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Qualitative and kinetic analysis of torrefaction of lignocellulosic biomass using DSC-TGA-FTIR

School of Engineering, University of Guelph, 50 stone Rd E, N1G2W1, ON, Canada

Special Issues: Renewable energy systems and agro-residue management

Torrefaction is a thermochemical conversion technique to improve the fuel properties of lignocellulosic biomass by treating at temperature 200 ℃-300 ℃ in the minimum oxygen environment for a reasonable residence time. In this study, thermal decomposition and thermal activities of miscanthus and wheat straw during the torrefaction at 200 ℃, 275 ℃, and 300 ℃ in a nitrogen environment for 45 minutes of residence time are analyzed in a simultaneous thermogravimetric analyzer (micro TGA) with a differential scanning calorimetry (DSC), and a macro-TGA. The output of the micro TGA is fed into the Fourier transform infrared spectrometry (FTIR) and qualitative analysis of the gaseous product is carried out. The composition of different gas products during the torrefaction of biomass are compared critically and kinetics were analyzed. It is found that the weight loss due to degradation of initial biomass in second stage (torrefaction process) is a much faster conversion process than the weight loss process in the first stage (drying process). The weight loss of biomass increases with increase in the residence time and torrefaction treatment temperatures. The yield after torrefaction is a solid bio-coal product. The torrefied product were less reactive and has nearly 25% better heating value than the raw biomass. Between the two feedstocks studied, torrefied miscanthus proved to be a more stable fuel than the torrefied wheat straw. The major gaseous components observed during torrefaction are water, carbon dioxide, carbon monoxide, 1,2-Dibromethylene.
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Keywords Torrefaction; kinetics; lignocellulosic; DSC-TGA-FTIR

Citation: Bimal Acharya, Ranjan R. Pradhan, Animesh Dutta. Qualitative and kinetic analysis of torrefaction of lignocellulosic biomass using DSC-TGA-FTIR. AIMS Energy, 2015, 3(4): 760-773. doi: 10.3934/energy.2015.4.760


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Copyright Info: 2015, Bimal Acharya, et al., licensee AIMS Press. This is an open access article distributed under the terms of the Creative Commons Attribution Licese (http://creativecommons.org/licenses/by/4.0)

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