Review Special Issues

Low temperature selective catalytic reduction of NOx with NH3 over Mn-based catalyst: A review

  • Received: 29 February 2016 Accepted: 04 May 2016 Published: 09 May 2016
  • The removals of NOx by catalytic technology at low temperatures (100–300 °C) for industrial flue gas treatment have received increasing attention. However, the development of low temperature catalysts for selective catalytic reduction (SCR) of NOx with ammonia is still a challenge especially in the presence of SO2. The current status of using Mn-based catalysts for low temperature SCR of NOx with ammonia (NH3-SCR) is reviewed. Reaction mechanisms and effects of operating factors on low temperature NH3-SCR are addressed, and the SCR efficiencies of Mn-based metal oxides with and without SO2 poisoning have also been discussed with different supports and co-metals. The key factors for enhancing low temperature NH3-SCR efficiency and SO2 resistance with Mn-based catalysts are identified to be (1) high specific surface area; (2) high surface acidity; (3) oxidation states of manganese; (4) well dispersion of manganese oxide metals; (5) more surface adsorbed oxygen; (6) more absorbed NO3 on the catalyst surface; (7) easier decomposition of ammonium sulfates. Moreover, the regenerative methods such as water washing, acid and/or alkali washing and heat treatment to the poisoned catalysts could help to recover the low temperature SCR efficiency to its initial level.

    Citation: TsungYu Lee, Hsunling Bai. Low temperature selective catalytic reduction of NOx with NH3 over Mn-based catalyst: A review[J]. AIMS Environmental Science, 2016, 3(2): 261-289. doi: 10.3934/environsci.2016.2.261

    Related Papers:

  • The removals of NOx by catalytic technology at low temperatures (100–300 °C) for industrial flue gas treatment have received increasing attention. However, the development of low temperature catalysts for selective catalytic reduction (SCR) of NOx with ammonia is still a challenge especially in the presence of SO2. The current status of using Mn-based catalysts for low temperature SCR of NOx with ammonia (NH3-SCR) is reviewed. Reaction mechanisms and effects of operating factors on low temperature NH3-SCR are addressed, and the SCR efficiencies of Mn-based metal oxides with and without SO2 poisoning have also been discussed with different supports and co-metals. The key factors for enhancing low temperature NH3-SCR efficiency and SO2 resistance with Mn-based catalysts are identified to be (1) high specific surface area; (2) high surface acidity; (3) oxidation states of manganese; (4) well dispersion of manganese oxide metals; (5) more surface adsorbed oxygen; (6) more absorbed NO3 on the catalyst surface; (7) easier decomposition of ammonium sulfates. Moreover, the regenerative methods such as water washing, acid and/or alkali washing and heat treatment to the poisoned catalysts could help to recover the low temperature SCR efficiency to its initial level.


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