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Rapid facile synthesis of Cu2ZnSnS4 films from melt reactions

  • Received: 04 February 2020 Accepted: 03 June 2020 Published: 05 June 2020
  • Films of Cu2ZnSnS4 (CZTS) were successfully deposited on glass substrates using blade technique in 5 min annealing time. The effect of heating temperature on the structural properties was investigated. The dithiocarbamates complexes of copper, zinc and tin were used as precursors through the blade technique. The films were kesterite phase and oriented preferentially along (112) direction. The chemical compositions at each temperature were studied in order to optimize the film stoichiometry. Cu/(Zn + Sn) ratio was between 0.815 and 0.877, and Zn/Sn was in the range of 0.93 to 1.

    Citation: Mundher Al-Shakban, Naktal Al-Dulaimi, Thokozani Xaba, Ahmad Raheel. Rapid facile synthesis of Cu2ZnSnS4 films from melt reactions[J]. AIMS Materials Science, 2020, 7(3): 302-311. doi: 10.3934/matersci.2020.3.302

    Related Papers:

  • Films of Cu2ZnSnS4 (CZTS) were successfully deposited on glass substrates using blade technique in 5 min annealing time. The effect of heating temperature on the structural properties was investigated. The dithiocarbamates complexes of copper, zinc and tin were used as precursors through the blade technique. The films were kesterite phase and oriented preferentially along (112) direction. The chemical compositions at each temperature were studied in order to optimize the film stoichiometry. Cu/(Zn + Sn) ratio was between 0.815 and 0.877, and Zn/Sn was in the range of 0.93 to 1.


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