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Electrical and optical properties of hybrid polymer solar cells incorporating Au and CuO nanoparticles

Materials Science and Engineering Department, University of Wisconsin-Milwaukee, 3200 North Cramer Street, Milwaukee, WI 53201, USA

Topical Section: The solar cell

In this study, to enhance the power conversion efficiency (PCE) of the polymer solar cells (PSCs), Gold (Au) and Copper oxide nanoparticles (CuO-NPs) are incorporated into the PEDOT:PSS and P3HT/PCBM active layers respectively. PSCs with a constant CuO-NP content were fabricated with varying amounts of Au NPs. Addition of Au NPs increased the power conversion efficiency by up to 18% compared to a reference cell without Au-NPs. The short circuit current(Jsc) of the cells containing 0.06 mg of Au NPs was measured at 7.491 mA/cm2 compared to 6.484 mA/cm2 in the reference cells with 0.6 mg of CuO nanoparticles; meanwhile, the external quantum efficiency(EQE) increased from 53% to 61%, showing an enhancement of 15.1%. Au-NPs improved the charge collection at the anode, which results in higher short circuit current and fill factor. However, the strong near field surrounding Au-NPs due to localized surface plasmonic resonance (LSPR) effect is not distributed into the active layer. Instead, it is spread horizontally through the PEDOT:PSS layer, thus minimizing the light absorption in the active layer.
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Keywords Au nanoparticles; CuO nanoparticles; plasmonic effect; UV-visible spectroscopy; PSCs

Citation: Aruna P. Wanninayake, Shengyi Li, Benjamin C. Church, Nidal Abu-Zahra. Electrical and optical properties of hybrid polymer solar cells incorporating Au and CuO nanoparticles. AIMS Materials Science, 2016, 3(1): 35-50. doi: 10.3934/matersci.2016.1.35

References

  • 1. Abu-Zahra N, Algazzar M (2013) Effect of crystallinity on the performance of P3HT/PC70BM/n-dodecylthiol polymer solar cells. J Sol Energy Eng 136(2):021023.
  • 2. Manceau M, Angmo D, Jorgensen M, et al. (2011) ITO-free flexible polymer solar cells: From small model devices to roll-to-roll processed large modules. Org Electron 12, 566–574.
  • 3. Michael CH, Ali D (2014) Efficient generation of model bulk heterojunction morphologies for organic photovoltaic device modeling. Appl Phys Rev 2: 014008.    
  • 4. Choulis SA, Kim Y, Nelson J, et al. (2004) High ambipolar and balanced carrier mobility in regioregular poly (3-hexy thiophene). Appl Phys Rev 85: 3890–3892.
  • 5. Ma W, Yang C, Gong X, et al. (2005) Thermally stable, efficient polymer solar cells with nanoscale control of the interpenetrating network morphology. Adv Funct Mater 15: 1617–1622.    
  • 6. Liao SH, Jhuo HJ, Yeh PN, et al. (2014) Single junction inverted polymer solar cell reaching power conversion efficiency 10.31% by employing dual-doped zinc oxide nano-film as cathode interlayer. Sci Rep, 4: 6813: 4–10.
  • 7. Raja R, Liu WS, Hsiow CY, et al. (2015) Terthiophene-C60 dyads as donor/acceptor compatibilizers for developing highly stable P3HT/ PCBM bulk heterojunction solar cells. J Mater Chem A 3: 14401–14408.    
  • 8. Jung K, Song HJ, Lee G, et al. (2014) Plasmonic organic solar cells employing nanobump assembly via aerosol-derived nanoparticles. ACS Nano 8: 2590-2601.    
  • 9. Deibel C, Dyakonov V (2010) Polymer–fullerene bulk heterojunction solar cells. Rep Prog Phys 3: 9.
  • 10. Gunes S, Neugebauer H, Sariciftci NS (2007) Conjugated polymer-based organic solar cells. Chem Rev 107: 1324–1338.    
  • 11. Atwater HA, Polman A (2010) Plasmonics for improved photovoltaic devices. Nat Mater 9: 205–213.    
  • 12. Schuller JA, Barnard ES, Cai W, et al. (2010) Plasmonics for extreme light concentration and manipulation. Nat Mater 9: 193–204.    
  • 13. Mahmoud AY, Izquierdo R, Truong VV (2014) Gold nanorods incorporated cathode for better performance of polymer solar cells. J Nanomater (2014): 464160.
  • 14. Brown M, Suteewong T, Kumar R, et al. (2011) Plasmonic dye-sensitized solar cells using core-shell metal-insulator nanoparticles. Nano Lett: 11: 438–445.    
  • 15. Kim SS, Na SI, Jo J, et al. (2008) Plasmon enhanced performance of organic solar cells using electrodeposited Ag nanoparticles. Appl Phys Lett 93: 073307.    
  • 16. Chou SY, Ding W (2013) Ultrathin, high-efficiency, broad-band, omni-acceptance, organic solar cells enhanced by plasmonic cavity with subwavelength hole array. Opt Express 21: 60–76.    
  • 17. Chen FC, Wu JL, Lee CL, et al. (2009) Plasmonic-enhanced polymer photovoltaic devices incorporating solution- processable metal nanoparticles. Appl Phys Lett 95: 013305.    
  • 18. Xie F, Choy W, Wang C, et al. (2011) Improving the efficiency of polymer solar cells by incorporating gold nanoparticles into all polymer layers. Appl Phys Lett 99: 153304.    
  • 19. Wang DH, Kim DY, Choi KW, et al. (2011) Enhancement of Donor–Acceptor Polymer Bulk Heterojunction Solar Cell Power Conversion Efficiencies by Addition of Au Nanoparticles. Angew Chem Int Ed 50: 5519–5523.    
  • 20. Xie F, Choy W, Zhu X, et al. (2011) Improving polymer solar cell performances by manipulating the self-organization of polymer. Appl Phys Lett 98: 243302.    
  • 21. Baek SW, Noh J, Lee CH, et al. (2013) Plasmonic Forward Scattering Effect in Organic Solar Cells: A Powerful Optical Engineering Method. Nat Sci Rep 3: 1726.
  • 22. Chen X, Zuo L, Fu W, et al. (2013) Insight into the efficiency enhancement of polymer solar cells by incorporating gold nanoparticles. Sol Energy Mat Sol 111: 1–8.    
  • 23. Choy W, Sha W, Li X, et al. (2014) Multi-Physical Properties of Plasmonic Organic Solar Cells. Prog Electromag Res 146: 25–46.    
  • 24. Choy W (2014) The emerging multiple metal nanostructures for enhancing the light trapping of thin film organic photovoltaic cells. Chem Commun 50: 11984–11993.    
  • 25. Gan Q, Bartoli FJ, Kafafi ZH (2013) Plasmonic-Enhanced Organic Photovoltaics: Breaking the 10% Efficiency Barrier. Adv Mater 25: 2385–2396.    
  • 26. Wanninayake AP, Gunashekar S, Li S, et al. (2015) CuO Nanoparticles Based Bulk Heterojunction Solar Cells: Investigations on Morphology and Performance. J Sol Energy Eng 137: 031016.    
  • 27. Wright M, Uddin A (2012) Organic-inorganic hybrid solar cells: A comparative review. Sol Energ Mat Sol C 107: 87–111.
  • 28. Bundgaard E, Shaheen SE, Krebs FC, et al. (2007) Bulk heterojunctions based on a low band gap copolymer of thiophene and benzothiadiazole. Sol Energ Mat Sol C 91: 1631–1637.    
  • 29. Fung D, Qiao LF, Choy W, et al. (2011) Optical and electrical properties of efficiency enhanced polymer solar cells with Au nanoparticles in a PEDOT–PSS layer. J Mater Chem 21: 16349–16356.    
  • 30. Hsu MH, Yu P, Huang JH, et al. (2011) Balanced carrier transport in organic solar cells employing embedded indium-tinoxide nanoelectrodes. Appl Phys Lett 98: 073308-1.    
  • 31. Li G, Shrotriya V, Yao Y, et al. (2005) Investigation of annealing effects and film thickness dependence of polymer solar cells based on poly„3-hexylthiophen. J Appl Phys 98: 043704.    
  • 32. Kim K, Carroll DL (2005) Roles of Au and Ag nanoparticles in efficiency enhancement of poly(3-octylthiophene)/C60 bulk heterojunction photovoltaic devices. Appl Phys Lett 87: 203113.    
  • 33. Krebs FC, Thomann Y, Thomann R, et al. (2008) A simple nanostructured polymer/ZnO hybrid solar cell-preparation and operation in air. Nanotechnology 19: 424013.    
  • 34. Wanninayake A, Gunashekar S, Li S, et al. (2015) Performance enhancement of polymer solar cells using copper oxide nanoparticles. Semicond Sci Technol 30: 064004.    
  • 35. Nguyen BP, Kim T, Park CR (2014) Nanocomposite-based bulk heterojunction hybrid solar cells. J Nanomater (2014): 243041.
  • 36. Eisenhawer B, Sensfuss S, Sivakov V, et al. (2011) Increasing the efficiency of polymer solar cells by silicon nanowires. Nanotechnology 22: 315401.    

 

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Copyright Info: 2016, Nidal Abu-Zahra, et al., licensee AIMS Press. This is an open access article distributed under the terms of the Creative Commons Attribution Licese (http://creativecommons.org/licenses/by/4.0)

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