjs.t3∑j=2A3jxj≤b3−A31ˉx1 | (3.2) |
By Theorem 5.2.2 of [3] we conclude that
Since
Thus, it can be concluded that
Corollary 3.1. Let
Proof. The statement is immediately derived from the fact that
Theorem 3.1. Let
Proof. Let
Moreover, we can choose
Besides, for all
Consequently, from Corollary 3.1, it can be concluded that:
In addition,
Eventually,
If we repeat the process, we can construct from
Therefore, we approach point
Corollary 3.2. The inducible region of the LTLP problem can be written as the union of some faces of S that are not necessarily connected.
Corollary 3.3. If
Proof. Notice that the problem (2.2) can be written equivalently as
min{f1(x1,x2,x3):(x1,x2,x3)∈conv IR} | (3.3) |
where conv
Through the above results, it has been demonstrated that there exists at least a vertex of
In this section, the modified trilevel Kth-Best algorithm is presented. In actual, the modified algorithm takes into account LTLP problems with unbounded middle and bottom level problems. These cases are not considered in the Kth-Best algorithm [19]. Also, it resolves some of drawbacks while finding an optimal solution for LTLP problems with opposing objectives. Moreover, in the next section, it is shown that in some LTLP problems, the proposed algorithm leads to reduction the amount of computations needed for finding an optimal solution.
The process of the modified trilevel Kth-Best algorithm is as follows:
The Algorithm
Step 1. Initialization: Set
Step 2. Find the optimal solution of the optimization problem (4.1). Let it be
min{f1(x1,x2,x3):(x1,x2,x3)∈S} | (4.1) |
Step 3. Solve the following problem.
min{αT3 3x3:x3∈Ω3(x[k]1,x[k]2)}. | (4.2) |
If the problem (4.2) is unbounded go to step 7, else let
Step 4. If
Step 5. Solve the following problem.
min{αT2 2x2+αT2 3x3:(x2,x3)∈S2(x[k]1),x3=x[k]3}. | (4.3) |
If problem (4.3) is unbounded go to step 7, else let
Step 6. If
Step 7. Set
Step 8. If
Figure 1 illustrates the process of modified trilevel Kth-Best algorithm.
Remark 4.1. It is clear that if
Proposition 4.1. Let the LTLP problem (2.1) has an optimal solution. Then the modified trilevel Kth-Best algorithm will terminate with an optimal solution of LTLP problem in a finite number of iterations.
Proof. Let
It is worth mentioning that, by omitting the examined extreme points from
To illustrate the advantages of the modified trilevel Kth-Best algorithm, the following examples are solved according to the outline indicated in the previous section.
Example 5.1. Consider the following LTLP problem:
minx12x1+2x2+5x3x1≤8x2≤5 where x2,x3 solve:maxx26x1+x2−3x3x1+x2≤8x1+4x2≥87x1−2x2≥0 where x3 solves:minx32x1+x2−2x35x1+5x2+14x3≤40x1,x2,x3≥0 |
In this example, we have
Ψ2(x1)={(72x1,114(40−452x1)):815≤x1≤169}∪{(8−x1,0):169≤x1≤8}. |
It is clear that for
Actually,
which is disconnected. This fact shows that despite the continuity of
By Corollary 3.3, an optimal solution of the above example occurs at the point
To solve the example by the modified trilevel Kth-Best algorithm, the process is as follows:
Iteration 1
1.
2.
3.
4.
Iteration 2
1.
2.
3.
4.
Iteration 3
1.
2.
3.
4. The point
As demonstrated in the solving process of this problem, although the number of iterations and the optimal solution found by the two algorithms are the same, the number of optimization problems needed to be solved in each iteration of the Kth-Best algorithm [19] are more than the number of optimization problems needed to be solved in the modified Kth-Best algorithm. Then the amount of computations in each iteration of the modified Kth-Best algorithm is less than that of the corresponding iteration in the Kth-Best algorithm..
The two following examples show some discrepancies in the Kth-Best algorithm [19] that cause an erroneous result.
Example 5.2.
minxf1(x,y,z)=−x−4z+2ywhere y, z soleve:s.tminyf2(x,y,z)=3y−2zwhere z solves:s.tminzf3(x,y,z)=2z−ys.tx+y+z≤20≤x,y,z≤1 |
In this example, we have
The Kth-Best algorithm process [19] for solving this problem is as follows:
Iteration 1 :
Therefore,
Iteration 2 :
Iteration 7 :
By solving the example via the modified trilevel Kth-Best algorithm, the process is as follows:
Iteration 1
1.
2.
3.
Iteration 2
1.
2.
3.
Continuing this method, at iteration 4 we get:
Note that, in the trilevel Kth-Best algorithm [19], the bottom-level optimal solution which is found for some fixed values of upper and middle-level variables, is not considered as a constraint for the second level problem. This causes the Kth-best algorithm is not capable of finding an optimal solution for some LTLP problems. This fact is considered in step 5 of the modified trilevel Kth-Best algorithm by fixing the lower level variable which is found as the optimal solution of problem (4.2) and substituting it in the problem (4.3).
Example 5.3.
minx1x1−4x2+2x3−x1−x2≤−3−3x1+2x2−x3≥−10where x2,x3 solve:minx2x1+x2−x3−2x1+x2−2x3≤−12x1+x2+4x3≤14where x3 solves:minx3x1−2x2−2x32x1−x2−x3≤2x1,x2,x3≥0 | (5.1) |
The process of the modified trilevel Kth-Best algorithm to solve this problem is as follows:
Iteration 1
1.
2. The bottom level problem corresponding to
3.
4.
5.
Iteration 2
1.
2. The bottom level problem corresponding to
3.
4.
5.
Iteration 3
1.
2. The bottom level problem corresponding to
3.
4.
5.
Iteration 4
1.
2. The bottom level problem corresponding to
3.
4.
5.
Iteration 5
1.
2. The bottom level problem corresponding to
3.
4.
5.
Iteration 6
1.
2. The bottom level problem corresponding to
3.
4.
5.
Iteration 7
1.
2. The bottom level problem corresponding to
.
4.
5.
Iteration 8
1.
2. The bottom level problem corresponding to
4.
5. There is no optimal solution.
In the above example, the constraint region is a bounded polyhedron. Let
minx3x1−2x2−2x32x1−x2−x3≤2x1=x∗1 , x2=x∗2 , x3≥0 | (5.2) |
It is easy to see that the problem (5.2) is unbounded. Therefore,
In this study, the linear trilevel programming problem whereby each planner has his (her) own constraints, was considered. Some geometric properties of the inducible region were discussed. Under certain assumptions, it is proved that if the inducible region is non-empty, then it is composed of the union of some non-empty faces of the constraint region
The authors declare no conflict of interest in this paper.
[1] |
Leslie HA, van Velzen MJM, Brandsma SH, et al. (2021) Discovery and quantification of plastic particle pollution in human blood. Environ Int 163: 107199. https://doi.org/10.1016/j.envint.2022.107199 doi: 10.1016/j.envint.2022.107199
![]() |
[2] | Raheem AB, Noor ZZ, Hassan A, et al. (2019) Current developments in chemical recycling of post-consumer polyethylene terephthalate wastes for new materials production: A review. J Clean Prod. 225: 1052–1064. https://doi.org/10.1016/j.jclepro.2019.04.019 |
[3] |
Benyathiar P, Kumar P, Carpenter G, et at. (2022) Polyethylene Terephthalate (PET) Bottle-to-Bottle Recycling for the Beverage Industry: A Review. Polymers 14: 2366. https://doi.org/10.3390/polym14122366 doi: 10.3390/polym14122366
![]() |
[4] |
Zhang Q, Huang R, Yao H, et al. (2021) Removal of Zn2+from polyethylene terephthalate (PET) glycolytic monomers by sulfonic acid cation exchange resin. J Environ Chem Eng 9:105326. https://doi.org/10.1016/j.jece.2021.105326 doi: 10.1016/j.jece.2021.105326
![]() |
[5] |
Vieira CO, Grice JE, Roberts MS, et al. (2018) ZnO:SBA-15 nanocomposites for potential use in sunscreen: Preparation, properties, human skin penetration and toxicity. Skin Pharmacol Physiol 32: 32–42. https://doi.org/10.1159/000491758 doi: 10.1159/000491758
![]() |
[6] | Imran M, Kim DH, Al-Masry WA, et al. (2013) Manganese-, cobalt-, and zinc-based mixed-oxide spinels as novel catalysts for the chemical recycling of poly(ethylene terephthalate) via glycolysis. Polym Degrad Stab. 98: 904–915. https://doi.org/10.1016/j.polymdegradstab.2013.01.007 |
[7] | Kawkumpa S, Saisema T, Seoob O, et al. (2019) Synthesis of polyurethane from glycolysis product of PET using ZnO as catalyst. RMUTSB Acad J 7: 29–39 https://li01.tci-thaijo.org/index.php/rmutsb-sci/article/view/150479 |
[8] |
Shen Z, Zhou H, Chen H, et al. (2018) Synthesis of Nano-Zinc Oxide Loaded on Mesoporous Silica by Coordination Effect and Its Photocatalytic Degradation Property of Methyl Orange. Nanomater 8: 317. https://doi.org/10.3390/nano8050317 doi: 10.3390/nano8050317
![]() |
[9] | Nguyen QNK, Yen NT, Hau ND, et al. (2020) Synthesis and Characterization of Mesoporous Silica SBA-15 and ZnO/SBA-15 Photocatalytic Materials from the Ash of Brickyards. J Chem Article ID 8456194, 8 pages: https://doi.org/10.1155/2020/8456194 |
[10] | Wen H, Zhou X, Shen Z, et al. (2019) Synthesis of ZnO nanoparticles supported on mesoporous SBA-15 with coordination effect -assist for anti-bacterial assessment. Colloids Surf. B 181: 285–294. https://doi.org/10.1016/j.colsurfb.2019.05.055 |
[11] | Bhuyan D, Saikia M, Saikia L. (2018) ZnO nanoparticles embedded in SBA-15 as an efficient heterogeneous catalyst for the synthesis of dihydropyrimidinones via Biginelli condensation reaction. Microporous Mesoporous Mater 256: 39–48. https://doi.org/10.1016/j.micromeso.2017.06.052 |
[12] |
Pal N, Paul M, Bhaumik A. (2011) Highly ordered Zn-doped mesoporous silica: An efficient catalyst for transesterification reaction. J Solid State Chem 184: 1805–1812. https://doi.org/10.1016/j.jssc.2011.05.033 doi: 10.1016/j.jssc.2011.05.033
![]() |
[13] |
Nagvenkar A, Naik S, Fernandes J. (2015) Zinc oxide as a solid acid catalyst for esterification reaction. Catal Commun 65: 20–23. https://doi.org/10.1016/j.catcom.2015.02.009 doi: 10.1016/j.catcom.2015.02.009
![]() |
[14] |
Yao H, Liu L, Yan D, et al. (2022) Colorless BHET obtained from PET by modified mesoporous catalyst ZnO/SBA-15. Chem Eng Sci 248: 117109. https://doi.org/10.1016/j.ces.2021.117109 doi: 10.1016/j.ces.2021.117109
![]() |
[15] |
Datta B, Pasha MA. (2013) Silica-ZnCl2: An Efficient Catalyst for the Synthesis of 4-Methylcoumarins. ISRN Org Chem 13: 1–5. https://doi.org/10.1155/2013/132794 doi: 10.1155/2013/132794
![]() |
[16] |
Lin CC, Li YY. (2009) Synthesis of ZnO nanowires by thermal decomposition of zinc acetate dihydrate. Mater Chem Phys 113: 334–337. https://doi.org/10.1016/j.matchemphys.2008.07.070 doi: 10.1016/j.matchemphys.2008.07.070
![]() |
[17] |
Jones F, Tran H, Lindberg D, et al. (2013) Thermal Stability of Zinc Compounds. Energy and Fuels 27: 5663–5669. https://doi.org/10.1021/ef400505u doi: 10.1021/ef400505u
![]() |
[18] |
Moosavi A, Sarrafi M, Aghaei A, et al. (2012) Synthesis of mesoporous ZnO/SBA-15 composite via sonochemical route. Micro Nano Lett 7: 130–133. DOI: 10.1049/mnl.2011.0461 doi: 10.1049/mnl.2011.0461
![]() |
[19] |
Saha J, Podder J. (2011) Crystallization Of Zinc Sulphate Single Crystals And Its Structural, Thermal And Optical Characterization. J Bangladesh Acad Sci 35: 203–210. https://doi.org/10.3329/jbas.v35i2.9426 doi: 10.3329/jbas.v35i2.9426
![]() |
[20] |
Foad Raji MP. (2013) Study of Hg(Ⅱ) species removal from aqueous solution using hybrid ZnCl2-MCM-41 adsorbent. Appl Surf Sci 282: 415–424. https://doi.org/10.1016/j.apsusc.2013.05.145 doi: 10.1016/j.apsusc.2013.05.145
![]() |
[21] |
Jiang Q, Wu ZY, Wang YM, et al. (2006) Fabrication of photoluminescent ZnO/SBA-15 through directly dispersing zinc nitrate into the as-prepared mesoporous silica occluded with template. J Mater Chem 16: 1536–1542. https://doi.org/10.1039/B516061H doi: 10.1039/B516061H
![]() |
[22] |
Tay YY, Li S, Sun CQ, et al. (2006) Size dependence of Zn 2p 32 binding energy in nanocrystalline ZnO. Appl Phys Lett 88: 173118. https://doi.org/10.1063/1.2198821 doi: 10.1063/1.2198821
![]() |
[23] | Winiarski J, Tylus W, Winiarska K, et al. (2018) XPS and FT-IR Characterization of Selected Synthetic Corrosion Products of Zinc Expected in Neutral Environment Containing Chloride Ions. J Spectrosc Article ID 2079278. https://doi.org/10.1155/2018/2079278 |
[24] |
Miyao T, Kitai M, Ogita T, et al. (2002) Generation of new acidic sites by dispersing zinc oxide fine particles on silica. Zeitschrift fur Phys Chemie 216: 931–939. https://doi.org/10.1524/zpch.2002.216.7.931 doi: 10.1524/zpch.2002.216.7.931
![]() |
[25] |
Gabrienko AA, Arzumanov SS, Toktarev AV, et al. (2017) Different Efficiency of Zn2+ and ZnO Species for Methane Activation on Zn-Modified Zeolite. ACS Catal 7: 1818–1830. https://doi.org/10.1021/acscatal.6b03036 doi: 10.1021/acscatal.6b03036
![]() |
[26] |
Zhiyong Y, Bensimon M, Sarria V, et al. (2007) ZnSO4-TiO2 doped catalyst with higher activity in photocatalytic processes. Appl Catal B Environ 76: 185–195. https://doi.org/10.1016/j.apcatb.2007.05.025 doi: 10.1016/j.apcatb.2007.05.025
![]() |
[27] | Cychosz KA, Thommes M. (2018) Progress in the Physisorption Characterization of Nanoporous Gas Storage Materials. Engineering. 4: 559–566. https://doi.org/10.1016/j.eng.2018.06.001 |
[28] |
Lao-Ubol S, Khunlad R, Larpkiattaworn S, et al. (2016) Preparation, Characterization and Catalytic Performance of ZnO-SBA-15 Catalysts. Key Eng Mater 690: 212–217. https://doi.org/10.4028/www.scientific.net/KEM.690.212 doi: 10.4028/www.scientific.net/KEM.690.212
![]() |
[29] |
Liu J, Liu Y, Liu H, et al. (2021) Silicalite-1 Supported ZnO as an Efficient Catalyst for Direct Propane Dehydrogenation. ChemCatChem 13: 4780–4786. https://doi.org/10.1002/cctc.202101069 doi: 10.1002/cctc.202101069
![]() |
[30] |
Liu G, Liu J, He N, Miao C, et al. (2018) Silicalite-1 zeolite acidification by zinc modification and its catalytic properties for isobutane conversion. RSC Adv 8: 18663–18671. https://doi.org/10.1039/C8RA02467G doi: 10.1039/C8RA02467G
![]() |
[31] | Xin J, Zhang Q, Huang J, et al. (2021) Progress in the catalytic glycolysis of polyethylene terephthalate. J Environ Manage. 296: 113267. https://doi.org/10.1016/j.jenvman.2021.113267 |
[32] |
Al-Sabagh AM, Yehia FZ, Eshaq G, et al. (2016) Greener routes for recycling of polyethylene terephthalate. Egypt J Pet 25: 53–64. https://doi.org/10.1016/j.ejpe.2015.03.001 doi: 10.1016/j.ejpe.2015.03.001
![]() |
[33] |
Imran M, Kim BK, Han M, et al. (2010) Sub- and supercritical glycolysis of polyethylene terephthalate (PET) into the monomer bis(2-hydroxyethyl) terephthalate (BHET). Polym Degrad Stab 95:1686–1693. https://doi.org/10.1016/j.polymdegradstab.2010.05.026 doi: 10.1016/j.polymdegradstab.2010.05.026
![]() |
1. | Sakander Hayat, Raman Sundareswaran, Marayanagaraj Shanmugapriya, Asad Khan, Venkatasubramanian Swaminathan, Mohamed Hussian Jabarullah, Mohammed J. F. Alenazi, Characterizations of Minimal Dominating Sets in γ-Endowed and Symmetric γ-Endowed Graphs with Applications to Structure-Property Modeling, 2024, 16, 2073-8994, 663, 10.3390/sym16060663 |