Review

Recent progress on ceria doping and shaping strategies for solar thermochemical water and CO2 splitting cycles

  • Received: 29 March 2019 Accepted: 29 May 2019 Published: 26 July 2019
  • Thermochemical redox cycling for either water or CO2 splitting is a promising strategy to convert solar energy into clean fuels. Such splitting reaction can convert water and recycled CO2 into H2 and CO respectively, the building blocks for the preparation of various synthetic liquid fuels. Attractively, CO2 is valorized in this way and can be used as a carbon-neutral fuel. However, the efficiency of the solar thermochemical process has to be improved to achieve an economically viable fuel production. For this purpose, an optimization of the reactive materials regarding both their chemical activity and long-term stability is a key requirement. To date, ceria is considered as the benchmark material for thermochemical redox cycles. Indeed, it is able to maintain a single cubic fluorite phase during thermal cycling over a large range of oxygen non-stoichiometry and also provides thermodynamically favorable oxidation. However, it suffers from a high reduction temperature and a low reduction extent. Several doping strategies of ceria have been developed to increase its redox activity and long-term performance stability. This paper provides an overview of the efforts made to enhance the thermochemical performance of ceria by investigation of dopant incorporation and material shaping for designed morphologies and microstructures.

    Citation: Anita Haeussler, Stéphane Abanades, Julien Jouannaux, Martin Drobek, André Ayral, Anne Julbe. Recent progress on ceria doping and shaping strategies for solar thermochemical water and CO2 splitting cycles[J]. AIMS Materials Science, 2019, 6(5): 657-684. doi: 10.3934/matersci.2019.5.657

    Related Papers:

  • Thermochemical redox cycling for either water or CO2 splitting is a promising strategy to convert solar energy into clean fuels. Such splitting reaction can convert water and recycled CO2 into H2 and CO respectively, the building blocks for the preparation of various synthetic liquid fuels. Attractively, CO2 is valorized in this way and can be used as a carbon-neutral fuel. However, the efficiency of the solar thermochemical process has to be improved to achieve an economically viable fuel production. For this purpose, an optimization of the reactive materials regarding both their chemical activity and long-term stability is a key requirement. To date, ceria is considered as the benchmark material for thermochemical redox cycles. Indeed, it is able to maintain a single cubic fluorite phase during thermal cycling over a large range of oxygen non-stoichiometry and also provides thermodynamically favorable oxidation. However, it suffers from a high reduction temperature and a low reduction extent. Several doping strategies of ceria have been developed to increase its redox activity and long-term performance stability. This paper provides an overview of the efforts made to enhance the thermochemical performance of ceria by investigation of dopant incorporation and material shaping for designed morphologies and microstructures.


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    [1] Meredig B, Wolverton C (2009) First-principles thermodynamic framework for the evaluation of thermochemical H2O- or CO2 -splitting materials. Phys Rev B 80: 245119. doi: 10.1103/PhysRevB.80.245119
    [2] Marxer D, Furler P, Takacs M, et al. (2017) Solar thermochemical splitting of CO2 into separate streams of CO and O2 with high selectivity, stability, conversion, and efficiency. Energ Environ Sci 10: 1142–1149. doi: 10.1039/C6EE03776C
    [3] Siegel NP, Miller JE, Ermanoski I, et al. (2013) Factors affecting the efficiency of solar driven metal oxide thermochemical cycles. Ind Eng Chem Res 52: 3276–3286. doi: 10.1021/ie400193q
    [4] Muhich CL, Ehrhart BD, Al-Shankiti I, et al. (2015) A review and perspective of efficient hydrogen generation via solar thermal water splitting. WIREs Energy Environ 5: 261–287.
    [5] Bhosale RR, Takalkar G, Sutar P, et al. (2019) A decade of ceria based solar thermochemical H2O/CO2 splitting cycle. Int J Hydrogen Energ 44: 34–60. doi: 10.1016/j.ijhydene.2018.04.080
    [6] McDaniel AH (2017) Renewable energy carriers derived from concentrating solar power and nonstoichiometric oxides. Curr Opin Green Sustain Chem 4: 37–43. doi: 10.1016/j.cogsc.2017.02.004
    [7] Furler P, Scheffe JR, Steinfeld A (2012) Syngas production by simultaneous splitting of H2O and CO2 via ceria redox reactions in a high-temperature solar reactor. Energ Environ Sci 5: 6098–6103. doi: 10.1039/C1EE02620H
    [8] Haeussler A, Abanades S, Jouannaux J, et al. (2018) Non-stoichiometric redox active perovskite materials for solar thermochemical fuel production: a review. Catalysts 8: 611–631. doi: 10.3390/catal8120611
    [9] McDaniel AH, Miller EC, Arifin D, et al. (2013) Sr- and Mn-doped LaAlO3−δ for solar thermochemical H2 and CO production. Energ Environ Sci 6: 2424–2428. doi: 10.1039/c3ee41372a
    [10] Scheffe JR, Weibel D, Steinfeld A (2013) Lanthanum-strontium-manganese perovskites as redox materials for solar thermochemical splitting of H2O and CO2. Energ Fuel 27: 4250–4257. doi: 10.1021/ef301923h
    [11] Demont A, Abanades S (2014) High redox activity of Sr-substituted lanthanum manganite perovskites for two-step thermochemical dissociation of CO2. RSC Adv 4: 54885–54891. doi: 10.1039/C4RA10578H
    [12] Demont A, Abanades S, Beche E (2014) Investigation of perovskite structures as oxygen-exchange redox materials for hydrogen production from thermochemical two-step water-splitting cycles. J Phys Chem C 118: 12682–12692. doi: 10.1021/jp5034849
    [13] McDaniel AH, Ambrosini A, Coker EN, et al. (2014) Nonstoichiometric perovskite oxides for solar thermochemical H2 and CO production. Energ Procedia 49: 2009–2018. doi: 10.1016/j.egypro.2014.03.213
    [14] Yang CK, Yamazaki Y, Aydin A, et al. (2014) Thermodynamic and kinetic assessments of strontium-doped lanthanum manganite perovskites for two-step thermochemical water splitting. J Mater Chem A 2: 13612–13623. doi: 10.1039/C4TA02694B
    [15] Deml AM, Stevanović V, Holder AM, et al. (2014) Tunable oxygen vacancy formation energetics in the complex perovskite oxide SrxLa1–xMnyAl1–yO3. Chem Mater 26: 6595–6602. doi: 10.1021/cm5033755
    [16] Ezbiri M, Takacs M, Theiler D, et al. (2017) Tunable thermodynamic activity of LaxSr1−xMnyAl1−yO3−δ (0 ≤ x ≤ 1, 0 ≤ y ≤ 1) perovskites for solar thermochemical fuel synthesis. J Mater Chem A 5: 4172–4182. doi: 10.1039/C6TA06644E
    [17] Demont A, Abanades S (2015) Solar thermochemical conversion of CO2 into fuel via two-step redox cycling of non-stoichiometric Mn-containing perovskite oxides. J Mater Chem A 3: 3536–3546. doi: 10.1039/C4TA06655C
    [18] Ezbiri M, Allen KM, Gàlvez ME, et al. (2015) Design principles of perovskites for thermochemical oxygen separation. Chem Sus Chem 8: 1966–1971. doi: 10.1002/cssc.201500239
    [19] Cooper T, Scheffe JR, Galvez ME, et al. (2015) Lanthanum manganite perovskites with Ca/Sr A-site and Al B-site doping as effective oxygen exchange materials for solar thermochemical fuel production. Energy Technol 3: 1130–1142. doi: 10.1002/ente.201500226
    [20] Sastre D, Carrillo AJ, Serrano DP, et al. (2017) Exploring the redox behavior of La0.6Sr0.4Mn1−xAlxO3 perovskites for CO2 -splitting in thermochemical cycles. Top Catal 60: 1108–1118.
    [21] Barcellos DR, Sanders MD, Tong J, et al. (2018) BaCe0.25Mn0.75O3−δ-a promising perovskite-type oxide for solar thermochemical hydrogen production. Energ Environ Sci 11: 3256–3265.
    [22] Nair MM, Abanades S (2018) Experimental screening of perovskite oxides as efficient redox materials for solar thermochemical CO2 conversion. Sustain Energ Fuels 2: 843–854. doi: 10.1039/C7SE00516D
    [23] Wang L, Al-Mamun M, Liu P, et al. (2018) Notable hydrogen production on LaxCa1−xCoO3 perovskites via two-step thermochemical water splitting. J Mater Sci 53: 6796–6806. doi: 10.1007/s10853-018-2004-2
    [24] Chen Z, Jiang Q, Cheng F, et al. (2019) Sr- and Co-doped LaGaO3–δwith high O2 and H2 yields in solar thermochemical water splitting. J Mater Chem A 7: 6099–6112. doi: 10.1039/C8TA11957K
    [25] Agrafiotis C, Roeb M, Sattler C (2015) A review on solar thermal syngas production via redox pair-based water/carbon dioxide splitting thermochemical cycles. Renew Sust Energ Rev 42: 254–285. doi: 10.1016/j.rser.2014.09.039
    [26] Kubicek M, Bork AH, Rupp JLM (2017) Perovskite oxides-a review on a versatile material class for solar-to-fuel conversion processes. J Mater Chem A 5: 11983–12000. doi: 10.1039/C7TA00987A
    [27] Sunarso J, Hashim SS, Zhu N, et al. (2017) Perovskite oxides applications in high temperature oxygen separation, solid oxide fuel cell and membrane reactor: a review. Prog Energ Combust 61: 57–77. doi: 10.1016/j.pecs.2017.03.003
    [28] Kaneko H, Miura T, Ishihara H, et al. (2007) Reactive ceramics of CeO2–MOx(M = Mn, Fe, Ni, Cu) for H2 generation by two-step water splitting using concentrated solar thermal energy. Energy 32: 656–663. doi: 10.1016/j.energy.2006.05.002
    [29] Andersson DA, Simak SI, Skorodumova NV, et al. (2007) Theoretical study of CeO2 doped with tetravalent ions. Phys Rev B 76: 174119. doi: 10.1103/PhysRevB.76.174119
    [30] Ackermann S, Sauvin L, Castiglioni R, et al. (2015) Kinetics of CO2 reduction over nonstoichiometric ceria. J Phys Chem C 119: 16452–16461. doi: 10.1021/acs.jpcc.5b03464
    [31] Kaneko H, Ishihara H, Taku S, et al. (2008) Cerium ion redox system in CeO2–x Fe2O3 solid solution at high temperatures (1273–1673 K) in the two-step water-splitting reaction for solar H2 generation. J Mater Sci 43: 3153–3161. doi: 10.1007/s10853-008-2499-z
    [32] Roeb M, Neises M, Monnerie N, et al. (2012) Materials-related aspects of thermochemical water and carbon dioxide splitting: a review. Materials 5: 2015–2054. doi: 10.3390/ma5112015
    [33] Montini T, Melchionna M, Monai M, et al. (2016) Fundamentals and catalytic applications of CeO2 -based materials. Chem Rev 116: 5987–6041. doi: 10.1021/acs.chemrev.5b00603
    [34] Trovarelli A (1996) Catalytic properties of ceria and CeO2 -containing materials. Catal Rev 38: 439–520. doi: 10.1080/01614949608006464
    [35] Bulfin B, Lowe AJ, Keogh KA, et al. (2013) Analytical model of CeO2 oxidation and reduction. J Phys Chem C 117: 24129–24137. doi: 10.1021/jp406578z
    [36] Bulfin B, Vieten J, Agrafiotis C, et al. (2017) Applications and limitations of two step metal oxide thermochemical redox cycles; a review. J Mater Chem A 5: 18951–18966. doi: 10.1039/C7TA05025A
    [37] Miller JE, McDaniel AH, Allendorf MD (2014) Considerations in the design of materials for solar-driven fuel production using metal-oxide thermochemical cycles. Adv Energy Mater 4: 1300469. doi: 10.1002/aenm.201300469
    [38] Abanades S, Flamant G (2006) Thermochemical hydrogen production from a two-step solar-driven water-splitting cycle based on cerium oxides. Sol Energy 80: 1611–1623. doi: 10.1016/j.solener.2005.12.005
    [39] Chueh WC, Haile SM (2009) Ceria as a thermochemical reaction medium for selectively generating syngas or methane from H2O and CO2. ChemSusChem 2: 735–739. doi: 10.1002/cssc.200900138
    [40] Chueh WC, Falter C, Abbott M, et al. (2010) High-flux solar-driven thermochemical dissociation of CO2 and H2O using nonstoichiometric ceria. Science 330: 1797–1801. doi: 10.1126/science.1197834
    [41] Carrillo RJ, Scheffe JR (2017) Advances and trends in redox materials for solar thermochemical fuel production. Sol Energy 156: 3–20. doi: 10.1016/j.solener.2017.05.032
    [42] Scheffe JR, Steinfeld A (2014) Oxygen exchange materials for solar thermochemical splitting of H2O and CO2 : a review. Mater Today 17: 341–348. doi: 10.1016/j.mattod.2014.04.025
    [43] Chueh WC, Haile SM (2010) A thermochemical study of ceria: exploiting an old material for new modes of energy conversion and CO2 mitigation. Philos T Roy Soc A 368: 3269–3294. doi: 10.1098/rsta.2010.0114
    [44] Rager T (2012) Re-evaluation of the efficiency of a ceria-based thermochemical cycle for solar fuel generation. Chem Commun 48: 10520–10522. doi: 10.1039/c2cc34617f
    [45] Rhodes NR, Bobek MM, Allen KM, et al. (2015) Investigation of long term reactive stability of ceria for use in solar thermochemical cycles. Energy 89: 924–931. doi: 10.1016/j.energy.2015.06.041
    [46] Ji HI, Davenport TC, Ignatowich MJ, et al. (2017) Gas-phase vs. material-kinetic limits on the redox response of nonstoichiometric oxides. Phys Chem Chem Phys 19: 7420–7430.
    [47] Furler P, Scheffe J, Marxer D, et al. (2014) Thermochemical CO2 splitting via redox cycling of ceria reticulated foam structures with dual-scale porosities. Phys Chem Chem Phys 16: 10503–10511. doi: 10.1039/C4CP01172D
    [48] Farooqui AE, Pica AM, Marocco P, et al. (2018) Assessment of kinetic model for ceria oxidation for chemical-looping CO2 dissociation. Chem Eng J 346: 171–181. doi: 10.1016/j.cej.2018.04.041
    [49] Arifin D, Weimer AW (2018) Kinetics and mechanism of solar-thermochemical H2 and CO production by oxidation of reduced CeO2. Sol Energy 160: 178–185. doi: 10.1016/j.solener.2017.11.075
    [50] Ackermann S, Scheffe JR, Steinfeld A (2014) Diffusion of oxygen in ceria at elevated temperatures and its application to H2O/CO2 splitting thermochemical redox cycles. J Phys Chem C 118: 5216–5225. doi: 10.1021/jp500755t
    [51] Davenport TC, Yang CK, Kucharczyk CJ, et al. (2016) Maximizing fuel production rates in isothermal solar thermochemical fuel production. Appl Energ 183: 1098–1111. doi: 10.1016/j.apenergy.2016.09.012
    [52] Bader R, Venstrom LJ, Davidson JH, et al. (2013) Thermodynamic analysis of isothermal redox cycling of ceria for solar fuel production. Energ Fuel 27: 5533–5544. doi: 10.1021/ef400132d
    [53] Meng QL, Lee C, Ishihara T, et al. (2011) Reactivity of CeO2 -based ceramics for solar hydrogen production via a two-step water-splitting cycle with concentrated solar energy. Int J Hydrogen Energ 36: 13435–13441. doi: 10.1016/j.ijhydene.2011.07.089
    [54] Meng QL, Lee C, Shigeta S, et al. (2012) Solar hydrogen production using Ce1−xLixO2−δ solid solutions via a thermochemical, two-step water-splitting cycle. J Solid State Chem 194: 343–351. doi: 10.1016/j.jssc.2012.05.024
    [55] Scheffe JR, Steinfeld A (2012) Thermodynamic analysis of cerium-based oxides for solar thermochemical fuel production. Energ Fuel 26: 1928–1936. doi: 10.1021/ef201875v
    [56] Muhich C, Steinfeld A (2017) Principles of doping ceria for the solar thermochemical redox splitting of H2O and CO2 . J Mater Chem A 5: 15578–15590. doi: 10.1039/C7TA04000H
    [57] Jaiswal N, Kumar D, Upadhyay S, et al. (2013) Effect of Mg and Sr co-doping on the electrical properties of ceria-based electrolyte materials for intermediate temperature solid oxide fuel cells. J Alloy Compd 577: 456–462. doi: 10.1016/j.jallcom.2013.06.094
    [58] Scheffe JR, Jacot R, Patzke GR, et al. (2013) Synthesis, characterization, and thermochemical redox performance of Hf4+, Zr4+, and Sc3+ doped ceria for splitting CO2 . J Phys Chem C 117: 24104–24114. doi: 10.1021/jp4050572
    [59] Lee C, Meng QL, Kaneko H, et al. (2012) Solar hydrogen productivity of ceria-scandia solid solution using two-step water-splitting cycle. J Sol Energ-T Asme 135: 011002–011008. doi: 10.1115/1.4006876
    [60] Jiang Q, Zhou G, Jiang Z, et al. (2014) Thermochemical CO2 splitting reaction with CexM1−xO2−δ(M = Ti4+, Sn4+, Hf 4+ , Zr4+, La3+, Y3+ and Sm3+) solid solutions. Sol Energy 99: 55–66. doi: 10.1016/j.solener.2013.10.021
    [61] Ramos-Fernandez EV, Shiju NR, Rothenberg G (2014) Understanding the solar-driven reduction of CO2 on doped ceria. RSC Adv 4: 16456–16463. doi: 10.1039/C4RA01242A
    [62] Gokon N, Suda T, Kodama T (2015) Oxygen and hydrogen productivities and repeatable reactivity of 30-mol%-Fe-, Co-, Ni-, Mn-doped CeO2−δ for thermochemical two-step water-splitting cycle. Energy 90: 1280–1289. doi: 10.1016/j.energy.2015.06.085
    [63] Le Gal A, Abanades S (2012) Dopant Incorporation in ceria for enhanced water-splitting activity during solar thermochemical hydrogen generation. J Phys Chem C 116: 13516–13523.
    [64] Bhosale RR, Takalkar GD (2018) Nanostructured co-precipitated Ce0.9Ln0.1O2 (Ln = La, Pr, Sm, Nd, Gd, Tb, Dy, or Er) for thermochemical conversion of CO2 . Ceram Int 44: 16688–16697.
    [65] Meng QL, Lee CI, Kaneko H, et al. (2012) Solar thermochemical process for hydrogen production via two-step water splitting cycle based on Ce1−xPrxO2−δ redox reaction. Thermochim Acta 532: 134–138. doi: 10.1016/j.tca.2011.01.028
    [66] Jacot R, Moré R, Michalsky R, et al. (2017) Trends in the phase stability and thermochemical oxygen exchange of ceria doped with potentially tetravalent metals. J Mater Chem A 5: 19901–19913. doi: 10.1039/C7TA04063F
    [67] Bonk A, Maier AC, Schlupp MVF, et al. (2015) The effect of dopants on the redox performance, microstructure and phase formation of ceria. J Power Sources 300: 261–271. doi: 10.1016/j.jpowsour.2015.09.073
    [68] Montini T, Hickey N, Fornasiero P, et al. (2005) Variations in the extent of pyrochlore-type cation ordering in Ce2Zr2O8: a t‗-k pathway to low-temperature reduction. Chem Mater 17: 1157–1166. doi: 10.1021/cm0481574
    [69] Tani E, Yoshimura M, Somiya S (1983) Revised phase diagram of the system ZrO2–CeO2below 1400 °C. J Am Ceram Soc 66: 506–510. doi: 10.1111/j.1151-2916.1983.tb10591.x
    [70] Thomson JB, Armstrong AR, Bruce PG (1996) A new class of pyrochlore solid solution formed by chemical intercalation of oxygen. J Am Chem Soc 118: 11129–11133. doi: 10.1021/ja961202r
    [71] Montini T, Bañares MA, Hickey N, et al. (2004) Promotion of reduction in Ce0.5Zr0.5O2 : the pyrochlore structure as effect rather than cause? Phys Chem Chem Phys 6: 1–3.
    [72] Abanades S, Legal A, Cordier A, et al. (2010) Investigation of reactive cerium-based oxides for H2 production by thermochemical two-step water-splitting. J Mater Sci 45: 4163–4173. doi: 10.1007/s10853-010-4506-4
    [73] Abanades S, Le Gal A (2012) CO2 splitting by thermo-chemical looping based on ZrxCe1−xO2 oxygen carriers for synthetic fuel generation. Fuel 102: 180–186. doi: 10.1016/j.fuel.2012.06.068
    [74] Takacs M, Scheffe JR, Steinfeld A (2015) Oxygen nonstoichiometry and thermodynamic characterization of Zr doped ceria in the 1573–1773 K temperature range. Phys Chem Chem Phys 17: 7813–7822. doi: 10.1039/C4CP04916K
    [75] Le Gal A, Abanades S, Bion N, et al. (2013) Reactivity of doped ceria-based mixed oxides for solar thermochemical hydrogen generation via two-step water-splitting cycles. Energ Fuel 27: 6068–6078. doi: 10.1021/ef4014373
    [76] Fornasiero P, Dimonte R, Rao GR, et al. (1995) Rh-loaded CeO2–ZrO2 solid-solutions as highly efficient oxygen exchangers: dependence of the reduction behavior and the oxygen storage capacity on the structural-properties. J Catal 151: 168–177. doi: 10.1006/jcat.1995.1019
    [77] Le Gal A, Abanades S (2011) Catalytic investigation of ceria-zirconia solid solutions for solar hydrogen production. Int J Hydrogen Energy 36: 4739–4748. doi: 10.1016/j.ijhydene.2011.01.078
    [78] Vlaic G, Fornasiero P, Geremia S, et al. (1997) Relationship between the Zirconia-promoted reduction in the Rh-loaded Ce0.5Zr0.5O2 mixed oxide and the Zr–O local structure. J Catal 168: 386–392.
    [79] Yang Z, Woo TK, Hermansson K (2006) Effects of Zr doping on stoichiometric and reduced ceria: a first-principles study. J Chem Phys 124: 224704. doi: 10.1063/1.2200354
    [80] Esch F (2005) Electron localization determines defect formation on ceria substrates. Science 309: 752–755. doi: 10.1126/science.1111568
    [81] Shah PR, Kim T, Zhou G, et al. (2006) Evidence for entropy effects in the reduction of ceria-zirconia solutions. Chem Mater 18: 5363–5369. doi: 10.1021/cm061374f
    [82] Muhich C, Hoes M, Steinfeld A (2018) Mimicking tetravalent dopant behavior using paired charge compensating dopants to improve the redox performance of ceria for thermochemically splitting H2O and CO2. Acta Mater 144: 728–737. doi: 10.1016/j.actamat.2017.11.022
    [83] Bulfin B, Lange M, de Oliveira L, et al. (2016) Solar thermochemical hydrogen production using ceria zirconia solid solutions: efficiency analysis. Int J Hydrogen Energy 41: 19320–19328. doi: 10.1016/j.ijhydene.2016.05.211
    [84] Ganzoury MA, Fateen SEK, El Sheltawy ST, et al. (2016) Thermodynamic and efficiency analysis of solar thermochemical water splitting using Ce–Zr mixtures. Sol Energy 135: 154–162. doi: 10.1016/j.solener.2016.05.053
    [85] Le Gal A, Abanades S, Flamant G (2011) CO2 and H2O splitting for thermochemical production of solar fuels using nonstoichiometric ceria and ceria/zirconia solid solutions. Energ Fuel 25: 4836–4845. doi: 10.1021/ef200972r
    [86] Muhich CL, Blaser S, Hoes MC, et al. (2018) Comparing the solar-to-fuel energy conversion efficiency of ceria and perovskite based thermochemical redox cycles for splitting H2O and CO2. Int J Hydrogen Energy 43: 18814–18831. doi: 10.1016/j.ijhydene.2018.08.137
    [87] Call F, Roeb M, Schmücker M, et al. (2015) Ceria doped with zirconium and lanthanide oxides to enhance solar thermochemical production of fuels. J Phys Chem C 119: 6929–6938.
    [88] Kang M, Zhang J, Wang C, et al. (2013) CO2 splitting via two step thermochemical reactions over doped ceria/zirconia solid solutions. RSC Adv 3: 18878–18885. doi: 10.1039/c3ra43742f
    [89] Kang M, Wu X, Zhang J, et al. (2014) Enhanced thermochemical CO2 splitting over Mg-and Ca-doped ceria/zirconia solid solutions. RSC Adv 4: 5583–5590. doi: 10.1039/c3ra45595e
    [90] Bhosale RR, Kumar A, AlMomani F, et al. (2016) Assessment of CexZryHfzO2 based oxides as potential solar thermochemical CO2 splitting materials. Ceram Int 42: 9354–9362. doi: 10.1016/j.ceramint.2016.02.100
    [91] Jacot R, Naik JM, Moré R, et al. (2018) Reactive stability of promising scalable doped ceria materials for thermochemical two-step CO2 dissociation. J Mater Chem A 6: 5807–5816. doi: 10.1039/C7TA10966K
    [92] Meng QL, Tamaura Y (2014) Enhanced hydrogen production by doping Pr into Ce0.9Hf0.1O2 for thermochemical two-step water-splitting cycle. J Phys Chem Solids 75: 328–333.
    [93] Ruan C, Tan Y, Li L, et al. (2017) A novel CeO2 –xSnO2 /Ce2Sn2O7 pyrochlore cycle for enhanced solar thermochemical water splitting. AlChE J 63: 3450–3462. doi: 10.1002/aic.15701
    [94] Lin F, Wokaun A, Alxneit I (2015) Rh-doped ceria: solar organics from H2O, CO2 and sunlight? Energy Procedia 69: 1790–1799. doi: 10.1016/j.egypro.2015.03.151
    [95] Mostrou S, Büchel R, Pratsinis SE, et al. (2017) Improving the ceria-mediated water and carbon dioxide splitting through the addition of chromium. Appl Catal A 537: 40–49. doi: 10.1016/j.apcata.2017.03.001
    [96] Hoes M, Muhich CL, Jacot R, et al. (2017) Thermodynamics of paired charge-compensating doped ceria with superior redox performance for solar thermochemical splitting of H2O and CO2. J Mater Chem A 5: 19476–19484. doi: 10.1039/C7TA05824A
    [97] Kaneko H, Tamaura Y. (2009) Reactivity and XAFS study on (1 − x)CeO2 –xNiO (x = 0.025–0.3) system in the two-step water-splitting reaction for solar H2 production. J Phys Chem Solids 70: 1008–1014.
    [98] Lin F, Samson VA, Wismer AO, et al. (2016) Zn-modified ceria as a redox material for thermochemical H2O and CO2 splitting: effect of a secondary ZnO phase on its thermochemical activity. CrystEngComm 18: 2559–2569. doi: 10.1039/C6CE00430J
    [99] Yadav D, Banerjee R (2016) A review of solar thermochemical processes. Renew Sustain Energ Rev 54: 497–532. doi: 10.1016/j.rser.2015.10.026
    [100] Gibbons WT, Venstrom LJ, De Smith RM, et al. (2014) Ceria-based electrospun fibers for renewable fuel production via two-step thermal redox cycles for carbon dioxide splitting. Phys Chem Chem Phys 16: 14271–14280. doi: 10.1039/C4CP01974A
    [101] Gladen AC, Davidson JH (2016) The morphological stability and fuel production of commercial fibrous ceria particles for solar thermochemical redox cycling. Sol Energy 139: 524–532. doi: 10.1016/j.solener.2016.10.029
    [102] Furler P, Scheffe J, Gorbar M, et al. (2012) Solar thermochemical CO2 splitting utilizing a reticulated porous ceria redox system. Energ Fuel 26: 7051–7059. doi: 10.1021/ef3013757
    [103] Takacs M, Ackermann S, Bonk A, et al. (2017) Splitting CO2 with a ceria-based redox cycle in a solar-driven thermogravimetric analyzer. AlChE J 63: 1263–1271. doi: 10.1002/aic.15501
    [104] Cho HS, Myojin T, Kawakami S, et al. (2014) Solar demonstration of thermochemical two-step water splitting cycle using CeO2 /MPSZ ceramic foam device by 45kWth KIER solar furnace. Energy Procedia 49: 1922–1931. doi: 10.1016/j.egypro.2014.03.204
    [105] Ackermann S, Scheffe J, Duss J, et al. (2014) Morphological characterization and effective thermal conductivity of dual-scale reticulated porous structures. Materials 7: 7173–7195. doi: 10.3390/ma7117173
    [106] Marxer D, Furler P, Scheffe J, et al. (2015) Demonstration of the entire production chain to renewable kerosene via solar thermochemical splitting of H2O and CO2. Energ Fuel 29: 3241–3250. doi: 10.1021/acs.energyfuels.5b00351
    [107] Venstrom LJ, Petkovich N, Rudisill S, et al. (2012) The effects of morphology on the oxidation of ceria by water and carbon dioxide. J Sol Energ Eng 134: 011005–011012. doi: 10.1115/1.4005119
    [108] Petkovich ND, Rudisill SG, Venstrom LJ, et al. (2011) Control of heterogeneity in nanostructured Ce1–xZrxO2 binary oxides for enhanced thermal stability and water splitting activity. J Phys Chem C 115: 21022–21033. doi: 10.1021/jp2071315
    [109] Oliveira FAC, Barreiros MA, Abanades S, et al. (2018) Solar thermochemical CO2 splitting using cork-templated ceria ecoceramics. J CO2 Util 26: 552–563. doi: 10.1016/j.jcou.2018.06.015
    [110] Malonzo CD, De Smith RM, Rudisill SG, et al. (2014) Wood-templated CeO2 as active material for thermochemical CO production. J Phys Chem C 118: 26172–26181. doi: 10.1021/jp5083449
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