Loading [MathJax]/jax/element/mml/optable/GeneralPunctuation.js
Research article Special Issues

Influence of plantation climate and storage time on thermal and viscoelastic properties of natural rubber

  • The Sociedad de Caucho Colombo Argentina (SOCCA) collected natural rubber (NR) from Yarima, Colombia, for seven months spanning two years. The unvulcanized NR was used to conduct a preliminary study, part of a long-term study, to uncover some underlying mechanisms in charge of imparting variation between NR batches, such as the collection site's rainfall conditions and storage period by using calorimetry, rheometry, and a dynamic mechanical analyzer. The ultrasound study found that an increase in monthly rainfall increased the material's elastic constant at 10 MHz, and the crystallization study uncovered that the amount of crystallization decreased with increased rain while remaining relatively constant if rainfall was within the recommended rainfall amount for the tree. Additionally, stress relaxation measurements revealed that an increase in rainfall suggested an increase in the material's temperature sensitivity. The temperature sensitivity relates to the material's processability in which an increase in temperature with high sensitivity will have a more drastic decrease in stress during a relaxation test compared to a material with low sensitivity.

    Citation: Allen Jonathan Román, Jamelah Zena Travis, Juan Carlos Martínez Ávila, Tim A. Osswald. Influence of plantation climate and storage time on thermal and viscoelastic properties of natural rubber[J]. AIMS Bioengineering, 2021, 8(1): 95-111. doi: 10.3934/bioeng.2021010

    Related Papers:

    [1] Menita Carozza, Luca Esposito, Lorenzo Lamberti . Quasiconvex bulk and surface energies with subquadratic growth. Mathematics in Engineering, 2025, 7(3): 228-263. doi: 10.3934/mine.2025011
    [2] Claudia Lederman, Noemi Wolanski . Lipschitz continuity of minimizers in a problem with nonstandard growth. Mathematics in Engineering, 2021, 3(1): 1-39. doi: 10.3934/mine.2021009
    [3] Luca Capogna, Giovanna Citti, Nicola Garofalo . Regularity for a class of quasilinear degenerate parabolic equations in the Heisenberg group. Mathematics in Engineering, 2021, 3(1): 1-31. doi: 10.3934/mine.2021008
    [4] Giovanni Scilla, Bianca Stroffolini . Partial regularity for steady double phase fluids. Mathematics in Engineering, 2023, 5(5): 1-47. doi: 10.3934/mine.2023088
    [5] Caterina Ida Zeppieri . Homogenisation of high-contrast brittle materials. Mathematics in Engineering, 2020, 2(1): 174-202. doi: 10.3934/mine.2020009
    [6] Alessandra De Luca, Veronica Felli . Unique continuation from the edge of a crack. Mathematics in Engineering, 2021, 3(3): 1-40. doi: 10.3934/mine.2021023
    [7] Piermarco Cannarsa, Rossana Capuani, Pierre Cardaliaguet . C1;1-smoothness of constrained solutions in the calculus of variations with application to mean field games. Mathematics in Engineering, 2019, 1(1): 174-203. doi: 10.3934/Mine.2018.1.174
    [8] Zijie Deng, Wenjian Peng, Tian-Yi Wang, Haoran Zhang . Well-posedness of contact discontinuity solutions and vanishing pressure limit for the Aw–Rascle traffic flow model. Mathematics in Engineering, 2025, 7(3): 316-349. doi: 10.3934/mine.2025014
    [9] Gennaro Ciampa, Gianluca Crippa, Stefano Spirito . Propagation of logarithmic regularity and inviscid limit for the 2D Euler equations. Mathematics in Engineering, 2024, 6(4): 494-509. doi: 10.3934/mine.2024020
    [10] Neil S. Trudinger . On the local theory of prescribed Jacobian equations revisited. Mathematics in Engineering, 2021, 3(6): 1-17. doi: 10.3934/mine.2021048
  • The Sociedad de Caucho Colombo Argentina (SOCCA) collected natural rubber (NR) from Yarima, Colombia, for seven months spanning two years. The unvulcanized NR was used to conduct a preliminary study, part of a long-term study, to uncover some underlying mechanisms in charge of imparting variation between NR batches, such as the collection site's rainfall conditions and storage period by using calorimetry, rheometry, and a dynamic mechanical analyzer. The ultrasound study found that an increase in monthly rainfall increased the material's elastic constant at 10 MHz, and the crystallization study uncovered that the amount of crystallization decreased with increased rain while remaining relatively constant if rainfall was within the recommended rainfall amount for the tree. Additionally, stress relaxation measurements revealed that an increase in rainfall suggested an increase in the material's temperature sensitivity. The temperature sensitivity relates to the material's processability in which an increase in temperature with high sensitivity will have a more drastic decrease in stress during a relaxation test compared to a material with low sensitivity.


    Abbreviations

    NR:

    Natural Rubber; 

    1H-NMR:

    Proton Nuclear Magnetic Resonance; 

    DMA:

    Dynamic Mechanical Analyzer; 

    DSC:

    Differential Scanning Calorimetry; 

    TGA:

    Thermogravimetric analysis

    Dedicated to Giuseppe Mingione on the occasion of his 50th birthday, with admiration.

    In this paper we provide a limiting partial regularity criterion for vector-valued minimizers u:ΩRnRN, n2, N>1, of nonhomogeneous, quasiconvex variational integrals as:

    W1,p(Ω;RN)wF(w;Ω):=Ω[F(Dw)fw]dx, (1.1)

    with standard p-growth. More precisely, we infer the optimal [31, Section 9] ε-regularity condition

    supBϱΩϱmBϱ|f|mdxε Du has a.e. bounded mean oscillation,

    and the related borderline function space criterion

    fL(n,)  supBϱΩϱmBϱ|f|mdxε.

    This is the content of our main theorem.

    Theorem 1.1. Under assumptions (1.6)1,2,3, (1.7) and (1.10), let uW1,p(Ω,RN) be a local minimizer of functional (1.1). Then, there exists a number εε(data)>0 such that if

    fLn,(Ω)(|B1|4n/m)1/nε, (1.2)

    then there exists an open set ΩuΩ with |ΩΩu|=0 such that

    DuBMOloc(Ωu;RN×n). (1.3)

    Moreover, the set Ωu can be characterized as follows

    Ωu:={x0Ω:εx0,ϱx0>0such that E(u;Bϱ(x0))εx0 for some ϱϱx0},

    where E() is the usual excess functional defined as

    E(w,z0;Bϱ(x0)):=( Bϱ(x0)|z0|p2|Dwz0|2+|Dwz0|p dx)1p. (1.4)

    We immediately refer to Section 1.2 below for a description of the structural assumptions in force in Theorem 1.1. Let us put our result in the context of the available literature. The notion of quasiconvexity was introduced by Morrey [38] in relation to the delicate issue of semicontinuity of multiple integrals in Sobolev spaces: an integrand F() is a quasiconvex whenever

    B1(0)F(z+Dφ)dxF(z)holds for all  zRN×n,  φCc(B1(0),RN). (1.5)

    Under power growth conditions, (1.5) is proven to be necessary and sufficient for the sequential weak lower semicontinuity on W1,p(Ω;RN); see [1,4,35,36,38]. It is worth stressing that quasiconvexity is a strict generalization of convexity: the two concepts coincide in the scalar setting (N=1), or for 1-d problems (n=1), but sharply differ in the multidimensional case: every convex function is quasiconvex thanks to Jensen's inequality, while the determinant is quasiconvex (actually polyconvex), but not convex, cf. [24, Section 5.1]. Another distinctive trait is the nonlocal nature of quasiconvexity: Morrey [38] conjectured that there is no condition involving only F() and a finite number of its derivatives that is both necessary and sufficient for quasiconvexity, fact later on confirmed by Kristensen [29]. A peculiarity of quasiconvex functionals is that minima and critical points (i.e., solutions to the associated Euler-Lagrange system) might have very different behavior under the (partial) regularity viewpoint. In fact, a classical result of Evans [22] states that the gradient of minima is locally Hölder continuous outside a negligible, " singular" set, while a celebrated counterexample due to Müller and Šverák [39] shows that the gradient of critical points may be everywhere discontinuous. After Evans seminal contribution [22], the partial regularity theory was extended by Acerbi and Fusco [2] to possibly degenerate quasiconvex functionals with superquadratic growth, and by Carozza, Fusco and Mingione [8] to subquadratic, nonsingular variational integrals. A unified approach that allows simultaneously handling degenerate/nondegenerate, and singular/nonsingular problems, based on the combination of A-harmonic approximation [21], and p-harmonic approximation [20], was eventually proposed by Duzaar and Mingione [19]. Moreover, Kristensen and Mingione [30] proved that the Hausdorff dimension of the singular set of Lipschitz continuous minimizers of quasiconvex multiple integrals is strictly less than the ambient space dimension n, see also [5] for further developments in this direction. We refer to [3,15,16,25,26,27,28,37,41,42] for an (incomplete) account of classical, and more recent advances in the field. In all the aforementioned papers are considered homogeneous functionals, i.e., f0 in (1.1). The first sharp ε-regularity criteria for nonhomogeneous quasiconvex variational integrals guaranteeing almost everywhere gradient continuity under optimal assumptions on f were obtained by De Filippis [12], and De Filippis and Stroffolini [14], by connecting the classical partial regularity theory for quasiconvex functionals with nonlinear potential theory for degenerate/singular elliptic equations, first applied in the context of partial regularity for strongly elliptic systems by Kuusi and Mingione [33]. Potential theory for nonlinear PDE originates from the classical problem of determining the best condition on f implying gradient continuity in the Poisson equation Δu=f, that turns out to be formulated in terms of the uniform decay to zero of the Riesz potential, in turn implied by the membership of f to the Lorentz space L(n,1), [9,31]. In this respect, a breakthrough result due to Kuusi and Mingione [32,34] states that the same is true for the nonhomogeous, degenerate p-Laplace equation–in other words, the regularity theory for the nonhomogeneous p-Laplace PDE coincides with that of the Poisson equation up to the C1-level. This important result also holds in the case of singular equations [18,40], for general, uniformly elliptic equations [6], up to the boundary [10,11,13], and at the level of partial regularity for p-Laplacian type systems without Uhlenbeck structure, [7,33]. We conclude by highlighting that our Theorem 1.1 fits this line of research as, it determines for the first time in the literature optimal conditions on the inhomogeneity f assuring partial BMO-regularity for minima of quasiconvex functionals expressed in terms of the limiting function space L(n,).

    In Section 2 we recall some well-known results from the study of nonlinear problems also establishing some Caccioppoli and Gehring type lemmas. In Section 3 we prove the excess decay estimates; considering separately the nondegenerate and the degenerate case. Section 4 is devoted to the proof of Theorem 1.1.

    In (1.1), the integrand F:RN×nR satisfies

    { FC2loc(RN×n) Λ1|z|pF(z)Λ|z|p |2F(z)|Λ|z|p2 |2F(z1)2F(z2)|μ(|z2z1||z2|+|z1|)(|z1|2+|z2|2)p22 (1.6)

    for all zRN×n, Λ1 being a positive absolute constant and μ:[0,)[0,1] being a concave nondecreasing function with μ(0)=0. In the rest of the paper we will always assume p2. In order to derive meaningful regularity results, we need to update (1.5) to the stronger strict quasiconvexity condition

    B[F(z+Dφ)F(z)] dxλB(|z|2+|Dφ|2)p22|Dφ|2dx, (1.7)

    holding for all zRN×n and φW1,p0(B,RN), with λ being a positive, absolute constant. Furthermore, we allow the integrand F() to be degenerate elliptic in the origin. More specifically, we assume that F() features degeneracy of p-Laplacian type at the origin, i.e.,

    | F(z)F(0)|z|p2z|z|p1 |0as|z|0, (1.8)

    which means that we can find a function ω:(0,)(0,) such that

    |z|ω(s)  |F(z)F(0)|z|p2z|s|z|p1, (1.9)

    for every zRN×n and all s(0,). Moreover, the right-hand side term f:ΩRN in (1.1) verifies as minimal integrability condition the following

    fLm(Ω,RN)with  2>m>{ 2n/(n+2)if  n>2, 3/2if  n=2, (1.10)

    which, being p2, in turn implies that

    fW1,p(Ω,RN)andm<2p. (1.11)

    Here it is intended that, when pn, the Sobolev conjugate exponent p can be chosen as large as needed - in particular it will always be larger than p. By (1.5) and (1.6)2 we have

    |F(z)|c|z|p1, (1.12)

    with cc(n,N,Λ,p); see for example [35, proof of Theorem 2.1]. Finally, (1.7) yields that for all zRN×n, ξRN, ζRn it is

    2F(z)ξζ,ξζ2λ|z|p2|ξ|2|ζ|2, (1.13)

    see [24, Chapter 5].

    In this section we display our notation and collect some basic results that will be helpful later on.

    In this paper, ΩRn is an open, bounded domain with Lipschitz boundary, and n2. By c we will always denote a general constant larger than one, possibly depending on the data of the problem. Special occurrences will be denoted by c,˜c or likewise. Noteworthy dependencies on parameters will be highlighted by putting them in parentheses. Moreover, to simplify the notation, we shall array the main parameters governing functional (1.1) in the shorthand data:=(n,N,λ,Λ,p,μ(),ω()). By Br(x0):={xRn:|xx0|<r}, we denote the open ball with radius r, centred at x0; when not necessary or clear from the context, we shall omit denoting the center, i.e., Br(x0)Br - this will happen, for instance, when dealing with concentric balls. For x0Ω, we abbreviate dx0:=min{1,dist(x0,Ω)}. Moreover, with BRn being a measurable set with bounded positive Lebesgue measure 0<|B|<, and a:BRk, k1, being a measurable map, we denote

    (a)BBa(x) dx:=1|B|Ba(x)dx.

    We will often employ the almost minimality property of the average, i.e.,

    ( B|a(a)B|tdx)1/t2( B|az|tdx)1/t (2.1)

    for all zRN×n and any t1. Finally, if t>1 we will indicate its conjugate by t:=t/(t1) and its Sobolev exponents as t:=nt/(nt) if t<n or any number larger than one for tn and t:=max{nt/(n+t),1}.

    When dealing with p-Laplacian type problems, we shall often use the auxiliary vector field Vs:RN×nRN×n, defined by

    Vs(z):=(s2+|z|2)(p2)/4zwithp(1,),  s0,  zRN×n,

    incorporating the scaling features of the p-Laplacian. If s=0 we simply write Vs()V(). A couple of useful related inequalities are

    { |Vs(z1)Vs(z2)|(s2+|z1|2+|z2|2)(p2)/4|z1z2|, |Vs(z1+z2)||Vs(z1)|+|Vs(z2)|, |Vs1(z)||Vs2(z)|, if 12s2s12s2, |V(z1)V(z2)|2|V|z1|(z1z2)|2, if 12|z2||z1|2|z2|, (2.2)

    and

    |Vs(z)|2sp2|z|2+|z|pwith  p2, (2.3)

    where the constants implicit in " ", " " depend on n,N,p. A relevant property which is relevant for the nonlinear setting is recorded in the following lemma.

    Lemma 2.1. Let t>1, s[0,1] and z1,z2RN×n be such that s+|z1|+|z2|>0. Then

    10[s2+|z1+y(z2z1)|2]t2 dy(s2+|z1|2+|z2|2)t2,

    with constants implicit in "" depending only on n,N,t.

    The following iteration lemma will be helpful throughout the rest of the paper; for a proof we refer the reader to [24, Lemma 6.1].

    Lemma 2.2. Let h:[ϱ0,ϱ1]R be a non-negative and bounded function, and let θ(0,1), A,B,γ1,γ20 be numbers. Assume that h(t)θh(s)+A(st)γ1+B(st)γ2 holds for all ϱ0t<sϱ1. Then the following inequality holds h(ϱ0)c(θ,γ1,γ2)[A(ϱ1ϱ0)γ1+B(ϱ1ϱ0)γ2].

    We will often consider the "quadratic" version of the excess functional defined in (1.4), i.e.,

    ˜E(w,z0;Bϱ(x0)):=( Bϱ(x0)|V(Dw)z0|2dx)12. (2.4)

    In the particular case z0=(Dw)Bϱ(x0) (z0=(V(Dw))Bϱ(x0), resp.) we shall simply write E(w,(Dw)Bϱ(x0);Bϱ(x0))E(w;Bϱ(x0)) (˜E(w,(V(Dw))Bϱ(x0);Bϱ(x0))˜E(w;Bϱ(x0)), resp.). A simple computation shows that

    E(w;Bϱ(x0))p/2˜E(w;Bϱ(x0)). (2.5)

    Moreover, from (2.1) and from [23, Formula (2.6)] we have that

    ˜E(w;Bϱ(x0))˜E(w,V((Dw)Bϱ(x0));Bϱ(x0)). (2.6)

    In this section we collect some basic estimates for local minimizers of nonhomogeneous quasiconvex functionals. We start with a variation of the classical Caccioppoli inequality accounting for the presence of a nontrivial right-hand side term, coupled with an higher integrability result of Gehring-type.

    Lemma 2.3. Under assumptions (1.6)1,2,3, (1.7) and (1.10), let uW1,p(Ω,RN) be a local minimizer of functional (1.1).

    For every ball Bϱ(x0)Ω and any u0RN, z0RN×n{0} it holds that

    E(u,z0;Bϱ/2(x0))pcBϱ(x0)|z0|p2|uϱ|2+|uϱ|pdx+c|z0|p2(ϱmBϱ(x0)|f|m dx)2m, (2.7)

    where E() is defined in (1.4), (x):=u0+z0,xx0 and cc(n,N,λ,Λ,p).

    There exists an higher integrability exponent p2p2(n,N,λ,Λ,p)>p such that DuLp2loc(Ω,RN×n) and the reverse Hölder inequality

    ( Bϱ/2(x0)|Du(Du)Bϱ(x0)|p2dx)1p2c( Bϱ(x0)|Du|pdx)1p+c(ϱmBϱ(x0)|f|mdx)1m(p1), (2.8)

    is verified for all balls Bϱ(x0)Ω with cc(n,N,λ,Λ,p).

    Proof. For the ease of exposition, we split the proof in two steps, each of them corresponding to the proof of (2.7) and (2.8) respectively.

    Step 1: proof of (2.7).

    We choose parameters ϱ/2τ1<τ2ϱ, a cut-off function ηC1c(Bτ2(x0)) such that 1Bτ1(x0)η1Bτ2(x0) and |Dη|(τ2τ1)1. Set φ1:=η(u), φ2:=(1η)(u) and use (1.7) and the equivalence in (2.2)1 to estimate

    cBτ2(x0)|V|z0|(Dφ1)|2 dxBτ2(x0)[F(z0+Dφ1)F(z0)]dx=Bτ2(x0)[F(DuDφ2)F(Du)]dx+Bτ2(x0)[F(Du)F(DuDφ1)]dx+Bτ2(x0)[F(z0+Dφ2)F(z0)]dx=:I1+I2+I3, (2.9)

    where we have used the simple relation Dφ1+Dφ2=Duz0. Terms I1 and I3 can be controlled as done in [19, Proposition 2]; indeed we have

    I1+I3cBτ2(x0)Bτ1(x0)|V|z0|(Dφ2)|2dx+cBτ2(x0)Bτ1(x0)|V|z0|(Duz0)|2dx(2.2)2cBτ2(x0)Bτ1(x0)|V|z0|(Duz0)|2+| V|z0|(uτ2τ1) |2dx, (2.10)

    for cc(n,N,λ,Λ,p). Concerning term I2, we exploit (1.10), the fact that φ1W1,p0(Bτ2(x0),RN) and apply Sobolev-Poincaré inequality to get

    I2|Bτ2(x0)|(τm2Bτ2(x0)|f|m dx)1/m(τm2Bτ2(x0)|φ1|m dx)1m|Bτ2(x0)|(τm2Bτ2(x0)|f|m dx)1/m( Bτ2(x0)| φ1τ2 |2 dx)12|Bτ2(x0)|(τm2Bτ2(x0)|f|mdx)1/m( Bτ2(x0)|Dφ1|2dx)12εBτ2(x0)|V|z0|(Dφ1)|2dx+c|Bϱ(x0)|ε|z0|p2(ϱmBϱ(x0)|f|mdx)2m, (2.11)

    where cc(n,N,m) and we also used that ϱ/2τ2ϱ. Merging the content of the two above displays, recalling that η1 on Bτ1(x0) and choosing ε>0 sufficiently small, we obtain

    Bτ1(x0)|V|z0|(Duz0)|2dxcBτ2(x0)Bτ1(x0)|V|z0|(Duz0)|2+| V|z0|(uτ2τ1) |2dx+c|Bϱ(x0)||z0|p2(ϱmBϱ(x0)|f|mdx)2m,

    with cc(n,N,λ,Λ,p). At this stage, the classical hole-filling technique, Lemma 2.2 and (2.3) yield (2.7) and the first bound in the statement is proven.

    Step 2: proof of (2.8).

    To show the validity of (2.8), we follow [33, proof of Proposition 3.2] and first observe that if u is a local minimizer of functional F() on Bϱ(x0), setting fϱ(x):=ϱf(x0+ϱx), the map uϱ(x):=ϱ1u(x0+ϱx) is a local minimizer on B1(0) of an integral with the same integrand appearing in (1.1) satisfying (1.6)1,2,3 and fϱ replacing f. This means that (2.10) still holds for all balls Bσ/2(˜x)Bτ1(˜x)Bτ2(˜x)Bσ(˜x)B1(0), with ˜xB1(0) being any point, in particular it remains true if |z0|=0, while condition |z0|0 was needed only in the estimate of term I2 in (2.11), that now requires some change. So, in the definition of the affine map we choose z0=0, u0=(uϱ)Bσ(˜x) and rearrange estimates (2.10) and (2.11) as:

    I1+I3(2.3)cBτ2(˜x)Bτ1(˜x)|Duϱ|p+| uϱ(uϱ)Bσ(˜x)τ2τ1 |pdx,

    and, recalling that φ1W1,p0(Bτ2(˜x),RN), via Sobolev Poincaré, Hölder and Young inequalities and (1.11)2, we estimate

    I2|Bτ2(˜x)|(τ(p)2Bτ2(˜x)|fϱ|(p) dx)1(p)(τp2Bτ2(˜x)|φ1|p dx)1pc|Bτ2(˜x)|(τ(p)2Bτ2(˜x)|fϱ|(p)dx)1(p)( Bτ2(˜x)|Dφ1|pdx)1pc|Bσ(˜x)|ε1/(p1)(σ(p)Bσ(˜x)|fϱ|(p)dx)p(p)(p1)+εBτ2(˜x)|Dφ1|pdx,

    with cc(n,N,p). Plugging the content of the two previous displays in (2.9), reabsorbing terms and applying Lemma 2.2, we obtain

    Bσ/2(˜x)|Duϱ|p dxc Bσ(˜x)| uϱ(uϱ)Bσ(˜x)σ |p dx+c(σ(p)Bσ(˜x)|fϱ|(p)dx)p(p)(p1), (2.12)

    for cc(n,N,Λ,λ,p). Notice that

    n(p(p)(p1)1)pp1, (2.13)

    with equality holding when p<n, while for pn any value of p>1 will do. We then manipulate the second term on the right-hand side of (2.12) as

    (σ(p)Bσ(˜x)|fϱ|(p)dx)p(p)(p1)σpp1n(p(p)(p1)1)( B1(0)|fϱ|(p) dx)p(p)(p1)1Bσ(˜x)|fϱ|(p)dx(2.13)( B1(0)|fϱ|(p) dx)p(p)(p1)1Bσ(˜x)|fϱ|(p) dx=:Bσ(˜x)|Kϱfϱ|(p) dx,

    where we set

    K(p)ϱ:=|B1(0)|1p(p)(p1)fϱpp1(p)L(p)(B1(0)).

    Plugging the content of the previous display in (2.12) and applying Sobolev-Poincaré inequality we get

    Bσ/2(˜x)|Duϱ|pdxc( Bσ(˜x)|Duϱ|p dx)pp+c Bσ(˜x)|Kϱfϱ|(p) dx,

    with cc(n,N,Λ,λ,p). Now we can apply a variant of Gehring lemma [24, Corollary 6.1] to determine a higher integrability exponent ss(n,N,Λ,λ,p) such that 1<sm/(p) and

    ( Bσ/2(˜x)|Duϱ|spdx)1spc( Bσ(˜x)|Duϱ|pdx)1p+cK(p)/pϱ( Bσ(˜x)|fϱ|s(p) dx)1sp

    for cc(n,N,Λ,λ,p). Next, notice that

    K(p)/pϱ=( B1(0)|fϱ|(p)dx)1(p)(p1)1p( B1(0)|fϱ|s(p)dx)1s(p)(p1)1sp,

    so plugging this last inequality in (2.14) and recalling that s(p)m, we obtain

    ( Bσ/2(˜x)|Duϱ|spdx)1spc( Bσ(˜x)|Duϱ|pdx)1p+c( Bσ(˜x)|fϱ|m dx)1m(p1).

    Setting p2:=sp>p above and recalling that ˜xB1(0) is arbitrary, we can fix ˜x=0, scale back to Bϱ(x0) and apply (2.1) to get (2.8) and the proof is complete.

    In this section we prove some excess decay estimates considering separately two cases: when a smallness condition on the excess functional of our local minimizer u is satisfied and when such an estimate does not hold true.

    We start working assuming that a suitable smallness condition on the excess functional E(u;Bϱ(x0)) is fulfilled. In particular, we prove the following proposition.

    Proposition 3.1. Under assumptions (1.6)1,2,3, (1.7) and (1.10), let uW1,p(Ω,RN) be a local minimizer of functional (1.1). Then, for τ0(0,210), there exists ε0ε0(data,τ0)(0,1) and ε1ε1(data,τ0)(0,1) such that the following implications hold true.

    If the conditions

    E(u;Bϱ(x0))ε0|(Du)Bϱ(x0)|, (3.1)

    and

    (ϱmBϱ(x0)|f|m dx)1mε1|(Du)Bϱ(x0)|p22E(u;Bϱ(x0))p2, (3.2)

    are verified on Bϱ(x0), then it holds that

    E(u;Bτ0ϱ(x0))c0τβ00E(u;Bϱ(x0)), (3.3)

    for all β0(0,2/p), with c0c0(data)>0.

    If condition (3.1) holds true and

    (ϱmBϱ(x0)|f|m dx)1m>ε1|(Du)Bϱ(x0)|p22E(u;Bϱ(x0))p2, (3.4)

    is satisfied on Bϱ(x0), then

    E(u;Bτ0ϱ(x0))c0(ϱmBϱ(x0)|f|m dx)1m(p1), (3.5)

    for c0c0(data)>0.

    Proof of Proposition 3.1. For the sake of readability, since all balls considered here are concentric to Bϱ(x0), we will omit denoting the center. Moreover, we will adopt the following notation (Du)Bς(x0)(Du)ς and, for all φCc(Bϱ;RN), we will denote DφL(Bϱ)Dφ. We spilt the proof in two steps.

    Step 1: proof of (3.3).

    With no loss of generality we can assume that E(u;Bϱ)>0, which clearly implies, thanks to (3.1), that |(Du)ϱ|>0.

    We begin proving that condition (3.1) implies that

    Bϱ|Du|pdxc|(Du)ϱ|p, (3.6)

    for a constant cc(p,ε0)>0. Indeed,

    Bϱ|Du|pdxc Bϱ|Du(Du)ϱ|pdx+c|(Du)ϱ|p(1.4)cE(u;Bϱ)p+c|(Du)ϱ|p(3.1)c(εp0+1)|(Du)ϱ|p,

    and (3.6) follows.

    Consider now

    Bϱxu0(x):=|(Du)ϱ|p22(u(x)(u)ϱ(Du)ϱ,xx0)E(u;Bϱ)p/2, (3.7)

    and

    d:=(E(u;Bϱ)|(Du)ϱ|)p2.

    Let us note that we have

    Bϱ|Du0|2dx+dp2Bϱ|Du0|pdx|(Du)ϱ|p2E(u;Bϱ)pBϱ|Du(Du)ϱ|2dx+(E(u;Bϱ)|(Du)ϱ|)p(p2)2|(Du)ϱ|p(p2)2E(u;Bϱ)p22Bϱ|Du(Du)ϱ|pdx1E(u;Bϱ)pBϱ|(Du)ϱ|p2|Du(Du)ϱ|2dx+1E(u;Bϱ)pBϱ|Du(Du)ϱ|pdx1.

    Since |(Du)ϱ|>0 we have that the hypothesis of [12, Lemma 3.2] are satisfied with

    A:=2F((Du)ϱ)|(Du)ϱ|2p. (3.8)

    Then,

    | BϱADu0,Dφ dx|cDφ|(Du)ϱ|2p2E(u;Bϱ)p2(ϱmBϱ|f|m dx)1m+cDφμ(E(u;Bϱ)|(Du)ϱ|)1p[1+(E(u;Bϱ)|(Du)ϱ|)p22](3.1),(3.2)cε1Dφ+cDφμ(ε0)1p[1+εp220].

    Fix ε>0 and let δδ(data,ε)>0 be the one given by [33, Lemma 2.4] and choose ε0 and ε1 sufficiently small such that

    cε1+cμ(ε0)1p[1+εp220]δ. (3.9)

    With this choice of ε0 and ε1 it follows that u0 is almost A-harmonic on Bϱ, in the sense that

    | BϱADu0,Dφ dx|δDφ,

    with A as in (3.8). Hence, by [33, Lemma 2.4] we obtain that there exists h0W1,2(Bϱ;RN) which is A-harmonic, i.e.,

    BϱADh0,Dφ dx=0for all φCc(Bϱ;RN),

    such that

    B3ϱ/4|Dh0|2dx+dp2B3ϱ/4|Dh0|pdx82np, (3.10)

    and

    B3ϱ/4|u0h0ϱ|2+dp2|u0h0ϱ|pdxε. (3.11)

    We choose now τ0(0,210), which will be fixed later on, and estimate

    B2τ0ϱ|u0(x)h0(x0)Dh0(x0),xx0τ0ϱ|2dxcB2τ0ϱ|h0(x)h0(x0)Dh0(x0),xx0τ0ϱ|2dx+cB2τ0ϱ|u0h0τ0ϱ|2dx(3.11)c(τ0ϱ)2supBϱ/2|D2h0|2+cετn+20cτ20B3ϱ/4|Dh0|2dx+cετn+20(3.10)cτ20+cετn+20, (3.12)

    where cc(data)>0 and where we have used the following property of A-harmonic functions

    ϱγsupBϱ/2|D2h0|γcB3ϱ/4|Dh0|γdx, (3.13)

    with γ>1 and c depending on n, N, and on the ellipticity constants of A.

    Now, choosing

    ε:=τn+2p0,

    we have that this together with (3.9) gives that ε0ε0(data,τ0) and ε1ε1(data,τ0). Recalling the definition of u0 in (3.7) and (3.12) we eventually arrive at

    B2τ0ϱ|u(u)ϱ(Du)ϱ,xx0|(Du)ϱ|2p2E(u;Bϱ)p/2(h0(x0)Dh0(x0),xx0)|2(τ0ϱ)2dxc|(Du)ϱ|2pE(u;Bϱ)pτ20, (3.14)

    for cc(data)>0. By a similar computation, always using (3.13), (3.10) and (3.11), we obtain that

    dp2B2τ0ϱ|u0h0(x0)Dh0(x0),xx0τ0ϱ|pdxcdp2(τ0ϱ)psupBϱ/2|D2h0|p+cετn+p0cτp0.

    In this way, as for (3.14), by the definition of u0 in (3.7), we eventually arrive at

    B2τ0ϱ|u(u)ϱ(Du)ϱ,xx0|(Du)ϱ|2p2E(u;Bϱ)p/2(h0(x0)Dh0(x0),xx0)|p(τ0ϱ)pdxcd2p|(Du)ϱ|p(2p)2E(u;Bϱ)p22τp0cE(u;Bϱ)pτ20, (3.15)

    with cc(data).

    Denote now with 2τ0ϱ the unique affine function such that

    2τ0ϱmin affineB2τ0ϱ|u|2dx.

    Hence, by (3.14) and (3.15), we conclude that

    B2τ0ϱ|(Du)ϱ|p2|u2τ0ϱ2τ0ϱ|2+|u2τ0ϱ2τ0ϱ|pdxcτ2E(u;Bϱ)p. (3.16)

    Notice that we have also used the property that

    for , and for any affine function ; see [33, Lemma 2.3].

    Recalling the definition of the excess functional , in (1.4), we can estimate the following quantity as follows

    (3.17)

    where we have used the following property of the affine function

    for a constant ; see for example [33, Lemma 2.2].

    Now, starting from (3.1) and (3.9), we further reduce the size of such that

    (3.18)

    where is the same constant appearing in (3.17). Thus, combining (3.17) and (3.18), we get

    (3.19)

    The information provided by (3.18) combined with (3.16) allow us to conclude that

    (3.20)

    By triangular inequality and (3.19) we also get

    which, therefore, implies that

    (3.21)

    where . By triangular inequality, we can further estimate

    where . We now separately estimate the previous integrals. We begin considering . By Young and triangular inequalities we get

    with . In a similar fashion, we can treat the integral

    where we have used the following property of the affine function

    for a given constant ; see [33, Lemma 2.2]. Finally, the last integral can be treated recalling (3.21) and (2.1), i.e.,

    All in all, combining the previous estimate

    up to choosing such that

    Step 2: proof of (3.5).

    The proof follows by [12, Lemma 2.4] which yields

    Multiplying both sides by we get the desired estimate.

    It remains to considering the case when condition (3.1) does not hold true. We start with two technical lemmas. The first one is an analogous of the Caccioppoli inequality (2.7), where we take in consideration the eventuality .

    Lemma 3.1. Under assumptions (1.6), (1.7) and (1.10), let be a local minimizer of functional (1.1). For every ball and any , it holds that

    (3.22)

    where is defined in (1.4), and .

    Proof. The proof is analogous to estimate (2.7), up to treating in a different way the term in (2.9), taking in consideration the eventuality . Exploiting (1.10) and fact that , an application of the Sobolev-Poincaré inequality yields

    (3.23)

    where and we also used that . Hence, proceeding as in the proof of (2.7), we obtain that

    with . Concluding as in the proof of (2.7), we eventually arrive at (3.22). We will also need the following result.

    Lemma 3.2. Under assumptions (1.6), (1.7) and (1.10), let be a local minimizer of functional (1.1). For any and any it holds that

    (3.24)

    for any , with .

    Proof. Given the regularity properties of the integrand , we have that a local minimizer of (1.1) solves weakly the following integral identity (see [42, Lemma 7.3])

    (3.25)

    Now, fix and split

    We begin estimating the first integral . For we get

    (3.26)

    On the other hand, the integral can be estimated as follows

    Combining the inequalities above we obtain (3.24).

    In this setting the analogous result of Proposition 3.1 is the following one.

    Proposition 3.2. Under assumptions (1.6), (1.7) and (1.10), let be a local minimizer of functional (1.1). Then, for any and any , there exists such that if the smallness conditions

    (3.27)

    are satisfied on a ball , then

    (3.28)

    for any , with is the exponent in (3.34), and .

    Proof. We adopt the same notations used in the proof of Proposition 3.1. Let us begin noticing that condition (3.27) implies the following estimate

    (3.29)

    Indeed, by (1.4) and (3.27), we have

    Consider now

    for , which will be fixed later on. Applying (3.24) to the function yields

    For any and and let be the one given by [17, Lemma 1.1]. Then, up to choosing , and sufficiently small, we arrive at

    Then, Lemma 1.1 in [17] implies

    up to taking as small as needed. Now, denoting with , we have that

    Now, we choose , with being the exponent given by (2.8). Note that by the proof of (2.8) it actually follows that . Thus, choosing (where is given by (3.34)) we arrive at

    By Hölder's Inequality, we have that

    (3.30)

    Hence, since by (2.3) , an application of estimates (2.8) and (3.29) now yields

    (3.31)

    with .

    On the other hand, by classical properties of -harmonic functions, we have that

    (3.32)

    Hence, combining (3.30)–(3.32), we get that

    (3.33)

    Let us recall that, for any , given the -harmonic function we have

    (3.34)

    Moreover, using Jensen's Inequality we can estimate the following difference as follows

    Thus, up to taking sufficiently small, by the triangular inequality, we obtain that

    Hence, (2.2) yield

    and

    Then,

    and the desired estimate (3.28) follows.

    This section is devoted to the proof of Theorem 1.1. First, we prove the following proposition.

    Proposition 4.1. Under assumptions (1.6), (1.7) and (1.10), let be a local minimizer of functional (1.1). Then, there exists such that if the following condition

    (4.1)

    is satisfied on , for some , then

    (4.2)

    for .

    Proof. For the sake of readability, since all balls considered in the proof are concentric to , we will omit denoting the center.

    Let us start fixing an exponent such that

    (4.3)

    where and are the exponents appearing in Propositions 3.1 and 3.2. Moreover, given the constant and from Propositions 3.1 and 3.2, choose such that

    (4.4)

    With the choice of as in (4.4) above, we can determine the constant and of Proposition 3.1. Now, we proceed applying Proposition 3.2 taking and as in (4.4) there. This determines the constant and . We consider a ball such that

    (4.5)

    and

    (4.6)

    where the constant , with appearing in (3.5) and in (3.28). In particular, see that by (4.5) and (4.6) we are in the case when (4.1) does hold true.

    Now, we recall Proposition 3.2. Seeing that is satisfied (being (4.5)) we only check whether is verified too. If is satisfied then we obtain from (3.28), with in (4.4) that

    (4.7)

    where the last inequality follows from (4.5) and (4.6). If on the other hand it holds , by Proposition 3.1, then by (3.3) or (3.5) we eventually arrive at the same estimate (4.7).

    Iterating now the seam argument we arrive at

    and the estimate

    holds true. By the inequality above we have that for any

    Applying a standard interpolation argument we conclude that, for any , it holds

    (4.8)

    where . The desired estimate (4.2) now follows.

    Proof of Theorem 1.1. We proceed following the same argument used in [33, Theorem 1.5]. We star proving that, for any and any , with positive measure, we have that

    (4.9)

    Indeed, fix which will be chosen later on. Then, we have that

    (4.10)

    The first integral on the righthand side of (4.10) can be estimated in the following way

    On the other hand, the second integral can be estimated recalling the definition of the -norm. Indeed,

    Hence, putting all the estimates above in (4.10), choosing , we obtain (4.9).

    Now, recalling condition (1.2) we have that

    where is the one obtained in the proof of Proposition 4.1. From this it follows that, we can choose a radius such that

    (4.11)

    We want to show that the set appearing in (1.3) can be characterized by

    thus fixing and . We first star noting that the the set defined in (1.4) is such that . Indeed, let us consider the set

    (4.12)

    which is such that by standard Lebesgue's Theory. Moreover, by (2.5) it follows that

    so that, and we eventually obtained that . Now we show that is open. Let us fix and find a radius such that

    (4.13)

    By absolute continuity of the functional we have that there exists an open neighbourhood such that, for any it holds

    (4.14)

    This prove that is open. Now let us start noting that (4.11) and (4.14) yield that condition (4.1) is satisfied with . Hence, an application of Proposition 4.1 yields

    for any . Thus concluding the proof.

    The authors declare they have not used Artificial Intelligence (AI) tools in the creation of this article.

    The author is supported by INdAM Projects "Fenomeni non locali in problemi locali", CUP_E55F22000270001 and "Problemi non locali: teoria cinetica e non uniforme ellitticità", CUP_E53C220019320001, and also by the Project "Local vs Nonlocal: mixed type operators and nonuniform ellipticity", CUP_D91B21005370003.

    The author declares no conflict of interest.



    Conflict of interest



    The authors declare no conflict of interest.

    Author contributions



    Allen Jonathan Román: investigation, evaluation, conceptualization, and writing; Jamelah Zena Travis: investigation, evaluation, and writing; Juan Carlos Martínez Ávila: investigation; Tim A. Osswald: conceptualization.

    [1] Umar HY, Okore NE, Toryila M, et al. Evaluation of impact of climatic factors on latex yield of hevea brasiliensis (2017) . doi: 10.20431/2454-6224.0305004
    [2] Rao P, Vijayakumar KR (1992)  Natural rubber: Biology, Cultivation and Technology Development in Crop Science Elsevier Science.
    [3] Mesike CS, Esekhade TU (2014) Rainfall variability and rubber production in Nigeria. Afr J Environ Sci Technol 8: 54-57. doi: 10.5897/AJEST2013.1593
    [4] Kenneth OO, Okeoghene AE (2006) Evaluation of five weather characters on latex yield in hevea brasiliensis. Int J Agr Res 1: 234-239. doi: 10.3923/ijar.2006.234.239
    [5] Craciun G, Manaila E, Stelescu MD (2016) New elastomeric materials based on natural rubber obtained by electron beam irradiation for food and pharmaceutical use. Materials 9: 999. doi: 10.3390/ma9120999
    [6] Osswald TA (2017)  Understanding Polymer Processing München: Carl Hanser Verlag GmbH Publications. doi: 10.3139/9781569906484
    [7] Kuang X, Chen K, Dunn CK, et al. (2018) 3D printing of highly stretchable, shape-memory, and self-healing elastomer toward novel 4D printing. ACS Appl Mater Interfaces 10: 7381-7388. doi: 10.1021/acsami.7b18265
    [8] Choi JH, Kang HJ, Jeong HY, et al. (2005) Heat aging effects on material property and the fatigue life of vulcanized natural rubber, and fatigue life prediction equations. J Mech Sci Technol 19: 1229-1242. doi: 10.1007/BF02984044
    [9] Martinez JRS, Le Cam JB, Balandraud X, et al. (2013) Mechanisms of deformation in crystallizable natural rubber. Part 1: thermal characterization. Polymer 54: 2717-2726. doi: 10.1016/j.polymer.2013.03.011
    [10] Brüning K, Schneider K, Roth SV, et al. (2012) Kinetics of strain-induced crystallization in natural rubber studied by WAXD: dynamic and impact tensile experiments. Macromolecules 45: 7914-7919. doi: 10.1021/ma3011476
    [11] Wei Y, Zhang H, Wu L, et al. (2017) A review on characterization of molecular structure of natural rubber. MOJ Poly Sci 1: 197-199.
    [12] Kitaura T, Kobayashi M, Tarachiwin L, et al. (2018) Characterization of natural rubber end groups using high-sensitivity NMR. Macromol Chem Phys 219: 1700331. doi: 10.1002/macp.201700331
    [13] Sakdapipanich JT, Rojruthai P (2012) Molecular structure of natural rubber and its characteristics based on recent evidence. Biotechnology-Molecular Studies and Novel Applications for Improved Quality of Human Life Croatia: InTech, 213.
    [14] Tanaka Y (2001) Structural characterization of natural polyisoprenes: Solve the mystery of natural rubber based on structural study. Rubber Chem Technol 74: 355-375. doi: 10.5254/1.3547643
    [15] Tanaka Y, Sato H, Kageyu A (1983) Structure and biosynthesis mechanism of natural cis-polyisoprene from Goldenrod. Rubber Chem Technol 56: 299-303. doi: 10.5254/1.3538125
    [16] Tangpakdee J, Tanaka Y, Ogura K, et al. (1997) Structure of in vitro synthesized rubber from fresh bottom fraction of Hevea latex. Phytochemistry 45: 275-281. doi: 10.1016/S0031-9422(96)00839-4
    [17] James CR (1984)  NMR and Macromolecules Washington: American Chemical Society.
    [18] Tanaka Y, Takeuchi Y, Kobayashi M, et al. (1971) Characterization of diene polymers. I. Infrared and NMR studies: nonadditive behavior of characteristic infrared bands. J Polym Sci Pol Phys 9: 43-57. doi: 10.1002/pol.1971.160090104
    [19] Sato H, Tanaka Y (1979) 1H-NMR study of polyisoprenes. Polym Sci: Polym Chem Ed 17: 3551-3558. doi: 10.1002/pol.1979.170171113
    [20] Sotta P, Albouy PA (2020) Strain-induced crystallization in natural rubber: flory's theory revisited. Macromolecules 53: 3097-3109. doi: 10.1021/acs.macromol.0c00515
    [21] Lakes RS (2004) Viscoelastic measurement techniques. Rev Sci Instrum 75: 797-810. doi: 10.1063/1.1651639
    [22] Bruker (2014)  Bruker Avance Beginners Guide Bruker Corporation Publishing, 23-30.
    [23] Chen HY (1962) Determination of cis-1,4 and trans-1,4 contents of polyisoprenes by high resolution nuclear magnetic resonance. Anal Chem 34: 1793-1795. doi: 10.1021/ac60193a038
    [24] Basfar AA, Abdel-Aziz MM, Mofti S (2002) Influence of different curing systems on the physico-mechanical properties and stability of SBR and NR rubbers. Radiat Phys Chem 63: 81-87. doi: 10.1016/S0969-806X(01)00486-8
    [25] Gooding EGB (1952) Studies in the Physiology of Latex III. Effects of Various Factors on the Concentration of Latex of Hevea brasiliensis. New Phytol 51: 139-153. doi: 10.1111/j.1469-8137.1952.tb06122.x
    [26] Ellis EC, Turgeon R, Spanswick RM (1992) Quantitative analysis of photosynthate unloading in developing seeds of phaseolus vulgaris L.: II. pathway and turgor sensitivity. Plant Physiol 99: 643-651. doi: 10.1104/pp.99.2.643
    [27] Niklas KJ (1989) Mechanical behavior of plant tissues as inferred from the theory of pressurized cellular solids. Am J Bot 76: 929-937. doi: 10.1002/j.1537-2197.1989.tb15071.x
    [28] Osswald TA, Rudolph N (2015)  Polymer Rheology München: Carl Hanser Verlag GmbH Publications.
    [29] Minoura Y, Kamagata K (1964) Stress relaxation of raw natural rubber. J Appl Polym Sci 8: 1077-1087. doi: 10.1002/app.1964.070080305
    [30] Tosaka M, Kawakami D, Senoo K, et al. (2006) Crystallization and stress relaxation in highly stretched samples of natural rubber and its synthetic analogue. Macromolecules 39: 5100-5105. doi: 10.1021/ma060407+
    [31] Lakes R, Lakes RS (2009)  Viscoelastic Materials UK: Cambridge University Press. doi: 10.1017/CBO9780511626722
    [32] Tzoganakis C, Vlachopoulos J, Hamielec AE (1988) Production of controlled-rheology polypropylene resins by peroxide promoted degradation during extrusion. Polym Eng Sci 28: 170-180. doi: 10.1002/pen.760280308
    [33] Wainwright-Déri E Rubber–does ‘natural’ mean sustainable? (2018) .Available from: https://www.spott.org/news/rubber-does-natural-mean-sustainable/.
  • Reader Comments
  • © 2021 the Author(s), licensee AIMS Press. This is an open access article distributed under the terms of the Creative Commons Attribution License (http://creativecommons.org/licenses/by/4.0)
通讯作者: 陈斌, bchen63@163.com
  • 1. 

    沈阳化工大学材料科学与工程学院 沈阳 110142

  1. 本站搜索
  2. 百度学术搜索
  3. 万方数据库搜索
  4. CNKI搜索

Metrics

Article views(3244) PDF downloads(131) Cited by(1)

Figures and Tables

Figures(13)  /  Tables(2)

/

DownLoad:  Full-Size Img  PowerPoint
Return
Return

Catalog