
Emerging per and poly-fluoroalkyl substances (PFASs) are very resistant to degradation and have negative impacts on human and environmental health at very low concentrations. The initial stage in removing PFASs from contaminated locations is their detection and quantification. Particularly utilized in this context are Gas Chromatography-Mass Spectrometry (GC-MS), Liquid Chromatography-Tandem Mass Spectrometry (LC-MS/MS), and High-Performance Liquid Chromatography (HPLC). In this review, we seek to contribute to our understanding of the state-of-the-art in emerging PFAS by offering a complete analysis of PFAS in environments, taking into consideration their sources, classes, and properties. Polyfluoroalkyl ether substances (PFAES), short-chain PFA, replacement PFA, and fluorotelomer-based substances can bioaccumulate in living species, making their detection even more necessary. We intend to provide researchers with an overview of the current state of research on PFASs in environments, encompassing the toxicological effects and their detection and quantification methods, serving as a guide for current and future studies.
Citation: Eliasu Issaka, Mabruk Adams, Enock Adjei Agyekum, Josephine Baffoe, Blessing Tornyeava. Per- and poly-fluoroalkyl substances: A review of sources, properties, chromatographic detection, and toxicological implications[J]. AIMS Environmental Science, 2025, 12(2): 321-351. doi: 10.3934/environsci.2025015
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Emerging per and poly-fluoroalkyl substances (PFASs) are very resistant to degradation and have negative impacts on human and environmental health at very low concentrations. The initial stage in removing PFASs from contaminated locations is their detection and quantification. Particularly utilized in this context are Gas Chromatography-Mass Spectrometry (GC-MS), Liquid Chromatography-Tandem Mass Spectrometry (LC-MS/MS), and High-Performance Liquid Chromatography (HPLC). In this review, we seek to contribute to our understanding of the state-of-the-art in emerging PFAS by offering a complete analysis of PFAS in environments, taking into consideration their sources, classes, and properties. Polyfluoroalkyl ether substances (PFAES), short-chain PFA, replacement PFA, and fluorotelomer-based substances can bioaccumulate in living species, making their detection even more necessary. We intend to provide researchers with an overview of the current state of research on PFASs in environments, encompassing the toxicological effects and their detection and quantification methods, serving as a guide for current and future studies.
(x,y) : Cartesian coordinates; (u,v) : velocity components in the x and y direction; (ξ,η) : dimensionless coordinates; H : magnetic field intensity; Pr: Prandtl number; B : magnetic induction; B0, saturation magnetic induction; M : fluid magnetization; Ms : saturation magnetization; T : fluid temperature; Tc : fluid temperature far away from sheet; Tw : temperature of the sheet; θ : dimensionless temperature; ρ : density of fluid; µ: dynamic viscosity; ν : kinematic viscosity; μ0 : magnetic permeability; cp : specific heat constant pressure; k : thermal conductivity; λa : viscous dissipation parameter; ε : dimensionless temperature parameter; Mn : magnetohydrodynamic parameter; β : ferromagnetic interaction parameter; α, dimensionless distance; m : temperature exponent parameter; λ: stretching parameter.
Studies on biomagnetic fluid flow and heat transfer under the influence of external magnetic fields have been receiving growing attention of researchers owing to their important applications in bioengineering and clinical sciences. Observations derived from related investigation are useful in the design and development of magnetic devices for cell separation, reduction of blood flow during surgery, targeted transport of drugs through the use of magnetic particles as drug carriers, magnetic resonance imaging (MRI) of specific parts of the human body, electromagnetic hyperthermia in cancer treatment etc., as mentioned in earlier communications (see [1,2,3]).
Base on the principles of Ferrohydrodynamics (FHD), a biomagnetic fluid model was developed [4]. This was further extended [5] by combining the principles of Magnetohydrodynamics with those of FHD and applied his model to analyze the flow of blood under the influence of a magnetic field. In [6] the authors studied the flow of a heated ferrofluid over a linearly stretching sheet under the action of a magnetic field generated due to the presence of a magnetic dipole. Laminar two-dimensional flow of an incompressible biofluid over a stretching sheet was studied numerically [7]. The effect of heat transfer on the flow behaviour was also studied by these authors. Flows of biomagnetic viscoelastic fluids in different situations were investigated theoretically [2,3]. These studies reveal that the presence of external magnetic field bears the potential of influencing the flow behaviour of biomagnetic viscoelastic fluids quite appreciably. The mathematical analysed of biomagnetic fluid with stretching sheet [8]. Their model developed by the principles of ferrohydrodynamic and magnetohydrodynamic. In [9] authors presented the biomagnetic fluid over a stretching cylinder. Their problem is formulated by a BFD model which incorporates both principles of FerroHydroDynamics (FHD) and MagnetoHydroDynamics (MHD). In [10] authors discussed the mathematical modelling of the ferro-nanofluid flow with nanoparticles and microorganisms. In [11] authors discussed the theoretical study on the swimming of migratory gyrotactic microorganisms in a non-Newtonian blood flow based nanofluid via an anisotropically narrowing artery. In [12] authors also analyzed the heat transfer properties and the applications of the blood clot model with variable viscosity. In [13] authors also reported the peristaltic blood flow of Sisko fluid with magnetic nanoparticle and they considered Titanium magneto-nanoparticles.
Existence of dual solutions has been reported in various studies by different researchers. Some of them have presented stability analysis also. Mukhopadhyay [14] while dealing with a problem of heat transfer in a moving fluid over a moving flat surface observed the existence of dual solutions. Vajravelu et al. [15] while studying the unsteady flow and heat transfer over a shrinking sheet, with consideration of thermal radiation and viscous dissipation reported the existence of dual solutions for the flow field. In [16] authors observed dual solutions for an unsteady problem of flow past an inclined sheet. In [17] authors found the existence of dual solutions during MHD stagnation point flow over a stretching/shrinking sheet. It was reported [18] that dual solutions exist for boundary layer flow and heat transfer over an exponentially stretching/shrinking sheet. In [19] also discussed the existence of dual solutions for MHD stagnation point flow over a shrinking surface with partial slip. The multiple solutions of magnetohydrodynamic fluid flow and heat transfer of non-Newtonian fluid past a permeable nonlinear shrinking sheet involving convective boundary condition were studied by [20]. Stability analysis has presented in several studies (see [21,22,23]).
Use of Lie group transformation method has been found to be very effective in finding the solutions of highly nonlinear differential equations. It helps determine the invariants and similarity solutions for partial differential equations (see [24,25]). Several researchers (see [26,27,28,29,30]) have used Lie group analysis method for dealing with various problems of fluid flow and heat transfer.
Several problems of flow and heat transfer on sheets/channels under the action of external magnetic/electric fields that have applications to physiological fluid dynamics have been treated mathematically among others by Misra and his collaborators [31,32,33,34,35,36]. The flow and heat transfer of MHD blood as a third-grade non-Newtonian fluid conveying gold nanoparticles in the porous area of hollow vessel analyzed [37]. They considered the viscosity of nanofluid is considered a function of temperature. The numerical solutions of the MHD flow through a porous medium over a stretching sheet were studied [38]. The flow of a power law liquid by a stretchable surface subject to Joule heating, convective boundary conditions, Activation energy and viscous dissipation effects is examined [39]. In [40] authors analyzed the magnetohydrodynamic and thermal radiation on the unsteady flow of a Newtonian liquid through stagnation point due to a linear sheet with mass transpiration. The mixed convection heat transfer combined with thermal radiation of a viscoelastic liquid circulation driven by a porous accelerating sheet under the inclined uniform magnetic field impact were studied by [41].
However, in none of these studies, stability analysis/existence of multiple solutions has been considered. More particularly, to the best of our knowledge, there has not been any attempt to explore the existence of multiple solutions or to discuss the stability for any theoretical analysis for the flows of biomagnetic fluids. With this end in view an attempt has been made in this paper to explore the stability and existence of dual solutions in the context of flow and heat transfer of biomagnetic fluids on stretching/shrinking sheets. The governing equations being highly nonlinear, we have made use of the Lie group transformation method. Finally, the computational results have been obtained with the help of bvp4c function available in Matlab software. Detailed discussion has been made for variations of biomagnetic fluid velocity, temperature, skin friction and heat transfer rate. The study reveals that there exist dual solutions in specific ranges of the vital parameters involved and that one of the two solutions is stable and physically realistic. The validity of the numerical results presented has also been established.
Let us consider the two-dimensional incompressible boundary layer flow and heat transfer of a biomagnetic fluid over a stretching/shrinking sheet (Figure 1), where ¯x−axis is taken along the sheet and ¯y−axis along the normal direction. We assume that stretching/shrinking has a velocity u=axn, where a(>0) is a constant that signifies the stretching situation. When a<0, we have the case of a shrinking sheet. It is assumed that the free stream velocity is U∞(x)=bxn, where b is a positive constant. A magnetic dipole is supposed to be located below the sheet at a distance d which generates a magnetic field of constant strength. Also, we denote the temperature of the sheet by Tw(¯x) and the ambient temperature by Tc(¯x).
Under the assumptions of boundary layer approximation, as well as assumptions for the magnetic field i.e. it is strong enough to attain saturation magnetization and the induced magnetic field is negligible, the governing equations for the problem considering both electrical conductivity and polarization can be written as [5,8]
∂ˉu∂ˉx+∂ˉv∂ˉy=0 | (1) |
ˉu∂ˉu∂ˉx+ˉv∂ˉu∂ˉy=ˉU∞∂ˉU∞∂ˉx+ˉν∂2ˉu∂ˉy2+μ0ρM∂H∂ˉx+σB2(ˉx)ρ(ˉU∞−ˉu) | (2) |
ρcp(ˉu∂T∂ˉx+ˉv∂T∂ˉy)+μ0T∂M∂T(ˉu∂H∂ˉx+ˉv∂H∂ˉy)=k∂2T∂ˉy2 | (3) |
and the boundary conditions as
ˉu=uw(x)=a¯xn,v=vw(¯x),T=Tw=(T∞−D¯xm)at¯y=0 |
ˉu=U∞(x)=b¯xn,T→Tcas¯y→∞. | (4) |
¯u and ¯v being the velocity components along the ¯x− and ¯y− axes, respectively. Other parameters ρ and k represent respectively the fluid density and the thermal conductivity. cp cp is the specific heat at constant pressure, μ the fluid viscosity and μ0 the magnetic permeability. We consider that the magnetic field strength varies linearly with temperature T,M as a linear function of temperature T, given by M=K(Tc−T), K being a constant.
The horizontal and vertical components of the magnetic field generated by a magnetic dipole located at a distance d below the sheet are given by (cf. [7])
Hx(x,y)=−γ2πy+dx2+(y+d)2 and Hy(x,y)=γ2πxx2+(y+d)2
Then, the magnitude ‖H‖=H of the magnetic field is given by
H(x,y)=[H2x+H2y]1/2=γ2π1√x2+(y+d)2≈γ2π[1(y+d)2−12x2(y+d)4] | (5) |
We now introduce the following dimensionless quantities:
x=bcˉx,y=√(n+1)b2νˉy,u=ˉuc,v=√(n+1)2νbˉv,U∞=ˉU∞c,θ(η)=Tc−TTc−Tw | (6) |
where c is a characteristic velocity.
Substituting (6) into Equations (1)-(3), one obtains the non-dimensional equations:
u∂u∂x+v∂u∂y=U∞∂U∞∂x+n+12∂2u∂y2−(n+1)242βθx(y+d)4+Mn.xn−1(U∞−u) | (7) |
(u∂θ∂x+v∂θ∂y)+kμ0ρcp(ε−θ)(u∂H∂x+v∂H∂y)=1Prn+12∂2θ∂y2 | (8) |
in which β=γ2πμ0k(Tc−Tw)ρμ2, Pr=μcpk, Mn=σB20ρa, ε=Tc(Tc−Tw).
Further, on introducing a stream function ψ, where u=∂ψ∂y,v=−∂ψ∂x, the eqs (7) and (8) assume the form
∂ψ∂y∂2ψ∂x∂y−∂ψ∂x∂2ψ∂2y=U∞∂U∞∂x+n+12∂3ψ∂y3+Mnxn−1(U∞−∂ψ∂y)−(n+1)242βθx(y+d)4 | (9) |
∂ψ∂y∂θ∂x−∂ψ∂x∂θ∂x+kμ0ρcp(ε−θ)(∂ψ∂y∂H∂x−∂ψ∂x∂H∂y)=1Prn+12∂2θ∂y2 | (10) |
where the dimensionless form of the boundary conditions expressed in terms of ψ are obtained as
∂ψ∂y=axn,∂ψ∂x=−vw√2νbn+1,θ=1aty=0 |
and
∂ψ∂y=U∞=bxn,θ=0asy→∞. | (11) |
Since it is extremely difficult to solve the coupled nonlinear equations (9) and (10) subject to the boundary conditions (11) even numerically, we resort to the application of a novel type of similarity transformation, called the Lie group transformation (alternatively called the scaling group transformation) given by [30]
Γ:x∗=xeεα1,y∗=yeεα2,ψ∗=ψeεα3,u∗=ueεα4,v∗=veεα5,U∞∗=U∞eεα6,θ∗=θeεα7,H∗=Heεα8 | (12) |
Here ε is the group scaling parameter and αi(i=1,2,...,8) are arbitrary real numbers. Now we find out the values of αi such that the form of (9)-(11) is invariant under the scaling group transformation (12). This transformation can be treated as point transformation, which transforms the coordinates (x,y,ψ,u,v,U∞,θ,H) to (x∗,y∗,ψ∗,u∗,v∗,U∗∞,θ∗,H∗)
Substituting (12) into (9) and (10), we get
eε(α1+2α2−2α3)(∂ψ∗∂y∗∂2ψ∗∂x∗∂y∗−∂ψ∗∂x∗∂2ψ∗∂y∗2)=eε(α1−2α6)U∗∞∂U∗∞∂x∗+n+12eε(3α2−α3)∂3ψ∗∂y∗3 |
+Mx∗n−1eε(α1−nα1−α6)U∗∞+Mx∗n−1eε(α1−nα1+α2−α3)∂ψ∗∂y∗−(n+1)242βθ∗x∗(y∗+d)4eε(4α2−α1−α7) | (13) |
and
eε(α1+α2−α3−α7)(∂ψ∗∂y∗∂θ∗∂x∗−∂ψ∗∂x∗∂θ∗∂y∗)+kμ0ρcpeε(α1+α2−α3−α8)(∂ψ∗∂y∗∂H∗∂x∗−∂ψ∗∂x∗∂H∗∂y∗) |
−kμ0ρcpθ∗eε(α1+α2−α3−α7−α8)(∂ψ∗∂y∗∂H∗∂x∗−∂ψ∗∂x∗∂H∗∂y∗)=1Prn+12∂2θ∗∂y∗2eε(2α2−α7) | (14) |
The transformed equations (13) and (14) are invariant under the Lie group of transformation, if the following relations among the transform parameters are satisfied.
α1+2α2−2α3=α1−2α6=3α2−α3=α1−nα1−α6=α1−nα1+α2−α3=4α2−α1−α7 | (15) |
and
α1+α2−α3−α7=α1+α2−α3−α8=α1+α2−α3−α7−α8=2α2−α7 | (16) |
By using the equations (15)-(16) and the boundary conditions we obtain
α2=−n+12α1,α3=n+12α1,α6=nα1,α7=0,α8=0,α4=nα1,α5=n−12α1 | (17) |
If we insert (17) into the scaling (12), the set of transformations reduces to a one parameter group of transformations given by
Γ:x∗=xeεα1,y∗=yeεn−12α1,ψ∗=ψeεn+12α1,u∗=ueεnα1,v∗=veεn−12α1,U∗∞=U∞eεnα1,θ∗=θand |
H∗=H. |
Expanding by Tailor’s method and remaining terms up to O(ε2) of the one parameter group, we further get
x∗−x=xεα1+o(ε2),y∗−y=−yεn−12α1+o(ε2),ψ∗−ψ=ψεn+12α1+o(ε2), |
u∗−u=uεnα1+o(ε2),v∗−v=vεn−12α1+o(ε2),U∗∞−U∞=U∞εnα1,θ∗−θ=0 |
and
H∗−H=0. | (18) |
From Eq. (18), one can easily deduce the set of transformation in the form of the following characteristic equations:
dxxα1=dy−n−12yα1=dψn+12ψα1=duunα1=dvn−12vα1=dU∞nU∞α1=dθ0=dH0 | (19) |
Integrating the subsidiary equations
dxxα1=dy−n−12yα1, |
we get yxn−12=η (say)
From the subsidiary equations
dxxα1=dθ0, |
we get dθ=0, that is θ(η)= constant =θ (say).
Also integrating the equation dxxα1=dψn+12ψα1,
we get ψxn+12==f(η) (say)
i.e. ψ=xn+12f(η)
Thus the new similarity transformations are obtained as follows:
η=yxn−12,ψ=xn+12f(η),θ=θ(η) | (20) |
Substitution of (20) into (9)-(11), yields the system of nonlinear ordinary differential equations given below
f‴+ff″−2nn+1(f′2−1)+2Mnn+1(1−f′)−n+122βθ(η+α)4=0 | (21) |
and
θ″−Pr(2mn+1f′θ−fθ′)+2λaβ(ε−θ)f(η+α)3=0 | (22) |
The associated boundary conditions are:
f=S,f′=λ,θ=1atη=0f′→1,θ→0asη→∞ | (23) |
in which β=γ2πμ0k(Tc−Tw)ρμ2, λa=μ2ρk(Tc−Tw), Pr=μcpk, Mn=σB20ρa, ε=Tc(Tc−Tw), α=√aρμ. Also λ=ab is the stretching/shrinking parameter, where λ>0 indicates the stretching sheet, λ<0 represents the shrinking sheet and S=2vw√2(n+1)νbx(n−1)/2 is the suction/injection parameter where suction defined by S>0 and S<0 refers to injection.
The important physical characteristics skin friction coefficient Cfx and the local Nusselt number Nux are described as Cfx=τw12ρu2w and
Nux=xqwk(Tc−Tw) | (24) |
In Eqn. (24), τw is the shear stress at wall, while qw represents the wall heat flux, defined by
τw=μ(∂u∂y)y=0andqw=−k(∂T∂y)y=0 | (25) |
Introducing (25) into Eqn. (24), the skin friction coefficient and local Nusselt number can be written in dimensionless form as
12Cfx√Rex=f″(0)andNux/√Rex=−θ′(0) | (26) |
where Rex=uw(x)xν is the local Reynolds number based on the stretching velocity uw(x).
In this section, we present a stability analysis for the unsteady flow of the biomagnetic fluid, by considering the momentum equation in the form
∂u∂t+u∂u∂x+v∂u∂y=U∞∂U∞∂x+n+12∂2u∂y2−(n+1)242βθx(y+d)4+Mn.xn−1(U∞−u) | (27) |
∂θ∂t+(u∂θ∂x+v∂θ∂y)+kμ0ρcp(ε−θ)(u∂H∂x+v∂H∂y)=1Prn+12∂2θ∂y2 | (28) |
where t denotes the time. Here we define another set of dimensionless variables (in tune with equation (20)) as
ψ=xn+12f(η,τ),η=yxn−12,τ=txn−1,θ=θ(η,τ)
In terms of these variables, the expression for the axial and transverse velocities read
u=xn∂f∂η(η,τ)andv=−xn−12n+12[f(η,τ)+n−1n+1η∂f∂η(η,τ)−2n−1n+1τ∂f∂η(η,τ)] | (29) |
Substituting (29) in equation (27) and (28), we have
∂3f∂η3+f∂2f∂η2−2nn+1(∂f∂η)2+2nn+1+2Mnn+1(1−∂f∂η)−n+122βθ(η+α)4−2n+1∂2f∂η∂τ |
−2(n−1)n+1τ∂f∂τ∂2f∂η2=0, | (30) |
∂2θ∂η2−Pr(2mn+1∂f∂ηθ−f∂θ∂η+∂θ∂τ−τ∂f∂η∂θ∂τ+τ∂f∂τ∂θ∂η)+2λaβ(ε−θ)f(η+α)3=0 | (31) |
The associated boundary conditions being
f(0,τ)=S,∂f∂η(0,τ)=λ,∂θ∂η(0,τ)=1 |
and
∂f∂η(η,τ)→0,θ(η,τ)→0asη→∞ | (32) |
To test the stability of the steady flow solution f(η)=F(η), θ(η)=θ0(η) that satisfy the boundary value problem (2) and (3), we write
f(η,τ)=F(η)+e−γτg(η,τ), |
θ(η,τ)=θ0(η)+e−γτG(η,τ) | (33) |
where γ is an unknown eigenvalue parameter and g(η,τ) and G(η,τ) are small as compared to F(η) and θ0(η). By substituting (33) into equation (30) and (31), we get the following linearized problem:
∂3g∂η3+F∂2g∂η2+g∂2F∂η2−2nn+12∂g∂η∂F∂η−2Mnn+1∂g∂η+2n+1γ∂g∂η−2n+1∂2g∂η∂τ− |
2(n−1)n+1τ(∂2g∂η∂τ−γg)∂2F∂η2=0 | (34) |
∂3G∂η3+Pr(F∂G∂η+γG+g∂θ0∂η−G∂F∂η−2θ0∂g∂η)−2βλaεg(η+α)3+2βλa(FG+θ0g)(η+α)3=0 | (35) |
subject to the boundary conditions:
g(0,τ)=0,∂g∂η(0,τ)=0,G(0,τ)=0 |
and
∂g∂η(η,τ)→0,G(0,τ)→0asη→∞ | (36) |
For τ=0, we have f(η)=F(η)andθ(η)=θ0(η) we have the case of steady flow of the fluid characterized by equation (21), while g(η)=g0(η) and G(η)=G0(η) in (34) and (35) characterizes the initial growth or decay of the solution (33). To test our numerical procedure, the following linear eigenvalue problem corresponding to the steady state problem:
g‴0+Fg″0+g0F″−4nn+1F′g′0−2Mnn+1g′0+2n+1γg′0=0 | (37) |
G″0+Pr(FG′0+g0θ′0−g0F′+γG0+g′0θ′0)−2βλεg0(η+α)3+2βλ(FG0+θ0g0)(η+α)3=0 | (38) |
along with the conditions:
g0(0)=0,g′0(0)=0,G0(0)=0
and
g′0(η)→0,G0(0)→0asη→∞. | (39) |
The smallest eigenvalue γ will determine the stability of the corresponding steady flow solution F(η) for all the parameters involved. Hence the boundary condition of g0′(η)→0asη→∞ can be relaxed as suggested by Harris et al. [45] and replace by a new boundary condition g0″(0)=1.
Now we solve the set of nonlinear ordinary differential equations (21) and (22) with boundary conditions (23) numerically by using bvp4c function technique in MATLAB package. We consider f=y1,f′=y2,f″=y3,θ=y4,θ′=y5. Then the equations (7) and (8) are transformed into a system of first order ordinary differential equations as given below.
f′=y2f″=y2′=y3f‴=y3′=−y1y3+2nn+1(y22−1)−2Mnn+1(1−y2)+n+122βy4(η+α)4θ′=y5θ″=y5′=−Pry1y5+2mn+1Pry2y4−2λaβ(ε−y4)y1(η+α)3} | (40) |
along with the initial boundary conditions:
y1(0)=S,y2(0)=λ,y4(0)=1,y2(∞)=1,y4(∞)=0. | (41) |
Equations (40) and (41) are integrated numerically as an initial value problem to a given terminal point. All these simplifications are made by using bvp4c function available in MATLAB software.
The nonlinear ordinary differential equations (21) and (22) with boundary conditions (23), can be solved numerically using the bvp4c programme in MATLAB software. In order to continue to the derivation of the numerical results it is necessary to allocate values to the dimensionless parameters. For this problem, assume that the fluid is blood with ρ=1050kg/m3 and μ=3.2×10−3kgm−1s−1 [1]. The electrical conductivity of blood is σ=0.8sm−1 [5], and the temperature of the fluid is Tc=410c whereas the plate temperature is Tw=370c. As it is known, for temperatures above 41oC, blood cell irreversible structural damages occur, and this is the reason why someone’s life is in danger if he/she is exposed to such high fever. This biological limit of 41oC is by definition the Curie Temperature, Tc, of blood since the definition of Tc in general Ferrohydrodynamics is the temperature, beyond of which, we no longer have the magnetization effect on the fluid (Mn=0) [5]. For the above values of temperature, the temperature number is ε=78.5 [8] and the viscous dissipation number is 6.4×10−14 [8]. Generally, the specific heat under a constant pressure cp and thermal conductivity k of any fluid are temperature dependent. However, the ratio including the above quantities expressed by the Prandtl number can be considered constant with the temperature variation. Therefore, for the temperature range consider in this problem, cp=3.9×103Jkg−1k−1 and k=0.5Jm−1s−1k−1 and hence Pr=25 [6,8]. As far as the parameters related with the magnetic field, in the present study we adopted the values of β to be from 0 to 10, used also in the study of [1,6,8].
In order to establish the validity and accuracy of the method, we have computed the skin friction coefficient for steady flow with β=0,S=0,Mn=0,n=1 and compared with previous studies, as shown in Table 1. The computations of f″(0) in [42,43] were done by using the bvp4c solver and shooting method, respectively. Thus, the usage of these studies in validating the method used in the present study was suitable. It was found that the results were in good agreement. This reassured that the method used was accurate.
Present | Naganthran et.al [42] | Bhattacharyya[43] | ||||
λ | First solution | Second solution | First solution | Second solution | First solution | Second solution |
-0.25 | 1.402239 | 1.402240 | 1.4022405 | |||
-0.5 | 1.49567 | 1.495669 | 1.4956697 | |||
-0.75 | 1.48929 | 1.489298 | 1.4892981 | |||
-1.0 | 1.32882 | 0.00126 | 1.328816 | 0 | 1.3288169 | 0 |
-1.15 | 1.08225 | 0.11576 | 1.082231 | 0.116702 | 1.0822316 | 0.1167023 |
-1.2 | 0.93253 | 0.23286 | 0.932473 | 0.233649 | 0.9324728 | 0.2336491 |
While carrying out numerical computation, we observe that dual solutions exist for a certain range of stretching/shrinking of the sheet and suction parameter. Since the dual solutions exist, we need to ascertain which solution is physically meaningful. With this end in view, we have performed stability analysis. For the sake of brevity, the details of the stability analysis are not being presented here. However, on the basis of the stability test, we find that one set of solutions is stable and physically realizable, while the other solution set is not so.
Figures 2–7 depict the existence of dual solutions for skin friction f″(0) and wall heat transfer gradient θ′(0) for different values of the stretching/shrinking parameter and the suction parameter, when the value of ferromagnetic parameter and nonlinear stretching parameter changes.
The graphs presented in Figures 2 and 3 have been plotted by considering different values of the ferromagnetic parameter and so they clearly depict the ferromagnetic effect of the fluid. It is interesting to note that there exist two solution branches. The first branch represents the stable solution, while the second branch denotes the unstable solution for each value of λ corresponding to a given value of β. From Figure 2, we observe that unique solution exists for λ>−0.2 or λ>−0.3 or λ>−0.4 when β=3,5,7 respectively, while dual solutions exist when −1.395<λ<−0.4 for β=7, when −1.248<λ<−0.3 for β=5 and when −1.136<λ<−0.2 for β=3. Also no solution exists when λ<λc, where λc=−1.136,−1.248,−1.395 for β=3,5,7. respectively, λc being the critical value of λ, at which the two solution branches meet each other and thus a unique solution is obtained.
Variation of wall heat transfer rate θ′(0) with stretching parameter for various values of the ferromagnetic parameter are shown in Figure 3. From this figure, it can be seen that the solution is unique when λ=λc, while dual solutions exist when λc<λ<0.5 and no solutions exist, when λ<λc, where λc is the critical value of λ and the value of λc=−1.392,−1.235,−1.144 with specific values of β=3,5,7. From this figure we also observe that the critical value λc decreases, as the value of the ferromagnetic parameter increases and that of the skin friction coefficient decreases. One way further observe that the effect of the ferromagnetic parameter diminishes in the range of λ for which the solution exists.
The variations of the skin friction coefficient f″(0) and the local Nusselt number θ′(0) with suction parameter for different values of the ferromagnetic parameter are shown in figures 4 and 5 respectively. From these figures, it reveals that the solution is unique when S=Sc, while dual solution exists up to Sc<S<1 and no solutions for S<Sc. One way further note that as the ferromagnetic parameter increases, both the skin friction coefficient and the heat transfer rate at the wall surface decrease.
Figures 6 and 7 depict the variation of the skin friction coefficient f″(0) and heat transfer rate θ′(0) with the stretching/shrinking parameter λ, for different values of nonlinear stretching parameter n. We also note that dual solution exists for a specific range of values of the nonlinear stretching parameter. The aforesaid observations may be summarized as follows:
(ⅰ) For λc<λ<0, dual solutions exist.
(ⅱ) When λ=λc, the solution exists and is unique.
(ⅲ) For λ<λc, no solution exists.
(ⅳ) With an increase in n, there is a reduction in the skin friction coefficient and the heat transfer rate.
(ⅴ) As the nonlinear stretching parameter n increases, the range of similarity solution and that of the existence of dual solutions are both enlarged.
The effects of ferromagnetic parameter β on velocity and temperature distribution are shown in figures 8 and 9. These figures reveal that although the biomagnetic fluid velocity is enhanced as the ferromagnetic parameter increases for both cases (first and second solution), the fluid temperature is diminished, as the value of β rises. Here β is a ferromagnetic parameter and increment of the ferromagnetic parameter results in increment of the magnetic force. For this formulation this results to the increment of the resistance to the flow which is detected as velocity decrement and temperature increment. This signifies that the momentum boundary layer thickness becomes thinner with a rise in the value of the parameter β. For temperature distribution, since induce magnetic interaction parameter slow down the flow motion while passing the sheet which gives more time to the heat dissipates to the flow. This causes enhancement the temperature and simultaneously the thermal boundary layer thickness also gets thicker.
Figures 10 and 11 show that the effect of nonlinear stretching parameter (n) on the velocity and temperature distributions for a particular situation, when β=10,S=1,Mn=1,λ=1,m=1. Figure 10 indicates that the velocity of the biomagnetic fluid is significantly reduced throughout the flow field as n is increased, in the case of the first solution. This signifies that the momentum boundary layer thickness becomes thinner with a rise in the value of the parameter n. But the result is to the contrary in the case of the second solution, except at points very close to the sheet. Figure 11 shows that temperature reduces with increase in n, in the case of the first solution, while for the second solution, a reverse trend is observed.
The effect of suction parameter S on velocity and temperature distributions can be found from figures 12 and 13. According to the first solution (cf. Figure 12), the fluid velocity increases, as the suction velocity enhances, while a reverse trend is observed in the case of the second solution. This can be interpreted physically by saying that since during suction, the fluid in the vicinity of the wall is sucked away, the boundary layer thickness is reduced due to suction and thereby the fluid velocity is enhanced. Figure 13 demonstrates that the fluid temperature is reduced as the quantum of suction increases. This implies that the thermal boundary layer thickness decreases with as suction proceeds. This causes an increase in the rate of heat transfer. However, this is the observation from the first solution. A reverse trend is found to occur, if we consider the second solution. This observation implies that as the fluid is brought closer to the surface, the thermal boundary layer thickness diminishes.
The impact of temperature exponent (m) on velocity and temperature distributions are displayed in figures 14 and 15, respectively. The dual velocity and temperature distributions are also presented in the same figures, alongside the first solutions. It may be noted that in the case of the first solution, as m increases the velocity decreases. But a reverse trend is observed in the case of the second solution. The results imply that increase in the fluid index is accompanied by a reduction in temperature boundary layer thickness also. These are the observations, when we consider the first solution. But for the second solution, the observations are a bit different. Also, the temperature exponent (m) parameter enhances the thermal overshoot near the sheet for the second solution.
The paper is devoted to a theoretical study on the flow of a biomagnetic fluid, by using Lie group transformation method over a stretching/shrinking sheet, under the influence of a magnetic field generated owing to the presence of a magnetic dipole. The governing partial differential equations are transformed into nonlinear ordinary differential equations and solved numerically using BVP4C Matlab package. The effects of dimensionless governing parameters on velocity and temperature profiles of the flow are discussed with the help of graphs. Numerical computations are carried out and discussed for skin friction coefficient and local Nusselt number. Based on the present study we can make the following concluding remarks:
(ⅰ) The dual solutions exist only in the case of a shrinking sheet.
(ⅱ) The stability analysis emphasizes the existence of dual solutions, out of which only one is stable and can be realized physically. But the second solution is not so.
(ⅲ) With increase in the ferromagnetic effect during the fluid flow, the velocity, temperature and thermal boundary layer thickness are reduced.
(ⅳ) The ferromagnetic parameter acts as the controlling parameter and it bears the potential to increase/reduce the thickness of the boundary layer.
(ⅴ) With rise in suction rate/ skin friction the fluid temperature increases.
(ⅵ) With increase in nonlinear stretching, both the heat transfer rate and skin friction are reduced.
(ⅶ) In fine, we would like to make a mention that both the physical parameters S and Re of the problem depend on “x”, which plays the role of a scaling parameter. The present solution is comparable with those reported in [42] and [43]. In the solution we obtain, “x” is considered to be small and the magnetic field gradients are derived from the power series expansion in powers of x (cf. Anderson and Valnes [46]; Tzirtzilakis and Tanoudis [7]). Thus although the general problem is non-similar, the solution presented here is valid only for small values of x.
(ⅷ) As an important scope for future work, one can try the general problem, where x is not restricted to only small values of x. However, the present work will have its importance in validating the results of a non-similar problem.
M. Ferdows designed the study, developed the main conceptual ideas and were in charge of overall direction and planning. G. Murtaza developed the theoretical framework, performed the analytical calculations, Lie group transformation and performed the numerical simulations. J. C. Misra played an important role in making the proper presentation of the manuscript and also in discussing and interpreting the results. Tzirtzilakis and Alsenafi were interpreting the results and discussion, G. Murtaza and M. Ferdows helped to draft the manuscript. All authors discussed the results and commented on the manuscript and approved the final version of this manuscript.
The authors declare that they have no conflict of interest.
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1. | Mohammad Ferdows, Jahangir Alam, Ghulam Murtaza, Efstratios E. Tzirtzilakis, Shuyu Sun, Biomagnetic Flow with CoFe2O4 Magnetic Particles through an Unsteady Stretching/Shrinking Cylinder, 2022, 8, 2312-7481, 27, 10.3390/magnetochemistry8030027 | |
2. | Faris Alzahrani, O. Anwar Bég, M. Ferdows, Numerical solutions for magneto-convective boundary layer slip flow from a nonlinear stretching sheet with wall transpiration and thermal radiation effects, 2024, 85, 1040-7782, 1922, 10.1080/10407782.2022.2163945 |
Present | Naganthran et.al [42] | Bhattacharyya[43] | ||||
λ | First solution | Second solution | First solution | Second solution | First solution | Second solution |
-0.25 | 1.402239 | 1.402240 | 1.4022405 | |||
-0.5 | 1.49567 | 1.495669 | 1.4956697 | |||
-0.75 | 1.48929 | 1.489298 | 1.4892981 | |||
-1.0 | 1.32882 | 0.00126 | 1.328816 | 0 | 1.3288169 | 0 |
-1.15 | 1.08225 | 0.11576 | 1.082231 | 0.116702 | 1.0822316 | 0.1167023 |
-1.2 | 0.93253 | 0.23286 | 0.932473 | 0.233649 | 0.9324728 | 0.2336491 |
Present | Naganthran et.al [42] | Bhattacharyya[43] | ||||
λ | First solution | Second solution | First solution | Second solution | First solution | Second solution |
-0.25 | 1.402239 | 1.402240 | 1.4022405 | |||
-0.5 | 1.49567 | 1.495669 | 1.4956697 | |||
-0.75 | 1.48929 | 1.489298 | 1.4892981 | |||
-1.0 | 1.32882 | 0.00126 | 1.328816 | 0 | 1.3288169 | 0 |
-1.15 | 1.08225 | 0.11576 | 1.082231 | 0.116702 | 1.0822316 | 0.1167023 |
-1.2 | 0.93253 | 0.23286 | 0.932473 | 0.233649 | 0.9324728 | 0.2336491 |