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Review Topical Sections

Polydimethylsiloxane mechanical properties: A systematic review

  • Polydimethylsiloxane (PDMS) has been a promising material for microfluidic, particularly in lab-on-chip. Due to the panoply of good physical, mechanical and chemical properties, namely, viscosity, modulus of elasticity, colour, thermal conductivity, thermal coefficient of expansion, its application has been increasingly requested in quite different areas. Despite such characteristics, there are also some drawbacks associated, and to overcome them, several strategies have been developed to modify PDMS. Given the great variety of relevant conducted research in this field, the present work aims to gather the most relevant information, the advantages and disadvantages of some of the techniques used, and also identify potential gaps and challenges in it. To this end, a systematic literature review was conducted by collecting data from four different databases, Science Direct, American Chemical Society, Scopus, and Springer. Two authors independently screened the references, extracted the key information, and assessed the quality of the included studies. After the analysis of the collected data, 25 studies were selected that addressed the various mechanical properties of PDMS and how to modify them in order to suit a particular application.

    Citation: Inês Teixeira, Inês Castro, Violeta Carvalho, Cristina Rodrigues, Andrews Souza, Rui Lima, Senhorinha Teixeira, João Ribeiro. Polydimethylsiloxane mechanical properties: A systematic review[J]. AIMS Materials Science, 2021, 8(6): 952-973. doi: 10.3934/matersci.2021058

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  • Polydimethylsiloxane (PDMS) has been a promising material for microfluidic, particularly in lab-on-chip. Due to the panoply of good physical, mechanical and chemical properties, namely, viscosity, modulus of elasticity, colour, thermal conductivity, thermal coefficient of expansion, its application has been increasingly requested in quite different areas. Despite such characteristics, there are also some drawbacks associated, and to overcome them, several strategies have been developed to modify PDMS. Given the great variety of relevant conducted research in this field, the present work aims to gather the most relevant information, the advantages and disadvantages of some of the techniques used, and also identify potential gaps and challenges in it. To this end, a systematic literature review was conducted by collecting data from four different databases, Science Direct, American Chemical Society, Scopus, and Springer. Two authors independently screened the references, extracted the key information, and assessed the quality of the included studies. After the analysis of the collected data, 25 studies were selected that addressed the various mechanical properties of PDMS and how to modify them in order to suit a particular application.



    Inverse scattering problems are a central topic in applied mathematics, which have many applications of practical importance in modern technologies including radar, medical imaging, nondestructive testing, remote sensing, geophysical exploration and ultrasound tomography (cf. [27]). Inverse obstacle scattering problems and inverse medium scattering problems are two main themes in inverse scattering problems. Uniqueness issue in inverse scattering problems is concerned with the unique identifiability on the shape and/or the physical material parameters of the underlying obstacle and medium by the corresponding measurements through wave probing. In this paper, we provide an overview of some recent mathematical developments on the inverse scattering problems and the inverse medium scattering problems as well as the inverse diffraction grating problems regarding on the unique identifiability issue. Those are fundamental results in the inverse scattering theory.

    In this paper, we focus on the inverse obstacle and medium scattering problems for time-harmonic acoustic waves from an impenetrable or penetrable scatterer in a homogeneous background medium. Considering the scattering of a time-harmonic acoustic wave by a bounded obstacle ΩRn which is unknown or inaccessible, n2. Let k=ω/cR+ be the wavenumber with ωR+ and cR+, respectively, denoting the frequency and the sound speed. Assume that the incident wave is given by the plane wave of the form

    ui(x;k,d)=eikxd,xRn, (1)

    where dSn1 signifies the incident direction and Sn1:={xRn:|x|=1} is the unit sphere in Rn. Physically speaking, Ω can be a penetrable or an impenetrable obstacle in scattering phenomenon, which shall fulfill the following two systems, respectively. For a penetrable inhomogeneous medium, the forward medium scattering problem can be modeled by

    {Δu+k2Vu=0inRn,u(x)=ui(x)+us(x),limrrn12(usrikus)=0, (2)

    where V denotes the refractive index satisfying V(x)1 for xRn¯Ω, r=|x| and us is the scattered wave field generated by the presence of the obstacle Ω=supp(1V). The limit equation in (2) is known as the Sommerfield radiation condition which ensures the outgoing nature of the scattered wave us. The unique solvability of the scattering problem (2) in H2loc(Rn) is well-known if VL(Rn) (see [27] for details).

    If Ω is an impenetrable obstacle, the corresponding forward obstacle scattering problem can be formulated by the following Helmholtz system:

    {Δu+k2u=0inRn¯Ω,Bu=0onΩ,u=ui+usinRn,limrrn12(usrikus)=0. (3)

    The boundary operator relies on the physical property of the obstacle. Precisely speaking, B could be of Dirichlet type Bu:=u for the sound-soft obstacle or Neumann type Bu:=νu for the sound-hard obstacle or Robin type Bu:=νu+ηu with ν being the exterior unit normal vector to Ω and ηL(Ω) for the impedance obstacle. Here, η denotes the boundary impedance parameter fulfilling η0 and η0. In what follows, we formally take u=0 on Ω as νu+ηu=0 on Ω with η=+. In doing so, we can unify the three boundary conditions as the generalized impedance boundary condition:

    B(u)=νu+ηu=0on  Ω, (4)

    where η could be , corresponding to a sound-soft obstacle. It is well-understood in [27] and [48] that there exists a unique solution uH1loc(Rn¯Ω) for Ω with Lipschitz boundary Ω.

    The Sommerfeld radiation condition in (2) or (3) leads to the asymptotic expansion (cf. [27]) for us to (2) or (3) as follows

    us(x;k,d)=eikrr(n1)/2u(ˆx;k,d)+O(1r(n+1)/2)asr (5)

    uniformly with respect to all directions ˆx:=x/|x|Sn1, where u(ˆx;k,d) is referred to as the far-field pattern or the scattering amplitude, and ˆx denotes the observation direction. Furthermore, ˆx:=x/|x|Sn1 is a real-analytic function on Sn1. By introducing an operator F which sends the obstacle Ω together with the physical parameter V (the refractive index) or η (the boundary parameter) to the corresponding far-field pattern through the Helmholtz system (2) or (3), the inverse medium or obstacle problem can be formulated as the following abstract operator equations:

    FP(Ω,V)=u(ˆx;k,d), (6)

    and

    FI(Ω,η)=u(ˆx;k,d), (7)

    where FP and FI are defined by the forward medium or obstacle scattering system respecitivley, and are nonlinear. That is, one intends to determine (Ω,V) or (Ω,η) from the knowledge of u(ˆx;k,d).

    A primary issue for the inverse medium problem (6) and inverse obstacle problem (7) is the unique identifiability, which is concerned with the sufficient conditions such that the correspondence between Ω and u is one-to-one. There is a widespread belief that one can establish uniqueness for (6) and (7) by a single or at most finitely many far-field patterns. We remark that by a single far-field pattern we mean that u(ˆx,k,d) is collected for all ˆxSn1, but is associated with a fixed incident wave eikxd. Indeed, it states that the analytic function u on the unit sphere associated with at most finitely many k and d can determine the shape of a generic domain Ω and the physical parameter V or η. This problem is known as the Schiffer problem in the inverse scattering community. It is named after M. Schiffer for his pioneering contribution around 1960 which was actually appeared as a private communication in the monograph by Lax and Phillips [41]. There is a long and colourful history on the study of the Schiffer's problem, and we refer to a recent survey paper by Colton and Kress [28] which contains an excellent account of the historical development of this problem.

    By now, only under a-prior geometric assumptions on the size or the shape of the scatterer, unique identifiability results by using one incident plane wave have been established. Colton and Sleeman [29] proved that the shape of the obstacle could be uniquely determined with one incident wave when the size of the scatterer satisfies some generic conditions. The sound-soft ball can be uniquely determined by a single measurement (cf. [42]). Later, Alessandrani and Rondi in [2,3], Cheng and Yamamoto in [25] and [26], Liu and Zou [46] studied the global uniqueness results with respect to a single far-field pattern for sound-soft, sound-hard obstacles within a certain polyhedral geometry. The proofs in [2,3,25,46] mainly utilize the reflection principle for the Helmholtz equation with respect to a Dirichlet or Neumann hyperplane and the path argument, where the path argument is initially developed in [46]. Such kind of methodologies cannot tackle the uniqueness results for an impedance polygonal or polyhedral obstacle with a single far-field pattern. Please refer to Section 2 for more discussions related to the Schiffer's problem on the inverse obstacle problems.

    The obstacle with the impedance boundary condition can be uniquely determined by the far-field pattern with infinite incident directions and one fixed wave number (cf. [40]). The Schiffer's problem for an impedance obstacle is mathematically challenging, which concerns with the unique determination for an impedance obstacle with a single far-field pattern. Recently, two of the authors establish the "local" unique identifiability results [23,24] on the polygonal or polyhedral obstacle with the impedance boundary condition by at most two far-field patterns, where the polygonal or polyhedral obstacles satisfy some generic geometrical conditions. Furthermore, the local arguments for uniquely determining the shape and boundary parameters of the impedance obstacle by at most two far-field patterns are developed in [23,24], which are quite different from the proofs in [2,3,25,46] for tackling the uniqueness results for sound-soft and sound-hard obstacles with respect to a single far-filed pattern. A direct consequence of the uniqueness results in [23,24] is that the shape of the convex hull of a concave polygonal or polyhedral obstacle can be uniquely determined by at most two far-field patterns. To our best knowledge, the findings in [23,24] are the first results concerning the uniqueness results with finite many far-field measurements for general concave polygonal or polyhedral obstacles. The corresponding detailed discussions for Schiffer's problem with respect to the aforementioned results can be seen in Section 2.

    For the inverse medium problem (6), Nachman [51], Novikov [52], and Ramm [53] established that the refractive index V in (2) could be uniquely determined from the far-field pattern with infinite incident directions and a fixed wave number. A uniqueness result in determining the refractive index V by using the Cauchy data for the inverse medium scattering problem (6) in the two-dimensional case was established by Bukhgeim [15]. Uniqueness and stability results using a single incident plane wave to determine the support of V under the assumption that the support is a convex polyhedron were presented in [10,12,35].

    Consider the direct medium scattering problem (6) with the transmission condition

    u=u+,νu=νu+ on   Ω,Ω=supp(1V),

    where u and u+ are interior and exterior total wave fields with respect to Ω corresponding to (2) separately, and ν is the exterior normal vector to Ω. Blåsten and Liu [12] proved that a single far-field pattern of the direct medium scattering problem (6) with the transmission condition determines the refractive index V on the corners of its support under certain assumptions, where these assumptions can be satisfied for example in the low acoustic frequency regime. As a consequence, if the refractive index V is piecewise constant with either a polyhedral nest geometry or a known polyhedral cell geometry, such as a pixel or voxel array, the unique identifiability for V by a single far-field pattern was established, which is the first unique determination result of its type in the literature.

    Recently, two of the authors [30] consider the unique determination of the shape of the reflective index's support Ω by a single far-field pattern corresponding to the direct medium scattering problem (6) with the conductive transmission condition

    u=u+,νu=νu++ηu+ on   Ω,

    where ηL(Ω). In the two-dimensional case, when Ω is a convex polygon, a single far-field pattern can uniquely determine the shape of Ω and the constant conductive parameter η under some generic assumptions. Please refer to Section 3 for more detailed discussions.

    Very recently, the inverse problem of recovering a conductive medium body was considered in [22]. The conductive medium body arises from several applications of practical importance, including the modeling of an electromagnetic object coated with a thin layer of a highly conducting material and the magnetotellurics in geophysics. The inverse problem is concerned with the determination of the material parameters inside the body as well as on the conductive interface by the associated electromagnetic far-field measurements. Under the transverse-magnetic polarisation, two of the authors derived two novel unique identifiability results in determining a 2D piecewise conductive medium body associated with a polygonal-nest or a polygonal-cell geometry by a single active or passive far-field measurement. The detailed discussion can be found in Section 3.

    Indeed, the unique identifiability [12,22,30] for the inverse medium problem (6) by a single far-field pattern relies heavily on the geometrical structures of the interior transmission eigenfunctions [21]. The study on the interior transmission eigenvalue problem has a long history and is of significant importance in scattering theory; see [27,37]. Let Ω be a bounded Lipschitz domain in Rn, n=2,3, and VL(Ω) be possibly complex-valued functions. The interior transmission eigenvalue problem can be formulated as

    {(Δ+k2)v=0inΩ,(Δ+k2(1+V))w=0inΩ,w=v,νw=νv, onΩ. (8)

    If there exits a nontrivial pair (v,w) and kR+ fulfill (8), then (v,w) is named as the transmission eigenfunctions and k is the corresponding interior transmission eigenvalue. One can refer [21] for a recent survey on the systematic discussions about the spectral properties of the transmission eigenvalues. In [11], Blåsten and Liu presented the first quantitive result on the intrinsic geometric properties of transmission eigenfunctions. We refer to Section 3 for more relevant discussions on recent progress on the study of transmission eigenfunctions and inverse medium scattering problems.

    The study on scattering problems by periodic structures especially for diffraction grating has received a lot of attention (cf. [5]). The corresponding discussions are of practical applications in many areas such as radar imaging, micro-optics and nondestructive testing. The problem was first raised by Rayleigh on the scattering of plane waves from corrugated surface. In Section 4, we will give more explanations on the recent developments and the mathematical formulations towards the direct and inverse diffraction grating problems.

    The rest of the paper is organized as follows. In Section 2, we discuss some recent progress on Schiffer's problem on inverse obstacle scattering problems including sound-soft, sound-hard and impedance obstacles within a certain polyhedral geometry. The study on the unique identifiability for impedance obstacles are important due to the novelty and challenge compared with the sound-soft and sound-hard cases. In Sections 3, we present some intriguing studies on the inverse medium scattering problem together with the geometrical structures of interior transmission eigenfunctions at the corner point. Section 4 is devoted to the mathematical developments of inverse diffraction grating problems. Similar to Section 2, we mainly present the unique determination for gratings with impedance boundary. In Section 5, we conclude our review paper on recent progress on inverse scattering problems and present some intriguing open problems.

    In this section, we focus on the unique determination of the shape of the obstacle in (7) by finite many far-field patterns when the obstacle is a polygon or a polyhedron. As mentioned in the introduction, the aforementioned theory is related to Schiffer's problem in inverse scattering problem, which has a long and colorful history; see a recent survey paper [28] for related developments. Indeed, for sound-soft or sound-hard polyhedral scatterers, the corresponding unique identifiability results can be found in [2], [25], [44], [45] and [46], where the mathematical arguments adopt the reflection principle and path argument. In [47], the partial determination for impedance obstacle by finite many far-field patterns was also attained by Liu and Zou following the reflection principle argument. Recently, Cao, Diao, Liu and Zou in [23] and [24] developed a completely new approach on Schiffer's problem for impedance obstacles in R2 and R3, respectively. The methods therein can uniformly tackle Schiffer's problem for sound-soft, sound-hard and impedance obstacles and are completely local, which can be applicable to recover the obstacle and the surface impedance parameter simultaneously in a more general scenario. The technical arguments in [23] and [24] are heavily related to the geometrical structures of Laplacian eigenfunctions at the intersecting point of two line segments or plane cells when the underlying Laplacian eigenfunctions fulfill certain homogenous boundary conditions on the corresponding line segments or plane cells; see more discussions in Subsection 2.1.

    In the following, we first review recent progress on the geometrical structures of Laplacian eigenfunctions (cf. [23,24]). Subsections 2.2 and 2.3 are devoted to review the unique inedibility results for sound-soft, sound-hard and impedance polyhedral scatterers.

    The geometric structures of Laplacian eigenfunctions and their deep relationship to the quantitive behaviours of the underlying eigenfunctions in R2 was revealed in [23]. As an extension and continuation, in [24], two of the authors investigated the analytic behaviours of Laplacian eigenfunctions at corners in R3. These new findings and novel results are of significant importance in spectral theory and Schiffer's problem in the inverse obstacle scattering problems.

    For uL2(Ω) and λR+, where ΩRn is an open subset, consider the Laplacian eigenvalue problem

    Δu=λu in Ω. (9)

    Recall the following two definitions in [23].

    Definition 2.1. [23,Definition 1.1] For a Laplacian eigenfunction u in (9), a line segment ΓhΩ is called a nodal line of u if u=0 on Γh, where hR+ signifies the length of the line segment. For a given complex-valued function ηL(Γh), if it holds that

    νu(x)+η(x)u(x)=0,xΓh, (10)

    then Γh is referred to as a generalized singular line of u. For the special case that η0 in (10), a generalized singular line is also called a singular line of u in Ω. We use NλΩ, SλΩ and MλΩ to denote the sets of nodal, singular and generalized singular lines, respectively, of an eigenfunction u in (9).

    Definition 2.2. [23,Definition 1.2] Let u satisfy (9) and be a nontrivial eigenfunction. For a given point x0Ω, if there exits a number NN{0} such that

    limr+01rmB(x0,r)|u(x)|dx=0  for  m=0,1,,N+1, (11)

    where B(x0,r) is a disk centered at x0 with radius rR+, we say that u vanishes at x0 up to the order N. The largest possible N such that (11) is fulfilled is called the vanishing order of u at x0, and we write

    Vani(u;x0)=N.

    If (11) holds for any NN, then we say that the vanishing order is infinity.

    Combining with Definition 2.1 and Definition 2.2, under the mathematical setup in [23,Section 3], where we assume that

    (Γ+h,Γh)=απ, α(0,2),andΓ+hΓh=0Ω, (12)

    with Γ±h being the intersecting two line segments, and (Γ+h,Γh) denoting the corresponding intersecting angle, we are provided with an accurate characterization of the relationship between the vanishing orders of Laplacian eigenfunctions and the intersecting angle of two nodal/generalized singular lines. Roughly speaking, it is known that the vanishing order is generically infinity if the intersecting angle is irrational and the vanishing order is finite if the intersecting angle is rational. The precise spectral results are as follows.

    Theorem 2.3. Let u be a Laplacian eigenfunction to (9). Suppose that there are two generalized singular lines Γ+h and Γh from MλΩ such that (12) holds. Assume that η1C1 and η2C2, where C1 and C2 are two constants. Then the Laplacian eigenfunction u vanishes up to the order N at 0:

    Nn,  if  u(0)=0  and  αqp,p=1,,n1, (13)

    where nN, n3 and for a fixed p, q=1,2,,p1.

    Theorem 2.4. Let u be a Laplacian eigenfunction to (9). Suppose that there are two nodal lines Γ+h and Γh from NλΩ such that (12) holds. Then the Laplacian eigenfunction u vanishes up to the order N at 0:

    Nn,  if  αqp,p=1,,n1, (14)

    where nN, n3 and for a fixed p, q=1,2,,p1.

    Theorem 2.5. Let u be a Laplacian eigenfunction to (9). Suppose that there are two singular lines Γ+h and Γh from SλΩ such that (12) holds. Then the Laplacian eigenfunction u vanishes up to the order N at 0:

    Nn,  if  u(0)=0  and  αqp,p=1,,n1, (15)

    where nN, n3 and for a fixed p, q=1,2,,p1.

    Next, we have vanishing orders of Laplacian eigenfunctions at the corner intersected by a generalized singular (singular) line and a nodal line.

    Theorem 2.6. Let u be a Laplacian eigenfunction to (9). Suppose that a generalized singular line Γ+hMλΩ intersects with a nodal line ΓhNλΩ at 0 with the angle (Γ+h,Γh)=απ. Assume that the boundary parameter η2C2 on Γ+h is a constant. Then the Laplacian eigenfunction u vanishes up to the order N at 0:

    Nn,  if  α2q+12p,p=1,,n1, (16)

    where nN, n2 and for a fixed p, q=0,1,,p1.

    Theorem 2.7. Let u be a Laplacian eigenfunction to (9). Suppose that a singular line Γ+hSλΩ intersects with a nodal line ΓhNλΩ at the origin with the angle (Γ+h,Γh)=απ. Then the Laplacian eigenfunction u vanishes up to the order N at 0:

    Nn,  if  α2q+12p,p=1,,n1, (17)

    where nN, n2 and for a fixed p, q=0,1,,p1.

    Theorem 2.8. Let u be a Laplacian eigenfunction to (9). Suppose that a singular line Γ+hSλΩ intersects with a generalized singular line ΓhMλΩ at the origin with the angle (Γ+h,Γh)=απ. Assume that the boundary parameter η1 on Γh is a non-zero constant, i.e., η1C10. Then the Laplacian eigenfunction u vanishes up to the order N at 0:

    Nn,  if  u(0)=0  and  αqp,p=1,,n1, (18)

    where nN, n3 and q=1,2,,p1 for a fixed p.

    Indeed, Theorem 2.8 is a direct corollary of Theorem 2.3 by taking η2=0.

    If α in (12) is irrational, which implies that the conditions (13), (14), (15), (16), (17) and (18) are automatically satified, we have the vanishing orders of Laplacian eigenfunctions for irrational intersection in the following few Theorems.

    Theorem 2.9. Let u be a Laplacian eigenfunction to (9). Suppose that there are two generalized singular lines Γ+h and Γh from MλΩ such that (12) holds. Assume that η1C1 and η2C2, where C1 and C2 are two constants. If (Γ+h,Γh)=απ with α(0,2) irrational, then there hold that

    Vani(u;0)=0,     if  u(0)0;Vani(u;0)=+,  if  u(0)=0.

    Theorem 2.10. Let u be a Laplacian eigenfunction to (9). Suppose that a generalized singular line ΓhMλΩ intersects with a nodal line Γ+hNλΩ at 0 with the angle (Γ+h,Γh)=απ. Assume that the boundary parameter η1C1 on Γh is a constant. If α(0,2) is irrational, then there holds

    Vani(u;0)=+.

    Theorem 2.11. Let u be a Laplacian eigenfunction to (9). Suppose that a singular line Γ+hSλΩ intersects with a generalized singular line ΓhMλΩ at 0 with the angle (Γ+h,Γh)=απ. Assume that the boundary parameter η1C1 on Γh is a constant. If α(0,2) is irrational, then there hold that

    Vani(u;0)=0,     if  u(0)0;Vani(u;0)=+,  if  u(0)=0.

    Theorem 2.12. Let u be a Laplacian eigenfunction to (9). Suppose that a singular line ΓhSλΩ intersects with a nodal line Γ+hNλΩ at 0 with the angle (Γ+h,Γh)=απ. If α(0,2) is irrational, then there holds

    Vani(u;0)=+.

    We can know from above theorems that the eigenfunction is generically vanishing to infinity, namely u is identically zero in Ω for irrational intersection. Here, the generic condition u(0)=0 can be easily fulfilled in the inverse obstacle scattering problem by the superposition of two incident waves and one can refer [23,Section 7] for more detailed discussions.

    In the subsequent studies, we only present some latest studies concerning the unique identifiability for sound-soft, sound hard and impedance polyhedral scatterers, respectively.

    In this subsection, we review the existing results on the unique identifiability for sound-soft or sound-hard polyhedral scatterers by finite many far-field patterns. In 1994, Liu and Nachman [43] investigated the unique determination results for the convex hull of a polyhedral obstacle by knowledge of the far-field pattern with the help of the reflection principle for solutions of the Helmholtz equation across a flat boundary. Later, Cheng and Yamamoto [25] proved that a polygonal obstacle in R2 could be uniquely determined by the far-field pattern under a certain geometrical condition, which was expressed by the absence of trapped rays in the exterior domain of the obstacle. Then, Alessandrini and Rondi [2] in 2005 studied the uniqueness of a sound-soft polyhedral scatterer by the far-field pattern corresponding to an incident wave at one given wavenumber and a given incident direction in Rn, n2. For further illustration, we consider the obstacle scattering problem (3) with Bu=u for time-harmonic acoustic waves with a sound-soft obstacle ΩRn, n2. Then the determination of Ω by a single far-field measurement can be stated as

    Theorem 2.13. [2,Theorem 2.2] Let us fix dSn1 and k>0. A polyhedral scatterer Ω is uniquely determined by the far-field pattern u.

    Theorem 2.13 can be proved by following a reflection argument discussed in [25]. Instead of examining the boundary behavior of the nodal set of u, Alessandrini and Rondi investigated the structure of the nodal set in the exterior of Ω. The detailed proof of Theorem 2.13 can be found in [2,Section 3].

    By introducing the concept of Dirichlet/Neumann set and Dirichlet/Neumann hyperplane, Liu and Zou [46] in 2006 initiated a nowadays well-known path argument to establish the uniqueness for both the sound-soft and sound-hard cases. Following the same definition of a polyhedral scatterer in [2], Liu and Zou derived the unique identifiability result as follows.

    Theorem 2.14. [46,Theorem 2] The polyhedral scatterer Ω is uniquely determined by a single far-field pattern u corresponding to an incident wave eikxd with k>0 and dSn1 fixed.

    Very recently, Cao, Diao, Liu and Zou [23] established a completely novel approach in dealing with the Schiffer's problem for sound-soft, sound-hard and impedance obstacles. The uniqueness results can be regarded as direct applications of the new spectral findings by utilizing the critical connection between the intersecing angles of the nodal/generalized singular lines and the vanishing order of the Laplacian eigenfunctions in R2. The relevant study for the three-dimensional case is also concerned in [24]. The unique identifiabilities in [23] and [24] develop a new argument that can treat the unique identifiability issue for several inverse scattering problems in a unified manner, especially in terms of general materials properties. Indeed, most existing uniqueness results concerning Schiffer's problem require certain geometrical a-prior knowledge, which is also need in [23] and [24]. Please refer to Subsection 2.3 for more detailed discussions.

    The existing studies on the unique identifiability for sound-hard obstacles with finitely many measurements depend heavily on the geometric setup of the scatterer. Cheng and Yamamoto in [25] presented the unique determination results for sound-hard polygons in R2 by two incident plane waves under a so called "non-trapping" condition. Later, Elschner and Yamamoto in 2005 demonstrated that a sound-hard polygonal obstacle could be uniquely determined by one single incident plane wave. However, the argument in [33] is only valid in R2. In 2006, Liu and Zou investigated the uniqueness for a very general sound-hard obstacle and the approaches they established work for any Rn, n1. We can see the following few theorems for the mathematical illustrations in the aforementioned literatures.

    Considering the scattering problem (3) with Bu=νu, the paper by Liu and Zou [46] significantly generalized the aforementioned results in two aspects. First the restriction on the geometry of the scatterer is relaxed to a very general sound-hard obstacle. Second, the uniqueness results in [46] are appliable to any dimension larger than 1. However, finitely many incident plane waves are still required therein. The main approach in the corresponding argument is reflection principle. We present the main theorem as follows without proof. One can refer [46,Section 2] for the rigorous analyses.

    Theorem 2.15. [46,Theorem 1] Let dSn1, =1,2,,n, be n linearly independent direcions and k>0 be fixed. A polyhedral scatterer Ω is uniquely determined by the far-field patterns U={u1,,u2,,,un,}.

    We would like to remark that the scatterer Ω defined in Theorem 2.15 is supposed to fulfill the requirements introduced in [2].

    Later, Liu, Petrini, Rondi and Xiao [44] also established an optimal stability estimate for the determination of sound-hard polyhedral scatterers in Rn, n2, with the help of a minimal number of far-field measurements. They gave more discussions of several admissible scatterers with minimal regularity assumptions, which can be utilized on many occasions. The main idea follows similar to [54].

    Very recently, as we mentioned earlier in Subsection 2.2, the unique determination for sound-hard obstacles in a certain polygonal setup without any further technical restrictions was derived in [23] for the two-dimiensional case and [24] for the three-dimensional case, respectively. Compared with the existing literatures, the results in [23] and [24] hold for the scatterers of more general material properties and can be obtained by at most two far-field patterns. To avoid repetation, we also refer to Subsection 2.3 for a brief introduction on the novel findings of Laplacian eigenfunctions as well as the Schiffer's problem for sound-hard obstacles, which are presented in a unified representation on the boundary condition in (21).

    As discussed in Subsection 2.2, there is a widespread consensus that the unique identifiability for a sound-soft obstacle can be derived by a single incident wave and for a sound-hard obstacle, the unique determination can be obtained by a single incident plane wave with some fixed kR+ and dSn1. However, the study on the Schiffer's problem for impedance obstacles still remains to be challenging since the reflection principle for Dirichlet and Neumann hyperplanes does not work for impedance hyperplanes. But the study for impedance obstacle is of more practical applications compared with sound-soft and sound-hard cases. In [17], [18], [19] and [20], reconstruction by linear sampling method was conducted for numerical studies. On the theoritical side, in 2007, Liu and Zou [47] addressed the unique determination for partially coated polyhedral scatterers in Rn, n2. Precisely speaking, two kinds of partially coated structures are considered. One is the scatterer of mixed sound-soft and impedance type. It suffices to derive the uniqueness results by one single incident wave. The other one is the scatterer of mixed sound-soft, sound-hard and impedance type. For this case, n independent incident waves are needed in the recovery in Rn with n3 and one incident wave is sufficient to uniquely determine the scatterer in R2. Here, considering the scattering problem (3), we only present the main unique identifiability results for partially coated obstacles according to the cases stated above. One can refer [47] for more details.

    For the scatterer Ω, assume that

    Ω=ΩDUΩI,

    where ΩDΩ and ΩIΩ are two disjoint relatively open subsets having U as their common boundary on Ω. The total wave field in (3) fulfills

    u=0onΩD,νu+iλu=0onΩI, (19)

    where λ(x)C(¯ΩI) satisfing λ(x)λ0>0. Then we can know that for the scatterer of mixed sound-soft and impedance type, there holds

    Theorem 2.16. [47,Theorem 2.1] For any fixed k0>0 and d0Sn1, let Ω and ˜Ω be two polyhedral scatterers on which the condition (19) is enforced with respective surface impedance λ(x) and ˜λ(x). Then we have Ω=˜Ω and λ=˜λ, as long as u(ˆx;Ω,λ,k0,d0)=u(ˆx;˜Ω,˜λ,k0,d0) for ˆxSn1.

    And for the scatterer of mixed sound-soft, sound-hard and impedance type, the following boundary conditions are satisfied

    u=0 onΩI,νu=0 onΩN,νu+iλu=0 onΩI. (20)

    In (20), ΩDΩ, ΩNΩ and ΩIΩ are three disjoint relatively open subsets. Then the unique determination can be derived as follows.

    Theorem 2.17. [47,Theorem 2.2] For any fixed k0>0 and n linearly independent directions d1,d2,,dnSn1, let u1(x),,un(x) be the total fields of the scattering problem associated with the boundary condition (20) corresponding to the incident waves eikxd1,,eikxdn, respectively. Let Ω and ˜Ω be two polyhedral scatterers on which (20) is enforced with respective surface impedance λ(x) and ˜λ(x). Then we have Ω=˜Ω and λ=˜λ, as long as u(ˆx;Ω,λ,k0,dj)=u(ˆx;˜Ω,˜λ,k0,dj) for j=1,,n and ˆxSn1.

    In particular, if ΩI=, which implies that the scatterer is of mixed sound-soft and sound-hard type, then the following theorem holds concerning more general results in R2 allowing all possible physical conditions.

    Theorem 2.18. [47,Theorem 2.4] For any fixed d0S1 and k0>0, let Ω and ˜Ω be two polygonal scatterers in R2 with unknown physical properties. Then we have Ω=˜Ω, and both scatterers have the same physical properties, as long as u(ˆx;Ω,k0,d0)=u(ˆx;˜Ω,k0,d0) for ˆxS1.

    As a direct application of the geometric structures of Laplacian eigenfunctions in Subsection 2.1, we have the unique identifiability results for Schiffer's problem for a certain type of admissible complex polygonal obstacle by at most two far-field patterns. Furthermore, the constant impedance boundary parameter η can be recovered simultaneously for impedance obstacle.

    Definition 2.19 [23,Definition 8.1] Suppose that ΩR2 is an obstacle associated with the following boundary condition

    Bu=νu+ηu=0onΩ. (21)

    Ω is said to be an admissible polygonal obstacle if it is an open polygon and on each edge of Ω, η is a constant (possibly zero) or . If all the angles of Ω are irrational, Ω is called an irrational obstacle. Otherwise, if there exists a corner angle of Ω being rational, then it is called a rational obstacle.

    Definition 2.20. Ω is said to be an admissible complex polygonal obstacle if it fulfills for NN

    (Ω,η)=N=1(Ω,η),withη=N=1ηχΩΩ, (22)

    where each Ω is an admissible polygonal obstacle. Moreover, if all Ω are irrational, =1,,N, then Ω is said to be irrational, otherwise, it is said to be rational of degree p, where p is the smallest degree among all the degrees of rational components.

    Now the unique determination results on Schiffer's problem with respect to an admissible complex irrational polygonal obstacle or an admissible complex rational polygonal obstacle of degree p3 by at most two far-field patterns can be stated as the following two theorems, respectively.

    Theorem 2.21. Let (Ω,η) and (˜Ω,˜η) be two admissible complex irrational obstacles. Let kR+ be fixed and dj, j=1,2 be two distinct incident directions from S1. Let G denote the unbounded connected component of R2¯(Ω˜Ω). Let u and ˜u be, respectively, the far-field patterns associated with (Ω,η) and (˜Ω,˜η). If

    u(ˆx,dj)=˜u(ˆx,dj),  ˆxS1,j=1,2, (23)

    then one has that

    (Ω¯˜Ω)(˜Ω¯Ω)

    cannot have a corner on G.

    The precise proof of this theorem can be found in [23,Theorem 8.3]. The similar unique identifiability also holds for the convex hull of an admissible complex irrational obstacle and the impedance boundary parameter η can be recovered at the same time. Indeed, we have the following corollary.

    Corollary 1. Let (Ω,η) and (˜Ω,˜η) be two admissible complex irrational obstacles. Let kR+ be fixed and dj, j=1,2 be two distinct incident directions from S1. Let G denote the unbounded connected component of R2¯(Ω˜Ω).Let u and ˜u be, respectively, the far-field patterns associated with (Ω,η) and (˜Ω,˜η). If

    u(ˆx,dj)=˜u(ˆx,dj),  ˆxS1,j=1,2, (24)

    then one has that

    CH(Ω)=CH(˜Ω):=Σ, (25)

    and

    η=˜η  on  Ω˜ΩΣ. (26)

    The uniqueness of the impedance boundary parameter η can be proved by contradiction with the help of Holmgren uniqueness property.

    For an admissible complex rational obstacle of degree p3, we have

    Theorem 2.22. Let (Ω,η) be an admissible complex rational obstacle of degree p3. Let kR+ be fixed and dj, j=1,2 be two distinct incident directions from S1. Set uj(x)=u(x;k,dj) to be the total wave fields associated with (Ω,η) and eikxdj, j=1,2, respectively. Recall that G denotes the unbounded connected component of R2¯(Ω˜Ω). If the following condition is fulfilled,

    L(u2u1u1u2)(xc)0, (27)

    where xc is any vertex of Ω, then then one has that

    (Ω¯˜Ω)(˜Ω¯Ω)

    cannot have a corner on G.

    Theorem 2.22 is based on the fact that the rational degree of an admissible complex rational polygonal obstacle is at least 2, which is a direct conclusion of theorem 2.3 to theorem 2.12.

    Remark 1. In (32), for a function fL2loc(R2¯Ω), L(f) is defined as

    L(f)(xc):=limr+01|Ωr(xc)|Ωr(xc)f(x) dx, (28)

    if the limit exists, where Ωr(xc)=B(xc,r)R2¯Ω,  rR+, with B(xc,r) being introduced in (11). Indeed, from a practical point of view, this condition (32) depends on the a-priori knowledge of the underlying obstacle as well as the choice of the incident waves. One can refer [23,Page 36] for more specific explanations.

    Similar to Corollary 1, the unique determination of the convex hull of an admissible complex rational obstacle can also be derived, which is omitted.

    The new approach developed in the proofs of Theorem 2.21 and Theorem 2.22 can uniformly tackle the unique determination for sound-soft, sound-hard and impedance obstacles by at most two far-field measurements and is completely local, which enables us to determine an impedance obstacle as well as its surface impedance by at most two far-field patterns.

    It is the first time in the literature to present a systematic study of the intriguing connections between the vanishing orders of Laplacian eigenfunctions and the intersecting angles of their nodal/generalized singular lines. The unique identifiability for the impedance or generalized impedance cases in Theorem 2.21 and 2.22 has been an open problem for a long time. Therefore, these results should be truly original and of significant interest in the spectral theory of Laplacian eigenfunctions and also Schiffer's problem for inverse obstacle scattering problems.

    As an extension of [23], two of the authors [24] further investigated in R3 the analytic behaviours of Laplacian eigenfunctions at places where nodal or generalized singular planes intersect. The relevant geometric setup is more complicated, where an edge corner intersected by two planes and a vertex corner intersected by at least three planes are considered respectively. Precisely speaking, the vanishing order of Laplacian eigenfunctions at an edge corner is related to the rationality of the intersecting angle similar to the two-dimensional case and the vertex corner case is related to the intersecting angle as well as the intrinsic properties of the Legendre polynomails. An important and direct application of these vanishing results is the unique identifiability for determining the scatterer and the surface impedance parameter (for impedance obstacle) by at most two far-field measurements. To avoid repetation, we skip the detailed analyses for the vanishing order of Laplacian eigenfunctions in [24,Section 2 and 3] at edge corners and vertex corners, respectively. But we present the unique determination results for sound-soft, sound-hard and impedance obstacles in a uniform way in the following theorem. In particular, for impedance obstacles, the corresponding surface parameter can be recovered simultaneously.

    The definition for an admissible polyhedral obstacle is quite different from that of two-dimensional case due to the more complicated geometric formulation. We refer to [24,Definition 6.1] for the rigorous statements.

    Similar to the two-dimensional case, we separately have the unique determination for an admissible complex irraitonal polyhedral obstacle and an admissible complex rational polyhedral obstacle of degree p3 in the following two therorems.

    Theorem 2.23. Consider a fixed kR+, and two distinct incident directions d1 and d2 from S2. Let (Ω,η) and (˜Ω,˜η) be two admissible complex irrational obstacles, with u and ˜u being their corresponding far-field patterns and G being the unbounded connected component of R3¯(Ω˜Ω). If u and ˜u are the same in the sense that

    u(ˆx;k,dj)=˜u(ˆx;k,dj),  forj=1,2and allˆxS2, (29)

    then (Ω¯˜Ω)(˜Ω¯Ω) cannot possess a vertex corner on G. Moreover,

    η=˜ηonΩ˜Ω. (30)

    Theorem 2.24. Consider a fixed kR+, and two distinct incident directions d1 and d2 from S2. Let (Ω,η) and (˜Ω,˜η) be two admissible complex rational obstacles of degree p3, with uj(x):=u(x;k,dj) and ˜uj:=˜u(x;k,dj) being their corresponding total wave fields associated with the incident field eikxdj, and u(ˆx;k,dj) and ˜u(ˆx;,k,dj) being their corresponding far-field patterns for j=1,2. We further write G for the unbounded connected component of R3¯(Ω˜Ω). Then the set (Ω¯˜Ω)(˜Ω¯Ω) can not possess a vertex corner on G, if the following conditions are satisfied:

    uj(ˆx;k,dj)=˜uj(ˆx;k,dj),  ˆxS2,j=1,2, (31)
    L(u2u1u1u2)(xc)0  and  L(˜u2˜u1˜u1˜u2)(xc)0 (32)

    for all vertices xc of Ω, where L is defined in (28).

    The main proofs of Theorem 2.23 and Theorem 2.24 are similar to the corresponding two-dimensional case, one can also refer [24,Section 6] for detailed analyses.

    We would like to emphasize that the unique identifiability results as well as the corresponding argument in both R2 and R3 are "localized" around the corner by utilizing the spectral results for Laplacian eigenfunctions. This indeed provides a completely new and effective approach in studying inverse scattering problems.

    As mentioned in the introduction, there are quite a lot of studies concerning the unique identifiability on the inverse medium scattering problems with the penetrable scatterers in the inhomogeneous medium, which shall be focused on the case that the support of the medium parameter is of polygonal or polyhedral geometry in this section. Before that, we first review some recent progress on geometrical structures of transmission eigenfunctions to (35), which have important applications in unique determinations by a single far-field pattern in the inverse medium problems.

    The interior transmission eigenvalue problem was first introduced by A. Kirsch [37] in 1986. The theoretical studies on interior transmission eigenvalue problems are of significant interest in the inverse medium scattering problems. An important application is to the invisibility phenomenon. The first quantitive result on the intrinsic properties of transmission eigenfunctions was studied by Blåsten and Liu in [11]. They rigorously investigated the vanishing properties of the interior transmission eigenfunctions at a corner whose angle is less than π by establishing a quantitive lower bound associated with incident Herglotz waves. Compared with the study for eigenvalues, the analyses concerning eigenfunctions are more difficult and still remain to be a fascinating topic. Later, in [9], it was further numerically investigated that the transmission eigenfunctions vanish near a corner whose angle is less than π, whereas the transmission eigenfunctions would localize at a corner whose angle is larger than π. Under the H2-regularity on the transmission eigenfunctions, Blåsten [8] proved that the the transmission eigenfunctions must vanish at the corner point if the corner is not degenerated.

    The mathematical argument in [11] is indirect which connects the vanishing property of the interior transmission eigenfunctions with the stability of a certain wave scattering problem with respect to variation of the wave field at the corner point. The main results in [11] can be summarized by

    Theorem 3.1. [11,Theorem 3.2] Let n{2,3} and V=ϕχΩ, where ϕ(x) is a Hölder-continuous function in Rn and Ω is a convex polygon in R2 or a cuboid in R3. Assume that k>0 is a transmission eigenvalue and the corresponding transmission eigenfunctions v,wL2(Ω) satisfying (8). If v can be approximated in the L2-norm by a sequence of Herglotz waves vj defined by

    vj(x)=Sn1eikξxgj(ξ)dσ(ξ),  ξSn1,xRn. (33)

    satisfying one of the following two assumptions

    (a) the kernel gjL2(Sn1) is uniformly bounded,

    (b) the Herglotz waves vj and its kernel gj fulfill that

    vvjL2(Ω)ej,gjL2(Sn1)C(lnj)β, (34)

    where the constants C>0 and 0<β<1/(2n+8),(n=2,3),

    then

    limρ01m(B(xc,r)Ω)B(xc,r)Ω|v(x)|dx=0,

    where m(B(xc,r)Ω) is the measure of B(xc,r)Ω, xc is any vertex of Ω such that ϕ(xc)0.

    Blåsten [8] utilized an energy identity from the enclosure method and constructed a new type of planar complex geometrical optics solution whose logarithm is a branch of the square root to reveal that the transmission eigenfunction v to (35) must vanish at the corner point in R2 or an edge corner point xc in R3 if v is Hölder-continuous at xc and V(xc)0. Indeed, it is stated that

    Theorem 3.2. [8,Theorem 4.2] Let n{2,3} and Ω be bounded domain in Rn. Let VL(Ω). Assume that k>0 is a transmission eigenvalue and the corresponding transmission eigenfunctions v,wL2(Ω) satisfying (8). Let xc be any vertex or edge point of Ω such that V is Cα smooth near xc. If v or w is H2-smooth in a neighborhood of xc in Ω, then v(xc)=w(xc)=0 if V(xc)0.

    In [13], Blåsten and Liu further extended their results on geometric structures of transmission eigenfunctions at corners intersected by line segments to the corners with curvature. Roughly speaking, they established a relationship among the value of transmission eigenfunctions, the diameter of the domain and the underlying refractive index, which yields that the interior transmission eigenfunctions must be nearly vanishing at a high-curvature point on the boundary. These new findings significantly relaxed the dependence on the geometry of the scatterer (smallness assumption) but focus on local structures, which are more practicle and interesting. The main theoretical results on the vanishing properties of transmission eigenfunctions at high-curvature point can be seen in [13,Section 3] and one can also refer to [13,Section 4] for the uniqueness results for the inverse scattering problem associated with the high curvature geometry of the underlying obstacle.

    Consider the following interior transmission eigenvalue problem with a conductive boundary condition for v,wH1(Ω),

    {Δw+k2(1+V)w=0  in Ω,Δv+k2v=0                      in Ω,w=v, νv+ηv=νw   on Ω, (35)

    where Ω is a bounded Lipschitz domain in Rn, n=2,3, VL(Ω) and ηL(Ω), νSn1 signifies the exterior unit normal vector to Ω. If for a certain kR+, there exists a pair of nontrivial solutions (v,w)H1(Ω)×H1(Ω) to (35), then k is called a conductive transmission eigenvalue and (v,w) is referred to as the corresponding pair of conductive transmission eigenfunctions. Especially, when η0, (35) degenerates to be (8).

    The geometric properties studied in [11] are significantly generalized in a recent paper [30] concerning the geometric structures of conductive transmission eigenfunctions to (35). Roughly speaking, the results are extended in the following three aspects. First, the conductive transmission eigenfunctions include the interior transmission eigenfunctions as a special case. The geometric structures established for the conductive transmission eigenfunctions in [30] include the results in [11] as a special case. Second, the vanishing property of the conductive transmission eigenfunctions is established for any corner as long as the corner singularity is not degenerate. Third, the regularity requirements on the interior transmission eigenfunctions in [11] are significantly relaxed for the conductive transmission eigenfunctions. Furthermore, geometrical structures have practical and important applications in the inverse medium problems. In the following, we review the intriguing discoveries regarding the geometric properties of conductive transmission eigenfunctions in R2 as well as a unique identification for the polygonal conductive obstacle by a single far-field measurement. The argument for the three-dimensional case follows a similar approach to the two-dimensional case with the help of the dimension reduction operator, hence we skip the details. However, we would like to point out that the corresponding analyses in R3 are much more tedious and one can refer to [30,Section 3] for more discussions.

    In order to present main results on the geometric properties of the conductive transmission eigenfunctions, which shall play a critical role in the unique identifiability for the conductive scatterer, we first introduce the following notations. Denote Bh(x) by an open ball of radius hR+ and centered at x and Wxc(θW) is an open sector in R2 with the vertex xc and the open angle θW.

    Then the main theorems in [30] concerning the vanishing properties of conductive transmission eigenfunctions can be summarized as follows.

    Theorem 3.3. [30,Theorem 2.1] Let vH1(Ω) and wH1(Ω) be a pair of eigenfunctions to (35) associated with kR+. Assume that the Lipschitz domain ΩR2 contains a corner ΩBR(xc)=ΩWxc(θW), where xc is the vertex of ΩWxc(θW) and R>0. Moreover, there exits a sufficiently small neighbourhood Sh(xc)=ΩBh(xc)=ΩWxc(θW) (i.e. h>0 is sufficiently small) of xc in Ω, where

    Γ±h(xc):=Wxc(θW)Bh(xc),ΣΛh(xc):=Sh(xc)Sh/2(xc),Sh/2(xc):=ΩBh/2(xc)=ΩWxc(θW), (36)

    such that qwCα(¯Sh(xc)) with q:=1+V and ηCα(¯Γ±h(xc)) for 0<α<1, and vwH2(ΣΛh(xc)). If the following conditions are fulfilled:

    (a) the transmission eigenfunction v can be approximated in H1(Sh) by the Herglotz functions vj, j=1,2,, with kernels gj satisfying

    vvjH1(Sh)j1Υ,gjL2(S1)Cjϱ, (37)

    for some constants C>0, Υ>0 and 0<ϱ<1, where vj is defined in (33);

    (b) the function η(x) doest not vanish at the corner, i.e.,

    η(xc)0, (38)

    (c) the open angle of the open sector Wxc(θW) satisfy

    θWπ, (39)

    then one has

    limρ+01m(Bρ(xc)Ω)Bρ(xc)Ω|v(x)|dx=0, (40)

    where m(Bρ(xc)Ω) is the area of Bρ(xc)Ω.

    The proof of this theorem is based on microlocal analysis combining with the specific complex geometrical optics solutions introduced in [8].

    If stronger regularity conditions can be fulfilled by the conductive transmission eigenfunction v to (35), it is apparent to have

    Theorem 3.4. [30,Theorem 2.2] Let vH2(Ω) and wH1(Ω) be eigenfunctions to (35). Assume that the Lipschitz domain ΩR2 contains a corner ΩBR(xc)=ΩWxc(θW), where xc is the vertex of ΩWxc(θW) and R>0. Moreover, there exits a sufficiently small neighbourhood Sh(xc)=ΩBh(xc)=ΩWxc(θW) (i.e. h>0 is sufficiently small) of xc in Ω such that qwCα(¯Sh(xc)) with q:=1+V and ηCα(¯Γ±h(xc)) for 0<α<1, and vwH2(ΣΛh(xc)), where Γ±h(xc) and ΣΛh(xc) are defined in (36). Under the following assumptions:

    (a) the function η(x) doest not vanish at the corner, i.e.,

    η(xc)0, (41)

    (b) the open angle of the open sector Wxc(θW) satisfy

    θWπ,

    then we have v(xc)=w(xc)=0.

    Consider the following medium scattering system for uH1loc(Rn) in a bounded domain ΩRn:

    {Δu+k2(1+V)u=0 in  Ω,Δu++k2u+=0 in  RnΩ,u+=u,νu+=νu on  Ω,u+=ui+us in  RnΩ,limrr(n1)/2(rusikus)=0, r=|x|, (42)

    where ui=ui=eikxd is the incident wave, V denotes the material parameter or potential of an inhomogeneous acoustic medium supported in Ω, and the last equation of (42) is the Sommerfield radiation condition which ensures the outgoing nature of the scattered wave us.

    The Sommerfeld radiation condition in (42) implies that the asymptotic expansion (5) still holds with the far-field pattern u(ˆx;ui) for all ˆx:=x/|x|Sn1. The inverse problem associated with (42) is to recover V by the knowledge of u(ˆx;ui). Blåsten and Liu first established the unique identifiability results by single far-field pattern for (42) when the support of V fulfills certain polyhedral cell and nest geometry; see [12,Section 2].

    Consider the scattering problem (42) with a piecewise constant refractive index

    V:=VχΣ,¯Ω=¯Σ,N, (43)

    where VC are constants and ΣRn are mutually disjoint bounded open subsets.

    Definition 3.5. [12,Definition 2.1] An admissible cell ΣRn is a bounded open convex polytope, i.e. a polygon in R2 and a polyhedron in R3.

    Based on Definition 3.5, in the following two definitions, the polyheral cell and nest geometry are defined, respectively.

    Definition 3.6. [12,Definition 2.2] For N let each of ΣRn be an admissible cell or the empty set, ¯Σ is simply connected, bounded and ΣΣk= if k. A bounded potential VL(Rn) is said to be piecewise constant with polyhedral cell geometry if

    1. there are constants VC such that

    V(x)==1VχΣ(x),

    with V=0 if Σ=, and

    2. each Σ has a vertex that can be connected to infinity by a path that stays distance dd0>0 from any Σk with k>.

    Definition 3.7. [12,Definition 2.4] For N, let each of ΣRn be an admissible cell or the empty set, and

    Σ

    A bounded potential V \in L^\infty( \mathbb{R}^n) is said to be piecewise constant with polyhedral nested geometry if there are constants V_\ell\in \mathbb{C} , with V_1\neq0 , V_{\ell+1}\neq V_\ell such that

    V(\mathbf{ x}) = \sum\limits_{\ell = 1}^\infty V_\ell \chi_{U_\ell}(\mathbf x)

    where U_\ell : = \Sigma_\ell \setminus \overline{\Sigma_{\ell+1}} .

    Blåsten and Liu also introduced a more general case that the potential V is of Hölder continuous at the corner. The corresponding definition for the admissible potential can be described by

    Definition 3.8. [12,Definition 2.4] A potential V \in L^\infty is a non-constant admissible potential if there is an admissible cell \Sigma\subset \mathbb{R}^n and bounded function \psi\in L^\infty( \mathbb{R}^n) such that V = \chi_\Sigma \psi . Moreover we require that \psi be Hölder C^\alpha -continuous in a neighbourhood of each of the vertices of \Sigma with \alpha>0 in 2D and \alpha>1/4 in 3D. Finally, the function \psi must not vanish at any of the vertices.

    Blåsten and Liu presented the main uniqueness results for the refractive index in a certain medium structure based on the assumption that for each \ell\in \mathbb{N} , the total wave field does not vanish at any vertex of \Sigma_\ell . This assumption can be fulfilled for low-frequencies with incident plane waves, i.e. k is small enough.

    Theorem 3.9. [12,Theorem 2.6] Let n\in\{2, 3\} and k>0 . Let V and \widetilde{V} be two piecewise constant potentials with common polyhedral cell geometry. Let u^i be an incident wave such that u(\mathbf x_c)\neq0 or \widetilde{u}(\mathbf x_c)\neq0 for each vertex \mathbf x_c of the cells of V and \widetilde{V} . If u^\infty(\hat{ \mathbf x}; u^i) = \widetilde{u}^\infty(\hat{ \mathbf x}; u^i) , then V = \widetilde{V} .

    Theorem 3.10. [12,Theorem 2.7] Let n\in\{2, 3\} and k>0 . Let V and \widetilde{V} be two piecewise constant potentials with polyhedral nested geometry. Let u^i be an incident wave such that u(\mathbf x_c)\neq0 or \widetilde{u}(\mathbf x_c)\neq0 for each vertex \mathbf x_c of the cells of V and \widetilde{V} . If u^\infty(\hat{ \mathbf x}; u^i) = \widetilde{u}^\infty(\hat{ \mathbf x}; u^i) then V = \widetilde{V} .

    For more general mediums with potentials of C^\alpha -continuity, it is known that

    Theorem 3.11. [12,Theorem 2.5] Let n\in\{2, 3\} , k>0 and V = \chi_\Sigma\psi, \widetilde{V} = \chi_{\widetilde{\Sigma}}\widetilde{\psi} be two non-constant admissible potentials. Let u^i be an incident wave such that u(\mathbf x_c)\neq0 or \widetilde{u}(\mathbf x_c)\neq0 for the total waves u, \widetilde{u} at each vertex \mathbf x_c of \Sigma or \widetilde{\Sigma} . Assume that

    u^\infty(\hat{ \mathbf x}; u^i) = \widetilde{u}^\infty(\hat{ \mathbf x}; u^i)

    for the far-field patterns arising from V and \widetilde{V} , respectively. Then \Sigma = \widetilde{\Sigma} and \psi(\mathbf x_c) = \widetilde{\psi}(\mathbf x_c) on each vertex \mathbf x_c of \Sigma = \widetilde{\Sigma} .

    Theorems 3.9, 3.10 and 3.11 were established by investigating the singular behaviors of the transmission eigenfunctions at the corner point, which can also be proved by using the geometrical structures of transmission eigenfunctions at the corner (cf. [8,11]).

    In the following, we are concerned with the time-harmonic electromagnetic wave scattering from a conductive medium body. The conductive medium body arises in several applications of practical importance, including the modeling of an electromagnetic object coated with a thin layer of a highly conducting material and the magnetotellurics in geophysics. Indeed, the following conductive scattering problem (44) can be derived by the transverse-magnetic (TM) polarisation from the time-harmonic Maxwell system

    \begin{equation} \begin{cases} \Delta u^-+k^2 q u^- = 0 & \mbox{ in }\ \Omega, \\[5pt] \Delta u^+ +k^2 u^+ = 0 & \mbox{ in }\ \mathbb{R}^2 \backslash \Omega, \\[5pt] u^+ = u^-, \quad \partial_\nu u^+ + \eta u^+ = \partial_\nu u^- & \mbox{ on }\ \partial \Omega, \\[5pt] u^+ = u^i+u^s & \mbox{ in }\ \mathbb{R}^2 \backslash \Omega, \\[5pt] \lim\limits_{r \rightarrow \infty} r^{1/2} \left( \partial_r u^s-{{\mathrm{i}}} k u^s \right) = 0, & \ r = |\mathbf x|, \end{cases} \end{equation} (44)

    where q = 1+V , u^i = e^{{{\mathrm{i}}} k {\mathbf x} \cdot \mathbf d} is the impinging incident wave and u^s is the corresponding scattered wave interrupt by \Omega . The well-posedness of the direct problem (44) is known (cf. [14]). The detailed discussions on the aforementioned two specific applications and the mathematical formulations of the associated inverse problems can be found in [22,Section 1] and [30,Section 4], respectively.

    Theorem 3.3 and Theorem 3.4 can be applied directly to establish the uniquely determination of the shape of an admissible conductive scatterer by a single far-field pattern.

    Definition 3.12. Let (\Omega;k, {\mathbf d}, q, \eta) be a conductive scatterer associated with the incident plane wave u^i = e^{{{\mathrm{i}}} k\mathbf x\cdot \mathbf d} with \mathbf d\in\mathbb{S}^{1} and k\in \mathbb R_+ . Consider the scattering problem (44) and u is the total wave fields therein. The scatterer is said to be admissible if it fulfills the following conditions:

    (a) \Omega is a bounded simply connected Lipschitz domain in \mathbb{R}^2 , and q\in L^\infty(\Omega) , \eta\in L^\infty(\partial\Omega) .

    (b) Following the notations in Theorem 3.3, if \Omega possesses a corner B_h(\mathbf x_c) \cap \Omega = \Omega\cap W_{\mathbf x_c}(\theta_W ) where \mathbf x_c the vertex of the sector W_{\mathbf x_c} and the open angle \theta_W of W_{\mathbf x_c}(\theta_W ) satisfies \theta_W \neq \pi , then qu\in C^\alpha(\overline{S_h(\mathbf x_c)}) , \eta\in C^\alpha(\overline{\Gamma_h^\pm(\mathbf x_c})) , where S_{h}(\mathbf x_c) and \Gamma_h^\pm (\mathbf x_c) are defined in (36).

    (c) The total wave field u is non-vanishing everywhere in the sense that for any \mathbf x\in\mathbb{R}^n ,

    \begin{equation} \lim\limits_{ \rho \rightarrow +0 }\frac{1}{m(B(\mathbf x, \rho ))} \int_{B(\mathbf x, \rho )} |u(\mathbf x)| {\rm d} x\neq 0. \end{equation} (45)

    Theorem 3.13. [30,Theorem 4.1] Consider the conductive scattering problem (44) associated with two conductive scatterers (\Omega_j; k, {\mathbf d}, q_j, \eta_j) , j = 1, 2 , in \mathbb{R}^2 . Let u^\infty_j(\hat{ \mathbf x}; u^i) be the far-field pattern associated with the scatterer (\Omega_j; q_j, \eta_j) and the incident field u^i . Suppose that (\Omega_j;k, {\mathbf d}, q_j, \eta_j) , j = 1, 2 are admissible and

    \begin{equation} u^\infty_1(\hat {\mathbf x}; u^i) = u^\infty_2(\hat{\mathbf x}; u^i) \end{equation} (46)

    for all \hat{\mathbf x}\in\mathbb{S}^{1} and a fixed incident wave u^i . Then

    \begin{equation} \Omega_1\Delta\Omega_2: = \big(\Omega_1\backslash\Omega_2\big)\cup \big(\Omega_2\backslash\Omega_1\big) \end{equation} (47)

    cannot possess a corner. Hence, if \Omega_1 and \Omega_2 are convex polygons in \mathbb{R}^2 , one must have

    \begin{equation} \Omega_1 = \Omega_2. \end{equation} (48)

    If conductive parameter \eta is constant, then it can be recovered simultaneously once the admissible conductive scatter \Omega is determined.

    Theorem 3.14. [30,Theorem 4.2] Consider the conductive scattering problem (44) associated with the admissible conductive scatters (\Omega_j;k, {\mathbf d}, q, \eta_j) , where \Omega_j = \Omega for j = 1, 2 and \eta_j\neq0 , j = 1, 2 , are two constants. Let u^{\infty}_j(\hat{\mathbf x}; u^i) be the far-field pattern associated with the scatter (\Omega;k, {\mathbf d}, q, \eta_j) and the incident field u^i . Suppose that (\Omega;k, {\mathbf d}, q, \eta_j) , j = 1, 2 , are admissible and

    \begin{equation} u^{\infty}_1(\hat{\mathbf x}; u^i) = u^{\infty}_2(\hat{\mathbf x}; u^i) \end{equation} (49)

    for all \hat{\mathbf x}\in\mathbb{S}^1 and a fixed incident wave u^i . Then if k is not an eigenvalue of the partial differential operator \Delta+k^2q in H_0^1(\Omega) , we have \eta_1 = \eta_2 .

    It is clear that Theorem 3.14 is established with a-prior knowledge that the medium parameter q is known. Indeed, in our recent study [22], we proved further that the medium parameter q as well as the conductive surface parameter \eta can be uniquely determined simultaneously by a single far-field measurement within a more general geometry. In [22,Section 2], two geometric setups called polygonal-nest geometry and polygonal-cell geometry for the conductive medium body were introduced.

    Similar to the geometric setup proposed from Definition 3.5 to Definition 3.7, following the rigorous definitions for the polygonal-nest geometry in [22,Definition 2.3] and the polygonal-cell geometry in [22,Definition 2.4], an admissible conductive medium of polygonal-nest or polygonal-cell structure was established in [22,Definition 4.1]. Indeed, the admissibility condition in [22,Definition 4.1] indicates that the total field u is not vanishing at any vertex of the polygonal-nest partition or the boundary of the polygonal-cell conductive medium body. For compatibility, a local uniqueness regarding the shape of an admissible polygonal-nest or polygonal-cell conductive medium body by a single far-field measurement was first presented without knowing the medium parameter and the conductive surface parameter.

    Before presenting the unique identification results, similar to (43), we are supposed to introduce some necessary notions first, which shall be utilized in the subsequent discussions. For a polygonal-nest conductive medium body (\Omega; q, \eta) as described in [22,Definition 2.3], denote

    \begin{equation} (\Omega; q, \eta) = \bigcup\limits_{\ell = 1}^N (U_\ell; q_\ell, \eta_{\ell}) \end{equation} (50)

    and

    \begin{equation} \Omega = \bigcup\limits_{\ell = 1}^N U_\ell, \ \ q = \sum\limits_{\ell = 1}^N q_\ell \chi_{U_\ell}, \ \ \eta = \sum\limits_{\ell = 1}^N \eta_{\ell} \chi_{\partial\Sigma_\ell}, \end{equation} (51)

    where U_\ell: = \Sigma_{\ell}\backslash\overline{\Sigma_{\ell+1}} and each \Sigma_{\ell} is a conductive medium body, q: = 1+V\in L^\infty( \mathbb{R}^n) with V being introduced in (42).

    For a polygonal-cell conductive medium body (\Omega; q, \eta) as described in [22,Definition 2.4], denote

    \begin{equation} (\Omega; q, \eta) = \bigcup\limits_{\ell = 1}^N (\Sigma_\ell; q_\ell, \eta^*) \end{equation} (52)

    and

    \begin{equation} \Omega = \bigcup\limits_{\ell = 1}^N \Sigma_\ell, \ \ q = \sum\limits_{\ell = 1}^N q_\ell \chi_{\Sigma_\ell}, \ \ \eta = \sum\limits_{\ell = 1}^N \eta^* \chi_{\partial\Sigma_\ell}, \end{equation} (53)

    where each \Sigma_{\ell} is a conductive medium body and \eta^* is the uniform conductive surface parameter.

    Fig. 1 (b) presents a typical polygonal-cell partition of \Omega with five hexagonal cells. It is interesting to note that it is the honeycomb graphene structure. We would like to emphasize that for a polygonal-cell partition, each cell is not necessary to be convex.

    Figure 1.  Schematic illustration of the two polygonal geometries in \mathbb{R}^2 for a conductive medium body.

    Definition 3.15. Let (\Omega;q, \lambda ) be polygonal-nest or polygonal-cell conductive medium body as described in (50) and (52), respectively. The scatterer is said to be admissible if it fulfills the following condition: consider a polygonal-nest conductive medium body with the polygonal-nest partition \{\Sigma_{\ell} \}_{\ell = 1}^N , for any vertex \mathbf{x}_c\in\partial\Sigma_\ell , u(\mathbf x_c)\neq0 ; consider a polygonal-cell conductive medium body, for any vertex \mathbf{x}_c\in\partial\Omega , u(\mathbf x_c)\neq0 , where u is the solution to (44).

    Theorem 3.16. [22,Theorem 4.1] Consider the conductive scattering problem (44) associated with two admissible polygonal-nest or polygonal-cell conductive medium bodies (\Omega_j; q_j, \eta_j) , j = 1, 2 , in \mathbb{R}^2 . Let u^\infty_j(\hat{\mathbf x}; u^i) be the far-field pattern associated with the conductive medium body (\Omega_j; q_j, \eta_j) and the incident field u^i , respectively. Suppose that

    \begin{equation} u^\infty_1(\hat{\mathbf x}; u^i) = u^\infty_2(\hat{\mathbf x}; u^i) \end{equation} (54)

    for all \hat{\mathbf x}\in\mathbb{S}^{1} and a fixed incident wave u^i . Then

    \begin{equation} \Omega_1\Delta\Omega_2: = \big(\Omega_1\backslash\Omega_2\big)\cup \big(\Omega_2\backslash\Omega_1\big) \end{equation} (55)

    cannot possess a corner. Furthermore, if \Omega_1 and \Omega_2 are two admissible polygonal-nest conductive medium bodies, one must have

    \begin{equation} \partial \Omega_1 = \partial \Omega_2. \end{equation} (56)

    It is easy to see from Theorem 3.16 that for a polygonal-nest medium body, the local uniqueness results readily imply the global uniqueness results. The corresponding proof for Theorem 3.16 is based on the geometrical structures of conductive transmission eigenfunctions established in Theorem 3.4.

    Next, the simultaneous unique determination for the piecewise constant medium parameter as well as the conductive surface parameter associated with an admissible polygonal-nest or polygonal-cell conductive medium body can be achieved as the following two theorems. However, a-prior knowledge on the cell structure of an admissible polygonal-cell conductive medium body is assumed to be known in advance. The proof of Theorems 3.17 and 3.18 can be obtained by utilizing certain microlocal analysis and the complex geometrical optics solution introduced in [8].

    Theorem 3.17. [22,Theorem 4.2] Considering the conductive scattering problem (44) associated with two admissible polygonal-cell conductive medium bodies (\Omega; q_j, \eta_j) in \mathbb{R}^2 , j = 1, 2 . For j = 1, 2 , we let the material parameters q_j and \eta_{j } with a common polygonal-cell partition \{\Sigma_{\ell} \}_{\ell = 1}^N defined in (53) be characterized by

    \begin{equation} q_j = \sum\limits_{\ell = 1}^{N}q_{\ell, j}\chi_{\Sigma_{\ell, j}}, \ \ \eta_j = \sum\limits_{\ell = 1}^{N} \eta_{j }^*\chi_{\partial \Sigma_{\ell, j} }. \end{equation} (57)

    Let u_j^{\infty}(\hat{\mathbf{x}}; u^i) be the corresponding far-field pattern associated with the incident wave u^i corresponding to (\Omega; q_j, \eta_j) , respectively. Suppose that (\Omega; q_j, \eta_j) , j = 1, 2 , fulfill

    \begin{equation} u_1^{\infty}(\hat{\mathbf{x}}; u^i) = u_2^{\infty}(\hat{\mathbf{x}}; u^i) \end{equation} (58)

    for all \hat{\mathbf{x}}\in\mathbb{S}^1 and a fixed incident wave u^i . Then we have q_{1} = q_{2} and \eta_{1} = \eta_{2} .

    Theorem 3.18. Considering the conductive scattering problem (44) associated with two admissible polygonal-nest conductive medium bodies (\Omega_j; q_j, \eta_j) in \mathbb{R}^2 , j = 1, 2 , where the associated polygonal-nest partitions \{\Sigma_{\ell, 1}\}_{\ell = 1}^{N_1} and \{\Sigma_{\ell, 2}\}_{\ell = 1}^{N_2} are defined in (51) with \Omega_1 = \bigcup_{\ell = 1}^{N_1} U_{\ell, 1} and \Omega_2 = \bigcup_{\ell = 1}^{N_2} U_{\ell, 2} , where U_{\ell, j} = \Sigma_{\ell, j} \backslash\overline{\Sigma_{\ell+1, j}} , \ell = 1, \ldots, N_j . For j = 1, 2 , we let the material parameters q_j and \eta_{j } be characterized by

    \begin{equation} q_j = \sum\limits_{\ell = 1}^{N_j}q_{\ell, j}\chi_{U_{\ell, j}}, \ \ \eta_j = \sum\limits_{\ell = 1}^{N_j} \eta_{{\ell, j} }\chi_{\partial \Sigma_{\ell, j} }. \end{equation} (59)

    Let u_j^{\infty}(\hat{\mathbf{x}}; u^i) be the corresponding far-field pattern associated with the incident wave u^i corresponding to (\Omega_j; q_j, \eta_j) , respectively. Suppose that (\Omega_j; q_j, \eta_j) , j = 1, 2 , fulfill

    \begin{equation} u_1^{\infty}(\hat{\mathbf{x}}; u^i) = u_2^{\infty}(\hat{\mathbf{x}}; u^i) \end{equation} (60)

    for all \hat{\mathbf{x}}\in\mathbb{S}^1 and a fixed incident wave u^i . Then we have N_1 = N_2 = N , \partial \Sigma_{\ell, 1} = \partial \Sigma_{\ell, 2} for \ell = 1, \ldots, N , q_1 = q_2 and \eta_1 = \eta_2 .

    The study on scattering theory by periodic structures has received a lot of attention in recent years. It arises from the first work studied by Rayleigh on the scattering by plane waves from corrugated surfaces. In particular, if the corrugations are exact sinusoids, then the sinusoidally corrugated surface provides a model of a reflection grating. There are quite many applications on grating problems in spectroscopy and oceanography. For example, it can be utilized to study the structure of the ocean surface by measuring sound scattering from below or the scattering of light or radar from above. We refer to [5] and [55] for more historical discussions.

    In this section, we focus on the existing studies on the uniqueness issue for inverse diffraction grating problems. It is known that a general periodic grating structure can be uniquely determined by one incident wave if the wave number k is a real number; see [5] and [34]. In [5], the researcher also presented the uniqueness results within C^2 -smooth functions in \mathbb{R}^2 in the case of lossy medium. Kirsch in [39] and Hettlich, Kirsch in [34] also investigated the case for C^2 -smooth functions by all quasi-periodic incident waves and for a sufficiently small wave number or grating height, respectively. In \mathbb{R}^3 , Ammari [4], Bao and Zhou [7] as well as Bao, Zhang and Zou [6] discussed the more complicated doubly periodic structures. By making use of reflection principle, Elschner, Schmidt and Yamamoto (see [31] and [32]) obtained some results on global uniqueness for the particular piecewise linear periodic structures.

    In the subsequent discussions, we just present some of the aforementioned results to illustrate the development on inverse diffraction grating problem. Consider the direct diffraction grating problem associated to Helmholtz system as:

    \begin{equation} \Delta u+k^2 u = 0\mbox{in}\ \ \Omega_f; \quad {\mathcal B}(u)\big|_{\Lambda _f} = 0 \mbox{on} \ \ \Lambda_f, \end{equation} (61)

    with the generalized impedance boundary condition

    \begin{equation} \mathcal{B}(u) = \partial_\nu u+\eta u = 0, \end{equation} (62)

    where \eta can also be \infty or 0 , corresponding to a sound-soft or sound-hard grating, respectively.

    In (61), for a periodic Lipschitz function f with period 2\pi ,

    \Omega_f: = \{ \mathbf x\in \mathbb{R}^2; x_2 > f(x_1), x_1 \in \mathbb{R}\}

    is filled with a material whose refraction index (or wave number) k is a positive constant. \Lambda_f signifies a diffraction grating profile given by the curve

    \begin{equation} \Lambda_f = \{(x_1, x_2) \in \mathbb{R}^2 ;\; x_2 = f(x_1)\}. \end{equation} (63)

    The corresponding incident wave is defined as

    \begin{equation} \notag u^i(\mathbf x;k, \mathbf d) = e^{{{\mathrm{i}}} k \mathbf d \cdot \mathbf x}, \quad \mathbf d = (\sin \theta, -\cos \theta)^\top , \quad \theta \in \left( - \frac{\pi}{2} , \frac{\pi}{2} \right), \end{equation}

    which propogates to \Lambda_{f} from the top.

    In order to derive the uniqueness results for the inverse grating problem associated with (61), the total wave field u should be \alpha -quasiperiodic in the x_1 -direction, with \alpha = k\sin \theta , which means that

    u(x_1+2\pi, x_2) = e^{2{{\mathrm{i}}} \alpha \pi}\cdot u(x_1, x_2),

    and the scattered field u^s satisfies the Rayleigh expansion (cf.[49,50]):

    \begin{align} u^s(\mathbf x;k, \mathbf d )& = \sum\limits_{n = -\infty}^{+\infty } u_n e^{{{\mathrm{i}}} { \xi}_n (\theta ) \cdot \mathbf x } \quad \mbox{for} \quad x_2 > \max\limits_{x_1\in [0, 2\pi]} f(x_1), \end{align} (64)

    where u_n\in \mathbb{C}(n\in \mathbb Z) are called the Rayleigh coefficient of u^s , and

    \begin{equation} \begin{split} \xi_n(\theta )& = \left(\alpha_n(\theta), \beta_n(\theta)\right)^\top, \quad \alpha_n(\theta ) = n+k\sin \theta, \\ \beta_n(\theta )& = \left\{\begin{array} {c} \sqrt{k^2- \alpha_n^2 (\theta) }, \quad\mbox{ if } |\alpha_n (\theta )| \leq k\\ \\[1pt] {{\mathrm{i}}} \sqrt{\alpha_n^2 (\theta)-k^2 }, \quad\mbox{ if } |\alpha_n (\theta)| > k \end{array}. \right. \end{split} \end{equation} (65)

    The existence and uniqueness of the \alpha -quasiperiodic solution to (61) for the sound-soft or impedance boundary condition with \eta\in \mathbb{C} being a constant satisfying \Im (\eta) >0 can be found in [1,16,38,39]. It should be pointed out that the uniqueness of the direct scattering problem associated with the sound-hard condition is not always true (see [36]). In our subsequent study, we assume the well-posedness of the forward scattering problem and focus on the study of the inverse grating problem.

    Introduce a measurement boundary as

    \Gamma_b: = \{ (x_1, b)\in \mathbb{R}^2 ;\; 0 \leq x_1 \leq 2 \pi, \, b > \max\limits_{x_1\in [0, 2\pi]}|f(x_1)| \}.

    The inverse diffraction grating problem is to determine (\Lambda_f, \eta) from the knowledge of u(\mathbf x|_{\Gamma_b};k, \mathbf d) , and can be formulated as the operator equation:

    \begin{equation} \label{eq:iopd} \notag \mathcal{F}(\Lambda_f, \eta ) = u(\mathbf x;k, \mathbf d), \quad \mathbf x\in \Gamma_b, \end{equation}

    where \mathcal{F} is defined by the forward diffraction scattering system, and is nonlinear.

    The pioneer work of Kirsch in [39] determined the unknown grating structure by the knowledge of incident waves and the scattered wave fields with the help of associated expansion of incident wave as

    \begin{equation} u^i(\mathbf{ x}) = u^i(x_1, x_2) = \sum\limits_{n\in\mathbb{Z}}\psi_ne^{{{\mathrm{i}}}\alpha_nx_1+{{\mathrm{i}}}\beta_n(b-x_2)}, \quad x_2\leq b, \end{equation} (66)

    where \mathbf{ x} = (x_1, x_2) , \psi_n are the Fourier coefficients of any \psi\in L^2(0, 2\pi) such that \mathcal{F}_{\Lambda_f}\psi(x_1) = u(x_1, b) . Instead of the notations introduced in [39], we follow the uniform notations in this section to present the main uniqueness result.

    Theorem 4.1. [39,Theorem 3.1] Assume that \beta_n\neq0 in (66) for all n\in\mathbb{N} . Let {f}, {\widetilde f}\in C^2( \mathbb{R}) be 2\pi -periodic and b>\max\{\max_{x_1\in \mathbb{R}}{f}, \max_{x_1\in \mathbb{R}}{\widetilde f}\} . If \mathcal{F}_{\Lambda_{f}} = \mathcal{F}_{\Lambda_{\widetilde f}} then \Lambda_{f} = \Lambda_{\widetilde f} , i.e. if the outputs are the same for {f} and {\widetilde{f}} for all incident waves (66), then \Lambda_{f} and \Lambda_{\widetilde f} have to coincide.

    All the literatures mentioned at the beginning of this subsections are concerning the unique recovery results on the inverse diffraction grating problem with the sound-soft (namely \eta = \infty in (62)) or sound-hard (namely \eta = 0 in (62), partially solved) boundary condition by a finite number of incident plane waves. However, the unique identifiability has still remained to be open for the impedance or generalized impedance cases until recently in [23], a completely new approach was proposed by utilizing the spectral properties of Laplacian eigenfunctions in Subsection 2.1 to address this problem in \mathbb{R}^2 . Indeed, the unique determination for the inverse diffraction grating problem in [23] is also referred to as a direct application of the geometric structures of Laplacian eigenfunctions presented in Subsection 2.1. We only provide the main unique determination results and some relating discussions here.

    First, we are supposed to give the precise definition of admissible polygonal gratings associated with the inverse diffraction grating problem.

    Definition 4.2. [23,Definition 8.1] Let (\Lambda_f, \eta) be a periodic grating as described in (63). Suppose there is a partition, [0, 2\pi] = \cup_{i = 1}^{\ell}[a_i, a_{i+1}] with a_i<a_{i+1} , a_1 = 0 and a_{\ell+1} = 2\pi . If on each piece [a_i, a_{i+1}] , 1\leq i\leq\ell , f is a linear polynomial and \eta is either a constant (possibly zero) or \infty , then (\Lambda_f, \eta) is said to be an admissible polygonal grating.

    Definition 4.3. Let (\Lambda_f, \eta) be an admissible polygonal grating. Let \Gamma^+ and \Gamma^- be two adjacent pieces of \Lambda_f . The intersecting point of \Gamma^+ and \Gamma^- is called a corner point of \Lambda_f , and \angle(\Gamma^+, \Gamma^-) is called a corner angle. If all the corner angles of \Lambda_f are irrational, then it is said to be an irrational polygonal grating. If a corner angle of \Lambda_f is rational, it is called a rational polygonal grating. The smallest degree of the rational corner angles of \Lambda_f is referred to as the rational degree of \Lambda_f .

    Similar to Theorem 2.21 and Theorem 2.22 for the study on admissible irrational and rational complex polygonal obstacles, we have the unique determination results for rational and irrational polygonal gratings, respectively. In particular, for the rational case, we are concerned with the admissible rational polygonal grating of degree p , p\geq3 , due to the fact that the rational degree of \Lambda_f is at least 2 .

    Theorem 4.4. [23,Theorem 8.13] Let (\Lambda_f, \eta) and (\Lambda_{\widetilde f}, \widetilde\eta) be two admissible irrational polygonal gratings, and \mathbf{G} be the unbounded connected component of \Omega_f\cap \Omega_{\widetilde f} . Let k\in\mathbb{R}_+ be fixed and \mathbf{d}_\ell , \ell = 1, 2 be two distinct incident directions from \mathbb{S}^1 , with

    \begin{equation} \label{eq:8incident} \notag \mathbf{d}_\ell = (\sin \theta_\ell, -\cos \theta_\ell)^\top , \quad \theta_\ell \in \left( - \frac{\pi}{2} , \frac{\pi}{2} \right). \end{equation}

    Let u(\mathbf x;k, \mathbf d_\ell ) and \widetilde u(\mathbf x;k, \mathbf d_\ell ) denote the total fields associated with (\Lambda_f, \eta) and (\Lambda_{\widetilde f}, \widetilde\eta) respectively and let \Gamma_b be a measurement boundary given by

    \Gamma_b: = \left\{ (x_1, b)\in \mathbb{R}^2 ;\; 0 \leq x_1 \leq 2 \pi, \, b > \max\left\{ \max\limits_{x_1\in [0, 2\pi]}|f(x_1)|, \, \max\limits_{x_1\in [0, 2\pi]}|\widetilde {f}(x_1)| \right\} \right \},

    If it holds that

    \begin{equation} u(\mathbf x;k, \mathbf d_\ell ) = \widetilde u(\mathbf x;k, \mathbf d_\ell ), \quad \ell = 1, 2, \quad \mathbf x = (x_1, b) \in \Gamma_b, \end{equation} (67)

    then it cannot be true that there exists a corner point of \Lambda_{f} lying on \partial\mathbf{G}\backslash\partial\Lambda_{\widetilde f} , or a corner point of \Lambda_{\widetilde f} lying on \partial\mathbf{G}\backslash \partial \Lambda_{f} .

    Combining with the fact that \{e^{{{\mathrm{i}}}\xi_\ell\cdot\mathbf{ x}}; \mathbf{ x}\in U, \ell = 1, 2, \cdots, n\} are linearly independent with n distinct vectors \xi_\ell, \ell = 1, 2, \cdots, n , for any open subset U\subset \mathbb{R}^2 , the proof of this theorem can be formulated similarly to the argument in Theorem 2.21. One can refer [23,Section 8] for the rigorous analyses.

    As the result in Theorem 2.22 for the inverse obstacle problem, the unique determination of an admissible rational polygonal grating of degree p , p\geq3 , can also be derived by two measurements if a similar condition to (27) is introduced in this new setup. In such a case, one can establish the local unique recovery result, similar to Theorem 4.4.

    In this paper, we present a review on some recent progress on inverse scattering problems including inverse obstacle problems, inverse medium scattering problems and inverse diffraction grating problems.

    For Schiffer' problem in inverse obstacle scattering in Section 2, there has been a colorful and long history for the relevant study. We investigate the unique identification of sound-soft, sound-hard and impedance obstacles with certain polyhedral geometry, respectively. The existing literatures are mainly concerned with the uniqueness discussions for sound-soft and sound-hard obstacles, where the reflection principle is utilized for establishing the corresponding results. It has been an open problem for a long time on the study about impedance case. In [47], Liu and Zou investigated the unique determination for certain partially coated structures of the obstacle following reflection principle. And very recently, in [23] and [24], by applying the geometric structures of Laplacian eigenfunctions in Subsection 2.1, the unique identifiability for a more general structure of impedance obstacles were considered in \mathbb{R}^2 and \mathbb{R}^3 , respectively. The theoretical findings and the corresponding applications are completely novel and inspiring.

    For inverse medium scattering problems in Section 3, we first review thegeometrical structure of interior transmission eigenfunctions and the more generalized case with the conductive boundary condition. Those theoretical novel findings play an important role in the corresponding applications for the unique identifiability of the inverse medium scattering problems within the polyhedral geometry by a single far-field measurement under certain assumptions. Recently, some simultaneous recovery results regarding the scatterer as well as the conductive surface parameter and the medium parameter were obtained in [22]. The study therein are more generalized with respect to the medium structure and the regularity assumptions.

    In the study on the inverse diffraction grating problem in Section 4, we first formulate the mathematical setup with the generalized impedance boundary which is more practical. By introducing the existing uniqueness results which are mainly concerning gratings with sound-soft or sound-hard boundary, we emphasize the developments on impedance case therein. The corresponding argument is similar to the unique identifiability for impedance obstacles by making use of the spectral properties of Laplacian eigenfunctions.

    At the end of our paper, we propose some interesting open problems as follows.

    ● Establish the global unique identifiability result for an impedance polyhedral obstacle by a single far-field measurement by relaxing the generic condition in Definition 2.19. A more challenging problem is to establish the unique identification for an impedance obstacle of a non-polyhedral geometry by a single far-field measurement.

    ● Develop a uniform approach to tackle the unique identification result for the Schiffer's problem associated with an impedance polyhedral obstacle in \mathbb{R}^n , n>4 .

    ● Establish the global unique identifiability result for a medium polyhedral scatterer by a single far-field measurement by relaxing the generic condition in Definitions 3.8 and 3.12. A more challenging problem is to establish the unique identification for a medium scatterer within more general geometries by a single far-field measurement.

    ● Generalize the geometrical structures of interior transmission eigenfunctions at the corner to a more general interior transmission eigenvalue problem with respect to the anisotropic metric which can be formulated as

    \begin{equation} \notag \begin{cases} \Delta_g u+k^2(1+V)u = 0 &\mbox{in} \quad\Omega, \\ \Delta v+k^2 v = 0&\mbox{in}\quad\Omega, \\ u = v, \quad \partial_{\nu_g}u = \partial_{\nu_g}v&\mbox{on}\quad\partial\Omega, \end{cases} \end{equation}

    where (\Omega, g) is a Riemannian manifold and \Delta_g is the Laplacian-Beltrami operator.

    The authors would like to thank Professor Hongyu Liu of City University of Hong Kong for proposing this project and providing a lot of stimulating discussions and helps during the writing of the paper.



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