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Optical Properties of Lanthanides in Condensed Phase, Theory and Applications

  • Received: 03 March 2015 Accepted: 22 March 2015 Published: 01 April 2015
  • The basic theories of electronic levels and transition probabilities of lanthanides are summarized. Their interpretation allows practical preparation of new materials having application in lighting, solar energy utilization, optoelectronics, biological sensors, active waveguides and highly sensitive bioassays for in vitro detection in medical applications. The ways by which the weak fluorescence arising from electronic transition within the four f-configurations can be intensified will be discussed. This includes the intermixing of the four f-states with ligands of the host matrix, excitation to higher d-electronic states. Additional intensification of luminescence by plasmonic interaction with gold, silver and copper nanoparticles will be discussed. A short history of the time development of the research and the names of the scientists who made the major contribution of our understanding of lanthanides spectroscopy are presented.

    Citation: Reisfeld Renata. Optical Properties of Lanthanides in Condensed Phase, Theory and Applications[J]. AIMS Materials Science, 2015, 2(2): 37-60. doi: 10.3934/matersci.2015.2.37

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  • The basic theories of electronic levels and transition probabilities of lanthanides are summarized. Their interpretation allows practical preparation of new materials having application in lighting, solar energy utilization, optoelectronics, biological sensors, active waveguides and highly sensitive bioassays for in vitro detection in medical applications. The ways by which the weak fluorescence arising from electronic transition within the four f-configurations can be intensified will be discussed. This includes the intermixing of the four f-states with ligands of the host matrix, excitation to higher d-electronic states. Additional intensification of luminescence by plasmonic interaction with gold, silver and copper nanoparticles will be discussed. A short history of the time development of the research and the names of the scientists who made the major contribution of our understanding of lanthanides spectroscopy are presented.


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    [1] Jorgensen CK (1971) Modern aspects of ligand field theory.North-Holland Pub. Co 538.
    [2] Reisfeld R, Jorgensen CK (1977) Lasers and Excited States of Lanthanidess.Springer-Verlag, Berlin Heidelberg, New-York .
    [3] Condon EU, Shortley GH (1963) The theory of atomic spectra, University Press Cambridge.See also Slater, J. C., (1929) Phys Rev 34: 1293-1322.
    [4] Racah G (1949) Theory of complex spectra.Phys Rev 76: 1352.
    [5] Bünzli JC, Chauvin AS (2014) Lanthanides in Solar Energy Conversion. Handbook on the Physics and Chemistry of Lanthanidess.Elsevier B.V., Amsterdam, chapter 261, 44: 169-281.
    [6] Jorgensen CK, Reisfeld R (1982) Chemistry and spectroscopy of lanthanidess.Topics in Current Chemistry 100: 126-166.
    [7] Reisfeld R, Jorgensen CK (1987) Chapter 58 Excited state phenomena in vitreous materials.Handbook on the Physics and Chemistry of Lanthanidess 9: 1-90.
    [8] Lehn JM (1987) Supramolecular chemistry scope and perspectivesmolecules supermolecules molecular devices.Nobel lecture .
    [9] Reisfeld R, Jorgensen CK (1992) Optical properties of colorants or luminescent species in sol-gel glasses.Struct Bond 77: 207-256.
    [10] Reisfeld R, Saraidarov T, Panzer G, et al. (2011) New Optical Material Europium EDTA complex in polyvinyl pyrrolidone films with fluorescence enhanced by silver plasmons.Opt Mater 34: 351-355.
    [11] Levchenko V, Grouchko M, Magdassi S, et al. (2011) Enhancement of luminescence of Rhodamine B by gold nanoparticles in thin films on glass for active optical materials applications.Opt Mater 34: 360-365.
    [12] Reisfeld R, Grinberg M, Levchenko V, et al. (2014) Sol-gel glasses with Enhanced Luminescence of Laser Dye Rhodamine B due to Plasmonic Coupling by Copper Nanoparticles.Opt Mater 36: 1611-1615.
    [13] Gaft M, Reisfeld R, Panczer G (2004) Luminescence Spectroscopy of Minerals and Materials.Springer Verlag, New-York .
    [14] Gan F (1992) Optical and Spectroscopic Properties of Glass.Springer Verlag, New York .
    [15] Reisfeld R (1975) Radiative and nonradiative transition of lanthanidess in glasses, Structure and Bonding 22: 123-175; Reisfeld, R. (1976) Excited states and energy transfer from donor cations to lanthanidess in the condensed phase.Struct Bond 30: 65-97.
    [16] Reisfeld R (1980) Multiphonon relaxation in glasses, Internat. School of Atomic and Molecular Spectroscopy.In: DiBartolo B., Goldberg V., NATO Advanced Study Institute on Radiationless Processes, Erice, Italy, 1979. Radiationless Processes, Plenum 489-498.
    [17] Binnemans K (2009) Lanthanide-Based Luminescent Hybrid Materials.Chem Rev 109: 4283-4374.
    [18] Judd BR (1962) Optical absorptionintensities of lanthanides ions.Phys Rev 127: 504.
    [19] Ofelt GS (1962) Intensities of crystal spectra of lanthanides ions.J Chem Phys 3: 37-511.
    [20] Wybourne BG (1965) Spectra of Lanthanidess Salts, 11 Spectroscopic Properties of Lanthanidess.In: Interscience Publishers, New York, London, Sydney 210-219.
    [21] Dieke GH (1968) Spectra and Energy Levels of Lanthanidess Ions in Crystals.In: Crosswhite, H. M., Crosswhite, H., Interscience Publishers, New York, London, Sydney, Toronto .
    [22] Görller-Walrand C, Binnermans K (1998) Spectral Intensities of f-f Transitions.Handbook on Physics and Chemistry of Lanthanidess Elsevier Science B. V. 25: 101-261.
    [23] Jorgensen CK, Judd BR (1964) Hypersensitive pseudoquadrupole transition in lanthanides.Mol Phys 8: 281-290.
    [24] Reisfeld R (2004) Lanthanides Ions: Their Spectroscopy of Cryptates and Related Complexes in Glasses.In: Schonherr, T. Struct Bond 106: 209-235.
    [25] Luminescence and energy transfer (1980) Struct Bond.42.
    [26] Reisfeld R (1976) Excited states and energy transfer from donor cations to lanthanidess in the condensed phase.Struct Bond 30: 65-97.
    [27] Longo R, Goncalves FR, Silva E, et al. (2000) Europium bipyridil cryptates.Chem Phys Lett 328: 67-74.
    [28] De Sa GF, Malta OL, de Donega CM, et al. (2000) Spectroscopic properties and design of highly luminescent lanthanide coordination complexes.Coordin Chem Rev 196: 165-195.
    [29] Demendoza J, Mesa E, Rodriguezubis JC, et al. (1991) A new macrobicyclic tris-bipyridine ligand and its CU-2(I) and AG-3(I) complexes.Angewandte Chemie-International (English edition) 30: 13331-13333.
    [30] Sabbatini N, Guardigli M, Manet I, et al. (1995) Lanthanide complexes of encapsulating ligands: Luminescent devices at the molecular level.Pure App Chem 67: 135-140.
    [31] Borzechowska M, Trush V, Turowska-Tyrk I, et al. (2002) Spectroscopic and magnetic studies of mixed lanthanide complexes: LnL3 α,α'Dipy in solution and in solid.J Alloys Compd 341: 98-106.
    [32] Reisfeld R (2004) Sol gel processed lasers.In: Sakka, S., Sol-Gel Technology Handbook 3, NATO Science Series, Springer, Netherlands 239-261.
    [33] Bünzli JCG (1989) Chemical and Earth Sciences, Theory and Practice.In: Bünzli, J. C., Chopin, G. R., Elsevier Amsterdam 219-293.
    [34] Comby S, Gummy F, Bunzli JC, et al. (2006) Luminescence Properties of an Yb podate in Sol-Gel Silica Films Solution, and Solid State.Chem Phys Lett 432: 128-132.
    [35] Reisfeld R (1996) Lasers based in sol-gel technology, Optical and Modern Application.In: Reisfeld, R., Jorgensen, C. K. Struct Bond 85: 215-217.
    [36] Balzani V, Lehn JM, Vandeloosdrect J, et al. (1991) Luminescence properties of Eu 3+ and Tb 3+ complexes of branched macrocyclic ligands containing 4 2,2'-bipyridine units.Angewandte Chemie-International (English edition) 30: 190-191.
    [37] Reisfeld R (2015) Luminescent solar concentrators and the ways to increase their efficiencies.Handbook Sol-Gel Vol. 3 to be published by Wiley-VCH .
    [38] Reisfeld R (2010) Invited paper, New Developments in Luminescence for Solar Energy Utilization.Opt Mater 32: 850-856.
    [39] Bunzli JC, Piguet C (2005) Taking advantage of luminescent lanthanide ions.Chem Soc Rev 34: 1048-1077.
    [40] Reisfeld R, Gaft M, Saraidarov T, et al. (2000) Nanoparticles of cadmium sulfide with europium and terbium in zirconia films having intersified luminescence.Materials Letters 45: 154-156.
    [41] Zhang J, Fu Y, Ray K, et al. (2013) Luminescent Properties of Eu(III) Chelates on Metal Nanorods.J Phys Chem C 117: 9372-9380.
    [42] Zhou S, Zheng W, Chen Z, et al. (2014) Dissolution-Enhanced Luminescent Bioassay Based on Inorganic Lanthanide Nanoparticles.Angew Chem Int Ed 53: 12498-12502.
    [43] Reisfeld R (2014) Fluorescence-active Waveguides by the Sol-Gel Method.Theory and Application, Zeitschrift fur Naturforsch B, Band 69, Heft 2: 131-140.
    [44] Auzel F (2004) Upconversion and Anti-Stokes Processes with f and d Ions in Solids.Chem Rev 104: 139-173.
    [45] Kenyon AJ (2002) Review Recent developments in rare-earthdoped materials for optoelectronics.Prog Quant Electron 26: 225-284.
    [46] Bünzli J-CG, Chauvin A-S (2014) Lanthanides in Solar Energy Conversion. Handbook on the Physics and Chemistry of Lanthanidess Elsevier B.V.North-Holland .
    [47] Leif RC, Vallarino LM, Becker MC, et al. (2006) Increasing the luminescence of lanthanide complexes.Cytometry Part A 69A: 767-778.
    [48] Armelao L, Quici S, Barigelletti F, et al. (2010) Design of luminescent lanthanide complexe: From molecules to highly efficient photo-emitting materials.Coordin Chem Rev 254: 487-505.
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