Review

Mechanical behaviors and biomedical applications of shape memory materials: A review

  • Received: 18 February 2018 Accepted: 19 June 2018 Published: 28 June 2018
  • A shape memory material (shape memory alloy (SMA) or shape memory polymer (SMP)) can experience large deformation and recover its original shape when exposed to a specific external stimulus. Shape memory materials have drawn significant attention due to their applications in biomedical devices, which typically require appropriate mechanical biocompatibility, including elastic modulus compatibility, adequate strength and fracture toughness, and superior fatigue resistance. In this review, we provide an overview of mechanisms and biomedical applications of some common SMAs and SMPs, experimental evidences on their mechanical biocompatibility, and some key aspects of computational modeling. Challenges and progress in developing new shape memory materials for biomedical applications are also presented.

    Citation: Chunsheng Wen, Xiaojiao Yu, Wei Zeng, Shan Zhao, Lin Wang, Guangchao Wan, Shicheng Huang, Hannah Grover, Zi Chen. Mechanical behaviors and biomedical applications of shape memory materials: A review[J]. AIMS Materials Science, 2018, 5(4): 559-590. doi: 10.3934/matersci.2018.4.559

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  • A shape memory material (shape memory alloy (SMA) or shape memory polymer (SMP)) can experience large deformation and recover its original shape when exposed to a specific external stimulus. Shape memory materials have drawn significant attention due to their applications in biomedical devices, which typically require appropriate mechanical biocompatibility, including elastic modulus compatibility, adequate strength and fracture toughness, and superior fatigue resistance. In this review, we provide an overview of mechanisms and biomedical applications of some common SMAs and SMPs, experimental evidences on their mechanical biocompatibility, and some key aspects of computational modeling. Challenges and progress in developing new shape memory materials for biomedical applications are also presented.


    1. Introduction

    Competitiveness and privatization are inevitable ways to resolve problems such as unemployment and stagnation in a developing country. According to Davies and Quinlivan (2006), when business profit is divided among countries, income per capita is increased [1]. In the global market, effective ways to promote the export of products from food industry companies will provide suitable bases, especially for developing countries; meanwhile perishability and marketing of such products are inevitable and should be taken into account.

    Iran is regarded as one of the countries with a background in exporting some agricultural products, especially tomato paste, to different countries through which it can create jobs and gain revenue. According to the FAO data since 2004, the Iranian tomato paste industry has generated about 60.9 million dollars worth of exports and a share of about 1.02% of the total non-oil exports [2]. During 2009–2011, the rank of Iran among major tomato paste exporter countries has improved from 10th to 7th and 6th. In 2011, the major tomato paste exporters were China, Italy, USA, Spain, Portugal, Iran, Turkey, Chili, Greece and Tunisia. The export share of Iran was approximately about 7% in Asia and 3% in the global market during the most recent 8 years (Figure 1). Additionally, Iranian tomato paste is imported by some countries, mainly Iraq, Tajikistan, Russia, Saudi Arabia, UAE, Afghanistan, Turkmenistan, Sweden, America, Canada, Kuwait, the United Kingdom, Azerbaijan, Qatar, Japan and Australia [2] and [3]. Such data indicates the improvement of the ability of Iran to compete with this product in foreign markets. Some factors and variables play major roles in export and can distinguish an effective producing sector from another. To export food-industry crops, some companies face lack of financial information, market access and sufficient marketing organization. Some studies on agricultural crops and their by-products are summarized below.

    Figure 1. The share of Iran in tomato paste export during 2005–2012.

    Saghaian et al. (2014), in their research on export demand estimation for the U.S. corn and soybeans to major destinations, used a log-log model and studied the advantage of using elasticity values. In this model, the export value of the product depends on variables such as the price of the corn and soybeans in America, the gross domestic product (GDP) and the exchange rate of importing countries. The results indicated that the income elasticity of China and Japan is 2.5 and 1, respectively, and corn and soybeans are substitutable crops [4].

    Curzi et al. (2013) carried out research on 70 countries and several thousand food products in the period of 1995–2007. The results indicated that when there is an increase in import competition, a complex relationship is induced between improvement in quality and competitiveness [5].

    In another study, Luckstead et al. (2013) indicated that although 85 percent of orange juice is produced in Florida and Sao Paulo, any reduction in US the tariff would change export values of the orange juice of Sao Paulo from Europe to the United States. Also, one of the remarkable aspects of the competition was reduction in cost of production of orange and orange juice [6].

    Pierre et al. (2013) studied the effect of non-tariff barriers on foreign direct investment and the capital flow, using a gravity model. They concluded that economic growth would be achieved through productivity and trade releasing [7].

    Hartman et al. (1999) studied the impact of tariff liberalization on importing juice concentrated orange and tomato paste of South America. Agglomeration and competitive models were used to aim cost comparisons of production in cases related to free trade, determine future locations for such by-products, analyze expected outcomes, and make cost comparisons and trade competitive model. Considering the increasing return to scale, greater production and export in South America, would decrease shipping cost. In case of Argentina and Brazil, it was recommended to increase their efficiency. Other results indicated that by freer trade, all countries engaging in such trade of two products, would gain more in the long run. This outcome includes both of producers and consumers, meanwhile there would not loss for U.S. producers [8].

    Considering China's fast economic growth, comparative advantages have been attained in some of agricultural crops in recent decades. Chen et al. (2008) have studied the impact of food safety on China's agricultural export by applying a gravity model in which developed countries import vegetables and fish crops. Among relevant variables, the output of Chinese selected exporting crops was used instead of mass factor in the model. Such a factor incorporated the supply side effect on the exporting crop coherent to the GDP of the importing country. In addition to distance, food safety standard was also used as non-tariff barriers in the model that was more effective than tariff rate. Other factors had expected effects on the export revenue [9].

    To relieve the problem of zero trade values and heteroscedasticity features in econometric models, Martinez-Zarzoso (2013) applied various methods characterized by estimators such as Pseudo Poisson Maximum Likelihood (PPML), Gamma Pseudo-Maximum-Likelihood (GPML), Nonlinear Least Squares (NLS), etc. in a gravity model. According to the results of the single estimations, using samples with real data indicated that selecting a suitable estimator was based on the nature of the data. It's noteworthy that PPML method is a case of Generalized Linear Model other than OLS (Ordinary Least Square) where in log-linear form is not effective for threshold values of dependent variable [10].

    It should be noted that, contrary to other similar studies which were often based on measuring factors affecting the annual total demand of countries or sectors, the present study is aimed to identify variables that affect the revenue share of a tomato-paste company among its rivals.

    In case of exporting companies, the size of the company is influential on amount of their product demand. There are up to 300,000 small and medium sized exporters in the US, which included more than 30 percent of major exports in 2012. It's noteworthy that such companies can be activated more by entering new markets. Alternative markets to export their goods depend on government enterprises while most of them did not have multiple locations to export and faced trade barriers [11]. Relating to this research, Kumar and Rai (2007) studied competitiveness of tomato and its by-products export. While India has a high rank in tomato production and cultivates more than 11 percent of the world's total tomato there, it loses a major part of the global market per annum. It is clear that by having nearly 4 percent of total production, India possesses only 0.1 percent of the total export share. In addition to criteria such as Revealed Comparative Advantages, researchers aimed to measure the effective factors of an export demand function to approach ways to promote global market share. Results indicated that in addition to competitive advantages, improving infrastructures plays a major role in the global arena. It is noteworthy that tomato by-products include value added creating income and job vacancies particularly rural societies. i.e., it will make other producing sectors engaged indirectly in a competitive cycle. Consequently, Indian policy-makers are tended to develop processed tomato in addition to itself solely [12].

    According to the report of Industry, Mine and Trade Ministry of Iran in 2015, there are 58 active tomato paste processing factories. Generally, the ratio of tomato to paste is reported 6–6.5 to 1 kg in processing factories of Iran. Most of techno-food companies incorporating tomato-paste and other by-products are small and medium sized companies. One of the main reasons is that their ownership and crop characteristics are strategically excluded from state enterprises in Iran. Consideration of comparative advantages aiming to promote export value share of such companies among global rivals would not only lead to inform their economic conditions to support lasting exports to their customer bases, but also provide better planning for surplus farmed tomato as the primary crop in various geographical regions of Iran. Some annual data incorporating total tomato production and tomato paste trade, are represented in Table 1. Regarding to the data of part1 in this paper, the annual export revenue data do not direct specially comparing among rivals in the exclusive competition arena. Export incentives do not either play a major role for Iranian exporting companies1.

    Table 1. Cultivated area and production of tomato and trade quantities of tomato-paste of Iran (2005–2014).
    Period Area Production Dry farming Irrigated farming Export Import
    1000ha Mt t/ha t/ha t t
    2005 147.4 0.5 15.5 34.4 28761 -
    2006 154.7 5.5 15.8 35.8 136898 0.0
    2007 195.4 4.8 14.6 24.7 139045 0.0
    2008 163.9 5.8 15.1 36.1 86821 0.0
    2009 164.9 5.7 16.3 38.9 102293 0.3
    2010 154.5 5.5 15.3 36.2 85778 0.0
    2011 149.9 5.4 15.9 36.6 140829 4054.0
    2012 150.8 5.6 16.1 37.6 111960 0.0
    2013 158.2 6.3 17.7 39.5 102301 13.4
    2014 151.9 6.0 19.1 39.6 128172 0.0
    *Note: Source: Based on FAO data and Customs Administration of Islamic Republic of Iran, 2015.
     | Show Table
    DownLoad: CSV

    1It's noticeable that according to the report of The Islamic Republic of Iran Customs Administration in 2015, by coordinating of Agriculture-Jahad and Industry, Mine and Trade Ministries of Iran, exempting export tax is related to some factors such as production surpluses, supporting producers, market status, etc. Some of agri-food crops are forbidden to export specially in drought years. However for tomato-paste this rate alternatively is determined to zero rate especially for the years of research and almost some recent years. i.e., by this way authorities aimed to plan for employment and developing production; Thereby the exporting crop will be comprised in Customs Affairs Bill and their clauses. Such enterprises do not work beneficially in a global arena and complementary factors are more impressive.

    To attain practical ways to competitiveness and marketing of tomato paste and to develop the export of other food-industry products, some of the potentially important variables such as, distance, number of documents to import, productivity, common language and religion and ad-valorem tariff on the export revenue share of an Iranian tomato paste producing company, are examined in this study.


    2. Materials and methods


    2.1. The gravity model

    According to the theoretical base of the gravity model, by Tinbergen (1962) and similar studies, the trade value, Tij, has a positive relationship with GDP and a negative relationship with distance [13]. The simple formula is:

    Tij=α0Yα1iYα2jDα3iηi (1)

    where Di comprises of all factors that prevent or cause trade; α0, α1 to α3 are parameters to be estimated and ɳi is the stochastic component. Yi and Yj are GDPs of trading companies [14].

    In line with the generalized gravity model, the volume of exports between countries in year t is expressed as:

    Tijt=β0Yβ1itYβ2jtYHβ3itYHβ4jtDISTβ5ijFβ6ijtuijt (2)

    Where YH and DIST denote per capita income and geographical distance, respectively, and Fij refers to a specific number of variables which can be the dummy variable, like the common border, language, as well as variables that can prevent or cause bilateral trade [10].


    2.2. Frequent zeros and share values

    In some of economic contexts the dependent variable is obtained fractionally as 0 ≥ y > 1, e.g. the market share, the fraction of allocated land for farming, etc. [15]. In this study, the dependent variable, Sijt, has zero and share values. It is defined as the export revenue share of the ith Iranian tomato paste company of the total revenue of other tomato paste companies exporting to the jth country and it takes a fraction from zero to one.

    It is noteworthy to mention that with respect to Newton's gravity, the gravity force can be very small but it cannot be zero, whereas in the trade model the trade between two countries can be zero. Nearly half of the observations related to trade contained zero values in a dependent variable. As a result, a log-linear model of the gravity equation causes some problems. One result of this is that zero data should be removed from the estimation process so that estimates can be carried out by an OLS log-linear model. Other solutions include adding 1 to the dependent variable or using a Tobit estimator. However, such procedures, too, will lead to an inconsistency that depends on the sample size and models [14].

    Standard count data model used by Dennis and Shepherd [16], Berthou and Fontagné [17] and Persson [18] ignored the upper bound. The fractional data described by Ramalho and Ramalho [15], explained two methods for modeling the fractional data neglecting boundaries 0, 1; the first method considers a suitable specification of a conditional expectation for dependent fractional variable and the second assumes a limited distribution. It means that a parametric model or a conditional mean is used in the first method as a sample with the range of y Є (0, 1).

    One practical approach is to use the generalized linear model (GLM)4 family. It covers different models such as linear regression, Poisson, exponential, etc. This method presumes the maximum likelihood or uses IRLS alternatively. For example, the Logit model in the binomial family has achieved results which are similar to those of the maximum likelihood through GLM [19]. In the GLM method, the normal form of the variance function is:

    V(y|x)=k(μ(xβ))λ (3)

    where λ has limited and non-negative integer value; and it determines different sets of GLM. The corresponding λ values provide Poisson, Gamma and other statistical distributions. Moreover, the GLM method assumes that there is a function which establishes the relation between the variance and mean and allows estimation of variance with different conditions, for instance if yit has a Gaussian or Normal or other distribution, and G provides the link function, assuming:

    E(Yit)=Xitβ (4)

    and it can be written as:

    g(E(Yit))=Xitβ (5)

    It can be also logistic regression; if there is a natural logarithm function and if yit has Poisson distribution, then:

    Ln{E(yit)}=xitβ,yPoisson (6)

    This is a Poisson regression that is also named the linear-log model. Therefore, other function combinations are also possible [14].

    In case of fractional response variable as yit and included in a panel form, let individuals as i = 1, N and time as t is 1 to T. The conditional expectation is:

    E(yi|xi)=G(xiθ) (7)

    where θ is the vector of parameters and G(.) is a nonlinear function bounded between zero and one [20]. It may include logit or probit functoinal form. In a fixed effect panel data the model (8) is as:

    E(yi|αi,xi)=G(xiθ+αi) (8)

    αi is the time invariant unobserved heterogeneity. Because of the characteristic of G (.) with unobservable cases, consistent coefficients would not be attainable [21]. Wagner (2003) indicated that in a long panel data including cross sections and a short time period, while cross sections are infinite, fixed effect estimators would be inconsistent [22]. It's also noticeable that Var (yi|xi) is probably not homoskedastic. In this circumstance, multivariate weighted nonlinear least square and generalized estimating equation are proposed for panel data in case of serial correlation and heteroskedasticity. They are similar and use a working version of matrix Var (yi|xi) [23].

    Since the maximum likelihood and usual quasi-likelihood estimations especially in generalized linear models are not robust, estimators with better robustness are recommended. They are unbounded influenced function [24].


    2.3. The model specification

    Among control variables, the log of GDPs of trading countries as the monetary value are commonly used in a gravity model [25]. What is pointed by Chen et al. (2008) was that output of elected exporting crops of China was used instead of mass factor rather than GDP2. In this study considering the exporting sectors i.e., tomato paste producing companies other than the exporting country as a whole, annual value added and value added per employee of companies are considered as coherent variables instead of GDPs and GDPs per capita in such gravity-like model.

    2In this regard, Evans (2001) and Hillberry (2002) offer some arguments [28,29].

    Non Tariff Barriers may include unnecessary documentary requirements and all barriers other than tariffs. According to GATT article Ⅷ, minimizing trade formalities and simplifying documentations are recommended. In this matter such simplifications include documents, documentation, and inspections and etc. [26].

    According to the model specification of Anderson and Van win coop (2003), estimating a gravity equation obligates to convert it to a log-linear equation [27].

    In this study, according to the extended gravity model and theoretical bases, the equation of regression with all related variables in the final model is specified as follows:

    Sijt=G{b0+b1(vait)+b2Ln(1+tarjt)+b3Ln(distjt)+b5(docjt)+b6Rligion+b7Language}+uijt (9)

    Where the dependent variable Sijt is export revenue share as defined earlier.

    vait is the value added per employee of a tomato paste producing unit as a common measure of productivity. There are some reasons such as different kinds of technology, capital stock, different production methods used in producing tomato paste units that have led to the selection of a homogeneous index as value added per employee among productivity indices; As mentioned above, this item is coherent with GDP per capita in the model.

    tarjt is the ad-valorem tariff of the country j.

    The variation between importing countries makes it possible to derive the tariff effect. This point can also be extended to non-tariff barriers.

    distj is the distance between Iranian company and partner j3; docsjt is the number of documents needed for annual imports; also referring to Non Tariff Barriers.

    3A part of data from CEPII is available at: Http://www.cepii.fr/anglaisgraph/bdd/distances.htm. Concerning the distance between the companies and the targeted country, it is measured by distance reported by merchants for neighboring countries. Meanwhile in some special cases such as shipping and airline, it is checked by the Google-Earth.

    Religion and language are also considered as dummy variables where the common religion is Islam it took 1 otherwise zero and in case of Persian language for importing country it takes 1 and otherwise takes zero.


    3. Results

    In this study, descriptive and analytical methods are used by applying econometric bases. The regression estimation method is used for fractional data in the panel data in the gravity model. In this research, 12 eligible exporting-producer companies along with 16 importing countries are included. These samples involved at least 70% of importing countries and 70% of exporting companies of Iranian tomato paste to form 192 cross-sections during the years 2005–20124.

    4The export process from all of the elected Iranian companies to all of the partners was not continuous during 8 years; and the data arrangement of cross-sections was logically skewed.

    As shown in Table 2, Harris-Tzavalis and Hadri Lagrange multiplier stationary tests approved I (0) for all variables.

    Table 2. The stationary test for the time period 2005–2012.
    Variable Sijt Ln (vait) Ln (1+tarjt) Ln (distj) Ln (docsjt)
    Harris-Tzavalis test (time trend not included)
    Z –26.74 –16.13 –27.71 –29.39 2.39
    P-value 0.0000 0.0000 0.0000 0.0000 0.0000
    (time trend included)
    Z –19.64 –15.50 –8.36 –5.66 –5.92
    P-value 0.0000 0.0000 0.0000 0.0000 0.0000
    Hadri Lagrange multiplier stationarity test (time trend not included)
    Z 8.16 19.27 9.92 9.86 37.87
    P-value 0.0003 0.0000 0.0000 0.0000 0.0000
    (time trend included)
    Z 3.04 3.14 8.91 9.01 4.09
    P-value 0.0000 0.0000 0.0000 0.0000 0.0000
    *Note: Source: research findings.
     | Show Table
    DownLoad: CSV

    It should be mentioned that while there exists an 8-year period for panel data, the estimation with the GLM group is directly based on pool data and does not work for fixed and random effects.

    According to the GLM family estimations, two parts including distribution and link function should be appropriately chosen; hereby, binomial and logit choice were defined to gain reasonable results shown in Tables 3 and 4, respectively. Moreover, the robust choice in standard error type contributed to resolving some of estimation problems such as heteroscedasticity and frequent values.

    Table 3. Results of the generalized linear model (GLM).
    Variable Cons. Ln (vait) Ln (1+tarjt) Ln (distj) Ln (docsjt) Religion Language
    Coefficient –23.393** 0.493*** –16.090** –0.273** 6.772** 1.630*** 1.240***
    Robust S.e 6.428 0.088 4.655 0.903 2.843 0.320 0.330
    Prob. 0.000 0.000 0.001 0.002 0.017 0.000 0.000
    Deviance = 37.57 Pseudo-R2 = 0.98 AIC = 0.0590849
    Pearson = 498.91 Log pseudolikelihood = –38 BIC = –11,180.6
    *Note: Source: Calculations of the research group.
     | Show Table
    DownLoad: CSV
    Table 4. Results of the Generalized Estimating Equations (GEE).
    Variable Cons. Ln (vait) Ln (1+ tarjt) Ln (distj) Ln (docsjt) Religion Language
    Coefficient –22.920** 0.530*** –14.835** –0.252* 6.211 1.903** 1.371*
    Semi Robust S.e 8.912 0.149 5.601 0.144 3.804 0.711 0.747
    Prob. 0.01 0.000 0.008 0.080 0.103 0.007 0.06
    Pseudo-R2 = 0.98 Wald chi2 (6) = 64.30
    Scale parameter: 1 Prob > chi2 = 0.00
    *Note: Source: Calculations of the research group.
     | Show Table
    DownLoad: CSV

    Similar to gravity model estimations, results show significant coefficients for five factors, with a negative sign for tariff and distance, and positive sign for value added per employee for the manufacturer company (the criterion of productivity), number of documents to import and common boundary or adjacency, on the export revenue share. The coefficients of GNP per capita or (YHjt) and other related variables were not so significant to use Wald test, therefore they were dropped from results.

    These results can have implications for the sample situation5. Furthermore, the two estimation methods apparently overlapped by Pseudo-R2. However, the analytical approach provides practical views.

    2According to the non-linear relationship between dependent and explanatory variables and considering dummy variables, as F(x'ijβ) is an approximation, to interpret coefficient values, partial effects should be aimed at.


    4. Conclusions

    In this research, effective factors with a major role in competitiveness of tomato paste exporting companies were investigated through a gravity model in a panel data framework.

    Since increasing and developing ways of increasing the revenue share of exporting companies were aimed at, the dependent variable approximately created a logit distribution with co-domain bounded between zero and close to one. GLMs and Generalized Estimating Equations (GEE) were used instead of other estimation methods to resolve problems such as neglecting heterogeneity, and ignoring the upper bound of the dependent variable, etc. However, based on the data structure during the estimation process, except for the robust option, GLM ignores the clustering. Thus it is recommended to justify outputs within GEE as it uses more data.

    In this section, in addition to discussing the results, some suggestions are provided as follows: In both Tables 3 and 4 as a productivity index, the coefficient of value added per employee had a positive effect. It can be simply concluded that the more factories are equipped with regard to automatic and updated machines, the more productivity will be gained. This has implications for industrializing and planning an open economy with greater markets. Mutually, a more open economy through post-sanctions contracts would gradually update the level of food technology. The joining of some local factories into the form of an oligopoly can be a bailout for provincial producers.

    The tariff coefficient sign implies that a one percent cut-off rate would increase the gain of exporting companies reflecting export share. It is noteworthy that importing countries with lower tariff rates mainly include Asian countries, especially the Middle East; Figure 2. It is suggested to merchant and business authorities to regulate a series of contracts and agreements with partners to cut or lower the importing tariff rates more (Development & Trade Organization, 2015). However, some business partners of the developed countries prefer their own importing rates. It may be because their local industries have aimed at the production trend via competitiveness. This is especially observable in the EU.

    Figure 2. A Proxy of Tariff rates in 2010.

    According to the report of the Trade and Development Organization of Iran during 2014–2015, any lowering or elimination of tariffs between Iran and partners should depend on trade negotiations and agreements through bartering goods and similar contracts. Since there are comparative advantages of some products, especially those from agri-food industries, it seems more appropriate for Iran to be a prevailed market within the Middle East countries than elsewhere. Relatedly, relieving some tariff and non-tariff obstacles obligates the membership of Iran in WTO. One result of the Uruguay Round was countries committing to cut tariffs and to bind their customs duty rates to levels which are difficult to raise. The current negotiations, under the Doha Agenda, involve continuing efforts to gain market access for agriculture and non-agricultural goods [30]. For Iran, the obstacles to international trade, such as sanctions, standard brands, etc. can be regarded as another reason. A primary item in the commercialization of a product is an open economy to achieve global standards, leading to the bargaining power that might tend to extend mutual tariff cuts. Therefore, the companies and affiliated merchandises are recommended to plan especial foreign markets which seem to have flexible customs rules or might lead to collaborate on tariff cuts in the long run. The effect of tariff liberalization through free trade between exporting and partner countries especially for tomato paste is approved in the long run. It would be beneficial for all society groups [8]. One of the unexpected results of the present study was the positive sign of documents to import, which is contrary to the theoretical bases. According to the reports of Trade Promotion Organization of Iran (2015), some informal exports and transits are being done while neglecting complete official registration. This implies that a wholesaler company may do official exports with a broad range of documents while other retailers do it with fewer registered trade details; consequently, a considerable volume of exports of tomato-paste did not undergo official arrangements and the owners of the producing companies were not necessarily engaged in the trade. Therefore, it is necessary to ensure efficient merchandising along with providing some commercial incentives for producers.

    As shown in Tables 1 and 2 the distance, common language and common religion have their expected theoretical effect. This specially highlights the concentration of companies on some of neighboring countries more, despite the activities of other Asian exporting competitors e.g. Iraq, Kuwait, Tajikistan, etc. However, it is clear that any improvement in these items is subordinated to quality, brand, and marketing techniques. A certain amount of exported tomato paste is packed in aseptic and barrel packages for some advantages such as sanitation and durability [31].

    Relating to this study, other approaches are recommended to be considered: Tomato paste is inevitably distributed by imperfect competition. Consequently working on brand, reputation and credibility might be as important as other qualitative privileges, companies should focus on partner companies, market glut and preferences in consumption and packing type. However, to continue increased trade with partners, facilitating trade procedure through application of the Internet is inevitably recommended since it saves time for inspections and delivery [32].

    As Kumar and Rai (2007) and Hirashima (2002) [12,33] indicate, competitiveness requires some facilities such as cold chain, sanitary, phytosanitary and in relation to the productivity, improving technology in cultivation and processing i.e., tomato and paste. Thus, to attain such goals, government is obligated to improve producing and processing techniques for local and global markets.


    Conflict of interest

    The authors declare no conflict of interest.


    [1] Huang WM, Ding Z, Wang CC, et al. (2010) Shape memory materials. Mater Today 13: 54–61.
    [2] Ji F, Zhu Y, Hu J, et al. (2006) Smart polymer fibers with shape memory effect. Smart Mater Struct 15: 1547. doi: 10.1088/0964-1726/15/6/006
    [3] Petrini L, Migliavacca F (2011) Biomedical applications of shape memory alloys. J Metall 2011: 1–14.
    [4] Cho JW, Kim JW, Jung YC, et al. (2005) Electroactive shape-memory polyurethane composites incorporating carbon nanotubes. Macromol Rapid Commun 26: 412–416. doi: 10.1002/marc.200400492
    [5] Lendlein A, Jiang H, Junger O, et al. (2005) Light-induced shape-memory polymers. Nature 434: 879–882. doi: 10.1038/nature03496
    [6] Lendlein A, Schmidt AM, Schroeter M, et al. (2005) Shape-memory polymer networks from oligo (ϵ-caprolactone) dimethacrylates. J Polym Sci, Part A: Polym Chem 43: 1369–1381. doi: 10.1002/pola.20598
    [7] Tzou H, Lee HJ, Arnold S (2004) Smart materials, precision sensors/actuators, smart structures, and structronic systems. Mech Adv Mater Struct 11: 367–393. doi: 10.1080/15376490490451552
    [8] Behl M, Lendlein A (2007) Shape-memory polymers. Mater Today 10: 20–28.
    [9] Wei Z, Sandstroröm R, Miyazaki S (1998) Shape-memory materials and hybrid composites for smart systems: Part I Shape-memory materials. J Mater Sci 33: 3743–3762. doi: 10.1023/A:1004692329247
    [10] El Feninat F, Laroche G, Fiset M, et al. (2002) Shape memory materials for biomedical applications. Adv Eng Mater 4: 91. doi: 10.1002/1527-2648(200203)4:3<91::AID-ADEM91>3.0.CO;2-B
    [11] Hornbogen E (2006) Comparison of shape memory metals and polymers. Adv Eng Mater 8: 101–106. doi: 10.1002/adem.200500193
    [12] Gunes IS, Jana SC (2008) Shape memory polymers and their nanocomposites: A review of science and technology of new multifunctional materials. J Nanosci Nanotechnol 8: 1616–1637. doi: 10.1166/jnn.2008.038
    [13] Ma J, Karaman I, Noebe RD (2010) High temperature shape memory alloys. Int Mater Rev 55: 257–315. doi: 10.1179/095066010X12646898728363
    [14] Tsuchiya K (2011) Mechanisms and properties of shape memory effect and superelasticity in alloys and other materials: A practical guide, In: Shape Memory and Superelastic Alloys, Woodhead Publishing, 3–14.
    [15] Leng J, Lan X, Liu Y, et al. (2011) Shape-memory polymers and their composites: Stimulus methods and applications. Prog Mater Sci 56: 1077–1135. doi: 10.1016/j.pmatsci.2011.03.001
    [16] Rousseau IA (2008) Challenges of shape memory polymers: A review of the progress toward overcoming SMP's limitations. Polym Eng Sci 48: 2075–2089. doi: 10.1002/pen.21213
    [17] Es-Souni M, Fischer-Brandies H (2005) Assessing the biocompatibility of NiTi shape memory alloys used for medical applications. Anal Bioanal Chem 381: 557–567. doi: 10.1007/s00216-004-2888-3
    [18] Geetha M, Singh A, Asokamani R, et al. (2009) Ti based biomaterials, the ultimate choice for orthopaedic implants-a review. Prog Mater Sci 54: 397–425. doi: 10.1016/j.pmatsci.2008.06.004
    [19] De Nardo L, Bertoldi S, Tanzi M, et al. (2011) Shape memory polymer cellular solid design for medical applications. Smart Mater Struct 20: 035004. doi: 10.1088/0964-1726/20/3/035004
    [20] Robertson S, Pelton A, Ritchie R (2012) Mechanical fatigue and fracture of Nitinol. Int Mater Rev 57: 1–37. doi: 10.1179/1743280411Y.0000000009
    [21] Schroeder T, Wayman C (1977) The two-way shape memory effect and other "training" phenomena in Cu-Zn single crystals. Scr Metall 11: 225–230.
    [22] Perkins J, Hodgson D (1990) The two-way shape memory effect. Eng Aspects Shape Mem Alloys 1990: 195–206.
    [23] Huang W, Toh W (2000) Training two-way shape memory alloy by reheat treatment. J Mater Sci Lett 19: 1549–1550. doi: 10.1023/A:1006721022185
    [24] Otsuka K, Ren X (2005) Physical metallurgy of Ti-Ni-based shape memory alloys. Prog Mater Sci 50: 511–678. doi: 10.1016/j.pmatsci.2004.10.001
    [25] Huang W (2002) On the selection of shape memory alloys for actuators. Mater Des 23: 11–19. doi: 10.1016/S0261-3069(01)00039-5
    [26] Huang WM, Song CL, Fu YQ, et al. (2013) Shaping tissue with shape memory materials. Adv Drug Delivery Rev 65: 515–535. doi: 10.1016/j.addr.2012.06.004
    [27] Carroll MC, Somsen C, Eggeler G (2004) Multiple-step martensitic transformations in Ni-rich NiTi shape memory alloys. Scr Mater 50: 187–192. doi: 10.1016/j.scriptamat.2003.09.020
    [28] Zhou Y, Fan G, Zhang J, et al. (2006) Understanding of multi-stage R-phase transformation in aged Ni-rich Ti-Ni shape memory alloys. Mater Sci Eng A S438–440: 602–607.
    [29] Fujishima K, Nishida M, Morizono Y, et al. (2006) Effect of heat treatment atmosphere on the multistage martensitic transformation in aged Ni-rich Ti-Ni alloys. Mater Sci Eng A 438: 489–494.
    [30] Khalil-Allafi J, Dlouhy A, Eggeler G (2002) Ni4Ti3-precipitation during aging of NiTi shape memory alloys and its influence on martensitic phase transformations. Acta Mater 50: 4255–4274. doi: 10.1016/S1359-6454(02)00257-4
    [31] Wagner MFX, Dey SR, Gugel H, et al. (2010) Effect of low-temperature precipitation on the transformation characteristics of Ni-rich NiTi shape memory alloys during thermal cycling. Intermetallics 18: 1172–1179. doi: 10.1016/j.intermet.2010.02.048
    [32] Kim JI, Liu Y, Miyazaki S (2004) Ageing-induced two-stage R-phase transformation in Ti-50.9at.%Ni. Acta Mater 52: 487–499.
    [33] Qin Q, Peng H, Fan Q, et al. (2018) Effect of second phase precipitation on martensitic transformation and hardness in highly Ni-rich NiTi alloys. J Alloys Compd 739: 873–881. doi: 10.1016/j.jallcom.2017.12.128
    [34] Luo J, Bobanga JO, Lewandowski JJ (2017) Microstructural heterogeneity and texture of as-received, vacuum arc-cast, extruded, and re-extruded NiTi shape memory alloy. J Alloys Compd 712: 494–509. doi: 10.1016/j.jallcom.2017.04.152
    [35] Luo J, Ye WJ, Ma XX, et al. (2018) The evolution and effects of second phase particles during hot extrusion and re-extrusion of a NiTi shape memory alloy. J Alloys Compd 735: 1145–1151. doi: 10.1016/j.jallcom.2017.11.133
    [36] Jani JM, Leary M, Subic A, et al. (2014) A review of shape memory alloy research, applications and opportunities. Mater Des 56: 1078–1113. doi: 10.1016/j.matdes.2013.11.084
    [37] Maruyama T, Kubo H (2011) 12-Ferrous (Fe-based) shape memory alloys (SMAs): Properties, processing and applications, In: Shape Memory and Superelastic Alloys, Woodhead Publishing, 141–159.
    [38] Yamauchi K (2011) 3-Development and commercialization of titanium-nickel (Ti-Ni) and copper (Cu)-based shape memory alloys (SMAs), In: Shape Memory and Superelastic Alloys, Woodhead Publishing, 43–52.
    [39] Wadood A (2016) Brief overview on nitinol as biomaterial. Adv Mater Sci Eng 2016: 1–9.
    [40] Buehler WJ, Wang FE (1968) A summary of recent research on the nitinol alloys and their potential application in ocean engineering. Ocean Eng 1: 105–120. doi: 10.1016/0029-8018(68)90019-X
    [41] Dikici B, Esen Z, Duygulu O, et al. (2015) Corrosion of metallic biomaterials, In: Advances in Metallic Biomaterials, Springer, 275–303.
    [42] Mantovani D (2000) Shape memory alloys: Properties and biomedical applications. JOM 52: 36–44.
    [43] Ryhänen J, Kallioinen M, Tuukkanen J, et al. (1998) In vivo biocompatibility evaluation of nickel-titanium shape memory metal alloy: Muscle and perineural tissue responses and encapsule membrane thickness. J Biomed Mater Res 41: 481–488. doi: 10.1002/(SICI)1097-4636(19980905)41:3<481::AID-JBM19>3.0.CO;2-L
    [44] Duerig T, Pelton A, Stöckel D (1999) An overview of nitinol medical applications. Mater Sci Eng A 273: 149–160.
    [45] Morgan N (2004) Medical shape memory alloy applications-the market and its products. Mater Sci Eng A 378: 16–23. doi: 10.1016/j.msea.2003.10.326
    [46] Dahlgren JM, Gelbart D (2009) System for mechanical adjustment of medical implants. Google Patents.
    [47] Pfeifer R, Müller CW, Hurschler C, et al. (2013) Adaptable orthopedic shape memory implants. Procedia Cirp 5: 253–258. doi: 10.1016/j.procir.2013.01.050
    [48] Maynard RS (1999) Distributed activator for a two-dimensional shape memory alloy. Google Patents.
    [49] Zider RB, Krumme JF (1988) Eyeglass frame including shape-memory elements. Google Patents.
    [50] Lim G, Park K, Sugihara M, et al. (1996) Future of active catheters. Sens Actuators A 56: 113–121. doi: 10.1016/0924-4247(96)01279-4
    [51] Tung AT, Park BH, Liang DH, et al. (2008) Laser-machined shape memory alloy sensors for position feedback in active catheters. Sens Actuators A 147: 83–92. doi: 10.1016/j.sna.2008.03.024
    [52] Pelton A, Schroeder V, Mitchell M, et al. (2008) Fatigue and durability of Nitinol stents. J Mech Behav Biomed Mater 1: 153–164. doi: 10.1016/j.jmbbm.2007.08.001
    [53] Dye D (2015) Shape memory alloys: Towards practical actuators. Nat Mater 14: 760–761. doi: 10.1038/nmat4362
    [54] Ogawa Y, Ando D, Sutou Y, et al. (2016) A lightweight shape-memory magnesium alloy. Science 353: 368. doi: 10.1126/science.aaf6524
    [55] Schone AC, Schulz B, Lendlein A (2016) Stimuli responsive and multifunctional polymers: progress in materials and applications. Macromol Rapid Commun 37: 1856–1859. doi: 10.1002/marc.201600650
    [56] Cao Y, Xu S, Li L, et al. (2017) Physically cross-linked networks of POSS-capped poly(acrylate amide)s: Synthesis, morphologies, and shape memory behavior. J Polym Sci, Part B: Polym Phys 55: 587–600. doi: 10.1002/polb.24303
    [57] Momtaz M, Razavi-Nouri M, Barikani M (2014) Effect of block ratio and strain amplitude on thermal, structural, and shape memory properties of segmented polycaprolactone-based polyurethanes. J Mater Sci 49: 7575–7584. doi: 10.1007/s10853-014-8466-y
    [58] Momtaz M, Barikani M, Razavi-Nouri M (2015) Effect of ionic group content on thermal and structural properties of polycaprolactone-based shape memory polyurethane ionomers. Iran Polym J 24: 505–513. doi: 10.1007/s13726-015-0341-4
    [59] Saed MO, Torbati AH, Starr CA, et al. (2017) Thiol-acrylate main-chain liquid-crystalline elastomers with tunable thermomechanical properties and actuation strain. J Polym Sci, Part B: Polym Phys 55: 157–168. doi: 10.1002/polb.24249
    [60] Yang B, Huang WM, Li C, et al. (2006) Effects of moisture on the thermomechanical properties of a polyurethane shape memory polymer. Polymer 47: 1348–1356. doi: 10.1016/j.polymer.2005.12.051
    [61] Gyarmati B, Mészár EZ, Kiss L, et al. (2015) Supermacroporous chemically cross-linked poly(aspartic acid) hydrogels. Acta Biomater 22: 32–38. doi: 10.1016/j.actbio.2015.04.033
    [62] Guo W, Lu CH, Orbach R, et al. (2015) pH-stimulated DNA hydrogels exhibiting shape-memory properties. Adv Mater 27: 73–78. doi: 10.1002/adma.201403702
    [63] Xie H, He MJ, Deng XY, et al. (2016) Design of poly(l-lactide)-poly(ethylene glycol) copolymer with light-induced shape-memory effect triggered by pendant anthracene groups. ACS Appl Mater Interfaces 8: 9431–9439. doi: 10.1021/acsami.6b00704
    [64] Park J, Yoo JW, Seo HW, et al. (2017) Electrically controllable twisted-coiled artificial muscle actuators using surface-modified polyester fibers. Smart Mater Struct 26: 035048. doi: 10.1088/1361-665X/aa5323
    [65] Zou H, Weder C, Simon YC (2015) Shape-Memory Polyurethane Nanocomposites with Single Layer or Bilayer Oleic Acid-Coated Fe3O4 Nanoparticles. Macromol Mater Eng 300: 885–892. doi: 10.1002/mame.201500079
    [66] Voit W, Ware T, Gall K (2010) Radiation crosslinked shape-memory polymers. Polymer 51: 3551–3559. doi: 10.1016/j.polymer.2010.05.049
    [67] Small Iv W, Wilson T, Benett W, et al. (2005) Laser-activated shape memory polymer intravascular thrombectomy device. Opt Express 13: 8204–8213. doi: 10.1364/OPEX.13.008204
    [68] Zhang F, Zhou T, Liu Y, et al. (2015) Microwave synthesis and actuation of shape memory polycaprolactone foams with high speed. Sci Rep 5: 11152. doi: 10.1038/srep11152
    [69] Du H, Song Z, Wang J, et al. (2015) Microwave-induced shape-memory effect of silicon carbide/poly(vinyl alcohol) composite. Sens Actuators A 228: 1–8. doi: 10.1016/j.sna.2015.01.012
    [70] Fang Y, Ni Y, Leo SY, et al. (2015) Reconfigurable photonic crystals enabled by pressure-responsive shape-memory polymers. Nat Commun 6: 7416. doi: 10.1038/ncomms8416
    [71] Fang Y, Ni Y, Choi B, et al. (2015) Chromogenic photonic crystals enabled by novel vapor-responsive shape-memory polymers. Adv Mater 27: 3696–3704. doi: 10.1002/adma.201500835
    [72] Hu J, Zhu Y, Huang H, et al. (2012) Recent advances in shape-memory polymers: Structure, mechanism, functionality, modeling and applications. Prog Polym Sci 37: 1720–1763. doi: 10.1016/j.progpolymsci.2012.06.001
    [73] Liu C, Qin H, Mather P (2007) Review of progress in shape-memory polymers. J Mater Chem 17: 1543–1558. doi: 10.1039/b615954k
    [74] Ahn Sk, Kasi RM (2011) Exploiting microphase-separated morphologies of side-chain liquid crystalline polymer networks for triple shape memory properties. Adv Funct Mater 21: 4543–4549. doi: 10.1002/adfm.201101369
    [75] Luo X, Mather PT (2010) Triple-shape polymeric composites (TSPCs). Adv Funct Mater 20: 2649–2656. doi: 10.1002/adfm.201000052
    [76] Wang L, Yang X, Chen H, et al. (2013) Design of triple-shape memory polyurethane with photo-cross-linking of cinnamon groups. ACS Appl Mater Interfaces 5: 10520–10528. doi: 10.1021/am402091m
    [77] Wang L, Yang X, Chen H, et al. (2013) Multi-stimuli sensitive shape memory poly(vinyl alcohol)-graft-polyurethane. Polym Chem 4: 4461–4468. doi: 10.1039/c3py00519d
    [78] Wang L, Wang W, Di S, et al. (2014) Silver-coordination polymer network combining antibacterial action and shape memory capabilities. RSC Adv 4: 32276–32282. doi: 10.1039/C4RA03829K
    [79] Behl M, Kratz K, Zotzmann J, et al. (2013) Reversible bidirectional shape-memory polymers. Adv Mater 25: 4466–4469. doi: 10.1002/adma.201300880
    [80] Zhou J, Turner SA, Brosnan SM, et al. (2014) Shapeshifting: Reversible shape memory in semicrystalline elastomers. Macromolecules 47: 1768–1776. doi: 10.1021/ma4023185
    [81] Miaudet P, Derré A, Maugey M, et al. (2007) Shape and temperature memory of nanocomposites with broadened glass transition. Science 318: 1294–1296. doi: 10.1126/science.1145593
    [82] Behl M, Kratz K, Noechel U, et al. (2013) Temperature-memory polymer actuators. Proc Natl Acad Sci 110: 12555–12559. doi: 10.1073/pnas.1301895110
    [83] Wang L, Di S, Wang W, et al. (2014) Tunable temperature memory effect of photo-cross-linked star PCL-PEG networks. Macromolecules 47: 1828–1836. doi: 10.1021/ma4023229
    [84] Hu J (2007) Shape memory textiles, In: Shape Memory Polymers and Textiles, Woodhead Publishing, 305–337.
    [85] Yanju L, Haiyang D, Liwu L, et al. (2014) Shape memory polymers and their composites in aerospace applications: A review. Smart Mater Struct 23: 023001. doi: 10.1088/0964-1726/23/2/023001
    [86] Baudis S, Behl M, Lendlein A (2014) Smart polymers for biomedical applications. Macromol Chem Phys 215: 2399–2402. doi: 10.1002/macp.201400561
    [87] Wache HM, Tartakowska DJ, Hentrich A, et al. (2003) Development of a polymer stent with shape memory effect as a drug delivery system. J Mater Sci Mater Med 14: 109–112.
    [88] Small W, Buckley PR, Wilson TS, et al. (2007) Shape memory polymer stent with expandable foam: A new concept for endovascular embolization of fusiform aneurysms. IEEE Trans Biomed Eng 54: 1157–1160. doi: 10.1109/TBME.2006.889771
    [89] Zheng Y, Li Y, Hu X, et al. (2017) Biocompatible shape memory blend for self-expandable stents with potential biomedical applications. ACS Appl Mater Interfaces 9: 13988. doi: 10.1021/acsami.7b04808
    [90] Kularatne RS, Kim H, Boothby JM, et al. (2017) Liquid crystal elastomer actuators: Synthesis, alignment, and applications. J Polym Sci, Part B: Polym Phys 55: 395–411.
    [91] Zhang Y, Gao H, Wang H, et al. (2018) Radiopaque highly stiff and tough shape memory hydrogel microcoils for permanent embolization of arteries. Adv Funct Mater 28: 1705962. doi: 10.1002/adfm.201705962
    [92] Hager MD, Bode S, Weber C, et al. (2015) Shape memory polymers: Past, present and future developments. Prog Polym Sci 49: 3–33.
    [93] Kratz K, Voigt U, Lendlein A (2012) Temperature-memory effect of copolyesterurethanes and their application potential in minimally invasive medical technologies. Adv Funct Mater 22: 3057–3065. doi: 10.1002/adfm.201200211
    [94] Serrano MC, Ameer GA (2012) Recent insights into the biomedical applications of shape-memory polymers. Macromol Biosci 12: 1156–1171. doi: 10.1002/mabi.201200097
    [95] Small W, Singhal P, Wilson TS, et al. (2010) Biomedical applications of thermally activated shape memory polymers. J Mater Chem 20: 3356–3366. doi: 10.1039/b923717h
    [96] Lendlein A, Langer R (2002) Biodegradable, elastic shape-memory polymers for potential biomedical applications. Science 296: 1673–1676. doi: 10.1126/science.1066102
    [97] Wischke C, Neffe AT, Steuer S, et al. (2009) Evaluation of a degradable shape-memory polymer network as matrix for controlled drug release. J Controlled Release 138: 243–250. doi: 10.1016/j.jconrel.2009.05.027
    [98] Balk M, Behl M, Wischke C, et al. (2016) Recent advances in degradable lactide-based shape-memory polymers. Adv Drug Delivery Rev 107: 136–152. doi: 10.1016/j.addr.2016.05.012
    [99] Yu K, Ritchie A, Mao Y, et al. (2015) Controlled sequential shape changing components by 3D printing of shape memory polymer multimaterials. Procedia Iutam 12: 193–203. doi: 10.1016/j.piutam.2014.12.021
    [100] Hardy JG, Palma M, Wind SJ, et al. (2016) Responsive biomaterials: Advances in materials based on shape-memory polymers. Adv Mater 28: 5717–5724. doi: 10.1002/adma.201505417
    [101] Chan BQY, Low ZWK, Heng SJW, et al. (2016) Recent advances in shape memory soft materials for biomedical applications. ACS Appl Mater Interfaces 8: 10070–10087. doi: 10.1021/acsami.6b01295
    [102] Mazza E, Ehret AE (2015) Mechanical biocompatibility of highly deformable biomedical materials. J Mech Behav Biomed Mater 48: 100–124. doi: 10.1016/j.jmbbm.2015.03.023
    [103] Niinomi M, Nakai M, Hieda J (2012) Development of new metallic alloys for biomedical applications. Acta Biomater 8: 3888–3903. doi: 10.1016/j.actbio.2012.06.037
    [104] Niinomi M (2010) Tend and present state of titanium alloys with body centered structure for biomedical applications. Bull Iron Steel Inst Jpn 15: 661–670.
    [105] Tane M, Akita S, Nakano T, et al. (2008) Peculiar elastic behavior of Ti-Nb-Ta-Zr single crystals. Acta Mater 56: 2856–2863. doi: 10.1016/j.actamat.2008.02.017
    [106] Sadrnezhaad SK, Hosseini SA (2009) Fabrication of porous NiTi-shape memory alloy objects by partially hydrided titanium powder for biomedical applications. Mater Des 30: 4483–4487. doi: 10.1016/j.matdes.2009.05.034
    [107] Xiong J, Li Y, Wang X, et al. (2008) Titanium-nickel shape memory alloy foams for bone tissue engineering. J Mech Behav Biomed Mater 1: 269–273. doi: 10.1016/j.jmbbm.2007.09.003
    [108] Oh IH, Nomura N, Hanada S (2002) Microstructures and mechanical properties of porous titanium compacts prepared by powder sintering. Mater Trans 43: 443–446. doi: 10.2320/matertrans.43.443
    [109] Wang M, Jiang M, Liao G, et al. (2012) Martensitic transformation involved mechanical behaviors and wide hysteresis of NiTiNb shape memory alloys. Prog Nat Sci Mater Int 22: 130–138. doi: 10.1016/j.pnsc.2012.03.010
    [110] Chen J, Wang G, Sun W (2005) Investigation on the fracture behavior of shape memory alloy NiTi. Metall Mater Trans A 36: 941–955. doi: 10.1007/s11661-005-0288-8
    [111] Kim HY, Hashimoto S, Kim JI, et al. (2004) Mechanical properties and shape memory behavior of Ti-Nb alloys. Mater Trans 45: 2443–2448. doi: 10.2320/matertrans.45.2443
    [112] Miyazaki S, Kim H, Hosoda H (2006) Development and characterization of Ni-free Ti-base shape memory and superelastic alloys. Mater Sci Eng A 438: 18–24.
    [113] Niinomi M (2003) Recent research and development in titanium alloys for biomedical applications and healthcare goods. Sci Technol Adv Mater 4: 445–454. doi: 10.1016/j.stam.2003.09.002
    [114] Mckelvey A, Ritchie R (2001) Fatigue-crack growth behavior in the superelastic and shape-memory alloy nitinol. Metall Mater Trans A 32: 731–743. doi: 10.1007/s11661-001-1008-7
    [115] Robertson S, Mehta A, Pelton A, et al. (2007) Evolution of crack-tip transformation zones in superelastic nitinol subjected to in situ fatigue: A fracture mechanics and synchrotron X-ray microdiffraction analysis. Acta Mater 55: 6198–6207. doi: 10.1016/j.actamat.2007.07.028
    [116] Figueiredo AM, Modenesi P, Buono V (2009) Low-cycle fatigue life of superelastic NiTi wires. Int J Fatigue 31: 751–758. doi: 10.1016/j.ijfatigue.2008.03.014
    [117] Yu XJ, Kumar KS (2012) Uniaxial, load-controlled cyclic deformation of recrystallized molybdenum sheet. Mater Sci Eng A 540: 187–197. doi: 10.1016/j.msea.2012.01.124
    [118] Yu XJ, Kumar KS (2016) Cyclic tensile response of Mo-27 at% Re and Mo-0.3 at% Si solid solution alloys. Mater Sci Eng A 676: 312–323.
    [119] Kim Y (2002) Fatigue properties of the Ti-Ni base shape memory alloy wire. Mater Trans 43: 1703–1706. doi: 10.2320/matertrans.43.1703
    [120] Pappas P, Bollas D, Parthenios J, et al. (2007) Transformation fatigue and stress relaxation of shape memory alloy wires. Smart Mater Struct 16: 2560. doi: 10.1088/0964-1726/16/6/060
    [121] Barrabés M, Sevilla P, Planell JA, et al. (2008) Mechanical properties of nickel-titanium foams for reconstructive orthopaedics. Mater Sci Eng C 28: 23–27. doi: 10.1016/j.msec.2007.02.001
    [122] Nayan N, Roy D, Buravalla V, et al. (2008) Unnotched fatigue behavior of an austenitic Ni-Ti shape memory alloy. Mater Sci Eng A 497: 333–340. doi: 10.1016/j.msea.2008.07.025
    [123] Kang G, Song D (2015) Review on structural fatigue of NiTi shape memory alloys: Pure mechanical and thermo-mechanical ones. Theor Appl Mech Lett 5: 245–254. doi: 10.1016/j.taml.2015.11.004
    [124] Zhang X, Liu H, Yuan B, et al. (2008) Superelasticity decay of porous NiTi shape memory alloys under cyclic strain-controlled fatigue conditions. Mater Sci Eng A 481: 170–173.
    [125] Fulcher J, Lu Y, Tandon G, et al. (2010) Thermomechanical characterization of shape memory polymers using high temperature nanoindentation. Polym Test 29: 544–552. doi: 10.1016/j.polymertesting.2010.02.001
    [126] Schmidt C, Sarwaruddin Chowdhury AM, Neuking K, et al. (2011) Thermo-mechanical behaviour of shape memory polymers, e.g., Tecoflex® by 1WE method: SEM and IR analysis. J Polym Res 18: 1807–1812.
    [127] Di Prima M, Gall K, Mcdowell D, et al. (2010) Cyclic compression behavior of epoxy shape memory polymer foam. Mech Mater 42: 405–416. doi: 10.1016/j.mechmat.2010.01.004
    [128] Ahmad M, Xu B, Purnawali H, et al. (2012) High performance shape memory polyurethane synthesized with high molecular weight polyol as the soft segment. Appl Sci 2: 535. doi: 10.3390/app2020535
    [129] Kang SM, Lee SJ, Kim BK (2012) Shape memory polyurethane foams. eXPRESS Polym Lett 6: 63–69. doi: 10.3144/expresspolymlett.2012.7
    [130] Zhang H, Wang H, Zhong W, et al. (2009) A novel type of shape memory polymer blend and the shape memory mechanism. Polymer 50: 1596–1601. doi: 10.1016/j.polymer.2009.01.011
    [131] Guo J, Wang Z, Tong L, et al. (2015) Shape memory and thermo-mechanical properties of shape memory polymer/carbon fiber composites. Composites Part A 76: 162–171. doi: 10.1016/j.compositesa.2015.05.026
    [132] Ni QQ, Zhang CS, Fu Y, et al. (2007) Shape memory effect and mechanical properties of carbon nanotube/shape memory polymer nanocomposites. Compos Struct 81: 176–184. doi: 10.1016/j.compstruct.2006.08.017
    [133] Mohr R, Kratz K, Weigel T, et al. (2006) Initiation of shape-memory effect by inductive heating of magnetic nanoparticles in thermoplastic polymers. Proc Natl Acad Sci U S A 103: 3540–3545. doi: 10.1073/pnas.0600079103
    [134] Xu B, Fu YQ, Ahmad M, et al. (2010) Thermo-mechanical properties of polystyrene-based shape memory nanocomposites. J Mater Chem 20: 3442–3448. doi: 10.1039/b923238a
    [135] Zheng X, Zhou S, Li X, et al. (2006) Shape memory properties of poly(d,l-lactide)/hydroxyapatite composites. Biomaterials 27: 4288–4295. doi: 10.1016/j.biomaterials.2006.03.043
    [136] Wei H, Zhang F, Zhang D, et al. (2015) Shape-memory behaviors of electrospun chitosan/poly(ethylene oxide) composite nanofibrous membranes. J Appl Polym Sci 132: n/a.
    [137] Cisse C, Zaki W, Zineb TB (2016) A review of modeling techniques for advanced effects in shape memory alloy behavior. Smart Mater Struct 25: 103001. doi: 10.1088/0964-1726/25/10/103001
    [138] Zhang L, Du H, Liu L, et al. (2014) Analysis and design of smart mandrels using shape memory polymers. Composites Part B 59: 230–237. doi: 10.1016/j.compositesb.2013.10.085
    [139] Mirzaeifar R, DesRoches R, Yavari A (2011) Analysis of the rate-dependent coupled thermo-mechanical response of shape memory alloy bars and wires in tension. Continuum Mech Thermodyn 23: 363–385. doi: 10.1007/s00161-011-0187-8
    [140] Uehara T, Asai C, Ohno N (2009) Molecular dynamics simulation of shape memory behaviour using a multi-grain model. Modell Simul Mater Sci Eng 17: 035011. doi: 10.1088/0965-0393/17/3/035011
    [141] Pun GP, Mishin Y (2010) Molecular dynamics simulation of the martensitic phase transformation in NiAl alloys. J Phys Condens Matter 22: 395403. doi: 10.1088/0953-8984/22/39/395403
    [142] Zhong Y, Zhu T (2014) Phase-field modeling of martensitic microstructure in NiTi shape memory alloys. Acta Mater 75: 337–347. doi: 10.1016/j.actamat.2014.04.013
    [143] Nguyen TD (2013) Modeling shape-memory behavior of polymers. Polym Rev 53: 130–152. doi: 10.1080/15583724.2012.751922
    [144] Leclercq S, Lexcellent C (1996) A general macroscopic description of the thermomechanical behavior of shape memory alloys. J Mech Phys Solids 44: 953–980. doi: 10.1016/0022-5096(96)00013-0
    [145] Falk F (1980) Model free energy, mechanics, and thermodynamics of shape memory alloys. Acta Metall 28: 1773–1780. doi: 10.1016/0001-6160(80)90030-9
    [146] Paiva A, Savi MA (2006) An overview of constitutive models for shape memory alloys. Math Probl Eng 2006: 39–62.
    [147] Tanaka K, Nagaki S (1982) A thermomechanical description of materials with internal variables in the process of phase transitions. Ing Arch 51: 287–299. doi: 10.1007/BF00536655
    [148] Liang C, Rogers CA (1990) One-dimensional thermomechanical constitutive relations for shape memory materials. J Intell Mater Syst Struct 1: 207–234. doi: 10.1177/1045389X9000100205
    [149] Brinson LC (1993) One-dimensional constitutive behavior of shape memory alloys: Thermomechanical derivation with non-constant material functions and redefined martensite internal variable. J Intell Mater Syst Struct 4: 229–242. doi: 10.1177/1045389X9300400213
    [150] Panico M, Brinson L (2007) A three-dimensional phenomenological model for martensite reorientation in shape memory alloys. J Mech Phys Solids 55: 2491–2511. doi: 10.1016/j.jmps.2007.03.010
    [151] Bouvet C, Calloch S, Taillard K, et al. (2004) Experimental determination of initial surface of phase transformation of SMA. J Phys IV Fr 115: 29–36. doi: 10.1051/jp4:2004115004
    [152] Arghavani J, Auricchio F, Naghdabadi R, et al. (2010) A 3-D phenomenological constitutive model for shape memory alloys under multiaxial loadings. Int J Plast 26: 976–991. doi: 10.1016/j.ijplas.2009.12.003
    [153] Moumni Z, Zaki W, Maitournam H (2009) Cyclic behavior and energy approach to the fatigue of shape memory alloys. J Mech Mater Struct 4: 395–411. doi: 10.2140/jomms.2009.4.395
    [154] Zhang Q, Yang QS (2012) Recent advance on constitutive models of thermal-sensitive shape memory polymers. J Appl Polym Sci 123: 1502–1508. doi: 10.1002/app.34307
    [155] Srivastava V, Chester SA, Anand L (2010) Thermally actuated shape-memory polymers: Experiments, theory, and numerical simulations. J Mech Phys Solids 58: 1100–1124. doi: 10.1016/j.jmps.2010.04.004
    [156] Liu Y, Gall K, Dunn ML, et al. (2006) Thermomechanics of shape memory polymers: Uniaxial experiments and constitutive modeling. Int J Plast 22: 279–313. doi: 10.1016/j.ijplas.2005.03.004
    [157] Diani J, Liu Y, Gall K (2006) Finite strain 3D thermoviscoelastic constitutive model for shape memory polymers. Polym Eng Sci 46: 486–492. doi: 10.1002/pen.20497
    [158] Li G, Xu W (2011) Thermomechanical behavior of thermoset shape memory polymer programmed by cold-compression: Testing and constitutive modeling. J Mech Phys Solids 59: 1231–1250. doi: 10.1016/j.jmps.2011.03.001
    [159] Baghani M, Naghdabadi R, Arghavani J, et al. (2012) A thermodynamically-consistent 3D constitutive model for shape memory polymers. Int J Plast 35: 13–30. doi: 10.1016/j.ijplas.2012.01.007
    [160] Wever D, Veldhuizen A, Sanders M, et al. (1997) Cytotoxic, allergic and genotoxic activity of a nickel-titanium alloy. Biomaterials 18: 1115–1120. doi: 10.1016/S0142-9612(97)00041-0
    [161] Shayan M, Chun Y (2015) An overview of thin film nitinol endovascular devices. Acta Biomater 21: 20–34. doi: 10.1016/j.actbio.2015.03.025
    [162] Cui ZD, Man HC, Yang XJ (2005) The corrosion and nickel release behavior of laser surface-melted NiTi shape memory alloy in Hanks' solution. Surf Coat Technol 192: 347–353. doi: 10.1016/j.surfcoat.2004.06.033
    [163] Cheng Y, Cai W, Li H, et al. (2004) Surface characteristics and corrosion resistance properties of TiNi shape memory alloy coated with Ta. Surf Coat Technol 186: 346–352. doi: 10.1016/j.surfcoat.2004.01.012
    [164] Firstov G, Vitchev R, Kumar H, et al. (2002) Surface oxidation of NiTi shape memory alloy. Biomaterials 23: 4863–4871. doi: 10.1016/S0142-9612(02)00244-2
    [165] Poon R, Yeung K, Liu X, et al. (2005) Carbon plasma immersion ion implantation of nickel-titanium shape memory alloys. Biomaterials 26: 2265–2272. doi: 10.1016/j.biomaterials.2004.07.056
    [166] Chen M, Yang X, Liu Y, et al. (2003) Study on the formation of an apatite layer on NiTi shape memory alloy using a chemical treatment method. Surf Coat Technol 173: 229–234. doi: 10.1016/S0257-8972(03)00733-3
    [167] Chu C, Hu T, Wu S, et al. (2007) Surface structure and properties of biomedical NiTi shape memory alloy after Fenton's oxidation. Acta Biomater 3: 795–806. doi: 10.1016/j.actbio.2007.03.002
    [168] Hu T, Wen C, Sun G, et al. (2010) Wear resistance of NiTi alloy after surface mechanical attrition treatment. Surf Coat Technol 205: 506–510. doi: 10.1016/j.surfcoat.2010.07.023
    [169] Walker J, Andani MT, Haberland C, et al. (2014) Additive manufacturing of Nitinol shape memory alloys to overcome challenges in conventional Nitinol fabrication. Proceedings of the ASME 2014 IMECE, V02AT02A037.
    [170] Ge Q, Sakhaei AH, Lee H, et al. (2016) Multimaterial 4D printing with tailorable shape memory polymers. Sci Rep 6: 31110. doi: 10.1038/srep31110
    [171] Hu N, Burgueño R (2015) Buckling-induced smart applications: Recent advances and trends. Smart Mater Struct 24.
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