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Exchange bias, and coercivity investigations in hematite nanoparticles

  • Hematite nanoparticles of average size of 20 nm were synthesized using sol-gel method and the structural characterisations were conducted using XRD and TEM. The XRD profile revealed the coexistence of small fraction of maghemite phase along with the main hematite phase. Magnetization versus applied field (M-H) measurements were performed between −5 and 5 T and respectively in the temperatures 2, 10, 30, 50, 70,100,150,200, and 300 K under zero field and 1, 2, 3, 4 T field cooling. At all field-cooling values, the coercivity was found to display a weak temperatures dependence below 150 K and a strong increase above 150 K reaching the largest value of 3352 Oe at 300 K for the field-cooling value of 3 T. Horizontal and vertical hysteresis loop shifts were observed at all temperatures in both the zero-field and field-cooled states. In the field-cooled state, both loop shifts where found to have significant and nonmonotonic field-cooling dependences. However, because saturation magnetization was not attained in all measurements our calculations were based on the minor hysteresis loops. M-H measurements were performed between −9 and 9 T at room temperature under zero field cooling and 1, 2, 3, 4, 5, 6 T field cooling. Saturation magnetization was not attained, and the loops displayed loop shifts similar to those for the ±5 T sweeping field. The highest coercivity value of 4400 Oe is observed for the 6 T field cooled MH loop. The ferromagnetic (FM) contribution towards the total magnetization was separated from the total magnetization and hysteresis loops displayed both horizontal and vertical shifts. The novel results of the temperature and field dependence of exchange bias were attributed mainly to the magnetic exchange coupling between the different magnetic phases (mainly the FM) and the spin-glass-like regions.

    Citation: Venkatesha Narayanaswamy, Imaddin A. Al-Omari, Aleksandr. S. Kamzin, Chandu V. V. Muralee Gopi, Abbas Khaleel, Sulaiman Alaabed, Bashar Issa, Ihab M. Obaidat. Exchange bias, and coercivity investigations in hematite nanoparticles[J]. AIMS Materials Science, 2022, 9(1): 71-84. doi: 10.3934/matersci.2022005

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  • Hematite nanoparticles of average size of 20 nm were synthesized using sol-gel method and the structural characterisations were conducted using XRD and TEM. The XRD profile revealed the coexistence of small fraction of maghemite phase along with the main hematite phase. Magnetization versus applied field (M-H) measurements were performed between −5 and 5 T and respectively in the temperatures 2, 10, 30, 50, 70,100,150,200, and 300 K under zero field and 1, 2, 3, 4 T field cooling. At all field-cooling values, the coercivity was found to display a weak temperatures dependence below 150 K and a strong increase above 150 K reaching the largest value of 3352 Oe at 300 K for the field-cooling value of 3 T. Horizontal and vertical hysteresis loop shifts were observed at all temperatures in both the zero-field and field-cooled states. In the field-cooled state, both loop shifts where found to have significant and nonmonotonic field-cooling dependences. However, because saturation magnetization was not attained in all measurements our calculations were based on the minor hysteresis loops. M-H measurements were performed between −9 and 9 T at room temperature under zero field cooling and 1, 2, 3, 4, 5, 6 T field cooling. Saturation magnetization was not attained, and the loops displayed loop shifts similar to those for the ±5 T sweeping field. The highest coercivity value of 4400 Oe is observed for the 6 T field cooled MH loop. The ferromagnetic (FM) contribution towards the total magnetization was separated from the total magnetization and hysteresis loops displayed both horizontal and vertical shifts. The novel results of the temperature and field dependence of exchange bias were attributed mainly to the magnetic exchange coupling between the different magnetic phases (mainly the FM) and the spin-glass-like regions.



    In recent years, the study of fractional derivatives has been an important topic. It has been used to model many phenomena in numerous fields such as science and engineering. There are many interpretations for fractional derivatives, such as the definition of Caputo [1], the definition of Riemann-Liouville [2], the definition of Grunwald-Letnikov [3], and most recently, Conformable [4], Atangana-Baleanu [5], Wallström [6], Jumarie [7], Klimek [8] and others.

    In practice, where quantitative results are needed for given real-world problems, numerically approximate solutions can often be demonstrably better, more reliable, more detailed, efficient and cost-effective than analytical ones for certain fractional structures. A number of studies [9,10,11,12,13,14] were therefore involved in developing approaches for providing estimated solutions. One of these approaches is the Hilbert space kernel reproduction (RKHS) method used for the first time by S. Zaremba for the harmonic and biharmonic functions at the beginning of the 20th century to find solutions for boundary value problems (BVPs).

    The RKHS precede the Dirac delta function in many ways, among which we mention providing an important structure for random distribution of multi-round data and, providing accurate approximation of multi-dimensional general functions and the possibility to pick any point in the integration interval.

    The RKHS algorithm has been successfully applied to various fields of numerical analysis, computational mathematics, probability and statistics [15,16], biology [17], quantum mechanics and wave mechanics [18]. Therefore wide range of research works have been directed to its applications in various stochastic categories [19], and defined problems involving operator equations [20], partial differential equations [21,22], integrative equations [23,24], and differential integration equations [24,25,26,27,28,29]. In addition, many studies have focused in recent years on the use of the RKHS method as a framework for seeking approximate numerical solutions to different problems [30,31,32,33,34,35,36,37,38,39].

    Moreover, the numerical solution of the different groups of BVP can be found in [40,41,42]. The two-point BVPs has a strong interest in applied mathematics, this kind of problems arise directly from mathematical models or by turning partial differential equations into ordinary differential equations. As this type of problems does not have an exact solution, many special techniques have been used to solve it, including the shooting method [43,44], the collocation method [45,46], the finite difference method [47,48], and the quasilinearization method [49,50]. The continuous genetic algorithm approach was used to solve these schemes in [51,52,53].

    The present paper is structured as follows: in Section 2, we set out some basic concepts and results from fractional calculus theory. In Section 3, the iterative form of the reproducing kernel algorithm is used to build and measure the solution of the fractional differential method with temporal two points. In Section 4 and 5, the convergence and error estimator are discussed to provide a number of numerical results to demonstrate the efficiency and accuracy of the reproducing kernel Hilbert space method. At last in section 6, a conclusion of the results is made.

    In applied mathematics and mathematical analysis, there are several definitions of fractional derivatives, Riemann-Liouville and Caputo are the most popular of all [54]. In this section, we list some of these definitions in addition to reproducing kernel spaces on finite domain [t0,tf].

    Definition 2.1. [55] Let nR+. The operator Jnt0 defined on L1[t0,tf] by

    Jnt0f(x):=1Γ(n)xt0(xζ)n1f(ζ)dζ,

    for t0xtf, is called the Riemann-Liouville fractional integral operator of order n. For n=0, we set J0t0:=I, the identity operator.

    Definition 2.2. [55] Let nR+ and m=[n]. The operator Dnt0 defined by

    Dnt0f:=DmJmnt0f=1Γ(mn)(ddx)mxt0(xζ)mn1f(ζ)dζ,

    is called the Riemann-Liouville fractional differential operator of order n. For n=0, we set D0t0:=I, the identity operator.

    Definition 2.3. [55] Let αR+ and n1<α<n. The operator Dαt0 defined by

    Dαt0f(x)=Jnαt0Dnf(x)=1Γ(nα)xt0(xζ)nα1(ddζ)nf(ζ)dζ,

    for t0xtf, is called the Caputo differential operator of order α.

    Definition 2.4. [35] Let M be nonempty set, the function K:M×MC is a reproducing kernel of the Hilbert space H if the following conditions are met:

    (1) K(.,t)M,tM,

    (2) the reproducing property: tM,zH:z(.),K(.,t)=z(t).

    The second condition means that the value of z at the point t is reproduced by the inner product of z with K.

    Note: The reproducing kernel is unique, symmetric and positive definite.

    Definition 2.5. L2[t0,tf]={ϑ|tft0ϑ2(t)dt<}.

    Definition 2.6. The space W12[t0,tf] is defined as:

    W12[t0,tf]={ϑ|ϑisabsolutelycontinuousrealvaluefunction,ϑL2[t0,tf]}.

    The inner product and its norm are given by:

    {ϑ1(t),ϑ2(t)W12=ϑ1(t0)ϑ2(t0)+tft0ϑ1(t)ϑ2(t)dt,ϑW12=ϑ(t),ϑ(t)W12.

    Definition 2.7. The space W22[t0,tf] is defined by:

    W22[t0,tf]={ϑ|ϑ,ϑareabsolutelycontinuousrealvaluefunctions,ϑL2[t0,tf],ϑ(t0)=0}.

    The inner product and its norm are given by:

    {ϑ1(t),ϑ2(t)W22=ϑ1(t0)ϑ2(t0)+ϑ1(t0)ϑ2(t0)+tft0ϑ1(t)ϑ2(t)dt,ϑW22=ϑ(t),ϑ(t)W22.

    Definition 2.8. W32[t0,tf]={ϑ|ϑ,ϑ,ϑareabsolutelycontinuous,ϑ(3)L2[t0,tf],ϑ(t0)=0,ϑ(tf)=0}.

    The inner product and its norm in W32[t0,tf] are given by:

    {ϑ1(t),ϑ2(t)W32=2i=0ϑ(i)1(t0)ϑ(i)2(t0)+tft0ϑ(3)1(t)ϑ(3)2(t)dt,ϑW32=ϑ(t),ϑ(t)W32,ϑW32.

    Remark 2.1. The Hilbert space Wm2[t0,tf] is called a reproducing kernel if for any fixed t[t0,tf], Kt(s)Wm2[t0,tf] such that ϑ(s),Kt(s)Wm2=ϑ(t) for any ϑ(s)Wm2[t0,tf] and s[t0,tf].

    Remark 2.2.

    (1) In [56], W12 is RKHS and its reproducing kernel is:

    K1(t,s)=12sinh1[cosh(t+s1)+cosh|ts|1].

    (2) In [57], W22 is RKHS and its reproducing kernel is:

    K2(s,t)=16{t(t2+3s(2+t)) ts,s(s2+3t(2+s)) t>s.

    In this section, we develop an iterative method for constructing and calculating fractional differential equations with a temporal two-point solution. In order to emphasize the idea, we start by considering the general form of the BVP:

    {Dαt0X(t)=F(t,X(t),Y(t)),Dαt0Y(t)=G(t,X(t),Y(t)),t0ttf,0α1. (3.1)

    Subject to BC's:

    X(t0)=δ,Y(tf)=β. (3.2)

    where:

    δ, β R, and Dα denotes the Caputo fractional derivative of order α and

    {X(t)=[x1(t),x2(t),...,xm(t)],Y(t)=[y1(t),y2(t),...,yl(t)], and {δ=[δ1(t),δ2(t),...,δm(t)],β=[β1(t),β2(t),...,βl(t)],F=[f1(t),f2(t),...,fm(t)],G=[g1(t),g2(t),...,gl(t)].

    We use the RKHS method to obtain a solution of BVPs (3.1) and (3.2) based on the following methodology:

    ● To attain a problem with homogenous BC's, we first assume that: Y(t0)=γ, (γ arbitrary) and

    {U(t)=X(t)X(t0),V(t)=Y(t)Y(t0). (3.3)

    We get:

    {Dαt0U(t)=Dαt0X(t),Dαt0V(t)=Dαt0Y(t). (3.4)

    Subject to:

    {U(t0)=0,V(t0)=Y(t0)γ=0. (3.5)

    ● Then, we construct the reproducing kernel space W22[t0,tf] in which each function satisfies the homogeneous boundary conditions of (3.5) using the space W12[t0,tf].

    Take Kt(τ) and Rt(τ) to be the reproducing kernel functions of the spaces W22[t0,tf] and W12[t0,tf] respectively.

    ● Next, we define the invertible bounded linear operator L:W22[t0,tf]W12[t0,tf] such that:

    {LU(t)=Dαt0U(t),LV(t)=Dαt0V(t). (3.6)

    The BVPs (3.4), (3.5) can therefore be transformed to the following form:

    {LU(t)=F(t,X(t),Y(t)),LV(t)=G(t,X(t),Y(t)),U(t0)=0,V(t0)=0. (3.7)

    Where U(t) and V(t) are in W22[t0,tf] and F,GW12[t0,tf].

    Applying Riemann-Liouville fractional integral operator Jαt0 to both sides using U(t0)=0 and V(t0)=0, we get:

    U(t)=1Γ(t0)tt0(tτ)α1F(τ,X(τ),Y(τ))dτ=F(t,X(t),Y(t)),V(t)=1Γ(t0)tt0(tτ)α1G(τ,X(τ),Y(τ))dτ=G(t,X(t),Y(t)).

    Thus, we can notice that: LU(t)=U(t), and so the BVPs are transformed to the equivalent form:

    {U(t)=F(t,X(t),Y(t)),V(t)=G(t,X(t),Y(t)),U(t0)=0,V(t0)=0. (3.8)

    ● When choosing a countable dense set {ti}i=1 from [t0,tf] for the reproducing kernel of the space W22[t0,tf], we define a complete system on W22[t0,tf] as: Ψi(t)=LΦi(t) where Φi(t)=Rti(τ), and L is the adjoint operator of L.

    Lemma 3.1. Ψi(t) can be written on the following form:

    Ψi(t)=LτKt(τ)|τ=ti.

    Proof. It is clear that:

    Ψi(t)=LΦi(t)=LΦi(τ),Kt(τ)W22,=Φi(τ),LKt(τ)W12=LτKt|τ=ti.

    ● The orthonormal function system {¯Ψηi(t)}i=1, η=1,2 of the space W22[t0,tf] can be derived from Gram-Schmidt orthogonalization process of {Ψηi(t)}i=1 as follows:

    ¯Ψηi(t)=ik=1BηikΨηk(t),i=1,2,...,η=1,2,

    where Bηik are positive orthogonalization coefficients such that:

    Bη11=1Ψη1,Bηii=1Ψηi2i1k=1(Cηik)2,Bηij=i1k=1CηikBηkjΨηi2i1k=1(Cηik)2,j<i. (3.9)

    Cηik given by: Ψηi,ΨηkW22.

    Theorem 3.1. If the operator L is invertible i.e: L1 exist, and if {ti}i=1 is dense on [t0,tf], then {Ψηi}i=1, η=1,2 is the complete function system of the space W22[t0,tf].

    Proof. For each fixed U(t),V(t)W22[t0,tf], let U(t),Ψ1i(t)=0,and V(t),Ψ2i(t)=0,i=1,2,... that is:

    U(t),Ψ1i(t)W22=U(t),LΦ1i(τ)W22=LU(t),Φ1i(t)W12=LU(ti)=0,V(t),Ψ2i(t)W22=V(t),LΦ2i(τ)W22=LV(t),Φ2i(t)W12=LV(ti)=0,

    since {ti}i=1 is dense on [t0,tf] then LU(t)=0, and LV(t)=0 it follows that U(t)=0,V(t)=0 since L1 exist and U(t),V(t) are continuous.

    Theorem 3.2. For each U(t),V(t)W22[t0,tf] the series

    {i=0U(t),¯Ψ1i(t)W22¯Ψ1i(t),i=0V(t),¯Ψ2i(t)W22¯Ψ2i(t),

    are convergent in the sense of the norm of W22[t0,tf]. In contrast if {ti}i=1 is dense subset on [t0,tf] then the solutions of (3.8) given by:

    {U(t)=i=1ik=1B1ikF(tk,U(tk),V(tk))¯Ψ1i(t),V(t)=i=1ik=1B2ikG(tk,U(tk),V(tk))¯Ψ2i(t). (3.10)

    Proof. Let U(t),V(t)W22[t0,tf] be the solutions of (3.8), since U(t),V(t)W22[t0,tf], and i=1U(t),¯Ψ1i(t)W22[t0,tf]¯Ψ1i(t) and i=1V(t),¯Ψ2i(t)W22[t0,tf]¯Ψ2i(t) represent the Fourier series expansion about normal orthogonal system {¯Ψηi(t)}i=1, η=1,2, and W22[t0,tf] is Hilbert space, then the series i=1U(t),¯Ψ1i(t)W22[t0,tf]¯Ψ1i(t),i=1V(t),¯Ψ2i(t)W22[t0,tf]¯Ψ2i(t) are convergent in the sense of .W22[t0,tf]. In contrast, according to the orthogonal basis {¯Ψηi(t)}i=1, we have:

    U(t)=i=1U(t),¯Ψ1i(t)W22¯Ψ1i(t),=i=1U(t),ik=1B1ikΨ1k(t)W22¯Ψ1i(t),=i=1ik=1B1ikU(t),Ψ1k(t)W22¯Ψ1i(t),=i=1ik=1B1ikU(t),LΦ1k(t)W22¯Ψ1i(t),=i=1ik=1B1ikLU(t),Φ1k(t)W12¯Ψ1i(t),=i=1ik=1B1ikF(tk,U(t),V(t)),Φ1k(t)W12¯Ψ1i(t),=i=1ik=1B1ikF(tk,U(tk),V(tk)))¯Ψ1i(t).

    The same for finding V(t):

    V(t)=i=1ik=1B2ikG(tk,U(tk),V(tk))¯Ψ2i(t).

    The theorem is proved.

    Since W22 is Hilbert space we get:

    i=1ik=1B1ikLU(t),Φ1k(t)W12¯Ψ1i(t)< and i=1ik=1B2ikLV(t),Φ2k(t)W12¯Ψ2i(t)<.

    Hence:

    {Un(t)=ni=1ik=1B1ikF(tk,U(tk),V(tk))¯Ψ1i(t),Vn(t)=ni=1ik=1B2ikG(tk,U(tk),V(tk))¯Ψ2i(t), (3.11)

    are convergent in the sense of .W22 and (3.11) represents the numerical solution of (3.8).

    Remark 3.1.

    (1) If the system (3.7) is linear, then the exact solutions can be found directly from (3.10).

    (2) If the system (3.7) is non linear, then the exact and numerical solutions can be obtained by:

    {U(t)=i=1A1i¯Ψ1i(t),V(t)=i=1A2i¯Ψ2i(t), (3.12)

    where:

    {A1i=ik=1B1ikF(tk,Uk1(tk),Vk1(tk)),A2i=ik=1B2ikG(tk,Uk1(tk),Vk1(tk)). (3.13)

    We use the known quantities ληi,η=1,2 to approximate the unknowns Aηi,η=1,2 as follows: we put t1=t0 and set U0(t1)=U(t1),V0(t1)=V(t1) then U0(t1)=V0(t1)=0 from the conditions of (3.8), and define the n-term approximation to U(t),V(t) by:

    {Un(t)=ni=1λ1i¯Ψ1i(t),Vn(t)=ni=1λ2i¯Ψ2i(t), (3.14)

    where the coefficient ληi(η=1,2,i=1,2,...,n), are presented as follows:

    {λ1n=nk=1B1ikF(tk,Uk1(tk),Vk1(tk)),λ2n=nk=1B2ikG(tk,Uk1(tk),Vk1(tk)), (3.15)

    and so:

    {Un(t)=ni=1λ1i¯Ψ1i(t),Vn(t)=ni=1λ2i¯Ψ2i(t). (3.16)

    We can guarantee that the approximations Un(t),Vn(t) satisfies the conditions enjoined by (3.7) through the iterative process of (3.16).

    In this section, we present some convergence theories to emphasize that the approximate solution we got is close to the exact solution. Indeed, this finding is very powerful and efficient to RKHS theory and its applications.

    Lemma 4.1. Un(t)n=1, and Vn(t)n=1 are monotone increasing in the sense of the norm of .2W22.

    Proof. Since ¯Ψηi(t)i=1,η=1,2 are the complete orthonormal systems in the space W22[t0,tf] then we have:

    {Un(t)2W22=Un(t),Un(t)W22=ni=1λ1i¯Ψ1i(t),ni=1λ1i¯Ψ1i(t)W22=ni=1(λ1i)2,Vn(t)2W22=Vn(t),Vn(t)W22=ni=1λ2i¯Ψ2i(t),ni=1λ2i¯Ψ2i(t)W22=ni=1(λ2i)2.

    Thus Un(t)W22,Vn(t)W22 are monotone increasing.

    Lemma 4.2. As n, the approximate solutions Un(t),Vn(t) and its derivatives Un(t),Vn(t) are uniformly convergent to the exact solutions U(t),V(t) and its derivatives U(t),V(t) respectively.

    Proof. For any t[t0,tf]:

    |Un(t)U(t)|=|Un(t)U(t),Kt(τ)W22|,Kt(τ)W22Un(t)U(t)W22,N1Un(t)U(t)W22,N1R,

    and

    |Vn(t)V(t)|N2Vn(t)V(t)W22,N2R,

    if Un(t)U(t)W220,Vn(t)V(t)W220 as n, then the approximate solutions U(i)n(t),V(i)n(t) are uniformly converges to the exact solutions U(i)(t),V(i)(t)i=1,2 respectively.

    Theorem 4.1. If

    {Un(t)U(t),Vn(t)V(t),

    and F(t,U(t),V(t)),G(t,U(t),V(t)) are continuous in [t0,tf], then:

    {F(tn,Un1(tn),Vn1(tn))F(t,U(t),V(t))G(tn,Un1(tn),Vn1(tn))G(t,U(t),V(t))asn. (4.1)

    Proof. For the first part, we will prove that:

    {Un1(tn)U(t),Vn1(tn))V(t),

    it is easy to see that:

    {|Un1(tn)U(t)|=|Un1(tn)Un1(t)+Un1(t)U(t)||Un1(tn)Un1(t)|+|Un1(t)U(t)|,|Vn1(tn)V(t)|=|Vn1(tn)Vn1(t)+Vn1(t)V(t)||Vn1(tn)Vn1(t)|+|Vn1(t)V(t)|,

    by reproducing property of Kt(τ) we have:

    {Un1(tn)=Un1(τ),Ktn(τ),Vn1(tn)=Vn1(τ),Ktn(τ),

    and

    {Un1(t)=Un1(τ),Kt(τ),Vn1(t)=Vn1(τ),Kt(τ),

    thus

    {|Un1(tn)Un1(t)|=|Un1(τ),Ktn(τ)Kt(τ)W22|Un1(τ)W22Ktn(τ)Kt(τ)W22,|Vn1(tn)Vn1(t)|=|Vn1(τ),Ktn(τ)Kt(τ)W22|Vn1(τ)W22Ktn(τ)Kt(τ)W22,

    and from the symmetric property of Kt(τ) we get:

    Ktn(τ)Kt(τ)W220n,

    hence: |Un1(tn)Un1(t)|0 as tnt.

    By lemma (4.2)

    {Un(t)c.uU(t),Vn(t)c.uV(t),

    thus:

    {|Un1(t)U(t)|0|Vn1(t)V(t)|0 as n.

    Therefore

    {Un1(tn)U(t),Vn1(tn)V(t),

    in the sense of the .W22 as tnt and n for any t[t0,tf].

    Moreover, since F and G are continuous, we obtain:

    {F(tn,Un1(tn),Vn1(tn))F(t,U(t),V(t))G(tn,Un1(tn),Vn1(tn))G(t,U(t),V(t)) as n.

    Theorem 4.2. Suppose that UnW22 and VnW22 are bounded in Eq (3.14), if {ti}i=1 is dense on [t0,tf], then the approximate solutions Un(t), Vn(t) in Eq (3.14) convergent to the exact solutions U(t),V(t) of Eq (3.7) in the space W22[t0,tf] and U(t),V(t) given by (3.12).

    Proof. We first start by proving the convergence of Un(t) and Vn(t) from Eq (3.14) we conclude that:

    {Un+1(t)=Un(t)+λ1n+1¯Ψ1n+1(t),Vn+1(t)=Vn(t)+λ2n+1¯Ψ2n+1(t),

    by orthogonality of {¯Ψηi(t)}i=1,(η)=1,2 we get:

    {Un+1(t)2W22=Un(t)2W22+(λ1n+1)2==U0(t)2W22+n+1i=1(λ1i)2,Vn+1(t)2W22=Vn(t)2W22+(λ2n+1)2==V0(t)2W22+n+1i=1(λ2i)2,

    Un(t)W22,Vn(t)W22 are monotone increasing by Lemma (2). From the assymption that Un(t)W22,Vn(t)W22 are bounded, Un(t)W22,Vn(t)W22 are convergent as n, then c,d constants such that

    {i=1(λ1i)2=c,i=1(λ2i)2=d,

    if m>n using

    {(UmUm1)(Um1Um2)(Un+1Un),(VmVm1)(Vm1Vm2)(Vn+1Vn),

    further that

    {Um(t)Um1(t)2W22=(λ1m)2,Vm(t)Vm1(t)2W22=(λ2m)2,

    so:

    {Um(t)Un(t)2W22=mi=n+1(λ1i)20Vm(t)Vn(t)2W22=mi=n+1(λ2i)20 as n,m,

    since W22[t0,tf] is complete, U(t),V(t) in W22[t0,tf] such that

    {Un(t)U(t)Vn(t)V(t) as n,

    in the sense of the norm of W22[t0,tf].

    Now, we prove that U(t),V(t) are solutions of Eq (3.7). Since {ti}i=1 is dense on [t0,tf],t[t0,tf], subsequence {tnj} such that tnjjt. From lemma (3) and (4) in [25] we have:

    {LU(tnj)=F(tnj,Unj1(tnj),Vnj1(tnj)),LV(tnj)=G(tnj,Unj1(tnj),Vnj1(tnj)),

    let j goes to , by theorem (4.1) and the continuity of F and G we have:

    {LU(t)=F(t,U(t),V(t)),LV(t)=G(t,U(t),V(t)),

    that is U(t),V(t) are solutions of Eq (3.7).

    Theorem 4.3. Let ξn=|Un(t)U(t)|, ξn=|Vn(t)V(t)|, where: Un(t),Vn(t),U(t),V(t) denote the approximate and the exact solutions respectively, then the sequences of numbers {ξn},{ξn} are decreasing in the sense of the norm .W22 and ξnn0,ξnn0.

    Proof. From the extension form of U(t),V(t) and Un(t),Vn(t) in Eqs (3.12), (3.14) and (3.15) we can write:

    {ξn2W22=i=n+1λ1i¯Ψ1i(t)2W22=i=n+1(λ1i)2,ξn2W22=i=n+1λ2i¯Ψ2i(t)2W22=i=n+1(λ2i)2,

    and

    {ξn12W22=i=nλ1i¯Ψ1i(t)2W22=i=n(λ1i)2,ξn12W22=i=nλ2i¯Ψ2i(t)2W22=i=n(λ2i)2.

    Clearly: ξnn=1,ξnn=1 are decreasing in a sense of .W22 from theorem (3.2) the series i=1λ1i¯Ψ1i(t),i=1λ2i¯Ψ2i(t) are convergent, thus ξnW220,ξnW220 as n.

    Theorem 4.4. The approximate solutions Un(t),Vn(t) of (3.7) converge to its exact solutions U(t),V(t) with not less than the second order convergence. That is: |UnU|Mk2 and |VnV|Nk2, where k=tft0n.

    Proof. See [36].

    Numerical examples are conducted in order to verify the accuracy of this method. Computations are performed using Mathematica 11.0.

    Algorithm 1: Use the following stages to approximate the solutions of BVPs (3.4) and (3.5) based on RKHS method.

    Stage A: Fixed t[t0,tf] and set τ[t0,tf]

    for i=1,...,n do the following stages:

    - stage 1: set ti=t0+(tft0)in;

    - stage 2: if τt let

    Kτ(t)=3i=0pi(t)τi;

    else let

    Kτ(t)=3i=0qi(t)τi.

    - stage 3: For η=1,2;

    set

    Ψηi(t)=LτKt(τ)|τ=ti.

    Output the orthogonal functions system Ψηi(t).

    Stage B: Obtain the orthogonalization coefficients Bηij as follows:

    For η=1,2;

    For i=1,...,n;

    For j=1,...,i set Cηik=Ψηi,ΨηjW22 and B11=1Sqrt(Cη11).

    Output Cηij and B11.

    Stage C: For η=1,2;

    For i=1,...,n, set Bηii=(Ψηi2W22i1k=1(Cηik)2)12;

    else if ji set Bηij=(i1k=1CηikBηkj).(Ψηi2W22i1k=1(Cηik)2)12.

    Output the orthogonalization coefficients Bηij.

    Stage D: For η=1,2;

    For i=1,...,n set ¯Ψηi(t)=ik=1BηikΨηi(t).

    Output the orthonormal functions system ¯Ψηi(t).

    Stage E: Set t1=0 and choose U0(t1)=0,V0(t1)=0;

    For η=1,2;

    For i=1 set

    {λ11=B111F(t1,U0(t1),V0(t1)),λ21=B211G(t1,U0(t1),V0(t1)), and {U1(t)=λ11¯Ψ11(t),V1(t)=λ21¯Ψ21(t).

    For i=2,3,...,n set

    {λ1i=ik=1B1nkF(tk,Uk1(tk),Vk1(tk)),λ2i=ik=1B2nkG(tk,Uk1(tk),Vk1(tk)),

    set

    {Un(t)=ni=1λ1i¯Ψ1i(t),Vn(t)=ni=1λ2i¯Ψ2i(t).

    Outcome the numerical solutions Un(t),Vn(t).

    Then we implement the above algorithm using numerical simulations. We arrange the resulting data in tables and graphs for examples discussed on [t0,tf] as follows:

    Example 5.1. Consider the following system:

    {Dαω(t)=4ω+3Θ+6,DαΘ(t)=2.4ω+1.6Θ+3.6,0t0.5,0α1,

    subject to:

    {ω(0)=0,Θ(0.5)=2.25e1+2.25e0.2,

    with exact solution when α=1 is:

    {ω(t)=3.375e2t+1.875e0.4t+1.5,Θ(t)=2.25e2t+2.25e0.4t.

    After the initial conditions have been homogenised and algorithm 1 used, apply ti=0.5in, ¯i=1,n and n=40, the tables 1 and 2 describe the exact solutions of ω(t) and Θ(t) and approximate solutions for different values of α.

    Table 1.  Numerical results for ω(t) of example 5.1.
    t Exact Sol of ω(t) App Sol of ω(t) α=0.9 α=0.8 α=0.7 Abs Error Rel Error
    0. 0. 0. 0. 0. 0. 0. Indeterminate
    0.1 0.538264 0.538235 0.672451 0.820896 0.975714 2.8979×105 5.3838×105
    0.2 0.968513 0.968496 1.10364 1.22992 1.34045 1.6912×105 1.7462×105
    0.3 1.31074 1.31073 1.41427 1.49734 1.55882 7.6470×106 5.8341×106
    0.4 1.58128 1.58128 1.64374 1.68334 1.70372 5.4565×107 3.4507×107
    0.5 1.79353 1.79353 1.81496 1.8167 1.805 4.8467×106 2.7023×106

     | Show Table
    DownLoad: CSV
    Table 2.  Numerical results for Θ(t) of example 5.1.
    t Exact Sol Θ(t) App Sol of Θ(t) α=0.9 α=0.8 α=0.7 Abs Error Rel Error
    0. 0. 0. 0. 0. 0. 0. Complex Infinity
    0.1 0.319632 0.31963 0.397424 0.48192 0.56754 1.7129×106 5.3589×106
    0.2 0.568792 0.568797 0.643125 0.70952 0.76353 5.6398×106 9.9154×106
    0.3 0.760745 0.760756 0.812467 0.84948 0.87141 1.1152×105 1.4659×105
    0.4 0.906333 0.906349 0.930619 0.93950 0.93585 1.5248×105 1.6823×105
    0.5 1.01442 1.01443 1.01229 0.99765 0.97506 1.8229×105 1.7970×105

     | Show Table
    DownLoad: CSV

    Graphs of the approximate solutions of ω(t) are plotted in Figure 1 (a), for different values of α. It is obvious from Figure 1 (a) that the approximate solutions are in reasonable alignment with the exact solution when α=1 and the solutions are continuously based on a fractional derivative. The graph in Figure 1 (b) represent the absolute errors of θ(t).

    Figure 1.  Solution and graphical curves of Example 5.1.

    Example 5.2. Consider the following system:

    {Dαω=ω24(ω1)cos2(t)sin(t),DαΘ=ωΘ2Θt2cos(t)+2t,0t1,

    with conditions:

    {ω(0)=3,Θ(1)=1,

    when α=1 the exact solution is:

    {ω(t)=cos(t)+2,Θ(t)=t2.

    After homogenizing the initial conditions and using algorithm 1, apply ti=in, ¯i=1,n and n=35, the tables 3 and 4 describe the exact solutions of ω(t) and Θ(t) and approximate solutions for different values of α.

    Table 3.  Numerical results for ω(t) of example 5.2.
    t Exact Sol of ω(t) App Sol of ω(t) α=0.9 α=0.8 α=0.7 Abs Error
    0. 3. 3. 3. 3. 3. 0.
    0.2 2.98007 2.98008 2.97308 2.96301 2.94782 1.71231717×105
    0.4 2.92106 2.92108 2.89745 2.86363 2.81286 2.336775593×105
    0.6 2.82534 2.82537 2.77748 2.71004 2.61271 3.05778094×105
    0.8 2.69671 2.69675 2.6203 2.51736 2.38161 3.84719926×105
    1. 2.5403 2.54035 2.43686 2.3082 2.15981 4.636294967×105

     | Show Table
    DownLoad: CSV
    Table 4.  Numerical results for Θ(t) of example 5.2.
    t Exact Sol of Θ(t) App Sol of Θ(t) α=0.9 α=0.8 α=0.7 Abs Error
    0. 0. 0. 0. 0. 0. 0.
    0.2 0.04 0.0399862 0.0526074 0.0695245 0.0925163 1.379651819×105
    0.4 0.16 0.159985 0.198264 0.246476 0.306978 1.465169064×105
    0.6 0.36 0.359987 0.428814 0.509138 0.597815 1.348748932×105
    0.8 0.64 0.639991 0.735269 0.833398 0.919358 9.089432173×106
    1. 1. 1. 1.10687 1.19567 1.24369 0.

     | Show Table
    DownLoad: CSV

    Graphs of the approximate solutions of θ(t) are plotted in Figure 2 (b) for different values of α. The graph in Figure 2 (a) represent the absolute errors of ω(t).

    Figure 2.  Solution and graphical curves of Example 5.2.

    Example 5.3. Consider the following fractional system:

    {Dαω=Θρ+t,DαΘ=3t2,Dαρ=Θ+et,0t1,

    subject to:

    {ω(0)=1,Θ(0)=1,ρ(1)=1.25e1,

    with exact solution:

    {ω(t)=0.05t5+0.25t4+t+2et,Θ(t)=t3+1,ρ(t)=0.25t4+tet.

    After the initial conditions have been homogenised and algorithm 1 used, apply ti=in, ¯i=1,n and n=30, the tables 5-7 describe the exact solutions of ω(t), Θ(t) and ρ and approximate solutions for different values of α.

    Table 5.  Numerical results for ω(t) of example 5.3.
    t Exact Sol of ω(t) App Sol of ω(t) α=0.9 α=0.8 α=0.7 Absolute Error
    0. 1. 1. 1. 1. 1. 0.
    0.2 1.38165 1.38163 1.45132 1.52412 1.59527 2.778531454×105
    0.4 1.73557 1.73552 1.80231 1.85993 1.90359 4.434730105×105
    0.6 2.0797 2.07964 2.12935 2.16496 2.18472 5.613341879×105
    0.8 2.43669 2.43662 2.46954 2.48922 2.49658 6.305905268×105
    1. 2.83212 2.83206 2.8543 2.86685 2.87146 6.508054219×105

     | Show Table
    DownLoad: CSV
    Table 6.  Numerical results for Θ(t) of example 5.3.
    t Exact Sol of Θ(t) App Sol of Θ(t) α=0.9 α=0.8 α=0.7 Absolute Error
    0. 1. 1. 1. 1. 1. 0.
    0.2 1.008 1.38163 1.01064 1.01411 1.01865 7.327471963×1015
    0.4 1.064 1.73552 1.07942 1.09826 1.1212 1.720845688×1013
    0.6 1.216 2.07964 1.25738 1.30578 1.36221 8.968381593×1013
    0.8 1.512 2.43662 1.59278 1.6843 1.78757 1.98951966×1012
    1. 2. 2.83206 2.13222 2.27818 2.43862 1.869615573×1012

     | Show Table
    DownLoad: CSV
    Table 7.  Numerical results for ρ(t) of example 5.3.
    t Exact Sol of ρ(t) App Sol of ρ(t) α=0.9 α=0.8 α=0.7 Absolute Error
    0. -1. -1. -1. -1. -1. 0.
    0.2 -0.618331 -0.61828 -0.534717 -0.436751 -0.323107 5.101539186×105
    0.4 -0.26392 -0.263882 -0.161995 -0.0516111 0.0670132 3.825972939×105
    0.6 0.0835884 0.0836139 0.191075 0.304226 0.423533 2.55064838×105
    0.8 0.453071 0.453084 0.568489 0.69138 0.823913 1.275324046×105
    1. 0.882121 0.882121 1.01733 1.16604 1.3321 0.

     | Show Table
    DownLoad: CSV
    Table 8.  Error in ω(t) of the first example.
    t Error in ω(t) Error in ω(t) Error in ω(t) Error in ω(t)
    by RKHS for n=40 by RKHS for n=100 by Finite difference by Collocation
    0 0. Indeterminate 0. 0.
    0.1 2.89×105 3.93×106 2.08×102 1.62×104
    0.2 1.69×105 1.65×106 3.25×102 8.06×104
    0.3 7.64×106 8.48×107 3.79×102 4.04×104
    0.4 5.45×107 4.29×109 3.89×102 1.61×104
    0.5 4.84×106 4.19×107 3.70×102 1.73×104

     | Show Table
    DownLoad: CSV
    Table 9.  Error in Θ(t) of the first example.
    t Error in Θ(t) Error in Θ(t) Error in Θ(t) Error in Θ(t)
    by RKHS for n=40 by RKHS for n=100 by Finite difference by Collocation
    0 0. Indeterminate 2.81×102 1.41×104
    0.1 1.71×106 4.40×106 1.40×102 2.77×105
    0.2 5.63×106 1.86×106 5.01×103 7.64×105
    0.3 1.11×105 8.21×107 7.39×104 9.81×105
    0.4 1.52×105 9.84×107 6.04×104 1.31×104
    0.5 1.82×105 1.14×106 0. 0.

     | Show Table
    DownLoad: CSV
    Table 10.  Error in ω(t) of the second example.
    t Error in ω(t) Error in ω(t) Error in ω(t) Error in ω(t) Error in ω(t)
    by RKHS for n=35 by RKHS for n=60 by RKHS for n=100 by Finite difference by Collocation
    0 0. 0. 0. 0. Failed
    0.2 1.71×105 3.44×106 2.51×107 1.09×102 Failed
    0.4 2.33×105 4.69×106 3.49×107 2.62×102 Failed
    0.6 3.05×105 6.14×106 4.73×107 4.63×102 Failed
    0.8 3.84×105 7.73×106 5.98×107 7.11×102 Failed
    1 4.63×105 9.73×106 7.45×107 9.91×102 Failed

     | Show Table
    DownLoad: CSV
    Table 11.  Error in Θ(t) of the second example.
    t Error in Θ(t) Error in Θ(t) Error in Θ(t) Error in Θ(t) Error in Θ(t)
    by RKHS for n=35 by RKHS for n=60 by RKHS for n=100 by Finite difference by Collocation
    0 0. 0. 0. 5.54×102 Failed
    0.2 1.37×105 2.82×106 2.51×107 4.49×102 Failed
    0.4 1.46×105 3.00×106 3.49×107 3.34×102 Failed
    0.6 1.34×105 2.79×106 4.73×107 2.04×102 Failed
    0.8 9.08×106 2.03×106 5.98×107 7.77×103 Failed
    1 0. 0. 0. 0. Failed

     | Show Table
    DownLoad: CSV
    Table 12.  Error in ω(t) of the third example.
    t Error in ω(t) Error in ω(t) Error in ω(t) Error in ω(t)
    by RKHS for n=30 by RKHS for n=60 by Finite difference by Collocation
    0 0. 0. 0. 0.
    0.2 2.77×105 1.43×106 2.83×103 5.86×104
    0.4 4.43×105 1.42×106 1.24×102 5.29×104
    0.6 5.61×105 1.12×106 3.13×102 5.44×104
    0.8 6.30×105 6.62×106 6.06×102 4.86×104
    1 6.50×105 9.69×106 1.00×102 1.08×103

     | Show Table
    DownLoad: CSV
    Table 13.  Error in Θ(t) of the third example.
    t Error in Θ(t) Error in Θ(t) Error in Θ(t) Error in Θ(t)
    by RKHS for n=30 by RKHS for n=60 by Finite difference by Collocation
    0 0. 0. 0. 0.
    0.2 7.32×1015 6.28×1013 5.00×103 0.
    0.4 1.72×1013 2.80×1013 2.20×102 0.
    0.6 8.96×1013 4.10×1013 5.10×102 0.
    0.8 1.98×1012 5.94×1013 9.20×102 0.
    1 1.86×1012 5.37×1014 1.45×101 0.

     | Show Table
    DownLoad: CSV
    Table 14.  Error in ρ(t) of the third example.
    t Error in ρ(t) Error in ρ(t) Error in ρ(t) Error in ρ(t)
    by RKHS for n=30 by RKHS for n=60 by Finite difference by Collocation
    0 0. 0. 5.59×102 1.29×104
    0.2 5.10×105 1.48×106 6.47×102 5.49×105
    0.4 3.82×105 3.07×106 6.80×102 6.03×105
    0.6 2.55×105 4.66×106 6.14×102 5.73×105
    0.8 1.27×105 6.26×106 4.03×102 6.23×105
    1 0. 0. 0. 0.

     | Show Table
    DownLoad: CSV

    Graphs of the approximate solutions of ω(t) and θ(t) are plotted in Figure 3 (a), Figure 3 (b) for different values of α. The graph in Figure 3 (c) represent the absolute errors of ρ(t).

    Figure 3.  Solution and graphical curves of Example 5.3.

    Now, we consider the following tables where the RKHS method has been applied in order to give numerical approximations with other values of n, and then compare it with finite difference and collocation methods.

    In this article, we effectively utilize the RKHSM to develop an approximate solution of differential fractional equations with temporal two-point BVP. The results of examples demonstrate reliability and consistency of the method. In the future, we recommend further research on the RKHS method, as solving the temporal two-point boundary value problems with the conformable and the Atangana-Baleanu derivatives. We expect to achieve better results and good approximations for the solutions.

    The authors state that they have no conflict of interest. All authors have worked in an equal sense to find these results.



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