Research article Special Issues

Coating-assisted laser micromachining of UHMWPE: Thermal control and microchannel optimisation using PDMS and PAA

  • Received: 12 May 2025 Revised: 30 July 2025 Accepted: 12 August 2025 Published: 28 August 2025
  • Ultra-high molecular weight polyethylene (UHMWPE) is established as a material of choice in tribological and biomedical applications because of its superior impact resilience, low coefficient of friction, and outstanding wear resistance. Nevertheless, its intrinsic low thermal conductivity poses significant challenges during laser surface texture (LST), manifesting as thermal anomalies, including surface bulging and geometric distortion. In this study, we addressed these limitations by implementing a thermal regulation framework that integrates polymeric coatings, polyacrylic acid (PAA) and polydimethylsiloxane (PDMS), to mitigate thermally induced deformation in diode laser micromachining. A uniform coating thickness of 150 µm was applied through a controlled screen-printing protocol. The samples were then textured using a 520 nm, 4 W diode laser in a matrix of focal distances (22 to 54 mm) and scanning speeds (2 to 10 mm/s). Quantitative characterization of the resulting microchannels was conducted using confocal microscopy and profilometry, emphasizing dimensional metrics such as depth, width, and height of the curve. PDMS-coated substrates consistently demonstrated superior thermal stability and geometric accuracy among all configurations. At the optimal settings identified (38 mm focal distance, 4 mm/s scanning speed), microchannels exhibited a depth of 43.2 µm, a width of 35.2 µm and a minimal bulge height of 10 µm. This investigation contributes a scalable and cost-efficient approach to the advancing laser-based micromachining of UHMWPE, particularly in applications requiring precise surface architectures. The demonstrated integration of laser parameter optimization with polymer-based thermal modulation offers significant implications for designing and fabricating high-performance components in seawater-lubricated tribosystems and microfluidic biomedical platforms.

    Citation: Ojo Kurdi, Eko Hadi, Ari Santosa, Muhammad Hadi, Rifky Ismail, Oktarina Heriyani. Coating-assisted laser micromachining of UHMWPE: Thermal control and microchannel optimisation using PDMS and PAA[J]. AIMS Materials Science, 2025, 12(4): 845-860. doi: 10.3934/matersci.2025036

    Related Papers:

  • Ultra-high molecular weight polyethylene (UHMWPE) is established as a material of choice in tribological and biomedical applications because of its superior impact resilience, low coefficient of friction, and outstanding wear resistance. Nevertheless, its intrinsic low thermal conductivity poses significant challenges during laser surface texture (LST), manifesting as thermal anomalies, including surface bulging and geometric distortion. In this study, we addressed these limitations by implementing a thermal regulation framework that integrates polymeric coatings, polyacrylic acid (PAA) and polydimethylsiloxane (PDMS), to mitigate thermally induced deformation in diode laser micromachining. A uniform coating thickness of 150 µm was applied through a controlled screen-printing protocol. The samples were then textured using a 520 nm, 4 W diode laser in a matrix of focal distances (22 to 54 mm) and scanning speeds (2 to 10 mm/s). Quantitative characterization of the resulting microchannels was conducted using confocal microscopy and profilometry, emphasizing dimensional metrics such as depth, width, and height of the curve. PDMS-coated substrates consistently demonstrated superior thermal stability and geometric accuracy among all configurations. At the optimal settings identified (38 mm focal distance, 4 mm/s scanning speed), microchannels exhibited a depth of 43.2 µm, a width of 35.2 µm and a minimal bulge height of 10 µm. This investigation contributes a scalable and cost-efficient approach to the advancing laser-based micromachining of UHMWPE, particularly in applications requiring precise surface architectures. The demonstrated integration of laser parameter optimization with polymer-based thermal modulation offers significant implications for designing and fabricating high-performance components in seawater-lubricated tribosystems and microfluidic biomedical platforms.



    加载中


    [1] Cheng B, Shang H, Duan H, et al. (2025) Tribological behavior of ultra-high molecular weight polyethylene (UHMWPE) with different molecular weights under artificial seawater lubrication. J Appl Polym Sci 142: e56918. https://doi.org/10.1002/app.56918 doi: 10.1002/app.56918
    [2] Zhou X, Li B, Huang Q, et al. (2025) Effects of graphene oxide and graphene spatial orientation on tribological properties of UHMWPE composites. Wear 564–565: 205684. https://doi.org/10.1016/j.wear.2024.205684 doi: 10.1016/j.wear.2024.205684
    [3] Hussain O, Ahmad B, Sheikh SS (2021) Biotribological performance of medical-grade UHMW polyethylene-based hybrid composite for joint replacement. Polym Polym Compos 29: S1424–S1431. https://doi.org/10.1177/09673911211058088 doi: 10.1177/09673911211058088
    [4] Li W, Wang Z, Liu N, et al. (2022) Study on tribological characteristics of ultra-high molecular weight polyethylene under unsaturated lubrication of water and brine. Polymers 14: 4138. https://doi.org/10.3390/polym14194138 doi: 10.3390/polym14194138
    [5] Chang T, Yuan C, Guo Z (2019) Tribological behavior of aged UHMWPE under water-lubricated condition. Tribol Int 133: 1–11. https://doi.org/10.1016/j.triboint.2018.12.038 doi: 10.1016/j.triboint.2018.12.038
    [6] Baena JC, Peng Z (2017) Mechanical and tribological performance of UHMWPE influenced by temperature change. Polym Test 62: 102–109. https://doi.org/10.1016/j.polymertesting.2017.06.017 doi: 10.1016/j.polymertesting.2017.06.017
    [7] Rahman MDM, Biswas MAS, Hoque KN (2022) Recent development on micro-texturing of UHMWPE surfaces for orthopedic bearings: A review. Biotribology 31: 100216. https://doi.org/10.1016/j.biotri.2022.100216 doi: 10.1016/j.biotri.2022.100216
    [8] Sufyan M, Hussain M, Ahmad H, et al. (2019) Bulge micro-textures influence on tribological performance of ultra-high-molecular-weight-polyethylene (UHMWPE) under phosphatidylcholine (lipid) and bovine serum albumin (BSA) solutions. Biomed Phys Eng Express 5: 035021. https://doi.org/10.1088/2057-1976/ab0e94 doi: 10.1088/2057-1976/ab0e94
    [9] Cheng B, Shang H, Duan H, et al.(2024) Influence of laser-induced surface carbonization on the tribological properties of UHMWPE in a seawater environment. Appl Surf Sci 645: 158873. https://doi.org/10.1016/j.apsusc.2023.158873 doi: 10.1016/j.apsusc.2023.158873
    [10] Hadi ES, Kurdi O, BS AW, et al. (2022) Influence of laser processing conditions for the manufacture of microchannels on ultrahigh molecular weight polyethylene coated with PDMS and PAA. AIMS Mater Sci 9: 554–571. https://doi.org/10.3934/matersci.2022033 doi: 10.3934/matersci.2022033
    [11] López-Cervantes A, Domínguez-López I, Barceinas-Sánchez JDO, et al. (2013) Effects of surface texturing on the performance of biocompatible UHMWPE as a bearing material during in vitro lubricated sliding/rolling motion. J Mech Behav Biomed Mater 20: 45–53. https://doi.org/10.1016/j.jmbbm.2012.12.010 doi: 10.1016/j.jmbbm.2012.12.010
    [12] Hussain M, Sufyan M, Abbas N, et al. (2019) Influence of laser processing conditions for texturing on ultra-high-molecular-weight-polyethylene (UHMWPE) surface. Case Stud Therm Eng 14: 100491. https://doi.org/10.1016/j.csite.2019.100491 doi: 10.1016/j.csite.2019.100491
    [13] Yang X, Shi M, Dong L, et al. (2010) Effect of UV irradiation on mechanical properties and structure of poly(1, 3, 4-oxadiazole) fibers. Polym Degrad Stab 95: 2467–2473. https://doi.org/10.1016/j.polymdegradstab.2010.08.006 doi: 10.1016/j.polymdegradstab.2010.08.006
    [14] Zhu Y, Jiang Y, Lin R, et al. (2017) Research on thermal degradation process of p-nitrophenol-based polybenzoxazine. Polym Degrad Stab 141: 1–10. https://doi.org/10.1016/j.polymdegradstab.2017.05.001 doi: 10.1016/j.polymdegradstab.2017.05.001
    [15] McDonald JC, Whitesides GM (2002) Poly(dimethylsiloxane) as a material for fabricating microfluidic devices. Acc Chem Res 35: 491–499. https://doi.org/10.1021/ar010110q doi: 10.1021/ar010110q
    [16] Skakov M, Ocheredko I, Tuyakbayev B, et al. (2023) Development and studying of the technology for thermal spraying of coatings made from ultra-high-molecular-weight polyethylene. Coatings 13: 698. https://doi.org/10.3390/coatings13040698 doi: 10.3390/coatings13040698
    [17] Wang C, Bai X, Guo Z, et al. (2021) Friction and wear behaviours of polyacrylamide hydrogel microsphere/UHMWPE composite under water lubrication. Wear 477: 203841. https://doi.org/10.1016/j.wear.2021.203841 doi: 10.1016/j.wear.2021.203841
    [18] Sheng C, He G, Hu Z, et al. (2021) Yarn on yarn abrasion failure mechanism of ultrahigh molecular weight polyethylene fiber. J Eng Fiber Fabr 16: 1–9. https://doi.org/10.1177/15589250211052766 doi: 10.1177/15589250211052766
    [19] Asik MD, Walsh-Rock E, Inverardi N, et al. (2025) Enhanced antibiotic release and mechanical strength in UHMWPE antibiotic blends. J Bone Joint Surg 107: 586–593. https://doi.org/10.2106/JBJS.24.00689 doi: 10.2106/JBJS.24.00689
    [20] Hussain M, Naqvi RA, Abbas N, et al. (2020) Ultra-high-molecular-weight-polyethylene (UHMWPE) as a promising polymer material for biomedical applications: A concise review. Polymers 12: 323. https://doi.org/10.3390/polym12020323 doi: 10.3390/polym12020323
    [21] Sobajima A, Okihara T, Moriyama S, et al. (2020) Multiwall carbon nanotube composites as artificial joint materials. ACS Biomater Sci Eng 6: 7032–7040. https://doi.org/10.1021/acsbiomaterials.0c00916 doi: 10.1021/acsbiomaterials.0c00916
    [22] Zhang X, Tan D, Tang Q, et al. (2024) Impact of thermo-oxidative aging on the dry tribological performance and wear mechanisms of UHMWPE/ZrO2 friction pairs. AIP Adv 14: 035143. https://doi.org/10.1063/5.0197569 doi: 10.1063/5.0197569
    [23] Singh DK, Verma RK (2021) A critical review on ultra high molecular weight polyethylene (UHMWPE) for prosthesis and implant functions. E3S Web Conf 309: 01018. https://doi.org/10.1051/e3sconf/202130901018 doi: 10.1051/e3sconf/202130901018
    [24] AL-Maatoq M, Fuentealba P, Fachet M, et al. (2022) Carbon nanotube-based reinforced polymers for medical applications: Improving impact strength of polymer-polymer composites. J Nanomater 2022: 1760198. https://doi.org/10.1155/2022/1760198 doi: 10.1155/2022/1760198
    [25] Singh S, Das A, Kumar N, et al. (2025) Study on cut-resistance properties of composite yarn-based knitted UHMWPE textiles: Influence of reinforcement, radiant heat exposure, outdoor environment, and cutting angles. J Appl Polym Sci 142: e56690. https://doi.org/10.1002/app.56690 doi: 10.1002/app.56690
    [26] Khalil Y, Hopkinson N, Kowalski AJ, et al. (2022) Investigating the feasibility of processing activated carbon/UHMWPE polymer composite using laser powder bed fusion. Polymers 14: 3320. https://doi.org/10.3390/polym14163320 doi: 10.3390/polym14163320
    [27] Wang M, Zhang Y, Bin J, et al. (2022) Cold laser micro-machining of PDMS as an encapsulation layer for soft implantable neural interface. Micromachines 13: 1484. https://doi.org/10.3390/mi13091484 doi: 10.3390/mi13091484
    [28] Nayak C, Balani K (2021) Effects of reinforcements and gamma-irradiation on wear performance of ultra-high molecular weight polyethylene as acetabular cup liner in hip-joint arthroplasty: A review. J Appl Polym Sci 138: e51275. https://doi.org/10.1002/app.51275 doi: 10.1002/app.51275
    [29] Zhang Y, Jiang Q, Long M, et al. (2022) Femtosecond laser-induced periodic structures: Mechanisms, techniques, and applications. Opto-Electron Sci 1: 220005. https://doi.org/10.29026/oes.2022.220005 doi: 10.29026/oes.2022.220005
    [30] Ham SS, Lee H (2020) Development of method enhanced laser ablation efficiency according to fine curvature of the polymer through the preliminary preparation process using UV picosecond laser. Polymers 12: 959. https://doi.org/10.3390/polym12040959 doi: 10.3390/polym12040959
    [31] Paknejad M, Azarhoushang B, Zahedi A, et al. (2022) Investigation of material removal mechanisms of laser-structured Si3N4 via single diamond grit scratching. Res Sq. https://doi.org/10.21203/rs.3.rs-1974605/v1
    [32] Putignano C, Scarati D, Gaudiuso C, et al. (2019) Soft matter laser micro-texturing for friction reduction: An experimental investigation. Tribol Int 136: 82–86. https://doi.org/10.1016/j.triboint.2019.03.001 doi: 10.1016/j.triboint.2019.03.001
    [33] Faruk O, Yang Y, Zhang J, et al. (2023) A comprehensive review of ultrahigh molecular weight polyethylene fibers for applications based on their different preparation techniques. Adv Polym Technol 2023: 6656692. https://doi.org/10.1155/2023/6656692 doi: 10.1155/2023/6656692
    [34] Rudnik E, Dobkowski Z (1997) Thermal degradation of UHMWPE. J Therm Anal 49: 471–475. https://doi.org/10.1007/BF01987473 doi: 10.1007/BF01987473
    [35] Lei C, Pan Z, Chen J, et al. (2018) Influence of processing parameters on the structure size of microchannel processed by femtosecond laser. Opt Laser Technol 106: 47–51. https://doi.org/10.1016/j.optlastec.2018.03.024 doi: 10.1016/j.optlastec.2018.03.024
    [36] Cai T, Zhan S, Yang T, et al. (2022) Study on the tribological properties of UHMWPE modified by UV-induced grafting under seawater lubrication. Tribol Int 168: 107419. https://doi.org/10.1016/j.triboint.2021.107419 doi: 10.1016/j.triboint.2021.107419
    [37] Vadivel HS, Somberg J, Kalin M, et al. (2022) Tribological performance of a UHMWPE-based multiscale composite under different lubrication and loads. Lubr Sci 34: 480–492. https://doi.org/10.1002/ls.1603 doi: 10.1002/ls.1603
    [38] Imran M, Rahman RA, Ahmad M, et al. (2016) Fabrication of microchannels on PMMA using a low-power CO2 laser. Laser Phys 26: 096101. https://doi.org/10.1088/1054-660X/26/9/096101 doi: 10.1088/1054-660X/26/9/096101
    [39] Fernández-Pradas JM, Naranjo-León S, Morenza JL, et al. (2012) Surface modification of UHMWPE with infrared femtosecond laser. Appl Surf Sci 258: 9256–9259. https://doi.org/10.1016/j.apsusc.2011.09.106 doi: 10.1016/j.apsusc.2011.09.106
    [40] Konari PR, Clayton YD, Vaughan MB, et al. (2021) Experimental analysis of laser micromachining of microchannels in common microfluidic substrates. Micromachines 12: 1–13. https://doi.org/10.3390/mi12020138 doi: 10.3390/mi12020138
    [41] Teixidor D, Orozco F, Thepsonthi T, et al. (2013) Effect of process parameters in nanosecond pulsed laser micromachining of PMMA-based microchannels at near-infrared and ultraviolet wavelengths. Int J Adv Manuf Technol 67: 1651–1664. https://doi.org/10.1007/s00170-012-4598-x doi: 10.1007/s00170-012-4598-x
    [42] Adrian M, Zaharescu T, Jipa S, et al. (2008) The assessment of thermal and radiation stability of UHMWPE. J Optoelectron Adv Mater 10: 826–829.
    [43] Darvishi S, Cubaud T, Longtin JP (2012) Ultrafast laser machining of tapered microchannels in glass and PDMS. Opt Lasers Eng 50: 210–214. https://doi.org/10.1016/j.optlaseng.2011.09.003 doi: 10.1016/j.optlaseng.2011.09.003
    [44] Chung CK, Lin SL, Wang HY, et al. (2013) Fabrication and simulation of glass micromachining using CO2 laser processing with PDMS protection. Appl Phys A 113: 501–507. https://doi.org/10.1007/s00339-013-7555-0 doi: 10.1007/s00339-013-7555-0
    [45] Chung CK, Lin YC, Huang GR (2005) Bulge formation and improvement of the polymer in CO2 laser micromachining. J Micromech Microeng 15: 1878–1884. https://doi.org/10.1088/0960-1317/15/10/013 doi: 10.1088/0960-1317/15/10/013
    [46] Zhang D, Chen A, Wang Q, et al. (2020) Influence of distance between sample surface and focal point on the expansion dynamics of laser-induced silicon plasma under different sample temperatures in air. Optik 202: 163511. https://doi.org/10.1016/j.ijleo.2019.163511 doi: 10.1016/j.ijleo.2019.163511
    [47] Gu L, Yu G, Li CW (2018) A fast and low-cost microfabrication approach for six types of thermoplastic substrates with reduced feature size and minimized bulges using sacrificial layer-assisted laser engraving. Anal Chim Acta 997: 24–34. https://doi.org/10.1016/j.aca.2017.10.030 doi: 10.1016/j.aca.2017.10.030
    [48] Sunderlal Singh S, Khare A, Joshi SN (2020) Fabrication of microchannel on polycarbonate below the laser ablation threshold by repeated scan via the second harmonic of Q-switched Nd:YAG laser. J Manuf Process 55: 359–372. https://doi.org/10.1016/j.jmapro.2020.04.006 doi: 10.1016/j.jmapro.2020.04.006
    [49] Zhao R, Ma C, Gao X, et al. (2023) Investigation of overflow-water-assisted femtosecond laser-induced plasma modulation of microchannel morphology. Coatings 13: 1541. https://doi.org/10.3390/coatings13091541 doi: 10.3390/coatings13091541
    [50] Ariati R, Sales F, Souza A, et al. (2021) Polydimethylsiloxane composites characterization and its applications: A review. Polymers 13: 4258. https://doi.org/10.3390/polym13234258 doi: 10.3390/polym13234258
    [51] Ndeda R (2012) Modeling of factors influencing bulge formation in polymers during laser micromachining.
    [52] Feng H, Jiang S, Shang-Guan Y (2021) Three-dimensional computational fluid dynamic analysis of high-speed water-lubricated hydrodynamic journal bearing with groove texture considering turbulence. Proc Inst Mech Eng Part J 235: 2272–2286. https://doi.org/10.1177/1350650121998519 doi: 10.1177/1350650121998519
    [53] Cai J, Han Y, Xiang G, et al. (2022) Influence of the mass conservation cavitation boundary on the tribo-dynamic responses of the micro-groove water-lubricated bearing. Surf Topogr Metrol Prop 10: 045011. https://doi.org/10.1088/2051-672X/ac9acd doi: 10.1088/2051-672X/ac9acd
    [54] Kunizhev BI, Torshkhoeva ZS, Zhelikhazhev RN, et al. (2021) Destruction of polymers under the action of laser radiation. IOP Conf Ser Mater Sci Eng 1083: 012040. https://doi.org/10.1088/1757-899X/1083/1/012040 doi: 10.1088/1757-899X/1083/1/012040
    [55] Chakraborty A, Gottumukkala NR, Gupta MC (2023) Superhydrophobic surface by laser ablation of PDMS. Langmuir 39: 11259–11267. https://doi.org/10.1021/acs.langmuir.3c00818 doi: 10.1021/acs.langmuir.3c00818
    [56] Fan J, Jiang S, Liu Y, et al. (2025) Advanced porous SiOx/PAA microarchitectures: A sustainable approach to high-capacity and ultra-stable anodes. ACS Appl Mater Interfaces 17: 29669–29680. https://doi.org/10.1021/acsami.5c03534 doi: 10.1021/acsami.5c03534
    [57] Liang X, Yang Z (2021) Experimental study on the influence of friction pair material hardness on the tribological behaviors of water-lubricated thrust bearings. Ind Lubr Tribol 73: 929–936. https://doi.org/10.1108/ilt-03-2021-0083 doi: 10.1108/ilt-03-2021-0083
  • Reader Comments
  • © 2025 the Author(s), licensee AIMS Press. This is an open access article distributed under the terms of the Creative Commons Attribution License (http://creativecommons.org/licenses/by/4.0)
通讯作者: 陈斌, bchen63@163.com
  • 1. 

    沈阳化工大学材料科学与工程学院 沈阳 110142

  1. 本站搜索
  2. 百度学术搜索
  3. 万方数据库搜索
  4. CNKI搜索

Metrics

Article views(713) PDF downloads(71) Cited by(0)

Article outline

Figures and Tables

Figures(3)  /  Tables(4)

/

DownLoad:  Full-Size Img  PowerPoint
Return
Return

Catalog