Loading [MathJax]/jax/output/SVG/jax.js
Research article Topical Sections

Activity of coals of different rank to ozone

  • Received: 07 November 2017 Accepted: 04 December 2017 Published: 08 December 2017
  • Coals of different rank were studied in order to characterize their activity to ozone decomposition and changes of their properties at interaction with ozone. Effects of coal rank on their reactivity to ozone were described by means of kinetic modeling. To this end, a model was proposed for evaluation of kinetic parameters describing coals activity to ozone. This model considers a case when coals surface properties change during interaction with ozone (deactivation processes). Two types of active sites (zones at the surface that are able to decompose ozone) were introduced in the model differing by their deactivation rates. Activity of sites that are being deactivated at relatively higher rate increases with rank from 2400 1/min for lignite to 4000 1/min for anthracite. Such dependence is related to increase of micropores share in coals structure that grows from lignites to anthracites. Parameter characterizing initial total activity of coals to ozone decomposition also depends on rank by linear trend and vary between 2.40 for lignites up to 4.98 for anthracite. The proposed model could further be used in studies of coals oxidation processes and tendency to destruction under the weathering and oxidation conditions.

    Citation: Vladimir Kaminskii, Elena Kossovich, Svetlana Epshtein, Liudmila Obvintseva, Valeria Nesterova. Activity of coals of different rank to ozone[J]. AIMS Energy, 2017, 5(6): 960-973. doi: 10.3934/energy.2017.6.960

    Related Papers:

    [1] Jiwei Jia, Young-Ju Lee, Yue Feng, Zichan Wang, Zhongshu Zhao . Hybridized weak Galerkin finite element methods for Brinkman equations. Electronic Research Archive, 2021, 29(3): 2489-2516. doi: 10.3934/era.2020126
    [2] Linlin Tan, Bianru Cheng . Global well-posedness of 2D incompressible Navier–Stokes–Darcy flow in a type of generalized time-dependent porosity media. Electronic Research Archive, 2024, 32(10): 5649-5681. doi: 10.3934/era.2024262
    [3] Jingjing Zhang, Ting Zhang . Local well-posedness of perturbed Navier-Stokes system around Landau solutions. Electronic Research Archive, 2021, 29(4): 2719-2739. doi: 10.3934/era.2021010
    [4] Keqin Su, Rong Yang . Pullback dynamics and robustness for the 3D Navier-Stokes-Voigt equations with memory. Electronic Research Archive, 2023, 31(2): 928-946. doi: 10.3934/era.2023046
    [5] Derrick Jones, Xu Zhang . A conforming-nonconforming mixed immersed finite element method for unsteady Stokes equations with moving interfaces. Electronic Research Archive, 2021, 29(5): 3171-3191. doi: 10.3934/era.2021032
    [6] Jianxia He, Qingyan Li . On the global well-posedness and exponential stability of 3D heat conducting incompressible Navier-Stokes equations with temperature-dependent coefficients and vacuum. Electronic Research Archive, 2024, 32(9): 5451-5477. doi: 10.3934/era.2024253
    [7] Lin Shen, Shu Wang, Yongxin Wang . The well-posedness and regularity of a rotating blades equation. Electronic Research Archive, 2020, 28(2): 691-719. doi: 10.3934/era.2020036
    [8] Dan-Andrei Geba . Unconditional well-posedness for the periodic Boussinesq and Kawahara equations. Electronic Research Archive, 2024, 32(2): 1067-1081. doi: 10.3934/era.2024052
    [9] Lingrui Zhang, Xue-zhi Li, Keqin Su . Dynamical behavior of Benjamin-Bona-Mahony system with finite distributed delay in 3D. Electronic Research Archive, 2023, 31(11): 6881-6897. doi: 10.3934/era.2023348
    [10] Lianbing She, Nan Liu, Xin Li, Renhai Wang . Three types of weak pullback attractors for lattice pseudo-parabolic equations driven by locally Lipschitz noise. Electronic Research Archive, 2021, 29(5): 3097-3119. doi: 10.3934/era.2021028
  • Coals of different rank were studied in order to characterize their activity to ozone decomposition and changes of their properties at interaction with ozone. Effects of coal rank on their reactivity to ozone were described by means of kinetic modeling. To this end, a model was proposed for evaluation of kinetic parameters describing coals activity to ozone. This model considers a case when coals surface properties change during interaction with ozone (deactivation processes). Two types of active sites (zones at the surface that are able to decompose ozone) were introduced in the model differing by their deactivation rates. Activity of sites that are being deactivated at relatively higher rate increases with rank from 2400 1/min for lignite to 4000 1/min for anthracite. Such dependence is related to increase of micropores share in coals structure that grows from lignites to anthracites. Parameter characterizing initial total activity of coals to ozone decomposition also depends on rank by linear trend and vary between 2.40 for lignites up to 4.98 for anthracite. The proposed model could further be used in studies of coals oxidation processes and tendency to destruction under the weathering and oxidation conditions.


    Fluid flow problems have considerable attention from researchers and appear in many applications such as engineering, industry, biomedical sciences and other areas. The fluid flow problems are investigated in both theoretical and applied research, among which is the study of flow through a free-fluid domain and an adjacent porous medium. For example, Basirata et al. [1] studied the CO2 gas flow in a porous medium and free air above it. Oangwatcharaparkan and Wuttanachamsri [2] studied the fluid flow in a periciliary layer (PCL) in the human respiratory system where the mucus layer was on the top of a porous layer. In this research, we focus on fluid flow problems in which the fluid is moved by self-propelled solid phases rather than a pressure gradient. That is, the movement of solids affects the fluid flow whether the fluid is in the same layer as the solid phases or above the solid phases. An example domain that illustrates the regions of interest is represented in Figure 1.

    Figure 1.  Sample layers of a free-fluid region residing above an adjacent porous medium.

    Figure 1 shows a sampling domain consisting of two regions: the layer composed of fluid and self-propelled solid phases, which is considered as a porous medium, Ωp, and a free-fluid region, Ωf, residing on the porous medium. In this study, we consider a macroscopic flow where a bundle of solid phases is considered instead of a single self-propelled solid. The locomotion of solids affects the movement of fluids in the nearby areas. If fluid flows through different domains, then mathematical models are also distinct. That is, the equations for the flow above the porous medium and flow in the porous domain are different.

    There are several mathematical models used to describe problems of this type [3,4,5,6,7,8,9,10,11]. Khanafer et al. [3] used Darcy's Law and Brinkman-extended Darcy to investigate the fluid flow inside the hollow fiber bundle of an artificial lung and applied the Navier-Stokes equation for the fluid flow outside the fiber bundle. Ly et al. [4] investigated the problem of fluid flow in coupling a free fluid domain and a porous medium using the Stokes and Darcy equations, respectively. Wuttanachamsri and Schreyer [5] used the Stokes-Brinkman equations to compute the fluid velocities due to the self-propelled solid phases in a three-dimensional domain. Poopra and Wuttanachamsri [6] considered the fluid flow in the periciliary layer (PCL) in human lungs by using the Stokes-Brinkman equations with the Beavers and Joseph boundary condition. Wuttanachamsri [7] used Stokes-Brinkman equations in one dimension with the Stefan problem to estimate the free interface between a porous medium and an adjacent free-fluid region. The well-posedness of the system of the Stokes-Brinkman equations is also provided for both moving or static solid phase [12,13,14,15,16]. For the study of a static solid phase, Ingram [12] applied a finite element discretization to the Brinkman equation and demonstrated that the discretized problem was well-posed. Angot [13] studied the well-posedness of the Stokes-Brinkman and Stokes-Darcy with new jump interface conditions. Chamsri [14] showed the well-posedness of the Stokes-Brinkman model for the case of moving solid phase, while the porosity was assumed to be a constant.

    Unlike the usual problems, in this research, we use generalized Stokes-Brinkman equations, where the Brinkman model is developed from the Hybrid Mixture Theory (HMT) [17]. The HMT is a technique for upscaling a multiphase flow by applying an averaging theorem to a microscale equation to obtain a macroscale equation [18,19]. The macroscopic Brinkman equation is distinct from the models in the above literature because it is derived from the conservation of momentum, where the porosity in the equation is considered as a function of space. Therefore, the porosity is subject to a derivative operator, while the porosity in the Brinkman model in the available research is outside the derivative, although the porosity has been used as a function of space. Our model, the macroscopic Brinkman model, can be used for a bundle of self-propelled solid phases instead of a single solid for fluid flow in a porous medium. In addition, we derive the generalized Stokes equation to apply to the incompressible slow flow in the domain of the free-fluid region next to the porous medium. Extra terms appearing in the generalized Stokes and macroscale Brinkman equations aid to match shear stress at the free-fluid/porous-medium interface. Since our model differs from typical Stokes-Brinkman equations in available research, the well-posedness of the generalized Stokes-Brinkman equations in a macroscopic scale when the fluid is moved by self-propelled solid phases is provided, and the permeability in the model is considered as a second-order tensor, not just a constant.

    In Section 2, we derive the generalized Stokes-Brinkman equations. In order to present the well-posedness of the discretized form of the mathematical model using a mixed finite element technique, in Section 3, we present the weak formulation of the governing equations as well as the discretized form of the generalized Stokes-Brinkman equations. In Section 4, the continuity and coercivity of linear and bilinear functionals in the discretized system of equations are presented. The well-posedness of the generalized Stokes-Brinkman equations is illustrated in Section 5. The conclusion is drawn in Section 6. The fundamental definitions, theorems and lemmas proved in available literature and books, which are used in the proof of the well-posedness of the discretized equations, are provided in the Appendix.

    In this section, we present the derivation of our governing equations. For the generalized Stokes equation, we start with the generalized Navier-Stokes equation and then use a nondimensionalization method to obtain the generalized Stokes equation. This is shown in Section 2.1. To derive the Brinkman equation, we begin with a momentum equation obtained from Hybrid Mixture Theory (HMT) [19], an upscaling technique, and then use a nondimensionalization approach to have a macroscopic model in a porous medium, which is illustrated in Section 2.2. We rewrite our governing equations in Section 2.3 in order to summarize and use them in the next sections.

    To obtain the generalized Stokes equation, we start with the generalized Navier-Stokes equation, which is attained from substituting a stress tensor, developed from entropy inequality holding near equilibrium for a viscous fluid, into a momentum equation. The generalized Navier-Stokes equation is [20]

    ρut + ρ(uu) + p  (λ+μ)(u)  μu  ρg = 0, (2.1)

    where ρ is density, t is time, u is the velocity, p is pressure, λ is a constant, μ is the dynamic viscosity, and g is gravity. The generalized Navier-Stokes equation, Eq (2.1), is normalized with dimensionless variables, and we get

    ρu0fˆuˆt+ρu20L(ˆuˆˆu)+p0Lˆˆp(λ+μ)u0L2ˆ(ˆˆu)μu0L2ˆˆˆuρg0ˆg=0, (2.2)

    where the characteristic parameter L is the characteristic length; f is the characteristic frequency; u0 is the characteristic speed; p0 is the reference pressure; g0 is the gravitational acceleration. Multiplying Eq (2.2) by L2μu0 on both sides, we have

    ρfL2μˆuˆt+ρu0Lμ(ˆuˆˆu)+p0Lμu0ˆˆp(λ+μ)μˆ(ˆˆu)ˆˆˆuρg0L2μu0ˆg=0. (2.3)

    Next, we calculate the coefficients in Eq (2.3), where the values of the characteristic variables and other variables in International System (SI) units are shown in Table 1. The characteristic length is the highest length of cilia in the respiratory system [21], the reference f is the frequency of cilia beat in the human respiratory tract [22], the characteristic velocity u0 is the maximum speed of cilia for the effective stroke at temperature 37C, the reference pressure p0 is the pressure in the human respiratory tract, which is about one [23], g0 is the Earth's gravity, and ρ and μ are the density of water and dynamic viscosity at 37C, respectively. The constant λ is set equal to zero. The values of the coefficients are shown in Table 2.

    Table 1.  The values of characteristic and constant variables in Eq (2.3) in International System units.
    Variables L f u0 p0 g0 ρ μ
    SI Units m 1/s m/s kg/(ms2) m/s2 kg/m3 kg/(ms)
    Values 7 × 106 10 2.5 × 104 1 9.807 993.3 0.6913 × 103

     | Show Table
    DownLoad: CSV
    Table 2.  The values of the coefficients in Eq (2.3).
    Coefficients ρfL2μ ρu0Lμ p0Lμu0 λ+μμ ρg0L2μu0
    Values 7.0406×104 2.5×103 40.5034 1 2.7619

     | Show Table
    DownLoad: CSV

    From Table 2, the coefficients of the first two terms in Eq (2.3) are comparatively small compared with the others. Therefore, the unsteady and nonlinear terms in the equation are neglected, and then Eq (2.3) becomes

    p  (λ+μ)(u)  μu  ρg = 0. (2.4)

    In this work, we assume that the velocity u in two dimensions is smooth enough that the order of the derivative can be interchanged, that is, xuy=yux. Then, we obtain

    (u) = (u)T. (2.5)

    Substituting Eq (2.5) into the second term of Eq (2.4), we have

    p  λ(u)  μ(u)T  μu  ρg = 0, (2.6)

    or

    p  λ(u)  μ(u+(u)T)  ρg=0. (2.7)

    Since the rate of deformation for the liquid phase d=12(u+(u)T), we rewrite Eq (2.7) as

    p  λ(u)  (2μd)  ρg=0. (2.8)

    Notice that if λ=0, then Eq (2.8) becomes

    p  (2μd)  ρg = 0, (2.9)

    which is the generalized Stokes equation. If the matrix u is symmetric, then Eq (2.9) is the following Stokes equation:

    p  2μΔu  ρg = 0. (2.10)

    In this section, we show the derivation of the Brinkman equation in a macroscopic scale derived using Hybrid Mixture Theory (HMT). HMT is an upscaling technique used to derive multiphase equations such as the combination of solid and liquid phases. This method uses the averaging theorem to upscale equations from a microscale equation to a macroscale equation [19]. In this study, we focus on developing a model for fluid flow due to the movement of self-propelled solid phases. Here, we follow the procedure provided in [18]. We begin with the multiphase equation upscaled from the conservation of momentum [18] when the porosity is a function, not a constant:

    εlρlDlulDt + εlp + pεl  (εl2μdl)  εlρlgl = pεl  εlR(ulus), (2.11)

    where l and s mean the liquid and solid phases, respectively. The function εl is the porosity, which is a variable in space; dl=0.5(ul+(ul)T) is the rate of deformation tensor; R is a second-order tensor; ul and us are the velocities of liquid and solid phases, respectively. Substituting R=μεlk1, where k1 is the inverse of the permeability tensor, and taking DlulDt=ult+ulul into Eq (2.11), subtracting from both sides by pεl and dividing by εl on both sides, we have

    ρ(ult+ulul) + μk1(εlulεlus) + p  μεl(2εldl) = ρg. (2.12)

    Then, we normalize Eq (2.12). We use the same characteristic parameters as in the previous subsection. The dimensionless form of Eq (2.12) is

    kρfμˆulˆt+kρu0μL(ˆulˆˆul)+(εlˆulεlˆus)+kp0μu0LˆˆpkεlL2ˆ(2εlˆdl) = kρg0μu0ˆg. (2.13)

    Using the values in Table 1 to calculate the coefficients in Eq (2.13) with the permeability k=1014 m2 and porosity εl=1, which are the maximum values employed from [24], we obtain the values of the coefficients as illustrated in Table 3.

    Table 3.  The values of the coefficients in Eq (2.13).
    Coefficients kρfμ kρu0μL kp0μu0L kεlL2 kρg0μu0
    Values 1.4369×107 5.1316×107 8.3×103 2.0408×104 5.6365×104

     | Show Table
    DownLoad: CSV

    From the calculation demonstrated in Table 3, we neglect the first two terms in Eq (2.13), the time-dependent and nonlinear terms, because these expressions are significantly small in comparison with others. Therefore, Eq (2.12) becomes

    μk1(εlulεlus) + p  μεl(2εldl) = ρg, (2.14)

    which is called the Brinkman equation in a macroscopic scale. Notice that the macroscale Brinkman equation is distinct from the Brinkman in literature such as in [25],

    μk1εlul + p  μΔul= ρg, (2.15)

    because our model starts with the momentum equation that the porosity is a function and cannot be moved out of the derivative as a constant, as usually used in research. The porosity in the parentheses in the third term in Eq (2.14) cannot be canceled out with the denominator. Moreover, the first-order derivative of the rate of deformation times the porosity in Eq (2.14) cannot be changed to be the second-order derivative of the velocity as shown in Eq (2.15). It may seem that the difference is not much, but finding the numerical results of Eq (2.14) is more complicated than for Eq (2.15), including the proof of the well-posedness of the equation.

    Notice that the Brinkman equation in the macroscopic scale, Eq (2.14), has a good engagement with the generalized Stokes equation, Eq (2.9). Because there are no solid phases in the adjacent free-fluid domain, the porosity becomes one, and the permeability tends to infinity in this region. Therefore, the first term in Eq (2.14) disappears, and then the Brinkman equation, Eq (2.14), becomes generalized Stokes equation, Eq (2.9). Thus, the solutions in these two layers can be matched in the transition zone at the free-fluid/porous-medium interface by using the generalized Stokes-Brinkman model. The mathematical model is summarized in the next section.

    The models for a problem of this kind are summarized in this section. The models in both free-fluid layer and porous medium consist of two unknowns, which are the velocity ul and the pressure p. Therefore, in each region, we need one more equation, which is a continuity equation obtained from conservation of mass. Since a bundle of self-propelled solid phases effects the fluid flow, we employ the continuity equation for two-phase flow in the porous medium derived by HMT [26,27], which is

    (εlul) = f, (2.16)

    where f=˙εl/(1εl)+(εlus) and ˙εl=εl/t+usεl. Let Ω=ΩpΩf be our domain, and Ω is the boundary of the domain. Define the vectors

    u=εlulandf=ρg+μk1εlus. (2.17)

    From Eqs (2.14), (2.16) and (2.17), the system of equations used in domain Ωp is

    μk1uμεl(2εldl)+p = fin Ωp, (2.18)
    u = fin Ωp. (2.19)

    For the free-fluid domain Ωf, the flow is considered incompressible. Then, the divergence of velocity is zero. Therefore, in domain Ωf, we have the system of equations

    μ(2εldl)+p =0in Ωf, (2.20)
    u = 0in Ωf. (2.21)

    Before we prove the well-posedness of the generalized Stokes-Brinkman equations, Eqs (2.18) and (2.19), in the next section we provide the discretized form of the governing equations by using a finite element method.

    In this section, we first formulate the weak formulation of the generalized Stokes-Brinkman equations, Eqs (2.18) and (2.19), by using a mixed finite element method. To obtain the weak form of Eq (2.18), we multiply a weight function wH10(Ω) and integrate Eq (2.18) over the domain Ω on both sides, and we have

    Ωμ(k1u)w Ωμεl((2εldl))w +Ωpw = Ωfw. (3.1)

    Applying Green's first identity to the second and third terms on the left hand side of Eq (3.1) and using the property that the weight function is zero at the boundary, we have

    Ωμ(k1u)w +Ω2μεldl:(wεl) Ω(w)p = Ωfw. (3.2)

    Substituting dl=0.5[(uεl)+((uεl))T] into Eq (3.2), we obtain the weak formulation of Eq (2.18), which is

    Ωμ(k1u)w+Ωμεl(uεl):(wεl)+Ωμεl((uεl))T:(wεl)Ω(w)p = Ωfw. (3.3)

    Similarly, multiplying both sides of Eq (2.19) by another weight function qL20(Ω) and integrating both sides, we obtain the weak formulation of Eq (2.19):

    Ω(u)q = Ωfq. (3.4)

    The weak formulation of the generalized Stokes-Brinkman equations can be written in linear and bilinear functionals as follows.

    Problem 1. The weak form of the generalized Stokes-Brinkman equations is to find uH1s(Ω) and pL20(Ω) such that

    a(u,w)+b(w,p) = c1(w),wH10(Ω), (3.5)
    b(u,q) = c2(q), qL20(Ω), (3.6)

    where the linear and bilinear functionals are defined as

    a(u,w) = Ωμ(k1u)w+Ωμεl(uεl):(wεl)+Ωμεl((uεl))T:(wεl), (3.7)
    b(u,q) = Ω(u)q, (3.8)
    c1(w) = f,wH1(Ω)×H10(Ω), (3.9)
    c2(q) = Ωfq, (3.10)

    where the space H1s(Ω)={wH1(Ω):w|Ω=s}, and , is the duality pairing.

    Notice that the space L20(Ω) is used instead of L2(Ω) because the system of Eqs (2.18) and (2.19) demonstrates pressure up to an additive constant; see [28] on page 157 for details. The linear and bilinear functionals in Problem 1 can be written in the form of a linear operator as in Problem 2 (the definition of the linear operator is in the Appendix).

    Problem 2. Let A:H10(Ω)H1(Ω) and B:H10(Ω)L20(Ω) be linear operators. Find uH1s(Ω), pL20(Ω) such that

    Au+Bp = fin  H1(Ω), (3.11)
    Bu = fin  L20(Ω), (3.12)

    where

    fH1(Ω) = supwH10(Ω),w0f,wH1(Ω)×H10(Ω)wH1(Ω), (3.13)

    the norm H1(Ω) denotes the standard norm on the space H1(Ω), and the function us in f is a bounded continuous function.

    Next, we show that the linear and bilinear functionals in Problem 1 are continuous and coercive, and that will be used to prove the existence and uniqueness of the generalized Stokes-Brinkman equations in Section 5.

    In this section, we show that the linear and bilinear functionals in Problem 1 are continuous and coercive. These properties are necessary to prove the existence and uniqueness of the governing equations. We first proof the continuity as shown in Theorem 4.1.

    Theorem 4.1. The linear functionals c1(w),c2(q) and bilinear functionals a(,), b(,) are continuous. In particular,

    c1(w)  fH1(Ω)wH1(Ω),  wH1(Ω), (4.1)
    c2(q)  fL2(Ω)qL2(Ω),  qL2(Ω), (4.2)
    b(u,q)  n|u|H1(Ω)qL2(Ω),  uH1(Ω),qL2(Ω), (4.3)
    a(u,w)  QauH1(Ω)wH1(Ω),u,wH1(Ω), (4.4)

    where n is the dimensional number, and

    Qa=max{6μmax1i,j2|k1ij|, 2μ/εlH1(Ω)}.

    Proof. It is obvious that c1(w) and c2(q) are linear functionals, and a(u,w) and b(u,q) are bilinear functionals. Next, we show the continuity of c1(w). Let wH1(Ω). Then,

    |c1(w)|=|f,wH1(Ω)×H10(Ω)|=|f,wH1(Ω)×H10(Ω)wH1(Ω)wH1(Ω)|fH1(Ω)wH1(Ω),

    where we apply the definition of norm on the space H1(Ω), Eq (3.13), at the inequality. The proof of the continuities of c2(q) and b(u,q) has been shown in [16]. Next, we show the continuity of a(u,w) in a two-dimensional domain. Define u=(u1,u2) and w=(w1,w2). Then, from Eq (3.7), we have

    |a(u,w)|=|Ωμ(k1u)w+Ωμεl(uεl):(wεl)+Ωμεl((uεl))T:(wεl) ||Ωμ(k1u)w |+|Ωμεl(uεl):(wεl) | +|Ωμεl((uεl))T:(wεl) | μk1uL2(Ω)wL2(Ω)+μεl(uεl)L2(Ω)(wεl)L2(Ω) +μεl((uεl))TL2(Ω)(wεl)L2(Ω)6μmax1i,j2|k1ij|uL2(Ω)wL2(Ω) +μεlL2(Ω)(uεl)L2(Ω)(wεl)L2(Ω) + μεlL2(Ω)((uεl))TL2(Ω)(wεl)L2(Ω)=6μmax1i,j2|k1ij|uL2(Ω)wL2(Ω) +2μεlL2(Ω)(uεl)L2(Ω)(wεl)L2(Ω) 6μmax1i,j2|k1ij|uH1(Ω)wH1(Ω)+ 2μεlL2(Ω)uεlH1(Ω)wεlH1(Ω)= 6μmax1i,j2|k1ij|uH1(Ω)wH1(Ω)+ 2μεlL2(Ω)uH1(Ω)εlH1(Ω)wH1(Ω)εlH1(Ω) 6μmax1i,j2|k1ij|uH1(Ω)wH1(Ω)+2μεlH1(Ω)uH1(Ω)wH1(Ω) max{6μmax1i,j2|k1ij|, 2μεlH1(Ω)}uH1(Ω)wH1(Ω)= QauH1(Ω)wH1(Ω),

    where Qa=max{6μmax1i,j2|k1ij|, 2μεlH1(Ω)} and the inequality [14]

    k1uL2(Ω)  6max1i,j2|k1ij|uL2(Ω) (4.5)

    is applied to the third inequality. For the fifth inequality, we use the fact that L2(Ω)H1(Ω), so L2(Ω)H1(Ω)1. Therefore, a(u,w) is continuous.

    To show that the bilinear form a(,) is coercive, we first proof Lemma 4.2, which will be used in the proof of coercivity presented in Theorem 4.3.

    Lemma 4.2. Let wH1(Ω). Then,

    Ωμεl(wεl):(wεl) + Ωμεl((wεl))T:(wεl)  μ|V|2n2r(wεl)+((wεl))T2L2(Ω), (4.6)

    for some natural number nr.

    Proof. Let wH1(Ω). Since the porosity εl>0 is a real number, by the Archimedean property, there exists nrN such that εl1nr. Given W=wεl, then,

    Ωμεl(wεl):(wεl)+Ωμεl((wεl))T:(wεl)= ΩμεlW:W+Ωμεl(W)T:W= Ωμεl[W:W + (W)T:W]= Ωμεl[W + (W)T]:W= Ω2μεl12[W + (W)T]:W= Ω2μεlD:W= Ω2μεlDijWixj= Ω2μεl(D11W1x1+D12W1x2+D21W2x1+D22W2x2)= Ω2μεl(D211+D12(W1x2+W2x1)+D222)= Ω2μεl(D211+2D1212(W1x2+W2x1)+D222)= Ω2μεl(D211+2D212+D222)= Ω2μεl(D211+D212+D221+D222) 2μΩ(εl)2(D211+D212+D221+D222)= 2μ(Ω(εlD11)2+Ω(εlD12)2+Ω(εlD21)2+Ω(εlD22)2)= 2μ(εlD112L2(Ω)+εlD122L2(Ω)+εlD212L2(Ω)+εlD222L2(Ω)) 2μ((εlD11)2L2(Ω)+(εlD12)2L2(Ω)+(εlD21)2L2(Ω)+(εlD22)2L2(Ω)) 2μ(εlD11)2+(εlD12)2+(εlD21)2+(εlD22)2L2(Ω)= 2μ2i=12j=1|εlDij|2L2(Ω) 2μ(σmax(εlD))2L2(Ω)= 2μ(Ω(σmax(εlD))4dΩ)12= 2μ((σmax(εlD))4Ω1 dΩ)12= 2μ((σmax(εlD))4|V|)12= 2μ|V|(σmax(εlD))2= 2μ|V|εlD2L2(Ω)= 2μ|V|εl2(W+(W)T)2L2(Ω) 2μ|V|12nr(W+(W)T)2L2(Ω)= μ|V|2n2rW+(W)T2L2(Ω)=μ|V|2n2r(wεl)+((wεl))T2L2(Ω),

    where D=12(W+(W)T) is symmetric with the indicial notation Dij = 12(Wixj+Wjxi). The variable Dij is considered to be a real number for all i,j=1,2, and |V| is the volume of the domain Ω. For the first inequality, we use the fact that the porosity εl1. For the second and third inequalities, we apply H¨older's inequality and the triangle inequality, respectively. For the fourth inequality, we apply the spectral norm of a matrix E [29], i.e.,

    EL2(Ω) = σmax(E)  (mi=1sj=1|aij|2)12, (4.7)

    where σmax(E) represents the largest singular value of a matrix E, and s and m are the dimensional numbers. For the last inequality, we use the Archimedean property [30]. Therefore,

    ΩμεlW:W + Ωμεl(W)T:W  μ|V|2n2rW+(W)T2L2(Ω). (4.8)

    Hence, the proof is complete.

    Next, we show the coercivity of the bilinear functional a(,).

    Theorem 4.3. The bilinear functional a(,) is coercive, such that

    a(w,w)  Qcw2H1(Ω),wH1(Ω), (4.9)

    where Qc=min{μQk, μ|V|n2rK(N1)2} and Qk is a positive number.

    Proof. Let wH1(Ω). Then,

    a(w,w)= Ωμ(k1w)w+Ωμεl(wεl):(wεl)+Ωμεl((wεl))T:(wεl)= Ωμ(k1w)w+ΩμεlW:W + Ωμεl(W)T:W μQkw2L2(Ω)+μ|V|2n2rW+(W)T2L2(Ω)= μQkw2L2(Ω)+μ|V|2n2r(W+(W)T2L2(Ω)+W(W)T2L2(Ω)  W(W)T2L2(Ω)) μQkw2L2(Ω)+μ|V|2n2r[2W2L2(Ω)+2(W)T2L2(Ω) (W2L2(Ω)+ (W)T2L2(Ω))]= μQkw2L2(Ω)+μ|V|2n2r(W2L2(Ω)+(W)T2L2(Ω)) μQkw2L2(Ω)+μ|V|n2rW2L2(Ω)= μQkw2L2(Ω)+μ|V|n2r|W|2H1(Ω)= μQkw2L2(Ω)+μ|V|n2r|wεl|2H1(Ω) μQkw2L2(Ω)+μ|V|n2rKwεl2H1(Ω) μQkw2L2(Ω)+μ|V|n2rK(N1)w2H1(Ω)= μQkw2L2(Ω)+μ|V|n2rK(N1)2w2H1(Ω) min{μQk, μ|V|n2rK(N1)2}(w2L2(Ω)+w2H1(Ω)) min{μQk, μ|V|n2rK(N1)2}w2H1(Ω)= Qcw2H1(Ω),

    where Qc=min{μQk, μ|V|n2rK(N1)2}>0. The property [14]

    Ω(k1w)w  Qkw2L2(Ω)where  Qk>0 (4.10)

    and inequality (4.8) are used in the first inequality. Parallelogram law [31] u,wU, u+w2+uw2=2(u2+w2) and the fact that uw2u2+w2 are applied to the second inequality. Poincarˊe inequality [31] K>0 such that |w|Hm(Ω)1KwHm(Ω), wHm0(Ω) where m0, is applied to the fourth inequality. For the fifth inequality, we apply Archimedean property [30] rR, NN such that N1rN and use the fact that εl is a positive real number. Hence, the proof of the coercivity of the bilinear form a(w,w) is complete.

    In this section, we provide the proof of the existence and uniqueness of the generalized Stokes-Brinkman equations. Before illustrating the proof of the well-posedness, we present the following proposition.

    Proposition 5.1. Let fL2(Ω) and sH1/2(Ω). Then, there exist usH1(Ω) and a unique u0V such that

    us+u0H1(Ω)1βfL2(Ω)+(1+nβ)QssH1/2(Ω), (5.1)

    where n is the dimensional number, and β and Qs are positive constants.

    Proof. Let fL2(Ω), and sH1/2(Ω). Therefore, there exist usH1(Ω), a unique u0VH10(Ω) and Qs>0 such that us|Ω=s, fusL20(Ω), u0=fus,

    usH1(Ω)QssH1/2(Ω), (5.2)

    and there exists β>0 such that

    u0H1(Ω)β1fusL2(Ω). (5.3)

    See Lemma A.4 for the details. Next, we show that us+u0 is bounded, as follows.

    us+u0H1(Ω)usH1(Ω)+u0H1(Ω)QssH1/2(Ω)+1βfusL2(Ω)QssH1/2(Ω)+1βfL2(Ω)+1βusL2(Ω)QssH1/2(Ω)+1βfL2(Ω)+nβusH1(Ω)1βfL2(Ω)+(1+nβ)QssH1/2(Ω),

    where the fact that [16] ϕL2(Ω)n|ϕ|H1Ω, where n is the dimensional number, is applied to the fourth inequality.

    Next, we show the theorem of the well-posedness of the generalized Stokes-Brinkman equations.

    Theorem 5.2. Let fH1(Ω), fL2(Ω) and sH1/2(Ω). There exist a unique uH1s(Ω) and pL20(Ω) satisfying Problem 1. Moreover,

    uH1(Ω)  1QcfH1(Ω)+(1+QaQc)ˆuH1(Ω), (5.4)
    pL2(Ω)  1βfH1(Ω)+1βQauH1(Ω), (5.5)

    where ˆu=us+u0, β>0, as presented in Proposition 5.1, and Qa and Qc are defined in Theorem 4.1 and Theorem 4.3, respectively.

    Proof. Let fH1(Ω), fL2(Ω) and sH1/2(Ω). From Proposition 5.1, we have usH1(Ω) and u0VH10(Ω) such that us|Ω=s and u0=fus. Let ˆu=us+u0 and L(w)=c1(w)a(ˆu,w) for any wV. By adopting the linearity and continuity of c1() and bilinearity and continuity of a(,) along with the coercivity of a(,), we have that L() is a linear and continuous function. Then, from the Lax-Milgram theorem, there exists a unique ˜uVH10(Ω) such that a(˜u,w)=L(w). Let u=˜u+ˆu. Then,

    u|Ω=˜u|Ω+us|Ω+u0|Ω=0+s+0=s.

    Therefore, uH1s(Ω). Next, we show the uniqueness of u. Since a(˜u,w)=L(w)=c1(w)a(ˆu,w), by using the bilinear property of a(,), we have

    a(u,w)=a(˜u+ˆu,w)=c1(w). (5.6)

    Suppose that u1 and u2 are two such solutions satisfying

    a(u1,w)=c1(w) and a(u2,w)=c1(w). (5.7)

    Then, substituting w=u1u2 in Eq (5.7) and subtracting one equation from another equation, we get

    0=a(u1u2,u1u2)Qcu1u22H1(Ω)0,

    where we apply the coercivity of a(,), Theorem 4.3, at the first inequality. Since the constant Qc>0, it implies that u1u2H1(Ω)=0. Then, u1=u2. Therefore, u is unique, satisfying a(u,w)=c1(w), for all wV.

    Next, we show that u=˜u+us+u0 satisfies the continuity equation. Since ˜uV, ˜u=0. Then,

    u=(˜u+us+u0)=˜u+us+u0=0+us+fus=f,

    where u0=fus is applied at the third equality. Hence, u satisfies the continuity equation.

    We prove the existence and uniqueness of pL20(Ω). Define L1 such that L1,w=f,w=c1(w). Then, from Eq (5.6), we have

    a(˜u,w)+a(ˆu,w)L1,w=0, wV. (5.8)

    By the definition of the linear operator, seen in Appendix A, we can rewrite Eq (5.8) in operator notation as A˜u+AˆuL1=0. Then, A˜u+AˆuL1V0, where V0 is the polar set of V; see Appendix A for the definition. Given that B:L20(Ω)V0 is an isomorphism grad operator, from Theorem A.2 and the property of isomorphism, there exists a unique pL20(Ω) such that Bp=A˜u+AˆuL1=AuL1. Then,

    Au+Bp=L1=f.

    Therefore, there exist a unique uH1s(Ω) and pL20(Ω) satisfying Problems 1 and 2.

    Next, we show the variables u and p are bounded. We first illustrate that ˜u ia bounded. Employing Eq (4.9), we have

    Qc˜u2H1(Ω)a(˜u,˜u)=c1(˜u)a(ˆu,˜u)fH1(Ω)˜uH1(Ω)+QaˆuH1(Ω)˜uH1(Ω), (5.9)

    where the second inequality is obtained from Theorem 4.1. Dividing both sides of Eq (5.9) by ˜uH1(Ω) and Qc, we get

    ˜uH1(Ω)1QcfH1(Ω)+QaQcˆuH1(Ω). (5.10)

    Thus,

    uH1(Ω)=˜u+ˆuH1(Ω)˜uH1(Ω)+ˆuH1(Ω)1QcfH1(Ω)+(1+QaQc)ˆuH1(Ω).

    To show that p is bounded, we first employ Eq (3.5):

    b(w,p)=c1(w)a(u,w)fH1(Ω)wH1(Ω)+QauH1(Ω)wH1(Ω), (5.11)

    where inequalities (4.1) and (4.4) are applied to the inequality. Since

    supwH10(Ω)b(w,p)wH1(Ω)pL2(Ω)

    is independent of p, from Eq (A.11),

    p1L2(Ω)supwH10(Ω)b(w,p)wH1(Ω)=supwH10(Ω)b(w,p)wH1(Ω)pL2(Ω)infpL20(Ω)supwH10(Ω)b(w,p)wH1(Ω)pL2(Ω)β>0. (5.12)

    Rearranging Eq (5.12), we obtain that

    pL2(Ω)1βsupwH10(Ω)b(w,p)wH1(Ω)=1βsupwH10(Ω)c1(w)a(u,w)wH1(Ω)1βsupwH10(Ω)(fH1(Ω)wH1(Ω)+QauH1(Ω)wH1(Ω)wH1(Ω))=1βsupwH10(Ω)(fH1(Ω)+QauH1(Ω)).

    Since fH1(Ω)+QauH1(Ω) is independent of wH10(Ω),

    supwH10(Ω)(fH1(Ω)+QauH1(Ω))=fH1(Ω)+QauH1(Ω).

    Therefore,

    pL2(Ω)1β(fH1(Ω)+QauH1(Ω)).

    Hence, the proof of existence and uniqueness of the generalized Stokes-Brinkman equations is complete.

    In this research, we focus on the fluid movement in a porous medium induced by self-propelled solid phases and the adjacent free-fluid region. In the porous medium, we employ a macroscale equation derived from an upscaling technique called Hybrid Mixture Theory (HMT) because we consider a bundle of solid phases. Then, we apply a non-dimensionalization scheme to the macroscale equation to obtain the Brinkman equation. Our model is more general than the Brinkman equation in the literature because the porosity in our equation is considered as a function since the beginning of the derivation. Then, our model in the porous medium conserves the reality of the problem. In the free-fluid region, we start with the generalized Navier-Stokes equation and use the non-dimensionalization method to derive the generalized Stokes equation. Our Brinkman and generalized Stokes equations can be matched at the free-fluid/porous-medium interface. We name them as the generalized Stokes-Brinkman equations. We also show that the discretized form of the mathematical model is a well-posed system with the use of a mixed finite element method. The weak formulation of the generalized Stokes-Brinkman equations is rewritten in linear and bilinear functional structures. We show that the bilinear form a(,) is continuous and coercive. Then, we present the well-posedness of the generalized Stokes-Brinkman equations in the last theorem. The system of equations can be useful for more complexity of a real problem in a macroscopic scale than a typical Stokes-Brinkman equation and can be applied to the fluid flow through the regions where fluid is driven by the moving solid phases such as hairlike structures and animal hair. The numerical research will be presented in the next study.

    This research is supported by RA/TA graduate scholarship from the School of Science, King Mongkut's Institute of Technology Ladkrabang, Thailand, grant number RA/TA-2563-D-003.

    The authors declare no conflict of interest.

    In this Appendix, we provide notations, definitions, theorems and lemmas used in the proof of the well-posedness of the generalized Stokes-Brinkman equations. They are all presented and proved in [14,32,33,34].

    Notations and spaces

    In this section, we introduce some notations and spaces used in the proof of the well-posedness of the governing equations [14]. Define

    L20(Ω)={qL2(Ω):ΩqdΩ=0}, (A.1)
    H10(Ω)={wH1(Ω):w|Ω=0}, (A.2)
    H1s(Ω)={wH1(Ω):w|Ω=s}, (A.3)
    H1(Ω)=(H10(Ω)),the dual of H10(Ω), (A.4)
    V={wH1(Ω):w|Ω=0 and w=0}, (A.5)
    V={wH10(Ω):Ωww=0  w V}, (A.6)
    V0={wH1(Ω):w,wH1(Ω)×H10(Ω)=0  wV}, (A.7)

    where ,H1(Ω)×H10(Ω) denotes the duality pairing between H1(Ω) and H10(Ω). Notice that for n dimension, wH1(Ω)n and wH1(Ω)n×n. In any case, for the sake of simplicity, we write wH1(Ω), and the implication comes from the context of the surrounding sentences.

    Next, we provide the fundamental definition, theorems and lemma used in the proof of the existence and uniqueness of Problems 1 and 2 [14,31,32,33,34,35].

    Definition A.1. Let u,wH1(Ω) and qL20(Ω). Define linear operators A:H10(Ω)H1(Ω) and B:H10(Ω)L20(Ω) by

    Au,wH10(Ω)×H1(Ω):= a(u,w),u,wH10(Ω), (A.8)
    Bu,qH10(Ω)×L20(Ω):= b(u,q), uH10(Ω),qL20(Ω). (A.9)

    Let BL(L20(Ω);H1(Ω)) be the dual operator of B. Then,

    Bq,u= q,Bu:= b(u,q), uH10(Ω),qL20(Ω), (A.10)

    where the dual spaces of L20(Ω)=(L20(Ω)) and the dual spaces of H1(Ω)=(H10(Ω)).

    Theorem A.2. Let Ω be connected. Then,

    1. the operator grad is an isomorphism of L20(Ω) onto V0,

    2. the operator div is an isomorphism of V onto L20(Ω).

    Therefore, there exists β>0 such that

    infqL20(Ω)supwH10(Ω)b(w,q)wH1(Ω)qL2(Ω)β>0 (A.11)

    and for any qL20(Ω), there exists a unique uVH10(Ω) satisfying

    uH1(Ω)β1qL2(Ω). (A.12)

    Theorem A.3. There exist positive constants Qt and Qs such that, for each vH1(Ω), its trace on Ω belongs to H1/2(Ω), and

    vH1/2(Ω)QtvH1(Ω). (A.13)

    Conversely, for each given function sH1/2(Ω), there exists usH1(Ω) such that its trace on Ω coincides with s and

    usH1(Ω)QssH1/2(Ω). (A.14)

    Lemma A.4. Suppose that fH1(Ω), fL2(Ω) and sH1/2(Ω). Then, there exist usH1(Ω), Qs>0 and β>0 such that

    us|Ω=sandusH1(Ω)QssH1/2(Ω), (A.15)
    !u0VH10(Ω)satisfyingu0=fus, (A.16)

    and

    u0H1(Ω)β1fusL2(Ω). (A.17)
    [1] Speight J (2012) The chemistry and technology of coal. CRC Press, New York.
    [2] Puente GDL, Iglesias MJ, Fuente E, et al. (1998) Changes in the structure of coals of different rank due to oxidation-effects on pyrolysis behaviour. J Anal Appl Pyrolysis 47: 33–42. doi: 10.1016/S0165-2370(98)00087-4
    [3] Nelson MI, Chen XD (2007) Survey of experimental work on the self-heating and spontaneous combustion of coal. Reviews in Engineering Geology. Geological Society of America, 31–83.
    [4] De SK, Prabu V (2017) Experimental studies on humidified/water influx O2 gasification for enhanced hydrogen production in the context of underground coal gasification. Int J Hydrogen Energ 42: 14089–14102. doi: 10.1016/j.ijhydene.2017.04.112
    [5] Pan CX, Liu HL, Liu Q, et al. (2017) Oxidative depolymerization of Shenfu subbituminous coal and its thermal dissolution insoluble fraction. Fuel Process Technol 155: 168–173. doi: 10.1016/j.fuproc.2016.05.017
    [6] Boron DJ, Taylor SR (1985) Mild oxidations of coal.1. Hydrogen peroxide oxidation. Fuel 64: 209–211.
    [7] Yu J, Jiang Y, Tahmasebi A, et al. (2014) Coal oxidation under mild conditions: current status and applications. Chem Eng Technol 37: 1635–1644. doi: 10.1002/ceat.201300651
    [8] Hayatsu R, Winans RE, McBeth RL (1984) Oxidative degradation studies and modern concepts of the formation and transformation of organic constituents of coals and sedimentary rocks. Org Geochem 6: 463–471. doi: 10.1016/0146-6380(84)90069-X
    [9] Wang YG, Wei XY, Yan HL, et al. (2013) Mild oxidation of Jincheng No.15 anthracite. J Fuel Chem Technol 41: 819–825. doi: 10.1016/S1872-5813(13)60035-3
    [10] Rozhkova NN, Gorlenko LE, Emelyanova GI, et al. (2009) Effect of ozone on the structure and physicochemical properties of ultradisperse diamond and shungite nanocarbon elements. Pure Appl Chem 81: 2093–2105.
    [11] Semenova SA, Fedyaeva ON, Patrakov YF (2006) Liquid-phase ozonation of highly metamorphized coal. Chem Sustain Dev 14: 43–48.
    [12] Semenova S, Patrakov Y, Batina M (2009) Preparation of oxygen-containing organic products from bed-oxidized brown coal by ozonation. Russ J Appl Chem 82: 80–85. doi: 10.1134/S1070427209010157
    [13] Obvintseva LA, Sukhareva IP, Epshtein SA, et al. (2017) Interaction of coals with ozone at low concentrations. Solid Fuel Chem 51: 155–159. doi: 10.3103/S0361521917030077
    [14] Wu F, Wang M, Lu Y, et al. (2017) Catalytic removal of ozone and design of an ozone converter for the bleeding air purification of aircraft cabin. Build Environ 115: 25–33. doi: 10.1016/j.buildenv.2017.01.007
    [15] Guo W, Ke P, Zhang S (2015) Effects of environment control system operation on ozone retention inside airplane cabin. Procedia Eng 121: 396–403. doi: 10.1016/j.proeng.2015.08.1084
    [16] Ondarts M, Outin J, Reinert L, et al. (2015) Removal of ozone by activated carbons modified by oxidation treatments. Eur Phys J-Spec Top 224: 1995–1999. doi: 10.1140/epjst/e2015-02516-6
    [17] Gorlenko LE, Emelyanova GI, Kharlanov AN, et al. (2006) Low-temperature oxidative modification of lignites and lignite-based cokes. Russ J Phys Chem 80: 878–881. doi: 10.1134/S0036024406060069
    [18] Semenova SA, Patrakov YF (2007) Ozonation of coal vitrinites of different metamorphism degrees in gas and liquid phases. Solid Fuel Chem 41: 15–18. doi: 10.3103/S0361521907010041
    [19] Patrakov YF, Semenova SA (2012) Chemical composition of various petrographic constituents of brown coal from the Balakhtinskoe deposit. Solid Fuel Chem 46: 1–6. doi: 10.3103/S0361521912010119
    [20] Patrakov Y, Fedyaeva O, Semenova S, et al. (2006) Influence of ozone treatment on change of structural-chemical parameters of coal vitrinites and their reactivity during the thermal liquefaction process. Fuel 85: 1264–1272. doi: 10.1016/j.fuel.2005.11.005
    [21] Ksenofontova MM, Kudryavtsev AV, Mitrofanova AN, et al. (2005) Ozone application for modification of humates and lignins. In: Perminova IV, Hatfield K, Hertkorn N Editors, Use of Humic Substances to Remediate Polluted Environments: From Theory to Practice, Springer Netherlands, 473–484.
    [22] Lunin VV, Popovich MP, Tkachenko SN (1998) Physical chemistry of ozone, Moscow. Moscow State University Publishing, 480.
    [23] Batakliev T, Georgiev V, Anachkov M, et al. (2014) Ozone decomposition. Interdiscip Toxicol 7: 47–59.
    [24] Oyama ST (2000) Chemical and catalytic properties of ozone. Catal Rev 42: 279–322. doi: 10.1081/CR-100100263
    [25] Deitz VR, Bitner JL (1973) Interaction of ozone with adsorbent charcoals. Carbon 11: 393–401. doi: 10.1016/0008-6223(73)90079-1
    [26] World Health Organization (2006) WHO Air quality guidelines for particulate matter, ozone, nitrogen dioxide and sulfur dioxide: global update 2005: summary of risk assessment. Geneva: World Health Organization: 1–22.
    [27] Elansky NF (2012) Russian studies of atmospheric ozone in 2007–2011. Izv Atmos Ocean Phy 48: 281–298. doi: 10.1134/S0001433812030024
    [28] Epshtein SA, Kossovich EL, Kaminskii VA, et al. (2017) Solid fossil fuels thermal decomposition features in air and argon. Fuel 199: 145–156. doi: 10.1016/j.fuel.2017.02.084
    [29] Korovushkin VV, Epshtein SA, Durov NM, et al. (2015) Mineral and valent forms of iron and their effects on coals oxidation and self-ignition. Gornyi Zhurnal 2015: 70–74.
    [30] Epshtein SA, Kossovich EL, Dobryakova NN, et al. (2016) New approaches for coal oxidization propensity estimation. XVIII International Coal Preparation Congress. Springer International Publishing, Cham, 483–487.
    [31] Epshtein SA, Gavrilova DI, Kossovich EL, et al. (2016) Thermal methods exploitation for coals propensity to oxidation and self-ignition study. Gornyi Zhurnal 2016: 100–104.
    [32] Belikov IB, Zhernikov KV, Obvintseva LA, et al. (2008) Analyzer of atmospheric gas impurities based on semiconductor sensors. Instrum Exp Tech 2008: 139–140.
    [33] Obvintseva LA, Zhernikov KV, Belikov IB, et al. (2008) Semiconductor sensors and sensor containing gas analyzer for ozone monitoring in the atmosphere. Proceedings of the Eurosensors XXII Conference, 1594–1598.
    [34] Ito O, Seki H, Iino M (1988) Diffuse reflectance spectra in near-i.r. region of coals; a new index for degrees of coalification and carbonization. Fuel 67: 573–578.
    [35] Maroto-Valer MM, Love GD, Snape CE (1994) Relationship between carbon aromaticities and HC ratios for bituminous coals. Fuel 73: 1926–1928. doi: 10.1016/0016-2361(94)90224-0
    [36] Maroto-Valer MM (1998) Verification of the linear relationship between carbon aromaticities and H/C ratios for bituminous coals. Fuel 77: 783–785. doi: 10.1016/S0016-2361(97)00227-5
    [37] Gan H, Nandi SP, Walker PL (1972) Nature of the porosity in American coals. Fuel 51: 272–277. doi: 10.1016/0016-2361(72)90003-8
    [38] Nie B, Liu X, Yang L, et al. (2015) Pore structure characterization of different rank coals using gas adsorption and scanning electron microscopy. Fuel 158: 908–917. doi: 10.1016/j.fuel.2015.06.050
    [39] Mavor MJ, Owen LB, Pratt TJ (1990) Measurement and evaluation of coal sorption isotherm data. Proceedings of SPE Annual Technical Conference and Exhibition, Society of Petroleum Engineers, SPE 20728.
    [40] Rodrigues CF, Sousa MJLD (2002) The measurement of coal porosity with different gases. Int J Coal Geol 48: 245–251. doi: 10.1016/S0166-5162(01)00061-1
  • This article has been cited by:

    1. Nisachon Kumankat, Nachayadar Kamolmitisom, Two-Dimensional Fluid Flow Due to Blade-Shaped Waving of Cilia in Human Lungs, 2025, 13, 2227-7390, 1703, 10.3390/math13111703
  • Reader Comments
  • © 2017 the Author(s), licensee AIMS Press. This is an open access article distributed under the terms of the Creative Commons Attribution License (http://creativecommons.org/licenses/by/4.0)
通讯作者: 陈斌, bchen63@163.com
  • 1. 

    沈阳化工大学材料科学与工程学院 沈阳 110142

  1. 本站搜索
  2. 百度学术搜索
  3. 万方数据库搜索
  4. CNKI搜索

Metrics

Article views(5063) PDF downloads(821) Cited by(7)

/

DownLoad:  Full-Size Img  PowerPoint
Return
Return

Catalog