Research article

Integration of UV-cured Ionogel Electrolyte with Carbon Paper Electrodes

  • Received: 12 November 2013 Accepted: 18 February 2014 Published: 21 February 2014
  • A test bed with a coplanar architecture is employed to investigate the integration of an in situ cross-linked, polymer-supported ionogel with several commercially available, high surface area carbon paper electrodes. Specifically, a UV-cured poly(ethylene glycol) diacrylate (PEGDA)-supported ionogel electrolyte film is formed in situ against a variety of porous electrodes comprising: a carbon fiber paper, a carbon aerogel paper, and four carbon nanotube-based papers. Electrochemical impedance spectroscopy measurements reveal that the relative performance of a particular carbon paper with the neat ionic liquid is not necessarily indicative of its behavior when integrated with the solid ionogel electrolyte. The coplanar test bed can therefore serve as a useful tool to help guide the selection of suitable carbon-based electrode structures for supercapacitors that incorporate UV-cured ionogels created in situ for wearable energy storage applications.

    Citation: Stephanie Flores Zopf, Matthew J. Panzer. Integration of UV-cured Ionogel Electrolyte with Carbon Paper Electrodes[J]. AIMS Materials Science, 2014, 1(1): 59-69. doi: 10.3934/matersci.2014.1.59

    Related Papers:

  • A test bed with a coplanar architecture is employed to investigate the integration of an in situ cross-linked, polymer-supported ionogel with several commercially available, high surface area carbon paper electrodes. Specifically, a UV-cured poly(ethylene glycol) diacrylate (PEGDA)-supported ionogel electrolyte film is formed in situ against a variety of porous electrodes comprising: a carbon fiber paper, a carbon aerogel paper, and four carbon nanotube-based papers. Electrochemical impedance spectroscopy measurements reveal that the relative performance of a particular carbon paper with the neat ionic liquid is not necessarily indicative of its behavior when integrated with the solid ionogel electrolyte. The coplanar test bed can therefore serve as a useful tool to help guide the selection of suitable carbon-based electrode structures for supercapacitors that incorporate UV-cured ionogels created in situ for wearable energy storage applications.


    加载中
    [1] Kaempgen M, Chan CK, Ma J, et al. (2009) Printable thin film supercapacitors using single-walled carbon nanotubes. Nano Lett 9: 1872-1876. doi: 10.1021/nl8038579
    [2] Le Bideau J, Viau L, Vioux A. (2011) Ionogels, ionic liquid based hybrid materials. Chem Soc Rev 40: 907-925. doi: 10.1039/C0CS00059K
    [3] Sung J-H, Kim S-J, Lee K-H. (2004) Fabrication of all-solid-state electrochemical microcapacitors. J Power Sources 133: 312-319. doi: 10.1016/j.jpowsour.2004.02.003
    [4] Sung J-H, Kim S-J, Jeong S-H, et al. (2006) Flexible micro-supercapacitors. J Power Sources162: 1467-1470.
    [5] Stępniak I, Andrzejewska E. (2009) Highly conductive ionic liquid based ternary polymer electrolytes obtained by in situ photopolymerisation. Electrochim Acta 54: 5660-5665. doi: 10.1016/j.electacta.2009.05.004
    [6] Visentin AF, Panzer MJ. (2012) Poly(ethylene glycol) diacrylate-supported ionogels with consistent capacitive behavior and tunable elastic response. ACS Appl Mater Interfaces 4:2836-2839. doi: 10.1021/am300372n
    [7] Yang C-M, Ju JB, Lee JK, et al. (2005) Electrochemical performances of electric double layer capacitor with UV-cured gel polymer electrolyte based on poly[(ethylene glycol)diacrylate]-poly(vinylidene fluoride) blend. Electrochim Acta 50: 1813-1819. doi: 10.1016/j.electacta.2004.08.033
    [8] Meng C, Liu C, Chen L, et al. (2010) Highly flexible and all-solid-state paperlike polymer supercapacitors. Nano Lett 10: 4025-4031. doi: 10.1021/nl1019672
    [9] Choi BG, Hong J, Hong WH, et al. (2011) Facilitated ion transport in all-solid-state flexible supercapacitors. ACS Nano 5: 7205-7213. doi: 10.1021/nn202020w
    [10] Hu S, Rajamani R, Yu X. (2012) Flexible solid-state paper based carbon nanotube supercapacitor. Appl Phys Lett 100: 104103. doi: 10.1063/1.3691948
    [11] Kang YJ, Chung H, Han C-H, et al. (2012) All-solid-state flexible supercapacitors based on papers coated with carbon nanotubes and ionic-liquid-based gel electrolytes. Nanotechnology 23:065401. doi: 10.1088/0957-4484/23/6/065401
    [12] Jung HY, Karimi MB, Hahm MG, et al. (2012) Transparent, flexible supercapacitors from nano-engineered carbon films. Sci Rep 2: 773.
    [13] Pech D, Brunet M, Durou H, et al. (2010) Ultrahigh-power micrometre-sized supercapacitors based on onion-like carbon. Nature Nanotech 5: 651-654. doi: 10.1038/nnano.2010.162
    [14] El-Kady MF, Kaner RB. (2013) Scalable fabrication of high-power graphene micro-supercapacitors for flexible and on-chip energy storage. Nature Commun 4: 1475. doi: 10.1038/ncomms2446
    [15] Zhai Y, Dou Y, Zhao D, et al. (2011) Carbon materials for chemical capacitive energy storage. Adv Mater 23: 4828-4850. doi: 10.1002/adma.201100984
    [16] Liu C, Yu Z, Neff D, et al. (2010) Graphene-based supercapacitor with an ultrahigh energy density. Nano Lett 10: 4863-4868. doi: 10.1021/nl102661q
    [17] Gallego AKC, Rincon ME. (2006) Carbon nanofiber and PEDOT-PSS bilayer systems as electrodes for symmetric and asymmetric electrochemical capacitor cells. J Power Sources 162:743-747. doi: 10.1016/j.jpowsour.2006.06.085
    [18] Yang X, Zhu J, Qiu L, et al. (2011) Bioinspired effective prevention of restacking in multilayered graphene films: towards the next generation of high-performance supercapacitors. Adv Mater 23:2833-2838. doi: 10.1002/adma.201100261
    [19] Hulicova-Jurcakova D, Seredych M, Lu GQ, et al. (2009) Combined effect of nitrogen- and oxygen-containing functional groups of microporous activated carbon on its electrochemical performance in supercapacitors. Adv Funct Mater 19: 438-447. doi: 10.1002/adfm.200801236
    [20] Gou J, Tang Y, Liang F, et al. (2010) Carbon nanofiber paper for lightning strike protection of composite materials. Composites: Part B 41: 192-198.
  • Reader Comments
  • © 2014 the Author(s), licensee AIMS Press. This is an open access article distributed under the terms of the Creative Commons Attribution License (http://creativecommons.org/licenses/by/4.0)
通讯作者: 陈斌, bchen63@163.com
  • 1. 

    沈阳化工大学材料科学与工程学院 沈阳 110142

  1. 本站搜索
  2. 百度学术搜索
  3. 万方数据库搜索
  4. CNKI搜索

Metrics

Article views(5152) PDF downloads(1090) Cited by(7)

Article outline

Figures and Tables

Figures(4)  /  Tables(2)

Other Articles By Authors

/

DownLoad:  Full-Size Img  PowerPoint
Return
Return

Catalog