Research article Topical Sections

Electrospinning water-soluble/insoluble polymer blends

  • Received: 30 January 2018 Accepted: 04 March 2018 Published: 08 March 2018
  • Electrospun nanofiber mats can be used, e.g., as filter materials, in biotechnological and medical applications, as precursors for the preparation of carbon nanofibers, etc. In most cases, the large surface-to-volume ratio and correspondingly large contact area with the environment is utilized. This ratio can even be further increased by introducing nanostructures into the nanofibers. One possibility to modify the morphology of the nanofibers or the whole mats is based on the introduction of water-soluble additions in spinning solutions of insoluble polymers and afterwards washing them out. In this paper, polyacrylonitrile (PAN) nanofiber mats were blended with eight water-soluble polymers to test which blends are spinnable and result in which modifications of the single nanofibers and the nanofiber mats. Optical examination shows a broad range of possible morphologies which can be gained in this way, paving the way to tailoring the desired geometric properties of PAN nanofiber mats.

    Citation: Daria Wehlage, Robin Böttjer, Timo Grothe, Andrea Ehrmann. Electrospinning water-soluble/insoluble polymer blends[J]. AIMS Materials Science, 2018, 5(2): 190-200. doi: 10.3934/matersci.2018.2.190

    Related Papers:

  • Electrospun nanofiber mats can be used, e.g., as filter materials, in biotechnological and medical applications, as precursors for the preparation of carbon nanofibers, etc. In most cases, the large surface-to-volume ratio and correspondingly large contact area with the environment is utilized. This ratio can even be further increased by introducing nanostructures into the nanofibers. One possibility to modify the morphology of the nanofibers or the whole mats is based on the introduction of water-soluble additions in spinning solutions of insoluble polymers and afterwards washing them out. In this paper, polyacrylonitrile (PAN) nanofiber mats were blended with eight water-soluble polymers to test which blends are spinnable and result in which modifications of the single nanofibers and the nanofiber mats. Optical examination shows a broad range of possible morphologies which can be gained in this way, paving the way to tailoring the desired geometric properties of PAN nanofiber mats.


    加载中
    [1] Nakajima T, Kajiwara K, McIntyre JE (1994) Advanced Fiber Spinning Technology, Woodhead Publishing.
    [2] Li D, Xia Y (2004) Electrospinning of Nanofibers: Reinventing the Wheel? Adv Mater 16: 1151–1170. doi: 10.1002/adma.200400719
    [3] Subbiah T, Bhat GS, Tock RW, et al. (2005) Electrospinning of Nanofibers. J Appl Polym Sci 96: 557–569. doi: 10.1002/app.21481
    [4] Greiner A, Wendorff JH (2007) Electrospinning: A Fascinating Method for the Preparation of Ultrathin Fibers. Angew Chem Int Edit 46: 5670–5703. doi: 10.1002/anie.200604646
    [5] Lackowski M, Krupa A, Jaworek A (2011) Nonwoven Filtration Mat Production by Electrospinning Method. J Phys Conf Ser 301: 012013. doi: 10.1088/1742-6596/301/1/012013
    [6] Filatov Y, Budyka A, Kirichenko V (2007) Electrospinning of Micro- and Nanofibers: Fundamentals and Applications in Separation and Filtration Processes, Moscow: Begell House Inc.
    [7] Lemma SM, Esposito A, Mason M, et al. (2015) Removal of bacteria and yeast in water and beer by nylon nanofibrous membranes. J Food Eng 157: 1–6. doi: 10.1016/j.jfoodeng.2015.02.005
    [8] Wang X, Kim YG, Drew C, et al. (2004) Electrostatic Assembly of Conjugated Polymer Thin Layers on Electrospun Nanofibrous Membranes for Biosensors. Nano Lett 4: 331–334. doi: 10.1021/nl034885z
    [9] Ashammakhi N, Ndreu A, Yang Y, et al. (2012) Nanofiber-based scaffolds for tissue engineering. Eur J Plast Surg 35: 135–149. doi: 10.1007/s00238-008-0217-3
    [10] Schnell E, Klinkhammer K, Balzer S, et al. (2007) Guidance of glial cell migration and axonal growth on electrospun nanofibers of poly-epsilon-caprolactone and a collagen/polyepsilon-caprolactone blend. Biomaterials 28: 3012–3025. doi: 10.1016/j.biomaterials.2007.03.009
    [11] Klinkhammer K, Seiler N, Grafahrend D, et al. (2009) Deposition of electrospun fibers on reactive substrates for in vitro investigations. Tissue Eng Part C 15: 77–85. doi: 10.1089/ten.tec.2008.0324
    [12] Großerhode C, Wehlage D, Grothe T, et al. (2017) Investigation of microalgae growth on electrospun nanofiber mats. AIMS Bioeng 4: 376–385. doi: 10.3934/bioeng.2017.3.376
    [13] Natu MV, de Sousa HC, Gil MH (2011) Electrospun Drug-Eluting Fibers for Biomedical Applications, In: Zilberman M, Active Implants and Scaffolds for Tissue Regeneration. Studies in Mechanobiology, Tissue Engineering and Biomaterials, Berlin, Heidelberg: Springer, 8: 57–85. doi: 10.1007/8415_2010_56
    [14] Pan JF, Liu NH, Sun H, et al. (2014) Preparation and Characterization of Electrospun PLCL/Poloxamer Nanofibers and Dextran/Gelatin Hydrogels for Skin Tissue Engineering. PLoS One 9: e112885. doi: 10.1371/journal.pone.0112885
    [15] Gu JY, Liu NH, Yang XR, et al. (2014) Adiposed-derived stem cells seeded on PLCL/P123 eletrospun nanofibrous scaffold enhance wound healing. Biomed Mater 9: 035012. doi: 10.1088/1748-6041/9/3/035012
    [16] Maslakci NN, Ulusoy S, Uygun E, et al. (2017) Ibuprofen and acetylsalicylic acid loaded electrospun PVP-dextran nanofiber mats for biomedical applications. Polym Bull 74: 3283–3299. doi: 10.1007/s00289-016-1897-7
    [17] Kumar YS, Unnithan AR, Sen D, et al. (2015) Microgravity biosynthesized penicillin loaded electrospun polyurethane-dextran nanofibrous mats for biomedical applications. Colloid Surface A 477: 77–83. doi: 10.1016/j.colsurfa.2015.01.065
    [18] Rzayev ZMO, Bunyatova U, Simsek M (2017) Multifunctional colloidal nanofiber composites including dextran and folic acid as electro-active platforms. Carbohyd Polym 166: 83–92. doi: 10.1016/j.carbpol.2017.02.100
    [19] Deitzel JM, Kleinmeyer J, Harris D, et al. (2001) The Effect of Processing Variables on the Morphology of Electrospun Nanofibers and Textiles. Polymer 42: 261–272. doi: 10.1016/S0032-3861(00)00250-0
    [20] Grothe T, Brikmann J, Meissner H, et al. (2017) Influence of Solution and Spinning Parameters on Nanofiber Mat Creation of Poly(ethylene oxide) by Needleless Electrospinning. Mater Sci 23: 342–349.
    [21] Grimmelsmann N, Grothe T, Homburg SV, et al. (2017) Electrospinning and stabilization of chitosan nanofiber mats. IOP Conf Ser Mater Sci Eng 254: 102006. doi: 10.1088/1757-899X/254/10/102006
    [22] Böttjer R, Grothe T, Ehrmann A (2018) Functional Nanofiber Mats for Medical and Biotechnological Applications, In: Kyosev Y, Mahltig B, Schwarz-Pfeiffer A, Narrow and Smart Textiles, Springer International Publishing.
    [23] Panthi G, Park SJ, Chae SH, et al. (2017) Immobilization of Ag3PO4 nanoparticles on electrospun PAN nanofibers via surface oximation: Bifunctional composite membrane with enhanced photocatalytic and antimicrobial activities. J Ind Eng Chem 45: 277–286. doi: 10.1016/j.jiec.2016.09.035
    [24] Neisiany RE, Lee JKY, Khorasani SN, et al. (2017) Self-healing and interfacially toughened carbon fibre-epoxy composites based on electrospun core-shell nanofibers. J Appl Polym Sci 134: 44956. doi: 10.1002/app.44956
    [25] Kim GH, Park SH, Birajdar MS, et al. (2017) Core/shell structured carbon nanofiber/platinum nanoparticle hybrid web as a counter electrode for dye-sensitized solar cell. J Ind Eng Chem 52: 211–217. doi: 10.1016/j.jiec.2017.03.046
    [26] Guo JY, Niu QJ, Yuan YC, et al. (2017) Electrospun core-shell nanofibers derived Fe-S/N doped carbon material for oxygen reduction reaction. Appl Surf Sci 416: 118–123. doi: 10.1016/j.apsusc.2017.04.135
    [27] Sabantina L, Mirasol JR, Cordero T, et al. (2018) Investigation of Needleless Electrospun PAN Nanofiber Mats. AIP Conf Proc, In press.
    [28] Liu C, Lafdi K (2017) Fabrication and characterization of carbon nanofibers from polyacrylonitrile/pitch blends. J Appl Polym Sci 134: 45388. doi: 10.1002/app.45388
    [29] Ju YW, Oh GY (2017) Behavior of toluene adsorption on activated carbon nanofibers prepared by electrospinning of a polyacrylonitrile-cellulose acetate blending solution. Korean J Chem Eng 34: 2731–2737. doi: 10.1007/s11814-017-0171-5
    [30] Liu YW, Peng XX, Cao Q, et al. (2017) Gel Polymer Electrolyte Based on Poly(vinylidene fluoride)/Thermoplastic Polyurethane/Polyacrylonitrile by the Electrospinning Technique. J Phys Chem C 35: 19140–19146.
    [31] Böttjer R, Grothe T, Wehlage D, et al. (2018) Electrospraying poloxamer/(bio-)polymer blends using a needleless electrospinning machine. J Text Fib Mater 1: 2515221117743079.
    [32] Grothe T, Grimmelsmann N, Homburg SV, et al. (2017) Green Electrospinning of Nanofiber Mats from Biopolymers for Medical and Biotechnological Applications, In: Mahltig B, Textiles: Advances in Research and Applications, Nova Science Publishers.
    [33] Fuchs S, Hartmann J, Mazur P, et al. (2017) Electrospinning of Biopolymers and Biopolymer Blends. J Chem Pharm Sci 10: 1–3.
  • Reader Comments
  • © 2018 the Author(s), licensee AIMS Press. This is an open access article distributed under the terms of the Creative Commons Attribution License (http://creativecommons.org/licenses/by/4.0)
通讯作者: 陈斌, bchen63@163.com
  • 1. 

    沈阳化工大学材料科学与工程学院 沈阳 110142

  1. 本站搜索
  2. 百度学术搜索
  3. 万方数据库搜索
  4. CNKI搜索

Metrics

Article views(5727) PDF downloads(1356) Cited by(19)

Article outline

Figures and Tables

Figures(5)  /  Tables(2)

/

DownLoad:  Full-Size Img  PowerPoint
Return
Return

Catalog