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Correlation of the chemical composition, structure and mechanical properties of basalt continuous fibers

  • Received: 21 June 2019 Accepted: 30 August 2019 Published: 09 September 2019
  • This work presents the study of the dependence of the basalt continuous fibers (BCF) tensile strength on their chemical composition. 14 different basalt deposits were used to obtain continuous fibers by a laboratory scale system. Based on the data for more than 15 articles focused on natural basalt continuous fibers (32 different compositions) and experimental data of 14 experimental BCF series, the correlation of the tensile strength, the acid modulus and the NBO/T parameter was calculated. The PCC (pearson correlation coefficient) value of NBO/T and the tensile strength was 0.79, for acidity modulus and tensile strength -0.53.
    Raman data for experimental BCF confirm the significant influence of the chemical composition of basalts on their structure, which determines their tensile strength. With a decrease in NBO/T, the observed ratio between the Raman bands at low-and high-frequencies gradually increases.

    Citation: Sergey I. Gutnikov, Evgeniya S. Zhukovskaya, Sergey S. Popov, Bogdan I. Lazoryak. Correlation of the chemical composition, structure and mechanical properties of basalt continuous fibers[J]. AIMS Materials Science, 2019, 6(5): 806-820. doi: 10.3934/matersci.2019.5.806

    Related Papers:

  • This work presents the study of the dependence of the basalt continuous fibers (BCF) tensile strength on their chemical composition. 14 different basalt deposits were used to obtain continuous fibers by a laboratory scale system. Based on the data for more than 15 articles focused on natural basalt continuous fibers (32 different compositions) and experimental data of 14 experimental BCF series, the correlation of the tensile strength, the acid modulus and the NBO/T parameter was calculated. The PCC (pearson correlation coefficient) value of NBO/T and the tensile strength was 0.79, for acidity modulus and tensile strength -0.53.
    Raman data for experimental BCF confirm the significant influence of the chemical composition of basalts on their structure, which determines their tensile strength. With a decrease in NBO/T, the observed ratio between the Raman bands at low-and high-frequencies gradually increases.


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    [1] Sarasini F, Tirillò J, Seghini MC (2018) Influence of thermal conditioning on tensile behaviour of single basalt fibres. Compos Part B-Eng 132: 77–86. doi: 10.1016/j.compositesb.2017.08.014
    [2] Fiore V, Scalici T, Di Bella G, et al. (2015) A review on basalt fibre and its composites. Compos Part B-Eng 74: 74–94. doi: 10.1016/j.compositesb.2014.12.034
    [3] Wei B, Cao H, Song S (2010) Tensile behavior contrast of basalt and glass fibers after chemical treatment. Mater Design 31: 4244–4250. doi: 10.1016/j.matdes.2010.04.009
    [4] Overkamp T, Mahltig B, Kyosev Y (2018) Strength of basalt fibers influenced by thermal and chemical treatments. J Ind Text 47: 815–833. doi: 10.1177/1528083716674905
    [5] Lee JJ, Song J, Kim H (2014) Chemical stability of basalt fiber in alkaline solution. Fiber Polym 15: 2329–2334. doi: 10.1007/s12221-014-2329-7
    [6] Scheffler C, Förster T, Mäder E, et al. (2009) Aging of alkali-resistant glass and basalt fibers in alkaline solutions: evaluation of the failure stress by Weibull distribution function. J-Non Cryst Solids 355: 2588–2595. doi: 10.1016/j.jnoncrysol.2009.09.018
    [7] Lezzi PJ, Xiao QR, Tomozawa M, et al. (2013) Strength increase of silica glass fibers by surface stress relaxation: A new mechanical strengthening method. J-Non Cryst Solids 379: 95–106. doi: 10.1016/j.jnoncrysol.2013.07.033
    [8] Jain N, Singh VK, Chauhan S (2017) Review on effect of chemical, thermal, additive treatment on mechanical properties of basalt fiber and their composites. J Mech Behav Mater 26: 205–211.
    [9] Sabet SMM, Akhlaghi F, Eslami-Farsani R (2015) The effect of thermal treatment on tensile properties of basalt fibers. J Ceram Sci Tech 6: 245–248.
    [10] Kuzmin KL, Zhukovskaya ES, Gutnikov SI, et al. (2016) Effects of ion exchange on the mechanical properties of basaltic glass fibers. Int J Appl Glass Sci 7: 118–127. doi: 10.1111/ijag.12118
    [11] Li Z, Xiao T, Zhao S (2016) Effects of surface treatments on Mechanical properties of Continuous basalt fibre cords and their Adhesion with rubber matrix. Fiber Polym 17: 910–916. doi: 10.1007/s12221-016-5928-7
    [12] Gauvin F, Cousin P, Robert M (2015) Improvement of the interphase between basalt fibers and vinylester by nano-reinforced post-sizing. Fiber Polym 16: 434–442. doi: 10.1007/s12221-015-0434-x
    [13] Gutnikov SI, Malakho AP, Lazoryak BI, et al. (2009) Influence of alumina on the properties of continuous basalt fibers. Russ J Inorg Chem 54: 191–196. doi: 10.1134/S0036023609020041
    [14] Liu J, Yang J, Chen M, et al. (2018) Effect of SiO2, Al2O3 on heat resistance of basalt fiber. Thermochim Acta 660: 56–60.
    [15] Deák T, Czigány T (2009) Chemical composition and mechanical properties of basalt and glass fibers: A comparison. Text Res J 79: 645–651. doi: 10.1177/0040517508095597
    [16] Bauer F, Kempf M, Weiland F, et al. (2018) Structure-property relationships of basalt fibers for high performance applications. Compos Part B-Eng 145: 121–128. doi: 10.1016/j.compositesb.2018.03.028
    [17] Karamanov A, Pisciella P, Cantalini C, et al. (2000) Influence of Fe3+/Fe2+ ratio on the crystallization of iron-rich glasses made with industrial wastes. J Am Ceram Soc 83: 3153–3157. doi: 10.1111/j.1151-2916.2000.tb01697.x
    [18] Karamanov A, Pelino M (2001) Crystallization phenomena in iron-rich glasses. J Non-Cryst Solids 83: 139–151.
    [19] Moiseev EA, Gutnikov SI, Malakho AP, et al. (2008) Effect of iron oxides on the fabrication and properties of continuous glass fibers. Inorg Mater 44: 1026–1030. doi: 10.1134/S0020168508090215
    [20] Manylov MS, Gutnikov SI, Lipatov YV, et al. (2015) Effect of deferrization on continuous basalt fiber properties. Mendeleev Commun 5: 386−388.
    [21] Di Genova D, Vasseur J, Hess KU, et al. (2017) Effect of oxygen fugacity on the glass transition, viscosity and structure of silica- and iron-rich magmatic melts. J-Non Cryst Solids 470: 78–85.
    [22] Brooker RA, Kohn SC, Holloway JR, et al. (2001) Structural controls on the solubility of CO2 in silicate melts Part I : bulk solubility data. Chem Geol 174: 225–239. doi: 10.1016/S0009-2541(00)00353-3
    [23] Persikov ES, Bukhtiyarov PG, Sokol AG (2017) Viscosity of hydrous kimberlite and basaltic melts at high pressures. Russ Geol Geophys 58: 1093–1100. doi: 10.1016/j.rgg.2017.08.005
    [24] Smith DR, Cooper RF (2000) Dynamic oxidation of a Fe2+-bearing calcium–magnesium–aluminosilicate glass: the effect of molecular structure on chemical diffusion and reaction morphology. J-Non Cryst Solids 278: 145–163. doi: 10.1016/S0022-3093(00)00323-9
    [25] Ma Z, Tian X, Liao H, et al. (2018) Improvement of fly ash fusion characteristics by adding metallurgical slag at high temperature for production of continuous fiber. J Clean Prod 171: 464–481. doi: 10.1016/j.jclepro.2017.10.031
    [26] Perevozchikova BV, Pisciotta A, Osovetsky BM, et al. (2014) Quality evaluation of the Kuluevskaya basalt outcrop for the production of mineral fiber, Southern Urals, Russia. Energ Procedia 59: 309–314. doi: 10.1016/j.egypro.2014.10.382
    [27] Vasil'eva AA, Kychkin AK, Anan'eva ES, et al. (2014) Investigation into the properties of basalt of the Vasil'evskoe deposit in Yakutia as the raw material for obtaining continuous fibers. Theor Found Chem En 48: 667–670. doi: 10.1134/S004057951405011X
    [28] Chen X, Zhang Y, Huo H, et al. (2017) Improving the tensile strength of continuous basalt fiber by mixing basalts. Fiber Polym 18: 1796–1803. doi: 10.1007/s12221-017-6804-9
    [29] Mysen BO, Virgo D, Scarfe CM (1980) Relations between the anionic structure and viscosity of silicate melts-a Raman spectroscopic study. Am Mineral 65: 690–710.
    [30] Mysen BO, Virgo D, Seifert FA (1982) The structure of silicate melts: implications for chemical and physical properties of natural magma. Rev Geophys 20: 353–383. doi: 10.1029/RG020i003p00353
    [31] Gutnikov SI, Manylov MS, Lipatov YV, et al. (2013) Effect of the reduction treatment on the basalt continuous fiber crystallization properties. J-Non Cryst Solids 368: 45–50. doi: 10.1016/j.jnoncrysol.2013.03.007
    [32] Morozov NN, Bakunov VS, Morozov EN, et al. (2001) Materials based on basalts from the european north of Russia. Glass Ceram 58: 100–104. doi: 10.1023/A:1010947415202
    [33] Chen X, Zhang Y, Hui D, et al. (2017) Study of melting properties of basalt based on their mineral components. Compos Part B-Eng 116: 53–60. doi: 10.1016/j.compositesb.2017.02.014
    [34] Shebanov SM, Novikov IK, Koudryavtsev AA, et al. (2018) Strength characteristics of the filaments and a basalt fiber roving at different clamping lengths and deformation rates. Mech Compos Mater 54: 349–350. doi: 10.1007/s11029-018-9745-5
    [35] Wei B, Cao H, Song S (2010) Tensile behavior contrast of basalt and glass fibers after chemical treatment. Mater Design 31: 4244–4250. doi: 10.1016/j.matdes.2010.04.009
    [36] Chen X, Zhang Y, Huo H, et al. (2018) Study of high tensile strength of natural continuous basalt fibers. J Nat Fibers 1–9.
    [37] Kessler E, Gadow R, Straub J (2016) Basalt, glass and carbon fibers and their fiber reinforced polymer composites under thermal and mechanical load. AIMS Mater Sci 3: 1561–1576. doi: 10.3934/matersci.2016.4.1561
    [38] Dzhigiris DD, Makhova MF, Gorobinskaya VD, et al. (1983) Continuous basalt fiber. Glass Ceram 40: 467–470. doi: 10.1007/BF00703407
    [39] Wei B, Cao H, Song S (2010) Environmental resistance and mechanical performance of basalt and glass fibers. Mater Sci Eng A-Struct 527: 4708–4715. doi: 10.1016/j.msea.2010.04.021
    [40] Bhat T, Fortomaris D, Kandare E, et al. (2018) Properties of thermally recycled basalt fibres and basalt fibre composites. J Mater Sci 53: 1933–1944. doi: 10.1007/s10853-017-1672-7
    [41] Chen Z, Huang Y (2016) Mechanical and interfacial properties of bare basalt fiber. J Adhes Sci Technol 30: 2175–2187. doi: 10.1080/01694243.2016.1174510
    [42] Kuzmin KL, Gutnikov SI, Zhukovskaya ES, et al. (2017) Basaltic glass fibers with advanced mechanical properties. J-Non Cryst Solids 476: 144–150. doi: 10.1016/j.jnoncrysol.2017.09.042
    [43] Di Genova D, Morgavi D, Hess KU, et al. (2015) Approximate chemical analysis of volcanic glasses using Raman spectroscopy. J Raman Spectrosc 46: 1235–1244. doi: 10.1002/jrs.4751
    [44] Welsch AM, Knipping JL, Behrens H (2017) Fe-oxidation state in alkali-trisilicate glasses-A Raman spectroscopic study. J-Non Cryst Solids 471: 28–38. doi: 10.1016/j.jnoncrysol.2017.04.033
    [45] White WB, Minser DG (1984) Raman spectra and structure of natural glasses. J-Non Cryst Solids 67: 45–59. doi: 10.1016/0022-3093(84)90140-6
    [46] Di Muro A, Métrich N, Mercier M, et al. (2009) Micro-Raman determination of iron redox state in dry natural glasses: application to peralkaline rhyolites and basalts. Chem Geol 259: 78–88.
    [47] Mercier M, Di Muro A, Giordano D, et al. (2009) Influence of glass polymerisation and oxidation on micro-Raman water analysis in alumino–silicate glasses. Geochim Cosmochim Ac 73: 197–217. doi: 10.1016/j.gca.2008.09.030
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