Textile-based batteries with nanofiber interlayer

Redon Resuli; Ibrahim Turhan; Andrea Ehrmann; Tomasz Blachowicz; Redon Resuli; Ibrahim Turhan; Andrea Ehrmann; Tomasz Blachowicz

doi:10.3934/energy.2018.2.261

AIMS Energy

2018, Volume 6, Issue 2: 261-268. doi: 10.3934/energy.2018.2.261

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Research article

Textile-based batteries with nanofiber interlayer

1.
Bielefeld University of Applied Sciences, Faculty of Engineering and Mathematics, ITES, Bielefeld, Germany
2.
Silesian University of Technology, Institute of Physics – Center of Science and Education, Gliwice, Poland

Received: 13 January 2018 Accepted: 15 March 2018 Published: 19 March 2018

Abstract
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Textile batteries are of utmost interest for the emerging field of electronic textiles. Several research groups work on this topic, developing either fiber-based batteries or planar alternatives, e.g. by coating textile fabrics with metallic electrodes and an electrolyte between them. Since usual non-toxic electrolytes are fluid, using them in a textile battery necessitates gelling them or embedding them in a sponge-like matrix to avoid diffusion through the textile electrodes. Here we report on measurements of textile batteries, prepared from different conductive woven fabrics with a nanofiber mat as an interlayer filled with iodine-triiodide solution. Firstly, the highest voltages were achieved combining metal electrodes with a carbon electrode, showing that the electrolyte in this system is part of the redox system. Second, the metal electrodes were destroyed after short times, suggesting that iodine-triiodide is not an ideal choice for an electrolyte, although this material is often used. Finally, we show that even without setting up the complete battery, the electrolyte slowly destroys the metal layers, while it is itself degraded by photo-oxidation, underlining the necessity to find non-toxic, environmentally-friendly alternatives for iodine-triiodide to enable long-term storage. Assuming non-solid state for electrolytes, the level of their confinement by different types of corrugated materials was tested.
- textile battery,
- nanofiber mat,
- electrolyte,
- redox process,
- electrospinning,
- iodine-triiodide
Citation: Redon Resuli, Ibrahim Turhan, Andrea Ehrmann, Tomasz Blachowicz. Textile-based batteries with nanofiber interlayer[J]. AIMS Energy, 2018, 6(2): 261-268. doi: 10.3934/energy.2018.2.261

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Abstract

Textile batteries are of utmost interest for the emerging field of electronic textiles. Several research groups work on this topic, developing either fiber-based batteries or planar alternatives, e.g. by coating textile fabrics with metallic electrodes and an electrolyte between them. Since usual non-toxic electrolytes are fluid, using them in a textile battery necessitates gelling them or embedding them in a sponge-like matrix to avoid diffusion through the textile electrodes. Here we report on measurements of textile batteries, prepared from different conductive woven fabrics with a nanofiber mat as an interlayer filled with iodine-triiodide solution. Firstly, the highest voltages were achieved combining metal electrodes with a carbon electrode, showing that the electrolyte in this system is part of the redox system. Second, the metal electrodes were destroyed after short times, suggesting that iodine-triiodide is not an ideal choice for an electrolyte, although this material is often used. Finally, we show that even without setting up the complete battery, the electrolyte slowly destroys the metal layers, while it is itself degraded by photo-oxidation, underlining the necessity to find non-toxic, environmentally-friendly alternatives for iodine-triiodide to enable long-term storage. Assuming non-solid state for electrolytes, the level of their confinement by different types of corrugated materials was tested.

References

[1]	Jost K, Dion K, Gogotsi Y (2014) Textile energy storage in perspective. J Mater Chem A2: 10776–10787.
[2]	Gorgutsa S, Gu JF, Skorobogatiy M (2012) A woven 2D touchpad sensor and a 1Dslide sensor using soft capacitor fibers. Smart Mater Struct 21: 015010. doi: 10.1088/0964-1726/21/1/015010
[3]	Jost K, Stenger D, Perez CR, et al. (2013) Knitted and screen printed carbon fiber textile-supercapacitors for applications in wearable electronics. Energy Environ Sci 6: 2698–2705. doi: 10.1039/c3ee40515j
[4]	Liu Y, Gorgutsa S, Santato C, et al. (2012) Flexible, Solid Electrolyte-Based Lithium Battery Composed of LiFePO₄ Cathode and Li₄Ti₅O₁₂ Anode for Applications in Smart Textiles. J Electrochem Soc 159: A349–A356. doi: 10.1149/2.020204jes
[5]	Jost K, Perez CR, McDonough JK, et al. (2011) Carbon coated textiles for flexible energy storage. Energy Environ Sci 4: 5060. doi: 10.1039/c1ee02421c
[6]	Bhattacharya R, de Kok M, Zhou J (2009) Rechargeable electronic textile battery. Appl Phys Lett 95: 223305. doi: 10.1063/1.3269907
[7]	Hu L (2010) Stretchable, Porous, and Conductive Energy Textiles. NANO Lett 10: 708–714. doi: 10.1021/nl903949m
[8]	Balogun M-S, Yu M, Li C, et al. (2014) Facile synthesis of titanium nitride nanowires on carbon fabric for flexible and high-rate lithium ion batteries. J Mat Chem A 2: 10825–10829. doi: 10.1039/C4TA00987H
[9]	Balogun M-S, Yu M, Huang Y, et al. (2015) Binder-free Fe₂N nanoparticles on carbon textile with high power density as novel anode for high-performance flexible lithium ion batteries. Nano Energy 11: 348–355. doi: 10.1016/j.nanoen.2014.11.019
[10]	Balogun M-S, Qui W, Lyu F, et al. (2016) All-flexible lithium ion battery based on thermally-etched porous carbon cloth anode and cathode. Nano Energy 26: 446–455. doi: 10.1016/j.nanoen.2016.05.017
[11]	Vanýsek P (2012) Electrochemical Series. In: Haynes WM, Handbook of Chemistry and Physics: 93rd Edition. Chemical Rubber Company.
[12]	Bard AJ, Parsons R, Jordan J (1985) Standard Potentials in Aqueous Solutions. Marcel Dekker, New York.
[13]	Normann M, Herrmann A, Grethe T, et al. (2016) Energiegewinnung und -speicherung mittels Textilien. 15th Chemnitz Textile Technology Conference.
[14]	Boschloo G, Hagfeldt A (2009) Characteristics of the Iodide/Triiodide Redox Mediator in Dye-Sensitized Solar Cells. Accounts Chem Res 42: 1819–1826. doi: 10.1021/ar900138m
[15]	Normann M, Kyosev Y, Ehrmann A, et al. (2016) Multilayer Textile-Based Woven Batteries. In: Y. Kyosev (Ed.): Recent Developments in Braiding and Narrow Weaving, Springer International Publishing, 129–136.
[16]	Normann M, Grethe T, Schwarz-Pfeiffer A, et al. (2017) Development and characterization of textile batteries. IOP Conf Ser: Mater Sci Eng 175: 012058. doi: 10.1088/1757-899X/175/1/012058
[17]	Normann M, Grethe T, Zöll K, et al. (2017) Development of 2D and 3D structured textile batteries processing conductive material with Tailored Fiber Placement (TFP). IOP Conf Ser: Mater Sci Eng 254: 072016. doi: 10.1088/1757-899X/254/7/072016
[18]	Wei D, Cotton D, Ryhänen T (2012) All-solis-state textile batteries made from nano-emulsion conducting polymers inks for wearable electronics. Nanomaterials 2: 268–274. doi: 10.3390/nano2030268
[19]	Sabantina L, Mirasol JR, Cordero T, et al. (2018) Investigation of Needleless Electrospun PAN Nanofiber Mats. AIP Conference Proceedings, accepted.
[20]	Hellert C, Klemt C, Scheidt U, et al. (2017) Rehydrating dye sensitized solar cells. AIMS Energy 5: 397–403. doi: 10.3934/energy.2017.3.397

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